DE102007029428B4 - Elektrisch leitendes Element für eine Brennstoffzelle und Verfahren zu dessen Herstellung - Google Patents
Elektrisch leitendes Element für eine Brennstoffzelle und Verfahren zu dessen Herstellung Download PDFInfo
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- DE102007029428B4 DE102007029428B4 DE200710029428 DE102007029428A DE102007029428B4 DE 102007029428 B4 DE102007029428 B4 DE 102007029428B4 DE 200710029428 DE200710029428 DE 200710029428 DE 102007029428 A DE102007029428 A DE 102007029428A DE 102007029428 B4 DE102007029428 B4 DE 102007029428B4
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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| US7354862B2 (en) * | 2005-04-18 | 2008-04-08 | Intel Corporation | Thin passivation layer on 3D devices |
| WO2008006060A1 (en) * | 2006-07-07 | 2008-01-10 | Drexel University | Electrical insulation of devices with thin layers |
| KR101000697B1 (ko) * | 2008-07-17 | 2010-12-10 | 현대자동차주식회사 | 연료전지용 금속분리판 및 이의 표면층 형성 방법 |
| JP5430093B2 (ja) * | 2008-07-24 | 2014-02-26 | デクセリアルズ株式会社 | 導電性粒子、異方性導電フィルム、及び接合体、並びに、接続方法 |
| US8304143B2 (en) * | 2008-11-25 | 2012-11-06 | GM Global Technology Operations LLC | Conductive and hydrophilic coating for PEMFC bipolar plate |
| US8530100B2 (en) * | 2009-12-10 | 2013-09-10 | Daimler Ag | Method of chemical treatment of fuel cell plate surface to modify wettability of flow field channels |
| CN101859905B (zh) * | 2010-06-23 | 2012-06-20 | 湖南大学 | 一种燃料电池用石墨/树脂复合双极板的制备方法 |
| DE102011007759A1 (de) * | 2011-04-20 | 2012-10-25 | Siemens Aktiengesellschaft | Elektrolysezelle mit einem Blechpaket übereinander gestapelter Bleche mit Ausnehmungen und Verfahren zu deren Herstellung und Betrieb |
| JP6111727B2 (ja) * | 2013-02-20 | 2017-04-12 | 本田技研工業株式会社 | 燃料電池セパレータ |
| CN104470297B (zh) * | 2013-09-22 | 2018-08-07 | 富钰精密组件(昆山)有限公司 | 包覆有硅胶的外壳及使用该外壳的电子装置 |
| JP6670448B2 (ja) * | 2016-08-16 | 2020-03-25 | 株式会社オートネットワーク技術研究所 | 蓄電モジュール |
| CN106935880B (zh) * | 2017-03-08 | 2019-08-30 | 上海电力学院 | 一种质子交换膜燃料电池用铝合金双极板的表面改性方法 |
| KR102429014B1 (ko) * | 2017-08-16 | 2022-08-03 | 현대자동차 주식회사 | 연료전지용 분리판 및 연료전지용 분리판의 코팅 방법 |
| JP2019102339A (ja) * | 2017-12-05 | 2019-06-24 | トヨタ自動車株式会社 | 燃料電池用セパレータの製造方法 |
| DE102017129352A1 (de) * | 2017-12-08 | 2019-06-13 | Ensinger Gmbh | Polymer-basierendes Substrat sowie Verfahren zu dessen Herstellung |
| DE102017129353A1 (de) | 2017-12-08 | 2019-06-13 | Ensinger Gmbh | Polymer-basierendes Substrat sowie Verfahren zu dessen Herstellung |
| US10978752B2 (en) * | 2018-03-19 | 2021-04-13 | Kabushiki Kaisha Toshiba | Secondary battery, battery pack, and vehicle |
| CN110522290A (zh) * | 2018-05-25 | 2019-12-03 | 佛山市顺德区美的电热电器制造有限公司 | 一种铝合金内锅及其制备方法和烹饪器具 |
| US11028242B2 (en) * | 2019-06-03 | 2021-06-08 | Enevate Corporation | Modified silicon particles for silicon-carbon composite electrodes |
| GB2584825B (en) * | 2019-05-08 | 2021-12-01 | Wootzano Ltd | Substrates for electronic skins |
| CN111978864A (zh) * | 2019-05-24 | 2020-11-24 | 电子科技大学 | 一种表面改性剂、其配置方法及其应用 |
| DE102019121670A1 (de) * | 2019-08-12 | 2021-02-18 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Aufbringen einer elektrisch isolierenden Lackschicht auf eine Bipolarplatte für eine Brennstoffzelle |
