DE1273818B - Verfahren zur Herstellung von Olefinpolymerisaten - Google Patents
Verfahren zur Herstellung von OlefinpolymerisatenInfo
- Publication number
- DE1273818B DE1273818B DEB52224A DEB0052224A DE1273818B DE 1273818 B DE1273818 B DE 1273818B DE B52224 A DEB52224 A DE B52224A DE B0052224 A DEB0052224 A DE B0052224A DE 1273818 B DE1273818 B DE 1273818B
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- optionally
- contact
- addition
- organometallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 14
- 230000008569 process Effects 0.000 title claims description 7
- 229920000098 polyolefin Polymers 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- -1 aluminum halides Chemical class 0.000 claims description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 14
- 150000001336 alkenes Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052739 hydrogen Chemical group 0.000 claims description 7
- 239000001257 hydrogen Chemical group 0.000 claims description 7
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002902 organometallic compounds Chemical class 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 description 17
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 3
- GWESVXSMPKAFAS-UHFFFAOYSA-N Isopropylcyclohexane Chemical compound CC(C)C1CCCCC1 GWESVXSMPKAFAS-UHFFFAOYSA-N 0.000 description 2
- 150000001350 alkyl halides Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000012985 polymerization agent Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/906—Comminution of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB52224A DE1273818B (de) | 1959-02-24 | 1959-02-24 | Verfahren zur Herstellung von Olefinpolymerisaten |
| DE19591420236 DE1420236A1 (de) | 1959-02-24 | 1959-03-18 | Verfahren zur Reinigung von Niederdruck-Polyolefinen |
| GB5419/60A GB894804A (en) | 1959-02-24 | 1960-02-16 | Method of polymerizing olefine hydrocarbons and catalyst therefor |
| US16113A US3208954A (en) | 1959-02-24 | 1960-02-16 | Method of preparing titanium trichloride for use as a catalyst in olefin polymerization consisting of grinding titanium trichloride with an aluminum halide |
| FR819296A FR1249050A (fr) | 1959-02-24 | 1960-02-23 | Procédé pour polymériser des hydrocarbures oléfiniques |
| NL248686A NL128619C (en, 2012) | 1959-02-24 | 1960-02-23 | |
| GB7924/60A GB927702A (en) | 1959-02-24 | 1960-03-07 | Purification of polyolefines |
| NL249363A NL249363A (en, 2012) | 1959-02-24 | 1960-03-12 | |
| BE588699A BE588699A (en, 2012) | 1959-02-24 | 1960-03-16 | |
| LU38398A LU38398A1 (en, 2012) | 1959-02-24 | 1960-03-17 | |
| FR821614A FR1256180A (fr) | 1959-02-24 | 1960-03-17 | Procédé pour épurer des polyoléfines basse pression |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB52224A DE1273818B (de) | 1959-02-24 | 1959-02-24 | Verfahren zur Herstellung von Olefinpolymerisaten |
| DEB0052524 | 1959-03-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1273818B true DE1273818B (de) | 1968-07-25 |
Family
ID=25965342
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB52224A Pending DE1273818B (de) | 1959-02-24 | 1959-02-24 | Verfahren zur Herstellung von Olefinpolymerisaten |
| DE19591420236 Pending DE1420236A1 (de) | 1959-02-24 | 1959-03-18 | Verfahren zur Reinigung von Niederdruck-Polyolefinen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19591420236 Pending DE1420236A1 (de) | 1959-02-24 | 1959-03-18 | Verfahren zur Reinigung von Niederdruck-Polyolefinen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3208954A (en, 2012) |
| BE (1) | BE588699A (en, 2012) |
| DE (2) | DE1273818B (en, 2012) |
| FR (1) | FR1249050A (en, 2012) |
| GB (2) | GB894804A (en, 2012) |
| LU (1) | LU38398A1 (en, 2012) |
| NL (2) | NL128619C (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL288068A (en, 2012) * | 1962-01-24 | |||
| GB981375A (en) * | 1962-10-31 | 1965-01-27 | Grace W R & Co | Polymerisation catalysts |
| DE1570525B1 (de) * | 1964-11-02 | 1970-01-22 | Exxon Research Engineering Co | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
| US3468865A (en) * | 1966-12-23 | 1969-09-23 | Owens Illinois Inc | Polymerization and catalysts |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE563350A (en, 2012) * | 1956-12-20 | |||
| BE543941A (en, 2012) * | 1954-12-24 | |||
| FR1163071A (fr) * | 1955-09-26 | 1958-09-22 | Montedison Spa | Procédé de préparation de hauts-polymères cristallins à partir d'oléfines |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2899418A (en) * | 1959-08-11 | Polymerization of olefins by mechanical activation process | ||
| NL98200C (en, 2012) * | 1955-06-16 | |||
| IT557013A (en, 2012) * | 1955-07-29 | 1900-01-01 | ||
| NL113758C (en, 2012) * | 1956-04-16 | |||
| BE557853A (en, 2012) * | 1956-05-28 | |||
| US3010787A (en) * | 1958-03-20 | 1961-11-28 | Exxon Research Engineering Co | Preparation of crystalline titanium chloride |
-
1959
- 1959-02-24 DE DEB52224A patent/DE1273818B/de active Pending
- 1959-03-18 DE DE19591420236 patent/DE1420236A1/de active Pending
-
1960
- 1960-02-16 US US16113A patent/US3208954A/en not_active Expired - Lifetime
- 1960-02-16 GB GB5419/60A patent/GB894804A/en not_active Expired
- 1960-02-23 NL NL248686A patent/NL128619C/xx active
- 1960-02-23 FR FR819296A patent/FR1249050A/fr not_active Expired
- 1960-03-07 GB GB7924/60A patent/GB927702A/en not_active Expired
- 1960-03-12 NL NL249363A patent/NL249363A/xx unknown
- 1960-03-16 BE BE588699A patent/BE588699A/xx unknown
- 1960-03-17 LU LU38398A patent/LU38398A1/xx unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE543941A (en, 2012) * | 1954-12-24 | |||
| FR1163071A (fr) * | 1955-09-26 | 1958-09-22 | Montedison Spa | Procédé de préparation de hauts-polymères cristallins à partir d'oléfines |
| BE563350A (en, 2012) * | 1956-12-20 |
Also Published As
| Publication number | Publication date |
|---|---|
| NL249363A (en, 2012) | 1964-04-10 |
| GB894804A (en) | 1962-04-26 |
| GB927702A (en) | 1963-06-06 |
| US3208954A (en) | 1965-09-28 |
| NL248686A (en, 2012) | 1964-03-10 |
| BE588699A (en, 2012) | 1960-09-16 |
| NL128619C (en, 2012) | 1970-04-15 |
| DE1420236A1 (de) | 1969-01-30 |
| FR1249050A (fr) | 1960-11-14 |
| LU38398A1 (en, 2012) | 1961-09-18 |
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