DE1948318A1 - Verfahren zur Herstellung von Peressigsaeure durch Oxydation von Acetaldehyd - Google Patents
Verfahren zur Herstellung von Peressigsaeure durch Oxydation von AcetaldehydInfo
- Publication number
- DE1948318A1 DE1948318A1 DE19691948318 DE1948318A DE1948318A1 DE 1948318 A1 DE1948318 A1 DE 1948318A1 DE 19691948318 DE19691948318 DE 19691948318 DE 1948318 A DE1948318 A DE 1948318A DE 1948318 A1 DE1948318 A1 DE 1948318A1
- Authority
- DE
- Germany
- Prior art keywords
- oxygen
- acetaldehyde
- reaction
- reaction vessel
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 title claims description 94
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 title claims description 58
- 238000000034 method Methods 0.000 title claims description 21
- 230000008569 process Effects 0.000 title claims description 12
- 230000003647 oxidation Effects 0.000 title claims description 7
- 238000007254 oxidation reaction Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000006243 chemical reaction Methods 0.000 claims description 105
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 48
- 239000001301 oxygen Substances 0.000 claims description 46
- 229910052760 oxygen Inorganic materials 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 21
- 239000012495 reaction gas Substances 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 13
- 239000012808 vapor phase Substances 0.000 claims description 7
- 239000003085 diluting agent Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000004880 explosion Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 2
- -1 air Chemical compound 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004200 deflagration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008570 general process Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 210000005166 vasculature Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/242—Tubular reactors in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00186—Controlling or regulating processes controlling the composition of the reactive mixture
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76407968A | 1968-10-01 | 1968-10-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1948318A1 true DE1948318A1 (de) | 1970-04-09 |
Family
ID=25069624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19691948318 Withdrawn DE1948318A1 (de) | 1968-10-01 | 1969-09-24 | Verfahren zur Herstellung von Peressigsaeure durch Oxydation von Acetaldehyd |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4137256A (enExample) |
| AT (1) | AT291961B (enExample) |
| BE (1) | BE739340A (enExample) |
| BR (1) | BR6912738D0 (enExample) |
| CH (1) | CH515210A (enExample) |
| DE (1) | DE1948318A1 (enExample) |
| ES (1) | ES372033A1 (enExample) |
| FR (1) | FR2019595A1 (enExample) |
| GB (1) | GB1256920A (enExample) |
| NL (1) | NL6914803A (enExample) |
| SE (1) | SE354848B (enExample) |
| SU (1) | SU383277A3 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2719956C2 (de) * | 1977-05-04 | 1982-12-02 | Bayer Ag, 5090 Leverkusen | Vorrichtung zum Mischen, Reagieren und Ausdampfen |
| US4617090A (en) * | 1984-12-20 | 1986-10-14 | The United States Of America As Represented By The United States Department Of Energy | Process for producing peracids from aliphatic hydroxy carboxylic acids |
| NZ219621A (en) * | 1987-03-13 | 1989-09-27 | Gesser Hyman Davidson | Converting ethane into ethanol and methanol |
| US6010729A (en) | 1998-08-20 | 2000-01-04 | Ecolab Inc. | Treatment of animal carcasses |
| RU2328339C2 (ru) * | 2006-07-03 | 2008-07-10 | Ангарская государственная техническая академия | Барботажный реактор жидкофазного хлорирования этилена с распределенным вводом реагентов |
| EP2155867B1 (en) * | 2007-05-10 | 2015-10-14 | Danisco US Inc. | Stable enzymatic peracid generating systems |
| CN114984897B (zh) * | 2022-05-20 | 2023-10-17 | 万华化学集团股份有限公司 | 一种氧化-过氧化物分解耦合反应装置及其用于有机醛氧化生产有机酸的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA678327A (en) * | 1964-01-21 | D. Cooley Stone | Preparation of peracetic acid | |
| US2314385A (en) * | 1940-02-21 | 1943-03-23 | Celanese Corp | Preparation of aliphatic peracids by oxidation of aldehydes |
| US3192256A (en) * | 1960-02-04 | 1965-06-29 | Celanese Corp | Process for making peracids by the oxidation of aldehydes |
| GB1149243A (en) * | 1965-08-24 | 1969-04-16 | Courtaulds Ltd | Improvements in and relating to the manufacture of peracetic acid |
-
1969
- 1969-09-24 DE DE19691948318 patent/DE1948318A1/de not_active Withdrawn
- 1969-09-24 BE BE739340D patent/BE739340A/xx unknown
- 1969-09-25 BR BR212738/69A patent/BR6912738D0/pt unknown
- 1969-09-26 AT AT911269A patent/AT291961B/de not_active IP Right Cessation
- 1969-09-29 SU SU1365892A patent/SU383277A3/ru active
- 1969-09-29 CH CH1464869A patent/CH515210A/de not_active IP Right Cessation
- 1969-09-30 ES ES372033A patent/ES372033A1/es not_active Expired
- 1969-09-30 SE SE13478/69A patent/SE354848B/xx unknown
- 1969-09-30 NL NL6914803A patent/NL6914803A/xx unknown
- 1969-09-30 FR FR6933367A patent/FR2019595A1/fr not_active Withdrawn
- 1969-09-30 GB GB1256920D patent/GB1256920A/en not_active Expired
-
1976
- 1976-02-03 US US05/654,953 patent/US4137256A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CH515210A (de) | 1971-11-15 |
| BE739340A (enExample) | 1970-03-02 |
| FR2019595A1 (enExample) | 1970-07-03 |
| ES372033A1 (es) | 1971-09-01 |
| SE354848B (enExample) | 1973-03-26 |
| NL6914803A (enExample) | 1970-04-03 |
| BR6912738D0 (pt) | 1973-01-11 |
| AT291961B (de) | 1971-08-10 |
| US4137256A (en) | 1979-01-30 |
| GB1256920A (enExample) | 1971-12-15 |
| SU383277A3 (enExample) | 1973-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |