DE1496068B2 - Verfahren zur erhoehung der chemischen widerstandsfaehig keit der oberflaeche von alkali kalk silikat glasgegen staenden - Google Patents
Verfahren zur erhoehung der chemischen widerstandsfaehig keit der oberflaeche von alkali kalk silikat glasgegen staendenInfo
- Publication number
- DE1496068B2 DE1496068B2 DE19651496068 DE1496068A DE1496068B2 DE 1496068 B2 DE1496068 B2 DE 1496068B2 DE 19651496068 DE19651496068 DE 19651496068 DE 1496068 A DE1496068 A DE 1496068A DE 1496068 B2 DE1496068 B2 DE 1496068B2
- Authority
- DE
- Germany
- Prior art keywords
- fluorine
- glass
- temperature
- chemical resistance
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 21
- 230000008569 process Effects 0.000 title claims description 9
- 239000000126 substance Substances 0.000 title claims description 9
- 239000005368 silicate glass Substances 0.000 title claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 title 1
- 235000011941 Tilia x europaea Nutrition 0.000 title 1
- 239000004571 lime Substances 0.000 title 1
- 239000011521 glass Substances 0.000 claims description 50
- 229910052731 fluorine Inorganic materials 0.000 claims description 40
- 239000011737 fluorine Substances 0.000 claims description 40
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 32
- -1 hydroxyl ions Chemical class 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 description 12
- 238000000605 extraction Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000012445 acidic reagent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910016569 AlF 3 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QSBKIIYQXUPMIR-UHFFFAOYSA-N [F].S(=O)=O Chemical compound [F].S(=O)=O QSBKIIYQXUPMIR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical class [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- OMRRUNXAWXNVFW-UHFFFAOYSA-N fluoridochlorine Chemical class ClF OMRRUNXAWXNVFW-UHFFFAOYSA-N 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 238000007511 glassblowing Methods 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB45361/65A GB1119784A (en) | 1965-10-26 | 1965-10-26 | Process for treating glass surfaces |
DEB0084411 | 1965-11-08 | ||
US545250A US3314772A (en) | 1965-10-26 | 1966-04-26 | Corrosion retarding fluorine treatment of glass surfaces |
US62620367A | 1967-03-27 | 1967-03-27 | |
NL6705012A NL6705012A (US20110009641A1-20110113-C00116.png) | 1965-10-26 | 1967-04-07 | |
AU20177/67A AU432244B2 (en) | 1963-10-22 | 1967-04-11 | Corrosion retarding fluorine treatmetn of glass surfaces |
BE697122 | 1967-04-17 | ||
BE700748 | 1967-06-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE1496068A1 DE1496068A1 (de) | 1969-07-10 |
DE1496068B2 true DE1496068B2 (de) | 1971-03-04 |
Family
ID=27570031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19651496068 Withdrawn DE1496068B2 (de) | 1965-10-26 | 1965-11-08 | Verfahren zur erhoehung der chemischen widerstandsfaehig keit der oberflaeche von alkali kalk silikat glasgegen staenden |
Country Status (5)
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3508895A (en) * | 1963-10-22 | 1970-04-28 | Brockway Glass Co Inc | Thermochemical method of strengthening glass |
US3501340A (en) * | 1967-11-01 | 1970-03-17 | Atomic Energy Commission | Method of cleaning glass and quartz surfaces |
US3709672A (en) * | 1971-01-11 | 1973-01-09 | Brockway Glass Co Inc | Method and apparatus for fluorine surface treatment of glass articles |
DE2557932A1 (de) * | 1975-12-22 | 1977-06-30 | Dynamit Nobel Ag | Verfahren zur herstellung von koernigem quarzglas |
US4260438A (en) * | 1979-10-19 | 1981-04-07 | Brockway Glass Company, Inc. | Preparation of glass container for thermoplastic closure |
US4311247A (en) * | 1979-10-19 | 1982-01-19 | Brockway Glass Company, Inc. | Glass container and thermoplastic closure combination |
