DE1767151C3 - Verfahren zur Herstellung von Carbonsäuren und/oder deren Estern - Google Patents

Verfahren zur Herstellung von Carbonsäuren und/oder deren Estern

Info

Publication number
DE1767151C3
DE1767151C3 DE1767151A DE1767151A DE1767151C3 DE 1767151 C3 DE1767151 C3 DE 1767151C3 DE 1767151 A DE1767151 A DE 1767151A DE 1767151 A DE1767151 A DE 1767151A DE 1767151 C3 DE1767151 C3 DE 1767151C3
Authority
DE
Germany
Prior art keywords
catalyst
reactor
methanol
rhodium
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1767151A
Other languages
German (de)
English (en)
Other versions
DE1767151B2 (de
DE1767151A1 (de
Inventor
John Harvey Craddock
Arnold Creve Coeur Hershman
Walter Robert Ballas Woods Knox
Frank Edward Houston Tex. Paulik
James Frank Roth
Robert George Schultz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of DE1767151A1 publication Critical patent/DE1767151A1/de
Publication of DE1767151B2 publication Critical patent/DE1767151B2/de
Application granted granted Critical
Publication of DE1767151C3 publication Critical patent/DE1767151C3/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
DE1767151A 1967-04-05 1968-04-05 Verfahren zur Herstellung von Carbonsäuren und/oder deren Estern Expired DE1767151C3 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US62858167A 1967-04-05 1967-04-05
US70163768A 1968-01-30 1968-01-30
US70163968A 1968-01-30 1968-01-30
US70163668A 1968-01-30 1968-01-30

Publications (3)

Publication Number Publication Date
DE1767151A1 DE1767151A1 (de) 1972-01-27
DE1767151B2 DE1767151B2 (de) 1979-03-01
DE1767151C3 true DE1767151C3 (de) 1979-10-25

Family

ID=27505183

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1767151A Expired DE1767151C3 (de) 1967-04-05 1968-04-05 Verfahren zur Herstellung von Carbonsäuren und/oder deren Estern

Country Status (9)

Country Link
AT (1) AT295487B (enExample)
BE (1) BE713296A (enExample)
BR (1) BR6898142D0 (enExample)
DE (1) DE1767151C3 (enExample)
FR (1) FR1573131A (enExample)
GB (2) GB1233121A (enExample)
IL (1) IL29769A (enExample)
NL (1) NL149779B (enExample)
SE (1) SE364255B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3333317A1 (de) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl Katalysatorsystem und verfahren zur herstellung von essigsaeure durch katalytische umlagerung von ameisensaeuremethylester

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3845121A (en) * 1971-11-10 1974-10-29 Monsanto Co Process for separating carbonylation products from reaction mixture without catalyst decomposition
SE413891B (sv) * 1973-09-04 1980-06-30 Halcon International Inc Sett att framstella en anhydrid av en monokarbonsyra.
SE426583B (sv) * 1975-03-10 1983-01-31 Halcon Res & Dev Sett att framstella etylidenacetat
JPS5538369A (en) * 1978-09-01 1980-03-17 Texaco Development Corp Manufacture of carboxylic acids and their esters
US4334092A (en) * 1980-06-30 1982-06-08 Texaco Inc. Method of preparing aliphatic carboxylic acids
NZ203225A (en) * 1982-02-13 1985-01-31 Bp Chem Int Ltd Coproduction of monocarboxylic acids and anhydrides
AU558736B2 (en) * 1982-03-26 1987-02-05 Davy Mckee (London) Limited Process for the production of ethanol
US4467106A (en) * 1982-04-15 1984-08-21 Ethyl Corporation Polyether/polyester glycol process
JPS6054334A (ja) * 1983-09-02 1985-03-28 Daicel Chem Ind Ltd カルボン酸の製造法
CA1228867A (en) * 1984-05-03 1987-11-03 Celanese Corporation Methanol carbonylation process
US5185462A (en) * 1987-01-08 1993-02-09 Bp Chemicals Limited Production of carboxylic acids and esters thereof
GB8807284D0 (en) * 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
US5442107A (en) * 1989-04-06 1995-08-15 Bp Chemicals Limited Preparing carboxylic acids
KR910009624A (ko) * 1989-11-13 1991-06-28 원본미기재 알릴계 부텐올과 부텐올 에스테르의 카보닐화
GB9100216D0 (en) * 1991-01-05 1991-02-20 Bp Chem Int Ltd Process
GB9120902D0 (en) * 1991-10-02 1991-11-13 Bp Chem Int Ltd Purification process
US5334755A (en) * 1992-04-24 1994-08-02 Chiyoda Corporation Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst
GB9211671D0 (en) * 1992-06-02 1992-07-15 Bp Chem Int Ltd Process
GB9218346D0 (en) * 1992-08-28 1992-10-14 Bp Chem Int Ltd Process
GB9305902D0 (en) * 1993-03-22 1993-05-12 Bp Chem Int Ltd Process
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
KR960006546B1 (ko) * 1993-07-28 1996-05-17 한국과학기술연구원 초산에스테르의 제조 방법
JP3308392B2 (ja) 1994-06-02 2002-07-29 ダイセル化学工業株式会社 カルボニル化反応方法
JP3332594B2 (ja) 1994-08-12 2002-10-07 ダイセル化学工業株式会社 酢酸の精製方法
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
GB9521501D0 (en) * 1995-10-20 1995-12-20 Bp Chem Int Ltd Process
GB9819079D0 (en) 1998-09-03 1998-10-28 Bp Chem Int Ltd Carbonylation process
GB9819606D0 (en) 1998-09-08 1998-11-04 Bp Chem Int Ltd Carbonylation process
EP2093209A1 (en) 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
KR101874523B1 (ko) 2017-08-23 2018-07-04 (주)부흥산업사 메탄올 카보닐레이션에 의한 초산제조용 불균일 촉매

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3333317A1 (de) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl Katalysatorsystem und verfahren zur herstellung von essigsaeure durch katalytische umlagerung von ameisensaeuremethylester

Also Published As

Publication number Publication date
GB1233122A (enExample) 1971-05-26
DE1767151B2 (de) 1979-03-01
IL29769A0 (en) 1968-06-20
IL29769A (en) 1972-10-29
GB1233121A (enExample) 1971-05-26
SE364255B (enExample) 1974-02-18
NL149779B (nl) 1976-06-15
BR6898142D0 (pt) 1973-06-12
NL6804850A (enExample) 1968-10-07
BE713296A (enExample) 1968-10-07
AT295487B (de) 1972-01-10
FR1573131A (enExample) 1969-07-04
DE1767151A1 (de) 1972-01-27

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)