DE1618578C - - Google Patents
Info
- Publication number
- DE1618578C DE1618578C DE1618578C DE 1618578 C DE1618578 C DE 1618578C DE 1618578 C DE1618578 C DE 1618578C
- Authority
- DE
- Germany
- Prior art keywords
- peroxydicarbonates
- tert
- substituted
- decomposition
- peroxydicarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 tert-amyl Chemical group 0.000 claims description 8
- 125000005634 peroxydicarbonate group Chemical group 0.000 claims description 7
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical class C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 230000000875 corresponding Effects 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 description 9
- 239000007858 starting material Substances 0.000 description 4
- XYXGFHALMTXBQX-UHFFFAOYSA-L carboxylatooxy carbonate Chemical compound [O-]C(=O)OOC([O-])=O XYXGFHALMTXBQX-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QWIQFVKKPYUHAT-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl) carbonochloridate Chemical compound CC(C)C1CCC(OC(Cl)=O)CC1 QWIQFVKKPYUHAT-UHFFFAOYSA-N 0.000 description 1
- YXFSGPPQRCUVRL-UHFFFAOYSA-N (4-tert-butylcyclohexyl) carbonochloridate Chemical compound CC(C)(C)C1CCC(OC(Cl)=O)CC1 YXFSGPPQRCUVRL-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-Dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- VNPCSRKMRZPBBO-UHFFFAOYSA-N C(=O)(OC1CCC(CC1)C(C)C)OOC(=O)OC1CCC(CC1)C(C)C Chemical compound C(=O)(OC1CCC(CC1)C(C)C)OOC(=O)OC1CCC(CC1)C(C)C VNPCSRKMRZPBBO-UHFFFAOYSA-N 0.000 description 1
- BGVTUNYGVHSKMD-UHFFFAOYSA-N C(=O)(OC1CCC(CC1)C1CCCCC1)OOC(=O)OC1CCC(CC1)C1CCCCC1 Chemical compound C(=O)(OC1CCC(CC1)C1CCCCC1)OOC(=O)OC1CCC(CC1)C1CCCCC1 BGVTUNYGVHSKMD-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- KIWBRXCOTCXSSZ-UHFFFAOYSA-N hexyl carbonochloridate Chemical compound CCCCCCOC(Cl)=O KIWBRXCOTCXSSZ-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N p-acetaminophenol Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Family
ID=
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