DE1643810A1 - Verfahren zur Oligomerisation von konjugierten Diolefinen - Google Patents
Verfahren zur Oligomerisation von konjugierten DiolefinenInfo
- Publication number
- DE1643810A1 DE1643810A1 DE19671643810 DE1643810A DE1643810A1 DE 1643810 A1 DE1643810 A1 DE 1643810A1 DE 19671643810 DE19671643810 DE 19671643810 DE 1643810 A DE1643810 A DE 1643810A DE 1643810 A1 DE1643810 A1 DE 1643810A1
- Authority
- DE
- Germany
- Prior art keywords
- organic
- butadiene
- molar ratio
- nickel
- lewis base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US584379A US3390195A (en) | 1966-10-05 | 1966-10-05 | Oligomericzation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1643810A1 true DE1643810A1 (de) | 1971-07-01 |
Family
ID=24337084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19671643810 Pending DE1643810A1 (de) | 1966-10-05 | 1967-09-30 | Verfahren zur Oligomerisation von konjugierten Diolefinen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3390195A (cg-RX-API-DMAC7.html) |
| BE (1) | BE704752A (cg-RX-API-DMAC7.html) |
| DE (1) | DE1643810A1 (cg-RX-API-DMAC7.html) |
| NL (1) | NL6713546A (cg-RX-API-DMAC7.html) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3544643A (en) * | 1968-01-27 | 1970-12-01 | Hoechst Ag | Process for the catalytic cyclo-dimerization of 1,3-diolefins |
| US3446861A (en) * | 1968-06-20 | 1969-05-27 | Goodyear Tire & Rubber | Cyclodimerization process |
| US3523981A (en) * | 1969-02-27 | 1970-08-11 | Olin Corp | Dimers of alpha-methyl styrene and its homologues |
| US3692852A (en) * | 1970-05-21 | 1972-09-19 | Phillips Petroleum Co | Semi-homogeneous liquid suspension catalyst complex for selective hydrogenation |
| US3800000A (en) * | 1972-01-03 | 1974-03-26 | Phillips Petroleum Co | Process for recovering a nickel(0) oligomerization catalyst in the form of a nickel(ii) dimerization catalyst |
| US3846461A (en) * | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| US4144257A (en) * | 1974-10-17 | 1979-03-13 | Takasago Perfumery Co., Ltd. | Process for preparing derivatives of conjugated diene dimers |
| US4270016A (en) * | 1979-06-01 | 1981-05-26 | Tolstikov Genrikh A | Method of preparing trans-, trans-, trans-1,5,9-cyclododecatriene |
| US5221774A (en) * | 1992-03-19 | 1993-06-22 | Phillips Petroleum Company | Ethylene oligomerization |
| US5233115A (en) * | 1992-12-09 | 1993-08-03 | Phillips Petroleum Company | Ethylene oligomerization |
| RU2109717C1 (ru) * | 1994-11-08 | 1998-04-27 | Институт нефтехимии и катализа с опытным заводом АН Республики Башкортостан | Способ совместного получения трео-5,6-дизамещенных гепт-1-енов и трео-5,6-дизамещенных дека-1,9-диенов |
| RU2145319C1 (ru) * | 1995-12-13 | 2000-02-10 | Институт нефтехимии и катализа с опытным заводом АН РБ | Способ получения 4,5-диалкил(фенил)-1,4z,9-декатриенов |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2854458A (en) * | 1954-07-15 | 1958-09-30 | Basf Ag | Complex heavy metal salts |
| US2809976A (en) * | 1954-07-16 | 1957-10-15 | Basf Ag | Production of acrylic acid or its derivatives using a cationic complex nickel catalyst |
| US2969408A (en) * | 1955-12-30 | 1961-01-24 | Phillips Petroleum Co | Process and catalyst for polymerization of olefins |
| US2886591A (en) * | 1956-04-18 | 1959-05-12 | Basf Ag | Production of acrylic acid esters |
| NL135124C (cg-RX-API-DMAC7.html) * | 1960-09-21 | 1900-01-01 | ||
| US3326990A (en) * | 1962-06-14 | 1967-06-20 | Columbian Carbon | Cycloolefin production using zieglertype reducing agent and a nickel chelate |
| GB977108A (en) * | 1962-03-26 | 1964-12-02 | Studiengesellschaft Kohle Mbh | Process of co-oligomerisation |
| US3247270A (en) * | 1962-06-14 | 1966-04-19 | Columbian Carbon | Cycloolefin production |
| GB1043143A (en) * | 1962-07-28 | 1966-09-21 | Basf Ag | Production of open chain oligomers of 1,3-dienes |
| NL290631A (cg-RX-API-DMAC7.html) * | 1962-11-30 | 1900-01-01 | ||
| US3296260A (en) * | 1963-01-15 | 1967-01-03 | Du Pont | Neutral and singly charged derivatives of decaboranes and decaborates |
| US3309418A (en) * | 1963-11-22 | 1967-03-14 | Toyo Rayon Co Ltd | Process for producing hexadienes |
| US3352931A (en) * | 1965-08-16 | 1967-11-14 | Phillips Petroleum Co | Catalytic oligomerization of butadiene |
-
1966
- 1966-10-05 US US584379A patent/US3390195A/en not_active Expired - Lifetime
-
1967
- 1967-09-30 DE DE19671643810 patent/DE1643810A1/de active Pending
- 1967-10-05 BE BE704752D patent/BE704752A/xx unknown
- 1967-10-05 NL NL6713546A patent/NL6713546A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6713546A (cg-RX-API-DMAC7.html) | 1968-04-08 |
| US3390195A (en) | 1968-06-25 |
| BE704752A (cg-RX-API-DMAC7.html) | 1968-04-05 |
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