| DE102019127626A1 (de) * | 2019-10-14 | 2021-04-15 | Elringklinger Ag | Bipolarplatte, Verfahren zur Herstellung und deren Verwendung |
| DE102019217131A1 (de) * | 2019-11-06 | 2021-05-06 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Bauteil-Thermoplast-Verbundes |
| DE102019217128A1 (de) * | 2019-11-06 | 2021-05-06 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Bauteil-Elastomer-Verbundes |
| DE102019217123A1 (de) * | 2019-11-06 | 2021-05-06 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Bauteil-Kunststoff-Verbundes |
| CN111509259A (zh) * | 2020-04-14 | 2020-08-07 | 上海神力科技有限公司 | 一种提高燃料电池极板表面粘合剂稳定性的方法 |
| CN111509260A (zh) * | 2020-04-14 | 2020-08-07 | 上海神力科技有限公司 | 提高燃料电池质子交换膜边框表面粘合剂稳定性的方法 |
| DE102020216104A1 (de) * | 2020-12-17 | 2022-06-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Brennstoffzellenstapel und Verfahren zur Herstellung |
| EP4285427A4 (en) | 2021-01-26 | 2025-03-19 | Electric Hydrogen Co. | Interconnection layers in electrochemical cells |
| CN114334860B (zh) * | 2021-12-28 | 2025-09-02 | 广东思泉新材料股份有限公司 | 一种石墨导热片及其制备、及半导体散热装置 |
| CN114613560B (zh) * | 2022-03-30 | 2024-04-26 | 萍乡华创电气有限公司 | 一种自洁型高强度瓷绝缘子及其制备方法 |
| DE102022108476A1 (de) | 2022-04-07 | 2023-10-12 | Ekpo Fuel Cell Technologies Gmbh | Bipolarplatte, Brennstoffzelle und Verfahren zur Herstellung einer Bipolarplatte |
| DE102024201668A1 (de) | 2024-02-23 | 2025-08-28 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung einer Bipolarplatte |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6372376B1 (en) * | 1999-12-07 | 2002-04-16 | General Motors Corporation | Corrosion resistant PEM fuel cell |
| DE10320765A1 (de) * | 2003-05-09 | 2004-11-25 | Degussa Ag | Mittel zur Beschichtung von Metallen zum Schutz vor Korrosion |
| US20060280992A1 (en) * | 2003-09-10 | 2006-12-14 | Michinari Miyagawa | Fuel cell separator |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4197151A (en) * | 1977-01-31 | 1980-04-08 | Muzik Glenn M | Graphic laminate and method of making same |
| US4356233A (en) * | 1981-05-20 | 1982-10-26 | Minnesota Mining And Manufacturing Company | Primed inorganic substrates overcoated with curable protective compositions |
| US4353947A (en) * | 1981-10-05 | 1982-10-12 | International Harvester Co. | Laminated composite structure and method of manufacture |
| US4579752A (en) * | 1984-10-29 | 1986-04-01 | At&T Bell Laboratories | Enhanced corrosion resistance of metal surfaces |
| US5006248A (en) * | 1989-10-23 | 1991-04-09 | Wisconsin Alumni Research Foundation | Metal oxide porous ceramic membranes with small pore sizes |
| US5139601A (en) * | 1990-04-11 | 1992-08-18 | Lord Corporation | Method for metal bonding |
| US5366787A (en) * | 1991-06-03 | 1994-11-22 | Mcdonnell Douglas Corporation | Panel structure fabrication |
| IT1270878B (it) | 1993-04-30 | 1997-05-13 | Permelec Spa Nora | Migliorata cella elettrochimica utilizzante membrane a scambio ionico e piatti bipolari metallici |
| DE69428253T2 (de) * | 1993-11-12 | 2002-06-27 | Ppg Industries Ohio, Inc. | Haltbare Sputterschicht aus Metalloxid |
| AT404442B (de) | 1994-12-21 | 1998-11-25 | Voest Alpine Ind Anlagen | Stranggiesskokille |
