DE1945102A1 - Thermoplastische Formmassen auf Basis gesaettigter Polyester - Google Patents
Thermoplastische Formmassen auf Basis gesaettigter PolyesterInfo
- Publication number
- DE1945102A1 DE1945102A1 DE19691945102 DE1945102A DE1945102A1 DE 1945102 A1 DE1945102 A1 DE 1945102A1 DE 19691945102 DE19691945102 DE 19691945102 DE 1945102 A DE1945102 A DE 1945102A DE 1945102 A1 DE1945102 A1 DE 1945102A1
- Authority
- DE
- Germany
- Prior art keywords
- polyester
- mold
- dicarboxylic acids
- saturated
- plates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims description 36
- 150000001875 compounds Chemical class 0.000 title claims description 7
- 229920006395 saturated elastomer Polymers 0.000 title claims description 6
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 4
- -1 aromatic dicarboxylic acids Chemical class 0.000 claims description 20
- 239000003513 alkali Substances 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910003480 inorganic solid Inorganic materials 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 238000000465 moulding Methods 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 238000005809 transesterification reaction Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- CHZLVSBMXZSPNN-UHFFFAOYSA-N 2,4-dimethylbenzenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C(C)=C1 CHZLVSBMXZSPNN-UHFFFAOYSA-N 0.000 description 1
- KXJCTUZHSGORSJ-UHFFFAOYSA-N 2-(10-methylundecyl)benzenesulfonic acid Chemical compound CC(C)CCCCCCCCCC1=CC=CC=C1S(O)(=O)=O KXJCTUZHSGORSJ-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical compound CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- MBRNKMIFWVMHPZ-UHFFFAOYSA-N bis(hydroxymethyl) benzene-1,4-dicarboxylate Chemical compound OCOC(=O)C1=CC=C(C(=O)OCO)C=C1 MBRNKMIFWVMHPZ-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE755832D BE755832A (fr) | 1969-09-05 | Matieres a mouler thermoplastiques a base de polyesters satures | |
| DE19691945102 DE1945102A1 (de) | 1969-09-05 | 1969-09-05 | Thermoplastische Formmassen auf Basis gesaettigter Polyester |
| NL7012640A NL7012640A (US08088918-20120103-C00476.png) | 1969-09-05 | 1970-08-26 | |
| US68048A US3663498A (en) | 1969-09-05 | 1970-08-28 | Thermoplastic moulding compositions on the basis of saturated polyesters |
| CH1312370A CH548433A (de) | 1969-09-05 | 1970-09-02 | Thermoplastische formmassen auf basis gesaettigter polyester. |
| ZA706049A ZA706049B (en) | 1969-09-05 | 1970-09-03 | Thermoplastic moulding compositions on the basis of saturated polyesters |
| ES383367A ES383367A1 (es) | 1969-09-05 | 1970-09-03 | Procedimiento para la obtencion de materiales termoplasti- cos de moldeo, a base de poliesteres saturados. |
| AT807070A AT305630B (de) | 1969-09-05 | 1970-09-04 | Herstellung von Spritzgußformkörpern aus thermoplastischen Formmassen |
| CA092,334A CA947892A (en) | 1969-09-05 | 1970-09-04 | Thermoplastic moulding compositions on the basis of saturated polyesters |
| GB4267770A GB1305073A (US08088918-20120103-C00476.png) | 1969-09-05 | 1970-09-07 | |
| FR7032411A FR2060427B1 (US08088918-20120103-C00476.png) | 1969-09-05 | 1970-09-07 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691945102 DE1945102A1 (de) | 1969-09-05 | 1969-09-05 | Thermoplastische Formmassen auf Basis gesaettigter Polyester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1945102A1 true DE1945102A1 (de) | 1971-03-18 |
