DE1106954B - Gegen die Einwirkung von ultraviolettem Licht stabilisierte Formmasse aus Polyolefinen - Google Patents
Gegen die Einwirkung von ultraviolettem Licht stabilisierte Formmasse aus PolyolefinenInfo
- Publication number
- DE1106954B DE1106954B DED23623A DED0023623A DE1106954B DE 1106954 B DE1106954 B DE 1106954B DE D23623 A DED23623 A DE D23623A DE D0023623 A DED0023623 A DE D0023623A DE 1106954 B DE1106954 B DE 1106954B
- Authority
- DE
- Germany
- Prior art keywords
- ultraviolet light
- weight
- polymer
- resorcinol
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 11
- 150000001875 compounds Chemical class 0.000 title claims description 10
- 238000000465 moulding Methods 0.000 title claims description 6
- 230000000694 effects Effects 0.000 title description 2
- -1 polyethylene Polymers 0.000 claims description 21
- 230000003712 anti-aging effect Effects 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 239000003223 protective agent Substances 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- GOZHNJTXLALKRL-UHFFFAOYSA-N (5-benzoyl-2,4-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1C(=O)C1=CC=CC=C1 GOZHNJTXLALKRL-UHFFFAOYSA-N 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- KZHVQMISPMLZLB-UHFFFAOYSA-N (4-benzoyl-2-chloro-3,5-dihydroxyphenyl)-phenylmethanone Chemical compound C(C1=CC=CC=C1)(=O)C=1C(=C(C(=C(O)C1)C(C1=CC=CC=C1)=O)O)Cl KZHVQMISPMLZLB-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- CJNUOAJVWLECMR-UHFFFAOYSA-N [3-(2-chlorobenzoyl)-2,4-dihydroxyphenyl]-(2-chlorophenyl)methanone Chemical compound ClC1=C(C(=O)C2=C(O)C=CC(=C2O)C(C2=C(C=CC=C2)Cl)=O)C=CC=C1 CJNUOAJVWLECMR-UHFFFAOYSA-N 0.000 description 2
- SVJIRELQERDSEU-UHFFFAOYSA-N [3-(4-chlorobenzoyl)-2,4-dihydroxyphenyl]-(4-chlorophenyl)methanone Chemical compound ClC1=CC=C(C(=O)C2=C(O)C=CC(=C2O)C(C2=CC=C(C=C2)Cl)=O)C=C1 SVJIRELQERDSEU-UHFFFAOYSA-N 0.000 description 2
- DMVOXQPQNTYEKQ-UHFFFAOYSA-N biphenyl-4-amine Chemical group C1=CC(N)=CC=C1C1=CC=CC=C1 DMVOXQPQNTYEKQ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HQEPZWYPQQKFLU-UHFFFAOYSA-N (2,6-dihydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC(O)=C1C(=O)C1=CC=CC=C1 HQEPZWYPQQKFLU-UHFFFAOYSA-N 0.000 description 1
- TVDQSGTUNLQGIC-UHFFFAOYSA-N (3,5-dibenzoyl-2,4-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=C(C(=O)C=2C=CC=CC=2)C(O)=C(C(=O)C=2C=CC=CC=2)C=C1C(=O)C1=CC=CC=C1 TVDQSGTUNLQGIC-UHFFFAOYSA-N 0.000 description 1
- KOKLAVMEUFYRKV-UHFFFAOYSA-N (3-benzoyl-2,4-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=C(C(=O)C=2C=CC=CC=2)C(O)=CC=C1C(=O)C1=CC=CC=C1 KOKLAVMEUFYRKV-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 206010068188 Heat illness Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- BUXMDTLZFAUGSI-UHFFFAOYSA-N [3-(2,4-dichlorobenzoyl)-2,4-dihydroxyphenyl]-(2,4-dichlorophenyl)methanone Chemical compound ClC1=C(C(=O)C2=C(O)C=CC(=C2O)C(C2=C(C=C(C=C2)Cl)Cl)=O)C=CC(=C1)Cl BUXMDTLZFAUGSI-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- SFBGWCMLAKEECF-UHFFFAOYSA-N aniline;propan-2-one Chemical compound CC(C)=O.NC1=CC=CC=C1 SFBGWCMLAKEECF-UHFFFAOYSA-N 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000005002 naphthylamines Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US537043A US2852488A (en) | 1955-09-27 | 1955-09-27 | Stabilized polyolefinic compositions and method for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1106954B true DE1106954B (de) | 1961-05-18 |
Family
ID=24140937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED23623A Pending DE1106954B (de) | 1955-09-27 | 1956-08-21 | Gegen die Einwirkung von ultraviolettem Licht stabilisierte Formmasse aus Polyolefinen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US2852488A (en, 2012) |
| BE (1) | BE550407A (en, 2012) |
| CH (1) | CH357194A (en, 2012) |
| DE (1) | DE1106954B (en, 2012) |
| FR (1) | FR1157854A (en, 2012) |
| GB (1) | GB796003A (en, 2012) |
| NL (2) | NL209723A (en, 2012) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000854A (en) * | 1957-02-20 | 1961-09-19 | Phillips Petroleum Co | Stabilization of polymers |
| US3060149A (en) * | 1957-12-30 | 1962-10-23 | Monsanto Chemicals | Stabilized polymer compositions |
| US3107229A (en) * | 1958-08-07 | 1963-10-15 | Bayer Ag | Process for stabilizing polyolefins |
| NL242155A (en, 2012) * | 1958-08-11 | |||
| US3030333A (en) * | 1958-08-12 | 1962-04-17 | Shell Oil Co | Light stabilized polypropylene |
| DE1191567B (de) * | 1958-09-18 | 1965-04-22 | Du Pont | Formmassen aus Propylenpolymerisaten und einer Stabilisatorkombination |
| BE582206A (en, 2012) * | 1958-09-22 | |||
| US2976260A (en) * | 1958-11-28 | 1961-03-21 | Eastman Kodak Co | Poly-alpha-olefins containing certain 4-alkoxy-2-hydroxybenzophenones and alkylene-bis-phenols |
| US3000856A (en) * | 1959-06-15 | 1961-09-19 | Eastman Kodak Co | Poly-alpha-olefin composition stabilized against ultraviolet light deterioration |
| US3039989A (en) * | 1959-06-18 | 1962-06-19 | Gen Electric | Curable polyethylene containing basic lead carbonate and a peroxide curing agent |
| US3000857A (en) * | 1959-10-26 | 1961-09-19 | Exxon Research Engineering Co | Heat and light stabilization of solid polypropylene |
| US3197526A (en) * | 1961-04-03 | 1965-07-27 | American Cyanamid Co | Premix stabilized polyester molding compositions containing sulfur and a substitutedaryl hydroxide |
| NL136117C (en, 2012) * | 1961-06-29 | |||
| US3296189A (en) * | 1965-07-29 | 1967-01-03 | Warren O Eastman | Chemically cross-linked polyethylene stabilized with polymerized trimethyl quinoline |
| EP0672732B1 (en) * | 1994-03-04 | 1999-06-02 | General Electric Company | Coatings useful for absorbing ultraviolet light |
| US5981073A (en) * | 1997-01-16 | 1999-11-09 | General Electric Company | Compounds based on dibenzoylresorcinol, and related compositions and articles |
| DE202007013400U1 (de) | 2007-08-21 | 2007-11-29 | Mapa Gmbh Gummi- Und Plastikwerke | Trinksauger |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB571943A (en) * | 1943-04-02 | 1945-09-17 | William Baird | Improvements in or relating to polymers of ethylene |
| US2434662A (en) * | 1944-02-03 | 1948-01-20 | Du Pont | Polyethylene stabilized with bis-(hydroxyphenyl) propanes |
| US2448799A (en) * | 1945-11-03 | 1948-09-07 | Du Pont | Ethylene polymer compositions |
| GB618839A (en) * | 1945-11-15 | 1949-02-28 | Du Pont | Improvements in or relating to polymers of ethylene |
| GB652730A (en) * | 1948-12-31 | 1951-05-02 | Pirelli General Cable Works | Improvements in or relating to methods for improving the resistance of polyethylene or polyethylene-containing materials to ultra violet light |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE487959A (en, 2012) * | 1949-09-15 | |||
| GB714772A (en) * | 1951-10-24 | 1954-09-01 | United Kingdom Chemicals Ltd | Improvements in or relating to the treatment of natural and synthetic rubbers |
-
0
- NL NL95971D patent/NL95971C/xx active
- NL NL209723D patent/NL209723A/xx unknown
- BE BE550407D patent/BE550407A/xx unknown
-
1955
- 1955-09-27 US US537043A patent/US2852488A/en not_active Expired - Lifetime
-
1956
- 1956-07-31 GB GB23629/56A patent/GB796003A/en not_active Expired
- 1956-08-17 FR FR1157854D patent/FR1157854A/fr not_active Expired
- 1956-08-21 DE DED23623A patent/DE1106954B/de active Pending
- 1956-09-14 CH CH357194D patent/CH357194A/de unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB571943A (en) * | 1943-04-02 | 1945-09-17 | William Baird | Improvements in or relating to polymers of ethylene |
| US2434662A (en) * | 1944-02-03 | 1948-01-20 | Du Pont | Polyethylene stabilized with bis-(hydroxyphenyl) propanes |
| US2448799A (en) * | 1945-11-03 | 1948-09-07 | Du Pont | Ethylene polymer compositions |
| GB618839A (en) * | 1945-11-15 | 1949-02-28 | Du Pont | Improvements in or relating to polymers of ethylene |
| GB652730A (en) * | 1948-12-31 | 1951-05-02 | Pirelli General Cable Works | Improvements in or relating to methods for improving the resistance of polyethylene or polyethylene-containing materials to ultra violet light |
Also Published As
| Publication number | Publication date |
|---|---|
| NL209723A (en, 2012) | |
| GB796003A (en) | 1958-06-04 |
| FR1157854A (fr) | 1958-06-04 |
| US2852488A (en) | 1958-09-16 |
| CH357194A (de) | 1961-09-30 |
| NL95971C (en, 2012) | |
| BE550407A (en, 2012) |
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