US4324601A (en) * | 1979-10-19 | 1982-04-13 | Brockway Glass Company, Inc. | Preparation of glass container for thermoplastic closure |
LU83731A1 (fr) * | 1981-11-04 | 1983-09-01 | Inst Nat Du Verre | Procede de desalcalinisation de la surface interne d'objets en verre creux |
US4421580A (en) * | 1982-01-15 | 1983-12-20 | Brockway Glass Company, Inc. | Preparation of glass container for thermoplastic closure |
EP0172698A1 (en) * | 1984-08-09 | 1986-02-26 | Owens-Illinois, Inc. | Method for increasing the chemical durability of borosilicate glass tubing and articles made therefrom |
US4836954A (en) * | 1987-12-22 | 1989-06-06 | Corning Glass Works | Fluorinated phyllosilicate and method |
US5438129A (en) * | 1993-09-27 | 1995-08-01 | Becton Dickinson And Company | DNA purification by solid phase extraction using partially fluorinated aluminum hydroxide adsorbant |
GB2322855A (en) * | 1997-03-03 | 1998-09-09 | British Tech Group | Introducing fluoride ions into glass |
DE19801861C2 (de) | 1998-01-20 | 2001-10-18 | Schott Glas | Verfahren zum Herstellen eines hohlen, innenbeschichteten Glasformkörpers |
DE19812056C1 (de) * | 1998-03-19 | 1999-10-28 | Schott Glas | Verfahren zum Herstellen eines Glasbehälters |
DE50006669D1 (de) * | 1999-09-15 | 2004-07-08 | Schott Rohrglas Gmbh | Verfahren und Vorrichtung zur Herstellung innenvergüteter Glasrohre |
DE10016108C2 (de) | 2000-03-31 | 2002-09-26 | Schott Glas | Heißformgebungsverfahren und Vorrichtung zur Herstellung eines Glaskörpers sowie dessen Verwendung |
AT412341B (de) * | 2003-06-17 | 2005-01-25 | Stoelzle Oberglas Ag & Co Kg | Verfahren und vorrichtung zur behandlung von ware, beispielsweise hohlware aus glas |
CN101679109B (zh) * | 2007-06-20 | 2011-11-09 | 旭硝子株式会社 | 采用氟化剂的氧化物玻璃的表面处理方法 |
DE102011053635B4 (de) | 2011-09-15 | 2016-01-14 | Schott Ag | Verfahren und Vorrichtung zur Herstellung von innenvergüteten Glasrohren sowie Verwendung hiervon |
CN104203860B (zh) * | 2012-03-26 | 2016-09-28 | 旭硝子株式会社 | 能够减小化学强化时的翘曲的玻璃板 |
DE102014101756B4 (de) | 2014-02-12 | 2016-01-21 | Schott Ag | Verfahren zur Herstellung von Glasrohren mit einer verbesserten chemischen Beständigkeit sowie Verwendung hiervon |
EP2966046A1 (en) * | 2014-07-09 | 2016-01-13 | Linde Aktiengesellschaft | Method of and apparatus for de-alkalization of glass surface of light bulb |
EP3176133A1 (en) * | 2015-12-01 | 2017-06-07 | Linde Aktiengesellschaft | A method of processing a glass |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1760427A (en) * | 1928-10-17 | 1930-05-27 | Westinghouse Lamp Co | Process for preventing weathering of glass |
US1807017A (en) * | 1930-06-17 | 1931-05-26 | Treating glass articles | |
US2154490A (en) * | 1936-12-09 | 1939-04-18 | Owens Illinois Glass Co | Method of treating hollow glass articles |
US2455719A (en) * | 1945-06-01 | 1948-12-07 | Woldemar A Weyl | Glass manufacture |
NL95486C (US20110009641A1-20110113-C00116.png) * | 1956-11-19 | |||
US3249246A (en) * | 1964-10-07 | 1966-05-03 | Ball Brothers Co Inc | Treatment of newly formed glass articles |
-
1965
- 1965-10-26 GB GB45361/65A patent/GB1119784A/en not_active Expired
- 1965-11-08 DE DE19651496068 patent/DE1496068B2/de not_active Withdrawn
-
1966
- 1966-04-26 US US545250A patent/US3314772A/en not_active Expired - Lifetime
-
1967
- 1967-04-07 NL NL6705012A patent/NL6705012A/xx unknown
- 1967-04-17 BE BE697122D patent/BE697122A/xx unknown
- 1967-06-30 BE BE700748D patent/BE700748A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
BE700748A (US20110009641A1-20110113-C00116.png) | 1967-12-01 |
DE1496068A1 (de) | 1969-07-10 |
GB1119784A (en) | 1968-07-10 |
US3314772A (en) | 1967-04-18 |
NL6705012A (US20110009641A1-20110113-C00116.png) | 1968-10-08 |
BE697122A (US20110009641A1-20110113-C00116.png) | 1967-10-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
E77 | Valid patent as to the heymanns-index 1977 | ||
EHJ | Ceased/non-payment of the annual fee |