Family
ID=5744725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19691945102 Pending DE1945102A1 (de) | 1969-09-05 | 1969-09-05 | Thermoplastische Formmassen auf Basis gesaettigter Polyester |
Country Status (11)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2350781A1 (de) * | 1972-10-12 | 1974-04-25 | Montedison Spa | Formmassen |
| EP0192112A2 (de) * | 1985-02-16 | 1986-08-27 | Bayer Ag | Luftreifen mit Notlaufeigenschaften |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3940366A (en) * | 1973-12-28 | 1976-02-24 | General Electric Company | Flame retardant polycarbonate composition |
| US3933734A (en) * | 1973-12-28 | 1976-01-20 | General Electric Company | Flame retardant polycarbonate composition |
| US3953399A (en) * | 1973-12-28 | 1976-04-27 | General Electric Company | Flame retardant polycarbonate composition |
| US4251406A (en) * | 1978-12-18 | 1981-02-17 | E. I. Du Pont De Nemours And Company | Water-borne alkyds |
| JPS61148262A (ja) * | 1984-12-21 | 1986-07-05 | Polyplastics Co | ポリブチレンテレフタレ−ト樹脂組成物 |
| JPH02151650A (ja) * | 1988-12-02 | 1990-06-11 | Polyplastics Co | 熱可塑性ポリエステル樹脂組成物 |
| KR960016597B1 (ko) * | 1993-06-09 | 1996-12-16 | 주식회사 에스·케이·씨 | 개선된 폴리에스테르 필름 및 그 제조방법 |
| US5602195A (en) * | 1994-07-27 | 1997-02-11 | Skc Limited | Polymeric film and process for the preparation thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1496659A (fr) * | 1965-10-16 | 1967-09-29 | Snia Viscosa | Procédé de fabrication de polyesters et en particulier de téréphtalates de polyéthylène linéaires et produits obtenus par ledit procédé |
| NL6606665A (US08088918-20120103-C00476.png) * | 1966-05-16 | 1967-11-17 |
-
0
- BE BE755832D patent/BE755832A/xx unknown
-
1969
- 1969-09-05 DE DE19691945102 patent/DE1945102A1/de active Pending
-
1970
- 1970-08-26 NL NL7012640A patent/NL7012640A/xx not_active Application Discontinuation
- 1970-08-28 US US68048A patent/US3663498A/en not_active Expired - Lifetime
- 1970-09-02 CH CH1312370A patent/CH548433A/xx not_active IP Right Cessation
- 1970-09-03 ES ES383367A patent/ES383367A1/es not_active Expired
- 1970-09-03 ZA ZA706049A patent/ZA706049B/xx unknown
- 1970-09-04 CA CA092,334A patent/CA947892A/en not_active Expired
- 1970-09-04 AT AT807070A patent/AT305630B/de not_active IP Right Cessation
- 1970-09-07 FR FR7032411A patent/FR2060427B1/fr not_active Expired
- 1970-09-07 GB GB4267770A patent/GB1305073A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2350781A1 (de) * | 1972-10-12 | 1974-04-25 | Montedison Spa | Formmassen |
| EP0192112A2 (de) * | 1985-02-16 | 1986-08-27 | Bayer Ag | Luftreifen mit Notlaufeigenschaften |
| EP0192112A3 (de) * | 1985-02-16 | 1987-12-16 | Bayer Ag | Luftreifen mit Notlaufeigenschaften |
Also Published As
| Publication number | Publication date |
|---|---|
| CH548433A (de) | 1974-04-30 |
| GB1305073A (US08088918-20120103-C00476.png) | 1973-01-31 |
| AT305630B (de) | 1973-03-12 |
| BE755832A (fr) | 1971-03-08 |
| CA947892A (en) | 1974-05-21 |
| US3663498A (en) | 1972-05-16 |
| ES383367A1 (es) | 1973-01-16 |
| ZA706049B (en) | 1971-06-30 |
| FR2060427B1 (US08088918-20120103-C00476.png) | 1974-04-26 |
| FR2060427A1 (US08088918-20120103-C00476.png) | 1971-06-18 |
| NL7012640A (US08088918-20120103-C00476.png) | 1971-03-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHN | Withdrawal |