DE1545397C3 - Verfahren zur hydrierenden Entfernung von Stickstoff- und Schwefelverbindungen aus einem Kohlenwasserstoffrückstände enthaltenden schwermetallhaltigen Erdölausgangsmaterial - Google Patents
Verfahren zur hydrierenden Entfernung von Stickstoff- und Schwefelverbindungen aus einem Kohlenwasserstoffrückstände enthaltenden schwermetallhaltigen ErdölausgangsmaterialInfo
- Publication number
- DE1545397C3 DE1545397C3 DE1545397A DEST026177A DE1545397C3 DE 1545397 C3 DE1545397 C3 DE 1545397C3 DE 1545397 A DE1545397 A DE 1545397A DE ST026177 A DEST026177 A DE ST026177A DE 1545397 C3 DE1545397 C3 DE 1545397C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- weight
- percent
- hydrogen
- aluminum oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims description 20
- 229910052757 nitrogen Inorganic materials 0.000 title claims description 10
- 229910001385 heavy metal Inorganic materials 0.000 title claims description 8
- 239000003208 petroleum Substances 0.000 title claims description 8
- 150000003464 sulfur compounds Chemical class 0.000 title claims description 5
- 239000007858 starting material Substances 0.000 title claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims description 83
- 150000002430 hydrocarbons Chemical group 0.000 claims description 27
- 239000002808 molecular sieve Substances 0.000 claims description 27
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 27
- 239000011148 porous material Substances 0.000 claims description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 20
- 229910017052 cobalt Inorganic materials 0.000 claims description 20
- 239000010941 cobalt Substances 0.000 claims description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052750 molybdenum Inorganic materials 0.000 claims description 20
- 239000011733 molybdenum Substances 0.000 claims description 20
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 20
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 19
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000010943 off-gassing Methods 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 150000002739 metals Chemical class 0.000 description 12
- 239000010779 crude oil Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 238000006477 desulfuration reaction Methods 0.000 description 8
- 230000023556 desulfurization Effects 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 3
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910001683 gmelinite Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/36—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed through which there is an essentially horizontal flow of particles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/06—Gasoil
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US510656A US3393148A (en) | 1965-11-30 | 1965-11-30 | Hydrofining catalyst and process using same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1545397A1 DE1545397A1 (de) | 1970-01-29 |
| DE1545397B2 DE1545397B2 (de) | 1979-10-18 |
| DE1545397C3 true DE1545397C3 (de) | 1984-05-30 |
Family
ID=24031628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1545397A Expired DE1545397C3 (de) | 1965-11-30 | 1966-11-29 | Verfahren zur hydrierenden Entfernung von Stickstoff- und Schwefelverbindungen aus einem Kohlenwasserstoffrückstände enthaltenden schwermetallhaltigen Erdölausgangsmaterial |
Country Status (8)
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3471399A (en) * | 1967-06-09 | 1969-10-07 | Universal Oil Prod Co | Hydrodesulfurization catalyst and process for treating residual fuel oils |
| US3509044A (en) * | 1967-06-26 | 1970-04-28 | Exxon Research Engineering Co | Hydrodesulfurization of petroleum residuum |
| US3449456A (en) * | 1968-06-03 | 1969-06-10 | Exxon Research Engineering Co | Startup procedure of isomerizing polymethylbenzene |
| BE755778A (fr) * | 1969-09-05 | 1971-03-04 | Texaco Development Corp | Desulfuration des huiles hydrocarbonees lourdes |
| US3548020A (en) * | 1969-10-29 | 1970-12-15 | Standard Oil Co | Process for the disproportionation of petroleum hydrocarbons |
| US3669873A (en) * | 1970-03-31 | 1972-06-13 | Chevron Res | Hydrofining-hydrocracking process |
| FR2097016B1 (US20100012521A1-20100121-C00001.png) * | 1970-07-27 | 1973-05-25 | Inst Francais Du Petrole | |
| US3793186A (en) * | 1971-07-19 | 1974-02-19 | Chevron Res | Lube oil improvement |
| JPS5550996B2 (US20100012521A1-20100121-C00001.png) * | 1971-09-24 | 1980-12-22 | ||
| GB1397959A (en) * | 1971-09-24 | 1975-06-18 | Standard Oil Co | Catalyst and process for hydrotreating petroleum hydrocarbons |
| US3923638A (en) * | 1971-12-10 | 1975-12-02 | Standard Oil Co | Two-catalyst hydrocracking process |
| US3926786A (en) * | 1972-11-20 | 1975-12-16 | Texaco Inc | Production of lubricating oils |
| US3944482A (en) * | 1973-08-08 | 1976-03-16 | Gulf Research & Development Company | Process for the cracking of high metals content feedstocks |
| US3893947A (en) * | 1973-09-10 | 1975-07-08 | Union Oil Co | Group VI-B metal catalyst preparation |
| US3977962A (en) * | 1974-02-07 | 1976-08-31 | Exxon Research And Engineering Company | Heavy crude conversion |
| US3977961A (en) * | 1974-02-07 | 1976-08-31 | Exxon Research And Engineering Company | Heavy crude conversion |
| US3928176A (en) * | 1974-04-01 | 1975-12-23 | Exxon Research Engineering Co | Heavy crude conversion |
| US4082695A (en) * | 1975-01-20 | 1978-04-04 | Mobil Oil Corporation | Catalyst for residua demetalation and desulfurization |
| US4069139A (en) * | 1975-12-29 | 1978-01-17 | Exxon Research & Engineering Co. | Hydrodesulfurization of oil utilizing a narrow pore size distribution catalyst |
| GB1597165A (en) * | 1977-03-30 | 1981-09-03 | Exxon France | White oils and method of making same |
| FR2390493B1 (fr) * | 1977-05-12 | 1985-04-26 | Linde Ag | Procede de preparation d'olefines |
| US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
| US4257922A (en) * | 1979-03-13 | 1981-03-24 | Electric Power Research Institute, Inc. | Process for coal liquefaction and catalyst |
| US4242236A (en) * | 1979-03-29 | 1980-12-30 | Chevron Research Company | 65-130 Angstrom mean radius silica-alumina catalyst support |
| US4301037A (en) * | 1980-04-01 | 1981-11-17 | W. R. Grace & Co. | Extruded alumina catalyst support having controlled distribution of pore sizes |
| DE3067678D1 (en) * | 1980-06-23 | 1984-06-07 | Exxon Research Engineering Co | Process for catalytic hydrogenation of hydrogenatable compounds in a hydrocarbon feedstock, and hydrogenated hydrocarbon products |
| US4513090A (en) * | 1981-07-09 | 1985-04-23 | Exxon Research And Engineering Co. | Crystalline silica zeolite-containing catalyst |
| US4431526A (en) * | 1982-07-06 | 1984-02-14 | Union Oil Company Of California | Multiple-stage hydroprocessing of hydrocarbon oil |
| US4780446A (en) * | 1982-09-30 | 1988-10-25 | W. R. Grace & Co. | Alumina-silica cogel |
| US4548710A (en) * | 1982-12-28 | 1985-10-22 | Union Oil Company Of California | Hydrocarbon processing |
| US4460707A (en) * | 1982-12-28 | 1984-07-17 | Union Oil Company Of California | Hydroprocessing catalyst and method for preparing it |
