DE112014001428T5 - Elektrochemische Abscheidungsprozesse für Halbleiterwafer - Google Patents
Elektrochemische Abscheidungsprozesse für Halbleiterwafer Download PDFInfo
- Publication number
- DE112014001428T5 DE112014001428T5 DE112014001428.1T DE112014001428T DE112014001428T5 DE 112014001428 T5 DE112014001428 T5 DE 112014001428T5 DE 112014001428 T DE112014001428 T DE 112014001428T DE 112014001428 T5 DE112014001428 T5 DE 112014001428T5
- Authority
- DE
- Germany
- Prior art keywords
- bath
- wafer
- voltage
- failure
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 235000012431 wafers Nutrition 0.000 title abstract description 38
- 239000004065 semiconductor Substances 0.000 title description 3
- 238000004070 electrodeposition Methods 0.000 title 1
- 238000009713 electroplating Methods 0.000 claims abstract description 8
- 239000003792 electrolyte Substances 0.000 claims description 15
- 230000010355 oscillation Effects 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 238000012544 monitoring process Methods 0.000 claims 3
- 238000007747 plating Methods 0.000 abstract description 34
- 239000002253 acid Substances 0.000 abstract description 6
- 239000006227 byproduct Substances 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 230000001351 cycling effect Effects 0.000 abstract description 3
- 230000003111 delayed effect Effects 0.000 abstract 1
- OBDVFOBWBHMJDG-UHFFFAOYSA-N 3-mercapto-1-propanesulfonic acid Chemical compound OS(=O)(=O)CCCS OBDVFOBWBHMJDG-UHFFFAOYSA-N 0.000 description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
- 229910052802 copper Inorganic materials 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000012528 membrane Substances 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- 230000005764 inhibitory process Effects 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 238000001514 detection method Methods 0.000 description 5
- -1 copper (I) thiolate Chemical class 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 206010013142 Disinhibition Diseases 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000004377 microelectronic Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000004769 chrono-potentiometry Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 230000028161 membrane depolarization Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000006259 organic additive Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- AIODYXCONSJORM-UHFFFAOYSA-N sodium;3-(3-sulfopropyldisulfanyl)propane-1-sulfonic acid Chemical compound [Na].OS(=O)(=O)CCCSSCCCS(O)(=O)=O AIODYXCONSJORM-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/18—Electroplating using modulated, pulsed or reversing current
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/12—Semiconductors
- C25D7/123—Semiconductors first coated with a seed layer or a conductive layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/288—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
- H01L21/2885—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition using an external electrical current, i.e. electro-deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76898—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics formed through a semiconductor substrate
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Automation & Control Theory (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrodes Of Semiconductors (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/835,870 US20140262794A1 (en) | 2013-03-15 | 2013-03-15 | Electrochemical deposition processes for semiconductor wafers |
US13/835,870 | 2013-03-15 | ||
PCT/US2014/015876 WO2014149245A1 (en) | 2013-03-15 | 2014-02-11 | Electrochemical deposition processes for semiconductor wafers |
Publications (1)
Publication Number | Publication Date |
---|---|
DE112014001428T5 true DE112014001428T5 (de) | 2015-12-24 |
Family
ID=51522611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE112014001428.1T Withdrawn DE112014001428T5 (de) | 2013-03-15 | 2014-02-11 | Elektrochemische Abscheidungsprozesse für Halbleiterwafer |
Country Status (7)
Country | Link |
---|---|
US (1) | US20140262794A1 (ko) |
KR (1) | KR20150132464A (ko) |
CN (1) | CN105027265A (ko) |
DE (1) | DE112014001428T5 (ko) |
SG (1) | SG11201506364YA (ko) |
TW (1) | TW201442149A (ko) |
WO (1) | WO2014149245A1 (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10154598B2 (en) * | 2014-10-13 | 2018-12-11 | Rohm And Haas Electronic Materials Llc | Filling through-holes |
CN107794553B (zh) * | 2017-10-27 | 2019-05-21 | 电子科技大学 | 一种电镀添加剂及其制备方法 |
US10648097B2 (en) * | 2018-03-30 | 2020-05-12 | Lam Research Corporation | Copper electrodeposition on cobalt lined features |
JP7100571B2 (ja) * | 2018-12-13 | 2022-07-13 | 株式会社荏原製作所 | めっき可能な基板の枚数を予測する予測モデルを構築する方法、不具合を引き起こす構成部材を予想するための選択モデルを構築する方法、およびめっき可能な基板の枚数を予測する方法 |
WO2021066412A1 (ko) * | 2019-09-30 | 2021-04-08 | 한국재료연구원 | 도금액에 포함된 첨가제 분해 산물 농도 측정방법{measuring method for concentration of additive breakdown product in plating solution} |
KR102223889B1 (ko) * | 2019-09-30 | 2021-03-09 | 한국재료연구원 | 도금액에 포함된 첨가제 분해 산물 농도 측정 장치 |
KR102445228B1 (ko) * | 2019-09-30 | 2022-09-21 | 한국재료연구원 | 도금액에 포함된 첨가제 분해 산물 농도 측정방법 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100877923B1 (ko) * | 2001-06-07 | 2009-01-12 | 롬 앤드 하스 일렉트로닉 머트어리얼즈, 엘.엘.씨 | 전해 구리 도금법 |
JP4434013B2 (ja) * | 2002-05-07 | 2010-03-17 | ユニバーシティ オブ サザン カリフォルニア | 適合接触マスクめっきを用いてめっき工程を行っている際に堆積の品質を測定する方法および装置 |
US7291253B2 (en) * | 2004-05-04 | 2007-11-06 | Eci Technology, Inc. | Detection of an unstable additive breakdown product in a plating bath |
TWI328622B (en) * | 2005-09-30 | 2010-08-11 | Rohm & Haas Elect Mat | Leveler compounds |
US20070261963A1 (en) * | 2006-02-02 | 2007-11-15 | Advanced Technology Materials, Inc. | Simultaneous inorganic, organic and byproduct analysis in electrochemical deposition solutions |
US8784636B2 (en) * | 2007-12-04 | 2014-07-22 | Ebara Corporation | Plating apparatus and plating method |
US7776741B2 (en) * | 2008-08-18 | 2010-08-17 | Novellus Systems, Inc. | Process for through silicon via filing |
TWI523976B (zh) * | 2010-05-19 | 2016-03-01 | 諾菲勒斯系統公司 | 利用具有雙態抑制劑的電解液之矽穿孔填充 |
US20120024713A1 (en) * | 2010-07-29 | 2012-02-02 | Preisser Robert F | Process for electrodeposition of copper chip to chip, chip to wafer and wafer to wafer interconnects in through-silicon vias (tsv) with heated substrate and cooled electrolyte |
-
2013
- 2013-03-15 US US13/835,870 patent/US20140262794A1/en not_active Abandoned
-
2014
- 2014-02-11 SG SG11201506364YA patent/SG11201506364YA/en unknown
- 2014-02-11 DE DE112014001428.1T patent/DE112014001428T5/de not_active Withdrawn
- 2014-02-11 WO PCT/US2014/015876 patent/WO2014149245A1/en active Application Filing
- 2014-02-11 KR KR1020157029505A patent/KR20150132464A/ko not_active Application Discontinuation
- 2014-02-11 CN CN201480010935.6A patent/CN105027265A/zh active Pending
- 2014-02-17 TW TW103105136A patent/TW201442149A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
WO2014149245A1 (en) | 2014-09-25 |
US20140262794A1 (en) | 2014-09-18 |
SG11201506364YA (en) | 2015-09-29 |
KR20150132464A (ko) | 2015-11-25 |
CN105027265A (zh) | 2015-11-04 |
TW201442149A (zh) | 2014-11-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |