DE2162951C2 - Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische Trennverfahren - Google Patents
Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische TrennverfahrenInfo
- Publication number
- DE2162951C2 DE2162951C2 DE2162951A DE2162951A DE2162951C2 DE 2162951 C2 DE2162951 C2 DE 2162951C2 DE 2162951 A DE2162951 A DE 2162951A DE 2162951 A DE2162951 A DE 2162951A DE 2162951 C2 DE2162951 C2 DE 2162951C2
- Authority
- DE
- Germany
- Prior art keywords
- parts
- adsorbents
- extraction
- crosslinked copolymers
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003463 adsorbent Substances 0.000 title claims description 21
- 238000000605 extraction Methods 0.000 title claims description 17
- 239000003795 chemical substances by application Substances 0.000 title claims description 11
- 229920001577 copolymer Polymers 0.000 title claims description 7
- 238000000034 method Methods 0.000 title description 15
- 238000013375 chromatographic separation Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 238000004587 chromatography analysis Methods 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 4
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 4
- XLHBQRJOHIHZGQ-UHFFFAOYSA-N heptadecan-9-amine Chemical compound CCCCCCCCC(N)CCCCCCCC XLHBQRJOHIHZGQ-UHFFFAOYSA-N 0.000 claims description 4
- SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 2
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 34
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 16
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 12
- -1 polyethylene Polymers 0.000 description 11
- 239000012876 carrier material Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004342 Benzoyl peroxide Substances 0.000 description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 description 8
- 238000010828 elution Methods 0.000 description 5
- 229920000609 methyl cellulose Polymers 0.000 description 5
- 239000001923 methylcellulose Substances 0.000 description 5
- 235000010981 methylcellulose Nutrition 0.000 description 5
- YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical compound CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 230000005526 G1 to G0 transition Effects 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
- ZJQIXGGEADDPQB-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-dimethylbenzene Chemical group CC1=CC=C(C=C)C(C=C)=C1C ZJQIXGGEADDPQB-UHFFFAOYSA-N 0.000 description 1
- YKKDJUGGSDWUKX-UHFFFAOYSA-N 1,2-bis(ethenyl)-3-ethylbenzene Chemical compound CCC1=CC=CC(C=C)=C1C=C YKKDJUGGSDWUKX-UHFFFAOYSA-N 0.000 description 1
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229910002007 uranyl nitrate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/016—Modification or after-treatment of ion-exchangers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2357/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (23)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE792928D BE792928A (fr) | 1971-12-18 | Procede de preparation de sorbants | |
| DE2162951A DE2162951C2 (de) | 1971-12-18 | 1971-12-18 | Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische Trennverfahren |
| IT54703/72A IT974064B (it) | 1971-12-18 | 1972-12-14 | Procedimento per produrre adsorben ti a base di resine sintetiche e prodotti cosi ottenuti |
