DE1302264B - - Google Patents
Info
- Publication number
- DE1302264B DE1302264B DE19641302264D DE1302264DA DE1302264B DE 1302264 B DE1302264 B DE 1302264B DE 19641302264 D DE19641302264 D DE 19641302264D DE 1302264D A DE1302264D A DE 1302264DA DE 1302264 B DE1302264 B DE 1302264B
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- iii
- polymerization
- cerium
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/37—Lanthanum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US261875A US3297667A (en) | 1963-02-28 | 1963-02-28 | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1302264B true DE1302264B (US20110009641A1-20110113-C00116.png) | 1970-11-12 |
Family
ID=22995253
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19641542529 Pending DE1542529A1 (de) | 1963-02-28 | 1964-02-26 | Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine |
DE19641302264D Pending DE1302264B (US20110009641A1-20110113-C00116.png) | 1963-02-28 | 1964-02-26 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19641542529 Pending DE1542529A1 (de) | 1963-02-28 | 1964-02-26 | Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine |
Country Status (6)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0011184A1 (de) * | 1978-11-11 | 1980-05-28 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Lösungspolymerisation von konjugierten Dienen |
Families Citing this family (71)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1030932A (en) * | 1963-10-30 | 1966-05-25 | Mitsui Chemical Ind Co Ltd | Method for polymerizing conjugated diolefines |
IT1085663B (it) | 1977-08-01 | 1985-05-28 | Snam Progetti | Procedimento per la polimerizzazione e copolimerizzazione di diolefine e mezzi adatti allo scopo |
IT1151542B (it) * | 1982-04-15 | 1986-12-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
US4544718A (en) * | 1984-09-13 | 1985-10-01 | Phillips Petroleum Company | Olefin polymerization |
US4556647A (en) * | 1984-09-13 | 1985-12-03 | Phillips Petroleum Company | Olefin polymerization |
US4575538A (en) * | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
DE19512116A1 (de) * | 1995-04-04 | 1996-10-10 | Bayer Ag | Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden |
US6001478A (en) * | 1997-08-08 | 1999-12-14 | Union Carbide Chemicals & Plastics Technology Corporation | Resin particle produced by diene polymerization with rare earth and transition metal catalysts |
DE19806931A1 (de) * | 1998-02-19 | 1999-08-26 | Bayer Ag | Verfahren zur Herstellung von Polydienen mit geregelter Mooney-Viskosität |
CN1203096C (zh) | 1999-04-06 | 2005-05-25 | 三井化学株式会社 | 不饱和单体的聚合催化剂、新的过渡金属化合物、使用它们的聚合方法和共聚物 |
DE60041550D1 (de) * | 1999-11-12 | 2009-03-26 | Bridgestone Corp | Modifizierte polymere hergestellt mit katalysator auf basys von lanthaniden |
US6977281B1 (en) * | 1999-11-12 | 2005-12-20 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
ES2412979T3 (es) * | 2000-11-10 | 2013-07-15 | Bridgestone Corporation | Cis-1,4-polibutadieno altamente funcionalizado preparado usando nuevos agentes de funcionalización |
DE10135314A1 (de) | 2001-07-19 | 2003-01-30 | Bayer Ag | Aufarbeitung von Polymersyntheselösungen |
US9226876B2 (en) * | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
US6871751B2 (en) * | 2001-10-19 | 2005-03-29 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, & syringe plungers |
US6699813B2 (en) | 2001-11-07 | 2004-03-02 | Bridgestone Corporation | Lanthanide-based catalyst composition for the manufacture of polydienes |
US6780948B2 (en) | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
US7008899B2 (en) * | 2003-08-11 | 2006-03-07 | Bridgestone Corporation | Lanthanide-based catalyst composition for producing cis-1,4-polydienes |
US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
JP5111101B2 (ja) | 2004-03-02 | 2012-12-26 | 株式会社ブリヂストン | バルク重合プロセス |
DE102004022676A1 (de) * | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
JP4294011B2 (ja) * | 2004-07-21 | 2009-07-08 | 日信工業株式会社 | 炭素系材料及びその製造方法、複合材料の製造方法 |
JP4279220B2 (ja) * | 2004-09-09 | 2009-06-17 | 日信工業株式会社 | 複合材料及びその製造方法、複合金属材料及びその製造方法 |
US7879952B2 (en) * | 2005-12-28 | 2011-02-01 | Bridgestone Corporation | Functionalized polymers |
US7671138B2 (en) * | 2006-05-26 | 2010-03-02 | Bridgestone Corporation | Polymers functionized with hydrobenzamides |
US20080006833A1 (en) * | 2006-06-02 | 2008-01-10 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device and liquid crystal display device |
JP2007323544A (ja) * | 2006-06-05 | 2007-12-13 | Sony Corp | 情報処理システム、情報処理装置、および方法、並びにコンピュータ・プログラム |
US7795354B2 (en) | 2006-06-16 | 2010-09-14 | Georgia-Pacific Chemicals Llc | Formaldehyde free binder |
US7732534B2 (en) * | 2006-08-28 | 2010-06-08 | Bridgestone Corporation | Polymers functionalized with nitro compounds |
US8088868B2 (en) | 2006-12-19 | 2012-01-03 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds |
US7879958B2 (en) * | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
RU2515980C2 (ru) * | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
US8268933B2 (en) * | 2007-12-31 | 2012-09-18 | Bridgestone Corporation | Polymers functionalized with polyimine compounds |
US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
US7807763B2 (en) * | 2008-04-07 | 2010-10-05 | Bridgestone Corporation | Method for bulk polymerization |
US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
US8188195B2 (en) | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
WO2010085622A2 (en) | 2009-01-23 | 2010-07-29 | Bridgestone Corporation | Polymers functionalized with nitrile compounds containing a protected amino group |
KR101692089B1 (ko) | 2009-01-23 | 2017-01-02 | 가부시키가이샤 브리지스톤 | 폴리시아노 화합물로 관능화된 중합체 |
US7902309B2 (en) | 2009-02-23 | 2011-03-08 | Bridgestone Corporation | Process and catalyst system for polydiene production |
FR2944800B1 (fr) * | 2009-04-28 | 2012-10-26 | Michelin Soc Tech | Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues |
US8623975B2 (en) | 2009-06-24 | 2014-01-07 | Bridgestone Corporation | Process for producing polydienes |
KR101762461B1 (ko) | 2009-10-14 | 2017-07-27 | 가부시키가이샤 브리지스톤 | 환식 비환식 디엔 공중합체의 제조 방법 및 고무 조성물 |
US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
WO2012040026A1 (en) | 2010-09-23 | 2012-03-29 | Bridgestone Corporation | Process for producing polydienes |
US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
US9000107B2 (en) | 2011-01-31 | 2015-04-07 | Bridgestone Corporation | Process for producing polydienes |
US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
BR112014011773B1 (pt) | 2011-11-17 | 2020-10-13 | Bridgestone Corporation | processo para a produção de polidienos |
US9353205B2 (en) | 2012-02-27 | 2016-05-31 | Bridgestone Corporation | Processes for the preparation of high-cis polydienes |
US9694629B1 (en) | 2012-02-29 | 2017-07-04 | Carolyn Dry | Self-repairing inflatable articles incorporating an integrated self-repair system |
US8685513B1 (en) | 2012-02-29 | 2014-04-01 | Carolyn M. Dry | Inflatable articles comprising a self-repairing laminate |
EP2825574B1 (en) | 2012-03-14 | 2016-02-24 | Bridgestone Corporation | Process for producing polydienes |
JP6069044B2 (ja) * | 2013-03-12 | 2017-01-25 | 住友ゴム工業株式会社 | ベーストレッド用ゴム組成物及び空気入りタイヤ |
CN105814132A (zh) | 2013-12-03 | 2016-07-27 | 株式会社普利司通 | 用于制备顺式-1,4-聚丁二烯和间同立构1,2-聚丁二烯的共混物的方法 |
TWI522378B (zh) | 2013-12-13 | 2016-02-21 | 奇美實業股份有限公司 | 改質的高順式丁二烯-異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎 |
TWI508979B (zh) | 2013-12-18 | 2015-11-21 | Chi Mei Corp | 改質的高順式異戊二烯聚合物、其製造方法及含有前述聚合物的輪胎 |
WO2016057985A1 (en) | 2014-10-10 | 2016-04-14 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
CN104557994B (zh) * | 2014-12-15 | 2017-02-22 | 黑龙江大学 | 单分子磁体[Dy2(saph)2(NO3)2(CH3OH)4]的制备方法 |
WO2016105931A1 (en) | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Oil-containing rubber compositions and related methods |
US10202474B2 (en) | 2015-09-11 | 2019-02-12 | Bridgestone Corporation | Process for producing polydienes |
US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
CN111630075B (zh) | 2017-12-15 | 2023-04-28 | 株式会社普利司通 | 官能化聚合物、用于制备该官能化聚合物的方法和含有该官能化聚合物的橡胶组合物 |
JP7059378B2 (ja) | 2017-12-30 | 2022-04-25 | 株式会社ブリヂストン | 複数の末端官能化ポリマーを含む組成物 |
US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
US11584808B2 (en) | 2019-12-30 | 2023-02-21 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3094514A (en) * | 1958-02-13 | 1963-06-18 | Goodrich Gulf Chem Inc | Polymerization process for aliphatic, conjugated dienes |
NL120306C (US20110009641A1-20110113-C00116.png) * | 1955-07-29 | 1900-01-01 | ||
GB865248A (en) * | 1956-12-28 | 1961-04-12 | Hoechst Ag | Process for the polymerisation of olefines |
AT213051B (de) * | 1958-04-24 | 1961-01-25 | Montedison Spa | Verfahren zum Polymerisieren von Diolefinen mit wenigstens einer Vinyldoppelbindung |
NL132382C (US20110009641A1-20110113-C00116.png) * | 1959-11-18 | |||
FR1281516A (fr) * | 1959-12-31 | 1962-01-12 | Bridgestone Tire Co Ltd | Procédé de préparation de cis-1, 4 polybutadiène et catalyseur pour sa mise en oeuvre et produits obtenus |
-
1963
- 1963-02-28 US US261875A patent/US3297667A/en not_active Expired - Lifetime
-
1964
- 1964-02-11 GB GB5595/64A patent/GB1061002A/en not_active Expired
- 1964-02-25 BE BE644291D patent/BE644291A/xx unknown
- 1964-02-26 DE DE19641542529 patent/DE1542529A1/de active Pending
- 1964-02-26 FR FR965269A patent/FR1390509A/fr not_active Expired
- 1964-02-26 DE DE19641302264D patent/DE1302264B/de active Pending
- 1964-02-28 NL NL6401996A patent/NL6401996A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0011184A1 (de) * | 1978-11-11 | 1980-05-28 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Lösungspolymerisation von konjugierten Dienen |
Also Published As
Publication number | Publication date |
---|---|
BE644291A (US20110009641A1-20110113-C00116.png) | 1964-06-15 |
NL6401996A (US20110009641A1-20110113-C00116.png) | 1964-08-31 |
US3297667A (en) | 1967-01-10 |
GB1061002A (en) | 1967-03-08 |
DE1542529A1 (de) | 1970-07-23 |
FR1390509A (fr) | 1965-02-26 |
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