DE1237071B - Verfahren zur Entfernung kleiner Mengen Kohlenoxid aus wasserstoffhaltigen Gasen durch Methanisierung - Google Patents
Verfahren zur Entfernung kleiner Mengen Kohlenoxid aus wasserstoffhaltigen Gasen durch MethanisierungInfo
- Publication number
- DE1237071B DE1237071B DE1962F0035790 DEF0035790A DE1237071B DE 1237071 B DE1237071 B DE 1237071B DE 1962F0035790 DE1962F0035790 DE 1962F0035790 DE F0035790 A DEF0035790 A DE F0035790A DE 1237071 B DE1237071 B DE 1237071B
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- nickel
- carbon oxide
- catalysts
- methanation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 21
- 239000007789 gas Substances 0.000 title claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 11
- 239000001257 hydrogen Substances 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title description 16
- 229910002090 carbon oxide Inorganic materials 0.000 title description 14
- 239000003054 catalyst Substances 0.000 claims description 32
- 239000007868 Raney catalyst Substances 0.000 claims description 7
- 229910000564 Raney nickel Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 26
- 229910052759 nickel Inorganic materials 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000012634 fragment Substances 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910000951 Aluminide Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001676573 Minium Species 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- -1 are present Chemical compound 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL287795D NL287795A (cs) | 1962-01-17 | ||
| DE1962F0035790 DE1237071B (de) | 1962-01-17 | 1962-01-17 | Verfahren zur Entfernung kleiner Mengen Kohlenoxid aus wasserstoffhaltigen Gasen durch Methanisierung |
| NL287795A NL140563B (nl) | 1962-01-17 | 1963-01-15 | Werkwijze ter verwijdering van kleine hoeveelheden koolmonoxyde uit waterstof-bevattende gassen door methanisering. |
| GB201763A GB979570A (en) | 1962-01-17 | 1963-01-16 | Improvements in or relating to the reduction of carbon monoxide in hydrogen-containing gases |
| JP139963A JPS511675B1 (cs) | 1962-01-17 | 1963-01-17 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1962F0035790 DE1237071B (de) | 1962-01-17 | 1962-01-17 | Verfahren zur Entfernung kleiner Mengen Kohlenoxid aus wasserstoffhaltigen Gasen durch Methanisierung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1237071B true DE1237071B (de) | 1967-03-23 |
Family
ID=7096159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1962F0035790 Pending DE1237071B (de) | 1962-01-17 | 1962-01-17 | Verfahren zur Entfernung kleiner Mengen Kohlenoxid aus wasserstoffhaltigen Gasen durch Methanisierung |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS511675B1 (cs) |
| DE (1) | DE1237071B (cs) |
| GB (1) | GB979570A (cs) |
| NL (2) | NL140563B (cs) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2742837A1 (de) * | 1977-09-23 | 1979-03-29 | Ehrenreich Gmbh & Co Kg A | Axial-kugelgelenk |
| EP1174486A4 (en) * | 1999-03-05 | 2002-07-24 | Osaka Gas Co Ltd | CARBON MONOXIDE SUPPRESSION SYSTEM AND METHOD |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1110147B (de) * | 1955-11-26 | 1961-07-06 | Ruhrchemie Ag | Verfahren zur katalytischen Methanisierung von im wesentlichen nur Kohlendioxyd und Wasserstoff enthaltenden Gasgemischen |
-
0
- NL NL287795D patent/NL287795A/xx unknown
-
1962
- 1962-01-17 DE DE1962F0035790 patent/DE1237071B/de active Pending
-
1963
- 1963-01-15 NL NL287795A patent/NL140563B/xx unknown
- 1963-01-16 GB GB201763A patent/GB979570A/en not_active Expired
- 1963-01-17 JP JP139963A patent/JPS511675B1/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1110147B (de) * | 1955-11-26 | 1961-07-06 | Ruhrchemie Ag | Verfahren zur katalytischen Methanisierung von im wesentlichen nur Kohlendioxyd und Wasserstoff enthaltenden Gasgemischen |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS511675B1 (cs) | 1976-01-19 |
| GB979570A (en) | 1965-01-06 |
| NL140563B (nl) | 1973-12-17 |
| NL287795A (cs) |
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