DE2032430B2 - Verfahren zur herstellung von polyaethern - Google Patents
Verfahren zur herstellung von polyaethernInfo
- Publication number
- DE2032430B2 DE2032430B2 DE19702032430 DE2032430A DE2032430B2 DE 2032430 B2 DE2032430 B2 DE 2032430B2 DE 19702032430 DE19702032430 DE 19702032430 DE 2032430 A DE2032430 A DE 2032430A DE 2032430 B2 DE2032430 B2 DE 2032430B2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- parts
- catalyst
- suspension
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 38
- 230000008569 process Effects 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000003054 catalyst Substances 0.000 claims description 60
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 34
- 239000000725 suspension Substances 0.000 claims description 34
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 25
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 21
- 239000000178 monomer Substances 0.000 claims description 20
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 229910052712 strontium Inorganic materials 0.000 claims description 7
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000003979 granulating agent Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- BQQUFAMSJAKLNB-UHFFFAOYSA-N dicyclopentadiene diepoxide Chemical compound C12C(C3OC33)CC3C2CC2C1O2 BQQUFAMSJAKLNB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 description 58
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 11
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- -1 alicyclic hydrocarbon radicals Chemical class 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 230000006911 nucleation Effects 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- HAPXCVYKFSWMNS-UHFFFAOYSA-N 2-methyl-3-(oxiran-2-yl)oxirane Chemical compound CC1OC1C1OC1 HAPXCVYKFSWMNS-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 241000158147 Sator Species 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- UJUQSXYCZKNGEY-UHFFFAOYSA-N 2-ethyl-3-(oxiran-2-yl)oxirane Chemical compound CCC1OC1C1OC1 UJUQSXYCZKNGEY-UHFFFAOYSA-N 0.000 description 1
- KOHBFAGTEWFCBI-UHFFFAOYSA-N 2-prop-1-enyloxirane Chemical compound CC=CC1CO1 KOHBFAGTEWFCBI-UHFFFAOYSA-N 0.000 description 1
- LIPRPMPWMFGAKB-UHFFFAOYSA-N 3,6-dioxatricyclo[3.1.0.02,4]hexane Chemical compound O1C2C1C1OC21 LIPRPMPWMFGAKB-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 241001072332 Monia Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- SIWFRAYSJGYECR-UHFFFAOYSA-N cyclopentadiene dioxide Chemical compound C1C2OC2C2OC12 SIWFRAYSJGYECR-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- VGGSQFUCUMXWEO-MICDWDOJSA-N deuterioethene Chemical compound [2H]C=C VGGSQFUCUMXWEO-MICDWDOJSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2651—Alkaline earth metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83788369A | 1969-06-30 | 1969-06-30 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2032430A1 DE2032430A1 (de) | 1971-01-14 |
| DE2032430B2 true DE2032430B2 (de) | 1973-02-15 |
| DE2032430C3 DE2032430C3 (enExample) | 1973-11-29 |
Family
ID=25275701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702032430 Granted DE2032430B2 (de) | 1969-06-30 | 1970-06-30 | Verfahren zur herstellung von polyaethern |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3624008A (enExample) |
| JP (1) | JPS5010558B1 (enExample) |
| BE (1) | BE752701A (enExample) |
| CA (1) | CA930895A (enExample) |
| DE (1) | DE2032430B2 (enExample) |
| FR (1) | FR2051460A5 (enExample) |
| GB (1) | GB1295106A (enExample) |
| NL (1) | NL142974B (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4619988A (en) * | 1985-06-26 | 1986-10-28 | Allied Corporation | High strength and high tensile modulus fibers or poly(ethylene oxide) |
| CN101392053B (zh) * | 2007-09-18 | 2011-04-06 | 上海化工研究院 | 一种环氧烷烃开环聚合催化剂的制备方法及应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3062755A (en) * | 1958-12-29 | 1962-11-06 | Union Carbide Corp | Polymerization of epoxides |
| US3037943A (en) * | 1958-12-29 | 1962-06-05 | Union Carbide Corp | Preparation of catalysts for the polymerization of epoxides |
| GB952898A (enExample) * | 1960-03-31 | |||
| FR79865E (enExample) * | 1960-05-18 | 1963-05-02 | ||
| US3214387A (en) * | 1960-06-10 | 1965-10-26 | Union Carbide Corp | Preparation of catalysts for the polymerization of epoxides |
| DE1520983B2 (de) * | 1961-03-14 | 1971-07-22 | Takeda Chemical Industries Ltd , Osaka (Japan) | Verfahren zur herstellung von alkylenoxydpolymeren |
-
1969
- 1969-06-30 US US837883A patent/US3624008A/en not_active Expired - Lifetime
-
1970
- 1970-06-24 CA CA086411A patent/CA930895A/en not_active Expired
- 1970-06-25 NL NL707009404A patent/NL142974B/xx unknown
- 1970-06-25 GB GB1295106D patent/GB1295106A/en not_active Expired
- 1970-06-30 DE DE19702032430 patent/DE2032430B2/de active Granted
- 1970-06-30 JP JP45056622A patent/JPS5010558B1/ja active Pending
- 1970-06-30 FR FR7024164A patent/FR2051460A5/fr not_active Expired
- 1970-06-30 BE BE752701D patent/BE752701A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1295106A (enExample) | 1972-11-01 |
| DE2032430A1 (de) | 1971-01-14 |
| FR2051460A5 (enExample) | 1971-04-02 |
| JPS5010558B1 (enExample) | 1975-04-22 |
| CA930895A (en) | 1973-07-24 |
| NL142974B (nl) | 1974-08-15 |
| DE2032430C3 (enExample) | 1973-11-29 |
| US3624008A (en) | 1971-11-30 |
| BE752701A (fr) | 1970-12-30 |
| NL7009404A (enExample) | 1971-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69122483T3 (de) | Verfahren zur Modifikation von Katalysatoren für Olefinpolymerisation | |
| DE1124245B (de) | Verfahren zur Entfernung von metallhaltigen Katalysatorrueckstaenden aus Kohlenwasserstoffpolymerisaten | |
| DE2153520A1 (de) | Verfahren zur selektiven Polymerisation von alpha-Olefinen | |
| DE2437629B2 (de) | Verfahren zur herstellung von unloeslichen in wasser nur wenig quellbaren polymerisaten von n-vinyllactamen | |
| DE2630585B2 (de) | Katalysatoren für die Polymerisation von a -Olefinen, mit 2 bis 6 Kohlenstoffatomen und deren Verwendung für die Polymerisation von a -Olefinen mit 2 bis 6 Kohlenstoffatomen | |
| DE3117588C2 (enExample) | ||
| DE2256780C2 (de) | Verfahren zur Herstellung von isotaktischem Polypropylen oder isotaktischen α-Olefincopolymeren mit wenigstens 50 Gewichtsprozent an Propyleneinheiten sowie feste titanhaltige Katalysatorkomponente zu dessen Durchführung | |
| DE1299868B (de) | Verfahren zur Polymerisation von Cyclopenten | |
| DE2656055A1 (de) | Verfahren zur polymerisation von alpha- olefinen mit mindestens 3 kohlenstoffatomen und der hierfuer verwendete katalysator | |
| EP0175335B1 (de) | Verfahren zur Herstellung von unlöslichen, nur wenig quellbaren pulverförmigen Polymeren | |
| DE4323192A1 (de) | Verfahren zur Herstellung von Homo- und Copolymerisaten von Alk-1-enen | |
| DE69009974T2 (de) | Agglomeration von festen Peroxiden. | |
| DE2533511A1 (de) | Verfahren zur herstellung von festem titantrichlorid und dessen verwendung als katalysator zur polymerisation von alpha-olefinen | |
| DE2032430B2 (de) | Verfahren zur herstellung von polyaethern | |
| DE3640185A1 (de) | Katalysator fuer die olefinpolymerisation | |
| DE1111393B (de) | Verfahren zur Polymerisation von olefinisch ungesaettigten Kohlenwasserstoffen | |
| DE1542225A1 (de) | Polymerisationsverfahren | |
| DE1909170B2 (de) | Verfahren zur herstellung von granularem polyvinylalkohol | |
| EP1124860A1 (de) | Verfahren zur herstellung eines polymers | |
| DE1261674B (de) | Verfahren zum Reinigen von festen Poly-alpha-olefinen | |
| DE1142701B (de) | Verfahren zum Verbessern der mechanischen Eigenschaften von Polymerisaten | |
| DE2929830A1 (de) | Katalysator fuer die olefinplymerisation und dessen herstellung | |
| DE2000585C3 (de) | Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung | |
| DE2037603C3 (de) | Verfahren zur Herstellung von Polymerisationskatalysatoren und deren Verwendung | |
| DE2240246A1 (de) | Verfahren zur herstellung von polyolefinen und dabei verwendeter katalysator |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |