DE1792647B2 - Verfahren zur herstellung eines katalysators - Google Patents
Verfahren zur herstellung eines katalysatorsInfo
- Publication number
- DE1792647B2 DE1792647B2 DE19681792647 DE1792647A DE1792647B2 DE 1792647 B2 DE1792647 B2 DE 1792647B2 DE 19681792647 DE19681792647 DE 19681792647 DE 1792647 A DE1792647 A DE 1792647A DE 1792647 B2 DE1792647 B2 DE 1792647B2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- weight
- percent
- molybdenum
- iron group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 15
- 229910052750 molybdenum Inorganic materials 0.000 claims description 15
- 239000011733 molybdenum Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 239000011651 chromium Substances 0.000 claims description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 239000010937 tungsten Substances 0.000 claims description 10
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 239000005078 molybdenum compound Substances 0.000 claims description 4
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 4
- 238000011282 treatment Methods 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 238000005470 impregnation Methods 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- -1 iron group metals Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 2
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003413 degradative effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000010555 transalkylation reaction Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US67196967A | 1967-10-02 | 1967-10-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1792647A1 DE1792647A1 (de) | 1972-02-24 |
| DE1792647B2 true DE1792647B2 (de) | 1976-04-01 |
Family
ID=24696613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19681792647 Granted DE1792647B2 (de) | 1967-10-02 | 1968-09-28 | Verfahren zur herstellung eines katalysators |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3496117A (enExample) |
| JP (1) | JPS4945066B1 (enExample) |
| AT (1) | AT286944B (enExample) |
| DE (1) | DE1792647B2 (enExample) |
| ES (1) | ES358682A1 (enExample) |
| FR (1) | FR1585528A (enExample) |
| GB (1) | GB1231887A (enExample) |
| IL (1) | IL30806A (enExample) |
| NL (1) | NL6814058A (enExample) |
| SE (1) | SE346698B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1147998B (de) * | 1959-07-30 | 1963-05-02 | Bayerische Schrauben Und Feder | Einrichtung zur Befestigung eines Leiterseiles in der Kopfrille eines Isolators |
| US4000085A (en) * | 1969-02-07 | 1976-12-28 | Institut Francais Du Petrole, Des Carburants Et Lubrifiants Et Entreprise De Recherches Et D'activities Petrolieres Elf | Process for manufacturing gels containing iron and molybdenum and the uses thereof |
| US3900427A (en) * | 1970-12-28 | 1975-08-19 | Exxon Research Engineering Co | Hydroprocessing catalyst |
| US3907713A (en) * | 1973-02-02 | 1975-09-23 | Standard Oil Co Ohio | Superior catalyst prepared by impregnation of preformed matrix |
| US4009125A (en) * | 1974-08-19 | 1977-02-22 | Basf Aktiengesellschaft | Spherical refining catalyst and process for its manufacture |
| US4414134A (en) * | 1981-01-05 | 1983-11-08 | The Standard Oil Co. | Impregnating catalysts |
| NL8501945A (nl) * | 1984-12-07 | 1986-07-01 | Unilever Nv | Katalysator geschikt voor het ontzwavelen en de bereiding van deze katalysator. |
| US4729980A (en) * | 1987-04-27 | 1988-03-08 | Intevep, S.A. | Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks and process for preparing the catalyst |
| CN114433112B (zh) * | 2020-11-06 | 2024-06-14 | 宁波中科远东催化工程技术有限公司 | 一种焦炉煤气加氢脱硫催化剂及其制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242101A (en) * | 1962-07-24 | 1966-03-22 | Sinclair Research Inc | Nickel-molybdenum-alumina hydrocarbon conversion catalyst |
| GB1050969A (enExample) * | 1962-09-25 | |||
| US3409562A (en) * | 1964-05-04 | 1968-11-05 | Chevron Res | Catalyst manufacture |
| US3375065A (en) * | 1965-01-25 | 1968-03-26 | Grace W R & Co | Method of cation exchanging synthetic faujasite |
-
1967
- 1967-10-02 US US671969A patent/US3496117A/en not_active Expired - Lifetime
-
1968
- 1968-09-24 GB GB1231887D patent/GB1231887A/en not_active Expired
- 1968-09-25 AT AT937368A patent/AT286944B/de not_active IP Right Cessation
- 1968-09-28 DE DE19681792647 patent/DE1792647B2/de active Granted
- 1968-09-30 ES ES358682A patent/ES358682A1/es not_active Expired
- 1968-10-01 SE SE13254/68A patent/SE346698B/xx unknown
- 1968-10-01 IL IL30806A patent/IL30806A/en unknown
- 1968-10-01 FR FR1585528D patent/FR1585528A/fr not_active Expired
- 1968-10-02 JP JP43071224A patent/JPS4945066B1/ja active Pending
- 1968-10-02 NL NL6814058A patent/NL6814058A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US3496117A (en) | 1970-02-17 |
| FR1585528A (enExample) | 1970-01-23 |
| IL30806A (en) | 1972-02-29 |
| GB1231887A (enExample) | 1971-05-12 |
| NL6814058A (enExample) | 1969-04-08 |
| JPS4945066B1 (enExample) | 1974-12-02 |
| ES358682A1 (es) | 1970-05-01 |
| IL30806A0 (en) | 1968-12-26 |
| AT286944B (de) | 1970-12-28 |
| SE346698B (enExample) | 1972-07-17 |
| DE1792647A1 (de) | 1972-02-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69125892T2 (de) | Überziehung von Absorbenzien von schwefelhaltigen Substanzen | |
| DE69004622T2 (de) | Selektive Entfernung von Schwefelwasserstoff mit einem einen Nickelpromotor enthaltenden Sorbentmittel. | |
| DE2648338A1 (de) | Verfahren zur modifizierung der porenvolumenverteilung eines aluminiumoxid- katalysatortraeger-vorstufenmaterials | |
| DE3220671A1 (de) | Hydrierungskatalysator fuer die entschwefelung und entfernung von schwermetallen | |
| DE1470524A1 (de) | Verfahren zur Herstellung von Nickel-Molybdaen-Tonerde-Katalysatoren | |
| DE2441199A1 (de) | Katalysatoren fuer die behandlung von schwefelverbindungen enthaltenden abgasen | |
| DE1260675B (de) | Verfahren zur Dampfreformierung von Kohlenwasserstoffen | |
| DE69606145T2 (de) | Katalytisches verfahren zur entschwefelung eines h2s und so2 enthaltenden gases | |
| DE68918345T2 (de) | Katalysator, verwendbar für die selektive Reduktion von Stickstoffoxiden. | |
| DE2252332A1 (de) | Katalysator aus einem oder mehreren hydrierungsaktiven metallen auf einem traegermaterial, verfahren zu seiner herstellung und seine verwendung | |
| DE1792647B2 (de) | Verfahren zur herstellung eines katalysators | |
| DE2363865A1 (de) | Verfahren zur entfernung von stickoxiden aus gasmischungen | |
| DE2559009C3 (de) | Fester Tragerkatalysator zur katalytischen Reduktion von Stickstoffoxiden | |
| DE1442731A1 (de) | Verfahren zur Umsetzung von Kohlenwasserstoffen mit Dampf unter Verwendung eines Katalysators | |
| DE2446006A1 (de) | Reduktionskatalysator zur abscheidung von stickoxiden aus abgasen | |
| DE2216328C3 (de) | Verfahren zur Herstellung eines Spinellverbindungen aufweisenden Trägerkatalysators und dessen Verwendung | |
| DE2411888C3 (de) | Verfahren zur Beseitigung von Stickstoffoxiden in Abgasen | |
| DE1667074A1 (de) | Katalysator und Verfahren zum hydrierenden Entschwefeln von Benzinfraktionen | |
| DE1113446B (de) | Verfahren zur Herstellung von Schwefelwasserstoff | |
| DE2707013C3 (de) | Katalysator und dessen Verwendung | |
| DE1201818B (de) | Verfahren zur Herstellung von Katalysatoren fuer die Umwandlung von Kohlenwasserstoffoelen | |
| DE2555189A1 (de) | Verfahren zur herstellung eines vanadiumkatalysators | |
| DE1244318B (de) | Verfahren zur Hydroraffination von verunreinigten, normalerweise fluessigen Kohlenwasserstofffraktionen, insbesondere Benzinen | |
| AT200158B (de) | Verfahren zur Herstellung von für die Isomerisierung und Dehydrierung geeigneten granulierten Katalysatoren. | |
| DE2406024C3 (de) | Katalysator, Verfahren zu dessen Herstellung und dessen Verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |