DE1189710B - Verfahren zum Vernetzen von AEthylenpolymeren - Google Patents
Verfahren zum Vernetzen von AEthylenpolymerenInfo
- Publication number
- DE1189710B DE1189710B DEG30897A DEG0030897A DE1189710B DE 1189710 B DE1189710 B DE 1189710B DE G30897 A DEG30897 A DE G30897A DE G0030897 A DEG0030897 A DE G0030897A DE 1189710 B DE1189710 B DE 1189710B
- Authority
- DE
- Germany
- Prior art keywords
- bis
- polymer
- crosslinking
- peroxide
- peroxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004132 cross linking Methods 0.000 title claims description 37
- 229920000573 polyethylene Polymers 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 17
- 229920000642 polymer Polymers 0.000 claims description 35
- -1 (cumylperoxy) -m-diisopropylbenzene Chemical compound 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 6
- UGJCILYXGIEERK-UHFFFAOYSA-N 2-tert-butylperoxy-1,3-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(C(C)C)=C1OOC(C)(C)C UGJCILYXGIEERK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 description 13
- 150000002978 peroxides Chemical class 0.000 description 12
- 239000000155 melt Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US946A US3118866A (en) | 1960-01-07 | 1960-01-07 | Polyethylene composition and process of crosslinking |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1189710B true DE1189710B (de) | 1965-03-25 |
Family
ID=21693672
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEG30897A Pending DE1189710B (de) | 1960-01-07 | 1960-11-10 | Verfahren zum Vernetzen von AEthylenpolymeren |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US3118866A (enEXAMPLES) |
| DE (1) | DE1189710B (enEXAMPLES) |
| GB (1) | GB897605A (enEXAMPLES) |
| NL (2) | NL259323A (enEXAMPLES) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3764628A (en) * | 1960-01-07 | 1973-10-09 | Grace W R & Co | Tertiary-tertiary bisperoxides |
| US3267066A (en) * | 1960-06-08 | 1966-08-16 | Konink Ind Mij Voorheen Noury | Process for the cross-linking of polyolefins and for the vulcanization of rubber |
| US3402205A (en) * | 1961-09-13 | 1968-09-17 | Hercules Inc | Polyperoxides |
| US3919326A (en) * | 1962-09-13 | 1975-11-11 | Hercules Inc | Polyperoxides |
| US3522225A (en) * | 1969-03-05 | 1970-07-28 | Montedison Spa | Vulcanization of elastomeric olefinic copolymers with organic diperoxides |
| US4267109A (en) * | 1975-06-30 | 1981-05-12 | Argus Chemical Corporation | Cyclic perketals and their use for cross-linking high density polyethylene |
| US4202790A (en) * | 1978-06-26 | 1980-05-13 | Hercules Incorporated | Peroxide blends |
| US4435473A (en) | 1980-04-02 | 1984-03-06 | Ppg Industries, Inc. | Aqueous peroxide emulsion for use with glass fibers |
| US4483784A (en) * | 1980-04-02 | 1984-11-20 | Ppg Industries, Inc. | Aqueous peroxide emulsion for use with glass fibers |
| US4391876A (en) * | 1980-04-02 | 1983-07-05 | Ppg Industries, Inc. | Aqueous peroxide emulsion for use with glass fibers |
| US4440885A (en) * | 1980-04-02 | 1984-04-03 | Ppg Industries, Inc. | Peroxide emulsions and sizing composition containing same |
| IT1197929B (it) * | 1986-10-29 | 1988-12-21 | Ausimont Spa | Composizione perossidiche liquide |
| US5539061A (en) * | 1992-08-31 | 1996-07-23 | Elf Atochem North America, Inc. | Liquid peroxide compositions |
| BR9204279A (pt) * | 1992-08-31 | 1994-03-01 | Atochem North America Elf | Composicao ou mistura liquida de peroxido,processo para preparar uma composicao ou mistura de peroxido,processo para preparar um peroxido liquido,polimeros e copolimeros,processo para reticular polimeros e copolimeros de peroxido reticulaveis termoplasticos e/ou elastomericos,e,composicao util na producao de polietileno reticulado |
| CA2085813C (en) * | 1992-12-18 | 2001-06-12 | Bankim B. Desai | Formulation of high abuse, high shrink barrier bags for meat packaging |
| FR2971510B1 (fr) * | 2011-02-10 | 2013-03-22 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2916481A (en) * | 1959-01-14 | 1959-12-08 | Fmc Corp | Crosslinking of polyethylene with novel peroxides |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA647433A (en) * | 1955-05-18 | 1962-08-28 | General Electric Company | Peroxide cured polyethylene |
| BE547998A (enEXAMPLES) * | 1955-05-24 | |||
| US2813127A (en) * | 1956-04-19 | 1957-11-12 | Shell Dev | Diperoxides |
| US2957030A (en) * | 1958-04-25 | 1960-10-18 | Hercules Powder Co Ltd | Organic peroxides |
-
0
- NL NL123668D patent/NL123668C/xx active
- US US25941D patent/USRE25941E/en not_active Expired
- NL NL259323D patent/NL259323A/xx unknown
-
1960
- 1960-01-07 US US946A patent/US3118866A/en not_active Expired - Lifetime
- 1960-11-10 DE DEG30897A patent/DE1189710B/de active Pending
-
1961
- 1961-01-05 GB GB558/61A patent/GB897605A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2916481A (en) * | 1959-01-14 | 1959-12-08 | Fmc Corp | Crosslinking of polyethylene with novel peroxides |
Also Published As
| Publication number | Publication date |
|---|---|
| US3118866A (en) | 1964-01-21 |
| GB897605A (en) | 1962-05-30 |
| NL259323A (enEXAMPLES) | |
| USRE25941E (en) | 1965-12-14 |
| NL123668C (enEXAMPLES) |
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