DE1520234A1 - Verfahren zur Polymerisation von Vinylmonomeren oder einer Monomermischung zu einem Sirup,der aus einer Loesung des Polymers im Monomeren besteht - Google Patents
Verfahren zur Polymerisation von Vinylmonomeren oder einer Monomermischung zu einem Sirup,der aus einer Loesung des Polymers im Monomeren bestehtInfo
- Publication number
- DE1520234A1 DE1520234A1 DE19611520234 DE1520234A DE1520234A1 DE 1520234 A1 DE1520234 A1 DE 1520234A1 DE 19611520234 DE19611520234 DE 19611520234 DE 1520234 A DE1520234 A DE 1520234A DE 1520234 A1 DE1520234 A1 DE 1520234A1
- Authority
- DE
- Germany
- Prior art keywords
- monomer
- initiator
- monomers
- polymer
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000178 monomer Substances 0.000 title claims description 37
- 238000006116 polymerization reaction Methods 0.000 title claims description 23
- 229920000642 polymer Polymers 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 15
- 239000006188 syrup Substances 0.000 title claims description 14
- 235000020357 syrup Nutrition 0.000 title claims description 14
- 239000000203 mixture Substances 0.000 title claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title description 5
- 229920002554 vinyl polymer Polymers 0.000 title description 5
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 239000003999 initiator Substances 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 8
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims 1
- 230000008034 disappearance Effects 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 8
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000010924 continuous production Methods 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 oyoloi Chemical group 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- FMFKNGWZEQOWNK-UHFFFAOYSA-N 1-butoxypropan-2-yl 2-(2,4,5-trichlorophenoxy)propanoate Chemical compound CCCCOCC(C)OC(=O)C(C)OC1=CC(Cl)=C(Cl)C=C1Cl FMFKNGWZEQOWNK-UHFFFAOYSA-N 0.000 description 1
- 101150061947 EIF2D gene Proteins 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1193660 | 1960-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1520234A1 true DE1520234A1 (de) | 1969-08-14 |
Family
ID=11138735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19611520234 Pending DE1520234A1 (de) | 1960-07-07 | 1961-07-03 | Verfahren zur Polymerisation von Vinylmonomeren oder einer Monomermischung zu einem Sirup,der aus einer Loesung des Polymers im Monomeren besteht |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE605838A (en, 2012) |
| CH (1) | CH428223A (en, 2012) |
| DE (1) | DE1520234A1 (en, 2012) |
| ES (1) | ES268817A1 (en, 2012) |
| GB (1) | GB937215A (en, 2012) |
| NL (1) | NL266816A (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004851A3 (en) * | 1978-04-22 | 1979-11-28 | Rohm Gmbh | Process for the partial polymerisation of vinyl monomers and use of the polymer syrups obtained |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU520196B2 (en) * | 1977-10-06 | 1982-01-21 | Sumitomo Chemical Company, Limited | Continuous production of prepolymer syrups |
| JPS55147514A (en) * | 1979-04-27 | 1980-11-17 | Sumitomo Chem Co Ltd | Continuous preparation of rubber-modified methyl methacrylate syrup |
| TW363978B (en) * | 1994-05-06 | 1999-07-11 | Akzo Nobel Nv | A method of radically (co)polymerizing at least one vinyl halide or vinylidene halide |
-
0
- BE BE605838D patent/BE605838A/xx unknown
- NL NL266816D patent/NL266816A/xx unknown
-
1961
- 1961-07-03 GB GB2393661A patent/GB937215A/en not_active Expired
- 1961-07-03 DE DE19611520234 patent/DE1520234A1/de active Pending
- 1961-07-04 CH CH780861A patent/CH428223A/de unknown
- 1961-07-06 ES ES0268817A patent/ES268817A1/es not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004851A3 (en) * | 1978-04-22 | 1979-11-28 | Rohm Gmbh | Process for the partial polymerisation of vinyl monomers and use of the polymer syrups obtained |
Also Published As
| Publication number | Publication date |
|---|---|
| CH428223A (de) | 1967-01-15 |
| ES268817A1 (es) | 1962-01-01 |
| BE605838A (en, 2012) | |
| NL266816A (en, 2012) | |
| GB937215A (en) | 1963-09-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SH | Request for examination between 03.10.1968 and 22.04.1971 |