DE19945716C2 - Keramikmasse für temperaturstabile Filter und Verfahren zu ihrer Herstellung - Google Patents

Keramikmasse für temperaturstabile Filter und Verfahren zu ihrer Herstellung

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Publication number
DE19945716C2
DE19945716C2 DE19945716A DE19945716A DE19945716C2 DE 19945716 C2 DE19945716 C2 DE 19945716C2 DE 19945716 A DE19945716 A DE 19945716A DE 19945716 A DE19945716 A DE 19945716A DE 19945716 C2 DE19945716 C2 DE 19945716C2
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ceramic mass
temperature
manufacture
stable filters
ceramic
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DE19945716A1 (de
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Gerhard Peperko
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TDK Electronics AG
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Epcos AG
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/003Titanates
    • C01G23/006Alkaline earth titanates
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    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/003Titanates
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/44Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminates
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01PWAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
    • H01P7/00Resonators of the waveguide type
    • H01P7/10Dielectric resonators
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/32Thermal properties
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C04B2235/3222Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5409Particle size related information expressed by specific surface values

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Insulating Materials (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Description

Die Erfindung betrifft eine Keramikmasse für temperatursta­ bile Filter.
Für Basisstationen im 900 MHz-Bereich (NM9500, GSM, AMPS, TACS) werden temperaturstabile Filter benötigt. Sowohl für die Reduktion der Größe der Filter als auch für die Kompensa­ tion der negativen Temperaturdrift der Frequenz wegen der Ge­ häuseausdehnung werden dielektrische Resonatoren für diese Filter verwendet.
Aufgabe der vorliegenden Erfindung ist es, eine Keramikmasse für temperaturstabile Filter anzugeben, welche eine bessere Temperaturstabilisierung bei gleichzeitiger Reduktion der Größe der Filter besitzt.
Diese Aufgabe wird erfindungsgemäß durch eine Keramikmasse ge­ löst, welche die im Patentanspruch 1 genannten Merkmale be­ sitzt.
Vorteilhafte Weiterbildungen sind in den Unteransprüchen an­ geführt.
Durch Wahl der Zusammensetzung können die grundsätzlichen Werte von dielektrischen Resonatoren aus dieser Keramik ein­ gestellt werden. Grundsätzlich läßt sich feststellen, daß mit steigendem Anteil von CaTiO3
  • a) die Dielektrizitätskonstante angehoben,
  • b) der Temperaturkoeffizient der Resonanzfrequenz angehoben,
  • c) die unbelastete Güte reduziert wird.
Für eine Keramikmasse mit y = 0, also ohne LaAlO3, der Zusam­ mensetzung (CaxNd1-x) (TixAl1-x)O3 ergeben sich die in der Ta­ belle 1 angeführten Werte für die Dielektrizitätskontante ε und unbelastete Güte Q0 in Prozent, wobei der Wert für x = 0,54 zu 100% angesetzt ist. Ferner ist in Tabelle 1 der Temperaturkoeffizient TK der Resonanzfrequenz angegeben.
Tabelle 1
Der unangenehmste Effekt ist dabei die Reduktion der Güte Q0 bei Übergang zu Temperaturkoeffizienten ≧ 0 ppm/°C.
In der folgenden Tabelle 2 sind die Güte-Werte Q0 einer Kera­ mikmasse (Ca1-x-yNdxLay)(Ti1-x-yAlx+y)O3 angeführt, wobei Q0 für y = 0 zu 100% angesetzt ist.
Tabelle 2
Somit läßt sich für y-Werte zwischen 0 und 0,1 die Güte anhe­ ben, da die Güte zwischen y = 0 und y = 0,05 durch ein Maximum läuft.
Ferner wurde untersucht, wie sich der Zusatz von ZnO und NiO auf die Werte der Dielektrizitätskonstante beziehungsweise der Güte auswirkt. Die Ergebnisse sind in Tabelle 3 ange­ führt.
Tabelle 3
Wie der Tabelle zu entnehmen ist, wirkt sich insbesondere der Zusatz von ZnO günstig auf den Q0-Wert aus.
Zur Herstellung der Keramikmasse werden Carbonate und Oxide der bevorzugten Rezeptur
(Ca1-x-yNdxLay)(Ti1-x-yAlx+y)O3 + z Gew.-% ZnO
mit 0,26 ≦ x + y ≦ 0,46, 0 ≦ y ≦ 0,1, 0 ≦ z ≦ 2
naß vermahlen und das entwässerte getrocknete Pulver bei Tem­ peraturen zwischen 1150 und 1200°C und Verweilzeiten von 2 bis 8 Stunden calciniert, darauf erfolgt die zweite Mahlung mit Zugabe organischer Bindermaterialien und Granulierung mittels Sprühtrocknung.
In der folgenden Tabelle 4 ist angeführt, wie sich bei einer Keramikmasse der Zusammensetzung (Ca0,64Nd0,36)(Ti0,64Al0,36)O3, Calcinierung bei 1180°C unterschiedliche spezifische Ober­ flächen spO des verwendeten Al2O3 auswirken.
Tabelle 4
Der Tabelle ist zu entnehmen, daß insbesondere die Verwendung von Al2O3 mit einer spezifischen Oberfläche ≧ 100 m2/g gün­ stige Auswirkungen hat.

Claims (4)

1. Keramikmasse für temperaturstabile Filter,
dadurch gekennzeichnet, daß sie die Zusammensetzung
(1 - x - y)CaTiO3 + x NdAlO3 + y LaAlO3
mit 0 < x < 0,5 und 0 ≦ y < 0,5 aufweist.
2. Keramikmasse nach Anspruch 1, dadurch gekennzeichnet, daß sie einen Zusatz z Gew.-% ZnO und/oder NiO mit 0 < z ≦ 2 aufweist.
3. Keramikmasse nach Anspruch 1 oder 2, gekennzeichnet durch die Zusammensetzung
(Ca1-x-yNdxLay)(Ti1-x-yAlx+y)O3 + z Gew.-% ZnO
mit 0,26 ≦ x + y ≦ 0,46, 0 ≦ y ≦ 0,1 und 0 < z ≦ 2.
4. Verfahren zum Herstellen einer Keramikmasse einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß Al2O3 mit einer spezifischen Oberfläche ≧ 100 m2/g verwen­ det wird.
DE19945716A 1999-09-23 1999-09-23 Keramikmasse für temperaturstabile Filter und Verfahren zu ihrer Herstellung Expired - Lifetime DE19945716C2 (de)

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DE19945716A DE19945716C2 (de) 1999-09-23 1999-09-23 Keramikmasse für temperaturstabile Filter und Verfahren zu ihrer Herstellung

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DE19945716A DE19945716C2 (de) 1999-09-23 1999-09-23 Keramikmasse für temperaturstabile Filter und Verfahren zu ihrer Herstellung

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Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
AU2001236069A1 (en) * 2000-11-20 2002-05-27 Ngk Spark Plug Co., Ltd. Microwave dielectric porcelain composition and dielectric resonator

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4104592A1 (de) * 1991-02-14 1992-08-20 Siemens Ag Verfahren zur herstellung einer hochtemperatursupraleiter-schicht auf einem silizium-substrat
EP0544399A2 (de) * 1991-11-26 1993-06-02 Xerox Corporation Pufferschicht aus epitaktischen Magnesiumoxid für das Wachstum von Schichten auf tetrahedrischen Halbleitern

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4104592A1 (de) * 1991-02-14 1992-08-20 Siemens Ag Verfahren zur herstellung einer hochtemperatursupraleiter-schicht auf einem silizium-substrat
EP0544399A2 (de) * 1991-11-26 1993-06-02 Xerox Corporation Pufferschicht aus epitaktischen Magnesiumoxid für das Wachstum von Schichten auf tetrahedrischen Halbleitern

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
Derwent-Abstr. zu JP 06239696 A *
Derwent-Abstr. zu JP 57019036 A *
Derwent-Abstr. zu RU 2091926 C1 *
Derwent-Abstr. zu SU 410468 A *
Derwent-Abstr. zu SU 446910 A *
Derwent-Abstr. zu SU 590299 A *

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