DE2003793A1 - Reflex-reflektierendes Gewebe und UEbertragungsfolie - Google Patents
Reflex-reflektierendes Gewebe und UEbertragungsfolieInfo
- Publication number
- DE2003793A1 DE2003793A1 DE19702003793 DE2003793A DE2003793A1 DE 2003793 A1 DE2003793 A1 DE 2003793A1 DE 19702003793 DE19702003793 DE 19702003793 DE 2003793 A DE2003793 A DE 2003793A DE 2003793 A1 DE2003793 A1 DE 2003793A1
- Authority
- DE
- Germany
- Prior art keywords
- reflective
- microns
- layer
- glass beads
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title description 37
- 239000011888 foil Substances 0.000 title description 3
- 239000011521 glass Substances 0.000 claims description 42
- 239000000049 pigment Substances 0.000 claims description 41
- 239000010410 layer Substances 0.000 claims description 40
- 239000011324 bead Substances 0.000 claims description 32
- 239000011230 binding agent Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000002356 single layer Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims 1
- 239000011118 polyvinyl acetate Substances 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 239000012790 adhesive layer Substances 0.000 description 18
- 229920005989 resin Polymers 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 239000011049 pearl Substances 0.000 description 13
- 239000004698 Polyethylene Substances 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 10
- 239000010408 film Substances 0.000 description 10
- -1 polyethylene Polymers 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 239000003822 epoxy resin Substances 0.000 description 9
- 239000004005 microsphere Substances 0.000 description 9
- 229920000647 polyepoxide Polymers 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920005749 polyurethane resin Polymers 0.000 description 7
- 229920001169 thermoplastic Polymers 0.000 description 7
- 239000004416 thermosoftening plastic Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 239000013039 cover film Substances 0.000 description 5
- 230000011514 reflex Effects 0.000 description 5
- 238000005108 dry cleaning Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000001055 blue pigment Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 2
- 229910000003 Lead carbonate Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000001053 orange pigment Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- GVNLTKPENATPJA-UHFFFAOYSA-N 4-methylpentan-2-one;hydrochloride Chemical compound Cl.CC(C)CC(C)=O GVNLTKPENATPJA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 241000612118 Samolus valerandi Species 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Optical Elements Other Than Lenses (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79254269A | 1969-01-21 | 1969-01-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2003793A1 true DE2003793A1 (de) | 1970-08-06 |
Family
ID=25157270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702003793 Pending DE2003793A1 (de) | 1969-01-21 | 1970-01-20 | Reflex-reflektierendes Gewebe und UEbertragungsfolie |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5144639B1 (enrdf_load_stackoverflow) |
| BE (1) | BE744645A (enrdf_load_stackoverflow) |
| CA (1) | CA926754A (enrdf_load_stackoverflow) |
| DE (1) | DE2003793A1 (enrdf_load_stackoverflow) |
| DK (1) | DK122980B (enrdf_load_stackoverflow) |
| FR (1) | FR2037319A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1303103A (enrdf_load_stackoverflow) |
| NL (1) | NL168339C (enrdf_load_stackoverflow) |
| SE (1) | SE365163B (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0255251A3 (en) * | 1986-08-01 | 1988-09-21 | Minnesota Mining And Manufacturing Company | Retroreflective sheet with enhanced brightness |
| EP0372727A3 (en) * | 1988-12-09 | 1991-07-17 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting adapted to be bonded to vulcanizable or curable substrate |
| CN111552016A (zh) * | 2020-05-25 | 2020-08-18 | 合肥路明反光材料有限公司 | 一种耐重工业水洗反光布 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH608315B (de) * | 1974-09-19 | Schlaepfer & Co Ag | Durch heissiegelung auf einem zu dekorierenden substrat anbringbares stickereielement und verfahren zu dessen herstellung. | |
| JPS6033169A (ja) * | 1983-08-03 | 1985-02-20 | Kubota Ltd | 移動車の操向角検出装置 |
| DK257390A (da) * | 1990-10-25 | 1992-04-26 | Reflex Promotion | Transfer til dekorering af overflader med billeder, der er ekstremt holdbare, og specielt billeder omfattende lysreflekterende og farvede omraader i vilkaarlig kombination, samt fremgangsmaade til fremstilling deraf |
| KR100228593B1 (ko) * | 1990-10-25 | 1999-11-01 | 스프레이그 로버트 월터 | 역반사성의 착색상을 형성하기 위한 전사제품 및 이를 제조하는 방법 |
| US5254390B1 (en) * | 1990-11-15 | 1999-05-18 | Minnesota Mining & Mfg | Plano-convex base sheet for retroreflective articles |
| DK167938B1 (da) * | 1991-12-04 | 1994-01-03 | Ulrich Oppenhejm | Presenning forsynet med en dekoration af reflekterende materiale og fremgangsmaade til fremstilling deraf |
| US5831766A (en) * | 1993-02-17 | 1998-11-03 | Reflexite Corporation | Retroreflective structure |
| US5637173A (en) * | 1993-02-17 | 1997-06-10 | Reflexite Corporation | Method for forming a retroreflective structure having free-standing prisms |
| US5503906A (en) * | 1993-05-05 | 1996-04-02 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US5344705A (en) * | 1993-05-05 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| NL1025360C2 (nl) * | 2004-01-29 | 2006-10-24 | Dox Vako Internat B V | Warmtelasbaar reflectiemateriaal. |
| WO2015123582A1 (en) | 2014-02-13 | 2015-08-20 | 3M Innovative Properties Company | Dual cure stain resistant microsphere articles |
-
1970
- 1970-01-19 SE SE57270A patent/SE365163B/xx unknown
- 1970-01-19 NL NL7000724A patent/NL168339C/xx not_active IP Right Cessation
- 1970-01-20 CA CA072627A patent/CA926754A/en not_active Expired
- 1970-01-20 FR FR7001886A patent/FR2037319A5/fr not_active Expired
- 1970-01-20 DE DE19702003793 patent/DE2003793A1/de active Pending
- 1970-01-20 BE BE744645D patent/BE744645A/xx not_active IP Right Cessation
- 1970-01-20 GB GB277470A patent/GB1303103A/en not_active Expired
- 1970-01-20 DK DK23670A patent/DK122980B/da unknown
- 1970-01-20 JP JP535070A patent/JPS5144639B1/ja active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0255251A3 (en) * | 1986-08-01 | 1988-09-21 | Minnesota Mining And Manufacturing Company | Retroreflective sheet with enhanced brightness |
| EP0372727A3 (en) * | 1988-12-09 | 1991-07-17 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting adapted to be bonded to vulcanizable or curable substrate |
| CN111552016A (zh) * | 2020-05-25 | 2020-08-18 | 合肥路明反光材料有限公司 | 一种耐重工业水洗反光布 |
Also Published As
| Publication number | Publication date |
|---|---|
| SE365163B (enrdf_load_stackoverflow) | 1974-03-18 |
| BE744645A (fr) | 1970-07-10 |
| DK122980B (da) | 1972-05-01 |
| FR2037319A5 (enrdf_load_stackoverflow) | 1970-12-31 |
| JPS5144639B1 (enrdf_load_stackoverflow) | 1976-11-30 |
| GB1303103A (enrdf_load_stackoverflow) | 1973-01-17 |
| CA926754A (en) | 1973-05-22 |
| NL168339B (nl) | 1981-10-16 |
| NL7000724A (enrdf_load_stackoverflow) | 1970-07-23 |
| NL168339C (nl) | 1982-03-16 |
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