| US4913797A (en) * | 1985-11-21 | 1990-04-03 | Mobil Oil Corporation | Catalyst hydrotreating and dewaxing process |
| US8114806B2 (en) * | 2008-04-10 | 2012-02-14 | Shell Oil Company | Catalysts having selected pore size distributions, method of making such catalysts, methods of producing a crude product, products obtained from such methods, and uses of products obtained |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2890162A (en) * | 1955-02-28 | 1959-06-09 | Exxon Research Engineering Co | Porous silica free gamma alumina base contacting agents and use thereof |
| US2924568A (en) * | 1955-02-28 | 1960-02-09 | Exxon Research Engineering Co | Process for hydrodesulfurizing and subsequently catalytically cracking gas oil |
| US2962435A (en) * | 1956-12-14 | 1960-11-29 | Union Oil Co | Hydrocarbon cracking process and catalyst |
| US3020245A (en) * | 1959-05-27 | 1962-02-06 | Catalysts & Chem Inc | Preparation of catalysts containing cobalt and molybdenum oxides |
| GB931936A (en) * | 1960-04-06 | 1963-07-24 | British Petroleum Co | Improvements relating to the production of alumina |
| NL262698A (US20100012521A1-20100121-C00001.png) * | 1960-04-15 | |||
| DE1256824B (de) * | 1960-11-29 | 1967-12-21 | Union Oil Co | Verfahren zum Hydrocracken von Kohlenwasserstoffen |
| US3143491A (en) * | 1962-02-20 | 1964-08-04 | Socony Mobil Oil Co Inc | Catalytic conversion of hydrocarbons with a silica-alumina and crystalline zeolite catalyst composite |
| US3169918A (en) * | 1962-07-02 | 1965-02-16 | Universal Oil Prod Co | Hydrorefining heavy oils using a pseudo-dry catalyst |
| US3242101A (en) * | 1962-07-24 | 1966-03-22 | Sinclair Research Inc | Nickel-molybdenum-alumina hydrocarbon conversion catalyst |
| US3277018A (en) * | 1964-01-24 | 1966-10-04 | Mobil Oil | Selective cracking catalyst |
| US3322666A (en) * | 1964-08-25 | 1967-05-30 | Gulf Research Development Co | Chemical process for hydrocracking and hydrorefining of hydrocarbon oils |
-
1965
- 1965-11-30 US US510656A patent/US3393148A/en not_active Expired - Lifetime
-
1966
- 1966-11-28 FR FR85284A patent/FR1503063A/fr not_active Expired
- 1966-11-29 DE DE1545397A patent/DE1545397C3/de not_active Expired
- 1966-11-29 DK DK617166AA patent/DK129945B/da not_active IP Right Cessation
- 1966-11-30 NL NL666616849A patent/NL139246B/xx not_active IP Right Cessation
- 1966-11-30 SE SE16390/66A patent/SE335896B/xx unknown
- 1966-11-30 ES ES0333965A patent/ES333965A1/es not_active Expired
- 1966-11-30 BE BE690488D patent/BE690488A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK129945B (da) | 1974-12-02 |
| BE690488A (US20100012521A1-20100121-C00001.png) | 1967-05-02 |
| DE1545397B2 (de) | 1979-10-18 |
| FR1503063A (fr) | 1967-11-24 |
| DK129945C (US20100012521A1-20100121-C00001.png) | 1975-05-12 |
| NL6616849A (US20100012521A1-20100121-C00001.png) | 1967-05-31 |
| SE335896B (US20100012521A1-20100121-C00001.png) | 1971-06-14 |
| NL139246B (nl) | 1973-07-16 |
| ES333965A1 (es) | 1967-10-16 |
| US3393148A (en) | 1968-07-16 |
| DE1545397A1 (de) | 1970-01-29 |
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Legal Events
| Date | Code | Title | Description |
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| 8281 | Inventor (new situation) |
Free format text: BERTOLACINI, RALPH JAMES, CHESTERTON, IND., US STRONG JUN., ERWIN RAYFORD, FLOSSMOOR, ILL., US |
|
| 8228 | New agent |
Free format text: ZUMSTEIN SEN., F., DR. ASSMANN, E., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
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| C3 | Grant after two publication steps (3rd publication) |