| CS8602A CS171740B2 (OSRAM) | 1971-12-18 | 1972-12-14 | |
| RO7200073165A RO63158A (fr) | 1971-12-18 | 1972-12-15 | Procede pour la preparation des substances adsorbantes |
| ZA728893A ZA728893B (en) | 1971-12-18 | 1972-12-15 | A process for the production of absorbents |
| AT1070672A AT334868B (de) | 1971-12-18 | 1972-12-15 | Adsorbentien, insbesondere fur die auftrennung von ionen und molekulen, und verfahren zur herstellung dieser adsorbentien |
| NL7217118.A NL156710B (nl) | 1971-12-18 | 1972-12-15 | Werkwijze ter bereiding van sorptiemiddelen, alsmede gevormde sorptiemiddelen bereid volgens deze werkwijze. |
| SU1862289A SU520052A3 (ru) | 1971-12-18 | 1972-12-15 | Способ получени сорбентов |
| IL41094A IL41094A (en) | 1971-12-18 | 1972-12-15 | A process for the production of absorbents for use in extraction chromatography |
| SE7216473A SE396016B (sv) | 1971-12-18 | 1972-12-15 | Sett att framstella ett polymerbaserat sorberingsmedel |
| DD167581A DD102391A5 (OSRAM) | 1971-12-18 | 1972-12-15 | |
| CA158,931A CA1014689A (en) | 1971-12-18 | 1972-12-15 | Production of polymeric absorbents |
| BR8859/72A BR7208859D0 (pt) | 1971-12-18 | 1972-12-15 | Processo para a preparacao de solventes |
| ES409725A ES409725A1 (es) | 1971-12-18 | 1972-12-16 | Procedimiento para la produccion de agentes absorbentes a base de resinas sinteticas. |
| PL1972159572A PL79180B1 (OSRAM) | 1971-12-18 | 1972-12-16 | |
| JP12583472A JPS5648828B2 (OSRAM) | 1971-12-18 | 1972-12-16 | |
| OA54785A OA04296A (fr) | 1971-12-18 | 1972-12-18 | Procédé de préparation de sorbants. |
| AR245705A AR193157A1 (es) | 1971-12-18 | 1972-12-18 | Agentes sorbentes a bases de resinas sinteticas y procedimiento para su produccion |
| FR7245101A FR2163763B1 (OSRAM) | 1971-12-18 | 1972-12-18 | |
| CH1839072A CH597307A5 (OSRAM) | 1971-12-18 | 1972-12-18 | |
| GB5827772A GB1407257A (en) | 1971-12-18 | 1972-12-18 | Process for the production of absorbents |
| US05/496,107 US3960762A (en) | 1971-12-18 | 1974-08-09 | Production of absorbents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2162951A DE2162951C2 (de) | 1971-12-18 | 1971-12-18 | Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische Trennverfahren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2162951A1 DE2162951A1 (de) | 1973-06-20 |
| DE2162951C2 true DE2162951C2 (de) | 1982-07-01 |
Family
ID=5828438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2162951A Expired DE2162951C2 (de) | 1971-12-18 | 1971-12-18 | Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische Trennverfahren |
Country Status (22)
| Country | Link |
|---|---|
| JP (1) | JPS5648828B2 (OSRAM) |
| AR (1) | AR193157A1 (OSRAM) |
| AT (1) | AT334868B (OSRAM) |
| BE (1) | BE792928A (OSRAM) |
| BR (1) | BR7208859D0 (OSRAM) |
| CA (1) | CA1014689A (OSRAM) |
| CH (1) | CH597307A5 (OSRAM) |
| CS (1) | CS171740B2 (OSRAM) |
| DD (1) | DD102391A5 (OSRAM) |
| DE (1) | DE2162951C2 (OSRAM) |
| ES (1) | ES409725A1 (OSRAM) |
| FR (1) | FR2163763B1 (OSRAM) |
| GB (1) | GB1407257A (OSRAM) |
| IL (1) | IL41094A (OSRAM) |
| IT (1) | IT974064B (OSRAM) |
| NL (1) | NL156710B (OSRAM) |
| OA (1) | OA04296A (OSRAM) |
| PL (1) | PL79180B1 (OSRAM) |
| RO (1) | RO63158A (OSRAM) |
| SE (1) | SE396016B (OSRAM) |
| SU (1) | SU520052A3 (OSRAM) |
| ZA (1) | ZA728893B (OSRAM) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2061293B (en) * | 1979-06-08 | 1983-08-24 | Commw Scient Ind Res Org | Process for composite polymer beads |
| US4447475A (en) * | 1980-12-03 | 1984-05-08 | Ici Australia Limited | Process for composite polymer beads |
| EP0073750B1 (en) * | 1981-02-27 | 1989-07-05 | Monocure Pty. Limited | Aqueous polymerizable compositions |
| HU203252B (en) * | 1986-01-16 | 1991-06-28 | Nitrokemia Ipartelepek | Process for producing ion-exchange resins with grain size mainly less than ten microns for analytical and preparative purposes |
| JPH01142462A (ja) * | 1987-11-30 | 1989-06-05 | Japan Atom Energy Res Inst | 抽出クロマトグラフィ材の製造方法 |
| NL9400013A (nl) * | 1994-01-06 | 1995-08-01 | Akzo Nobel Nv | Materiaal voor het extraheren van metaalionen uit een waterige oplossing. |
| NL9400012A (nl) * | 1994-01-06 | 1995-08-01 | Akzo Nobel Nv | Materiaal voor het verwijderen van gasvormige verontreinigingen uit een gasmengsel. |
| US6355094B1 (en) | 1994-01-06 | 2002-03-12 | Akzo Nobel N.V. | Material for the removal of gaseous impurities from a gas mixture |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1483946A (fr) * | 1966-04-28 | 1967-06-09 | Dia Prosim | Procédé de préparation de résines macroporeuses, et applications de celles-ci à l'obtention d'échangeurs d'ions |
| US3547684A (en) * | 1968-08-08 | 1970-12-15 | Dow Chemical Co | Process for making organic polymer filled gas chromatographic columns |
-
0
- BE BE792928D patent/BE792928A/xx unknown
-
1971
- 1971-12-18 DE DE2162951A patent/DE2162951C2/de not_active Expired
-
1972
- 1972-12-14 CS CS8602A patent/CS171740B2/cs unknown
- 1972-12-14 IT IT54703/72A patent/IT974064B/it active
- 1972-12-15 BR BR8859/72A patent/BR7208859D0/pt unknown
- 1972-12-15 CA CA158,931A patent/CA1014689A/en not_active Expired
- 1972-12-15 ZA ZA728893A patent/ZA728893B/xx unknown
- 1972-12-15 IL IL41094A patent/IL41094A/en unknown
- 1972-12-15 RO RO7200073165A patent/RO63158A/ro unknown
- 1972-12-15 DD DD167581A patent/DD102391A5/xx unknown
- 1972-12-15 SE SE7216473A patent/SE396016B/xx unknown
- 1972-12-15 NL NL7217118.A patent/NL156710B/xx not_active IP Right Cessation
- 1972-12-15 AT AT1070672A patent/AT334868B/de not_active IP Right Cessation
- 1972-12-15 SU SU1862289A patent/SU520052A3/ru active
- 1972-12-16 ES ES409725A patent/ES409725A1/es not_active Expired
- 1972-12-16 PL PL1972159572A patent/PL79180B1/pl unknown
- 1972-12-16 JP JP12583472A patent/JPS5648828B2/ja not_active Expired
- 1972-12-18 FR FR7245101A patent/FR2163763B1/fr not_active Expired
- 1972-12-18 CH CH1839072A patent/CH597307A5/xx not_active IP Right Cessation
- 1972-12-18 OA OA54785A patent/OA04296A/xx unknown
- 1972-12-18 GB GB5827772A patent/GB1407257A/en not_active Expired
- 1972-12-18 AR AR245705A patent/AR193157A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| AR193157A1 (es) | 1973-03-30 |
| CS171740B2 (OSRAM) | 1976-10-29 |
| SU520052A3 (ru) | 1976-06-30 |
| IT974064B (it) | 1974-06-20 |
| OA04296A (fr) | 1979-12-31 |
| AT334868B (de) | 1977-02-10 |
| CH597307A5 (OSRAM) | 1978-03-31 |
| GB1407257A (en) | 1975-09-24 |
| BR7208859D0 (pt) | 1973-09-20 |
| SE396016B (sv) | 1977-09-05 |
| JPS5648828B2 (OSRAM) | 1981-11-18 |
| FR2163763A1 (OSRAM) | 1973-07-27 |
| CA1014689A (en) | 1977-07-26 |
| DD102391A5 (OSRAM) | 1973-12-12 |
| BE792928A (fr) | 1973-06-18 |
| ES409725A1 (es) | 1975-11-16 |
| RO63158A (fr) | 1978-06-15 |
| PL79180B1 (OSRAM) | 1975-06-30 |
| DE2162951A1 (de) | 1973-06-20 |
| IL41094A0 (en) | 1973-02-28 |
| JPS4870594A (OSRAM) | 1973-09-25 |
| ATA1070672A (de) | 1976-06-15 |
| IL41094A (en) | 1976-02-29 |
| NL7217118A (OSRAM) | 1973-06-20 |
| NL156710B (nl) | 1978-05-16 |
| FR2163763B1 (OSRAM) | 1978-03-10 |
| ZA728893B (en) | 1973-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1570757C3 (de) | Verfahren zur Herstellung von Dispersionen von vernetzbaren Additionspolymeren in Kohlenwasserstoffen | |
| DE69912050T2 (de) | Polymer Packungsmaterial für Flussigkeitschromatographie und seine Herstellungsverfahren | |
| DE2162951C2 (de) | Vernetzte Copolymerisate und Verwendung vernetzter, Extraktionmittel enthaltender Copolymerisate als Adsorbentien für extraktionschromatographische Trennverfahren | |
| DE2732800A1 (de) | Extraktionsmittel und verfahren zu ihrer herstellung | |
| DE2802642A1 (de) | Verfahren zur entfernung einer schwachen saeure aus einer waessrigen loesung | |
| DE2623891C3 (de) | Verwendung feinteiliger Anionenaustauscherharze zur Trennung von Uranisotopen | |
| DE2324154A1 (de) | Verfahren zur herstellung von gleichfoermigen teilchen aus polymerkuegelchen | |
| DE2349595A1 (de) | Verfahren zur trennung von uranisotopen | |
| DE1417765A1 (de) | Abtrennung einer starken mehrbasigen Saeure von ihren Salzen | |
| DE2623890C2 (de) | Verfahren zum Trennen von Uranisotopen durch Ionenaustauschchromatographie und Vorrichtung zur Durchführung des Verfahrens | |
| DE69216445T2 (de) | Oxidationsbeständige Kationenaustauscherharze | |
| DE2056076A1 (de) | Vinyl pyridin/Divinylbenzol Copoly mensat, Verfahren zu dessen Herstellung und Anwendung desselben | |
| DE2846187A1 (de) | Kunstharze auf basis vernetzter mischpolymerisate aus mono- und polyvinylverbindungen | |
| DE2162508A1 (de) | Verfahren zur Herstellung vernetzter poröser Mischpolymerisate | |
| DE3226523C2 (de) | Ionenaustauscher für die Ionenaustauschchromatographie und Verfahren zu seiner Herstellung | |
| DE2636072C2 (de) | Mehrstufenverfahren zur Trennung von Uranisotopen | |
| DE2723603A1 (de) | Verfahren zur kontinuierlichen trennung von uranisotopen | |
| EP2330137A1 (de) | Methylenaminoethylsulfonsäure-Chelatharze | |
| EP0032671B1 (de) | Anionenaustauscher, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE3108943A1 (de) | Polymeres ionenaustauschharz | |
| DE2225329C2 (de) | Verfahren zur Herstellung von mikroporösen ionenaustauschfähigen Formkörpern | |
| EP0870772A2 (de) | Verfahren zur Herstellung vernetzter kugelförmiger Polymerisate | |
| DE2040356B2 (de) | Verfahren zum Imprägnieren von Gegenständen aus Holz, Gips oder porösem Material mit polymerisierbarer Flüssigkeit unter nachfolgender Polymerisation durch Bestrahlung | |
| DE1417898A1 (de) | Verfahren und Extraktionsmasse zur Gewinnung von Schwermetallen aus waessrigen Loesungen derselben | |
| DE1227431B (de) | Kationenaustauscher |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8339 | Ceased/non-payment of the annual fee |