| US5759876A (en) * | 1995-11-01 | 1998-06-02 | United Technologies Corporation | Method of making an antifuse structure using a metal cap layer |
| US5624769A (en) * | 1995-12-22 | 1997-04-29 | General Motors Corporation | Corrosion resistant PEM fuel cell |
| US5830291C1 (en) * | 1996-04-19 | 2001-05-22 | J & L Specialty Steel Inc | Method for producing bright stainless steel |
| US5846038A (en) * | 1996-08-21 | 1998-12-08 | Corrugated Container Corp. | Void filler with multiple intersecting cells |
| US5869141A (en) * | 1996-11-04 | 1999-02-09 | The Boeing Company | Surface pretreatment for sol coating of metals |
| US5750197A (en) * | 1997-01-09 | 1998-05-12 | The University Of Cincinnati | Method of preventing corrosion of metals using silanes |
| US5968630A (en) * | 1997-02-11 | 1999-10-19 | Tenneco Protective Packaging, Inc. | Laminate film-foam flooring composition |
| EP0973609B1 (en) * | 1997-02-26 | 2009-04-15 | Integument Technologies, Inc. | Polymer composites and methods for making and using same |
| US6232386B1 (en) * | 1997-02-26 | 2001-05-15 | Integument Technologies, Inc. | Polymer composites having an oxyhalo surface and methods for making same |
| WO1999014399A1 (en) * | 1997-09-17 | 1999-03-25 | Brent International Plc | Method and compositions for preventing corrosion of metal substrates |
| WO1999020705A1 (en) * | 1997-10-23 | 1999-04-29 | Aar Cornelis P J V D | Rubber to metal bonding by silane coupling agents |
| JP3980166B2 (ja) * | 1998-03-24 | 2007-09-26 | 日新製鋼株式会社 | 低温型燃料電池用セパレータ |
| US6319982B1 (en) * | 1998-09-08 | 2001-11-20 | Ck Witco Corporation | Waterborne silicone adhesives, sealants and coatings |
| JP2000156234A (ja) * | 1998-11-17 | 2000-06-06 | Nichias Corp | 燃料電池用セパレータ構造およびその作成方法 |
| US6133373A (en) * | 1998-12-21 | 2000-10-17 | Lauren International, Inc. | Water-borne fluoroelastomer coatings and cured films therefrom |
| JP3692274B2 (ja) * | 1999-02-09 | 2005-09-07 | 日清紡績株式会社 | 燃料電池用セパレータ及び固体高分子型燃料電池 |
| EP1029893B1 (en) * | 1999-02-16 | 2004-12-01 | Nichias Corporation | Resin composition |
| DE19911073C2 (de) | 1999-03-12 | 2003-04-30 | Rotzler Gmbh Co | Seilfenster für Seilwinden |
| US6878433B2 (en) * | 1999-12-21 | 2005-04-12 | The Procter & Gamble Company | Applications for laminate web |
| JP2001205731A (ja) * | 2000-01-26 | 2001-07-31 | Mitsubishi Plastics Ind Ltd | フッ素樹脂被覆金属複合体及びその製造方法 |
| DE10010669A1 (de) * | 2000-03-04 | 2001-09-06 | Degussa | Verfahren zur Herstellung eines extrusionsbeschichteten Metallgegenstands |
| JP4366872B2 (ja) * | 2000-03-13 | 2009-11-18 | トヨタ自動車株式会社 | 燃料電池用ガスセパレータおよび該燃料電池用セパレータの製造方法並びに燃料電池 |
| US6846528B2 (en) * | 2000-03-24 | 2005-01-25 | Ibiden Co., Ltd. | Translucent decorative board |
| US6773758B2 (en) * | 2000-05-17 | 2004-08-10 | Kaneka Corporation | Primer composition and bonding method |
| US6811913B2 (en) * | 2000-11-15 | 2004-11-02 | Technology Management, Inc. | Multipurpose reversible electrochemical system |
| US7968251B2 (en) * | 2000-11-24 | 2011-06-28 | GM Global Technology Operations LLC | Electrical contact element and bipolar plate |
| US20050095492A1 (en) * | 2001-05-15 | 2005-05-05 | Hydrogenics Corporation | Fuel cell stack |
| US6852439B2 (en) * | 2001-05-15 | 2005-02-08 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
| JPWO2003026052A1 (ja) * | 2001-09-18 | 2005-01-06 | 株式会社フルヤ金属 | 燃料電池用バイポーラ板及びその製造方法 |
| JP2003115321A (ja) * | 2001-10-02 | 2003-04-18 | Honda Motor Co Ltd | 燃料電池スタックの組立方法 |
| US6811918B2 (en) | 2001-11-20 | 2004-11-02 | General Motors Corporation | Low contact resistance PEM fuel cell |
| JP3601029B2 (ja) * | 2002-01-31 | 2004-12-15 | 本田技研工業株式会社 | 燃料電池用金属セパレータおよびその製造方法 |
| WO2003067682A2 (en) * | 2002-02-05 | 2003-08-14 | Gencell Corporation | Silane coated metallic fuel cell components and methods of manufacture |
| JP4469541B2 (ja) * | 2002-03-28 | 2010-05-26 | 三菱樹脂株式会社 | 燃料電池用セパレータ及びその製造方法 |
| US6662503B2 (en) * | 2002-04-04 | 2003-12-16 | Kohler Co. | Bathing enclosure wall panel |
| JP4072371B2 (ja) * | 2002-04-05 | 2008-04-09 | 三菱樹脂株式会社 | 燃料電池用セパレータ |
| JP3990592B2 (ja) * | 2002-04-26 | 2007-10-17 | 本田技研工業株式会社 | 燃料電池用セパレータ |
| JP2004014272A (ja) * | 2002-06-06 | 2004-01-15 | Mitsubishi Plastics Ind Ltd | 燃料電池用セパレータ |
| JP2004099695A (ja) * | 2002-09-06 | 2004-04-02 | Sekisui Film Kk | 塗布防曇剤及び農業用フィルム |
| US20040099845A1 (en) * | 2002-10-10 | 2004-05-27 | Simendinger William H. | Anti-corrosion composition |
| US6887613B2 (en) | 2002-12-04 | 2005-05-03 | General Motors Corporation | Corrosion resistant PEM fuel cell |
| WO2004066425A2 (en) * | 2003-01-24 | 2004-08-05 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
| US6793544B2 (en) | 2003-02-05 | 2004-09-21 | General Motors Corporation | Corrosion resistant fuel cell terminal plates |
| JP4553101B2 (ja) * | 2003-11-25 | 2010-09-29 | トヨタ自動車株式会社 | 燃料電池セパレータ及びその製造方法、並びに該セパレータを用いた燃料電池及び車両 |
| DE102004008784B3 (de) * | 2004-02-23 | 2005-09-15 | Infineon Technologies Ag | Verfahren zur Durchkontaktierung von Feldeffekttransistoren mit einer selbstorganisierten Monolage einer organischen Verbindung als Gatedielektrikum |
| JP4458877B2 (ja) * | 2004-02-25 | 2010-04-28 | 三菱樹脂株式会社 | 燃料電池用セパレータの製造方法 |
| US7820329B2 (en) * | 2004-03-18 | 2010-10-26 | The Procter & Gamble Company | Wafer alkaline cell |
| JP4975262B2 (ja) * | 2005-03-22 | 2012-07-11 | 三菱樹脂株式会社 | 燃料電池用セパレータおよびその製造方法 |
| WO2006126613A1 (ja) * | 2005-05-25 | 2006-11-30 | Hitachi Cable, Ltd. | 燃料電池用セパレータ及びその製造方法 |
| JP4527631B2 (ja) * | 2005-08-22 | 2010-08-18 | 株式会社日立製作所 | 固体高分子電解質型燃料電池の金属セパレータ |
-
2006
- 2006-06-27 US US11/475,499 patent/US8133591B2/en not_active Expired - Fee Related
-
2007
- 2007-06-26 DE DE200710029428 patent/DE102007029428B4/de not_active Expired - Fee Related
- 2007-06-27 CN CN200710146422XA patent/CN101123314B/zh not_active Expired - Fee Related
- 2007-06-27 JP JP2007168387A patent/JP4981542B2/ja not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6372376B1 (en) * | 1999-12-07 | 2002-04-16 | General Motors Corporation | Corrosion resistant PEM fuel cell |
| DE10320765A1 (de) * | 2003-05-09 | 2004-11-25 | Degussa Ag | Mittel zur Beschichtung von Metallen zum Schutz vor Korrosion |
| US20060280992A1 (en) * | 2003-09-10 | 2006-12-14 | Michinari Miyagawa | Fuel cell separator |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102007029428A1 (de) | 2008-01-17 |
| CN101123314A (zh) | 2008-02-13 |
| US8133591B2 (en) | 2012-03-13 |
| US20070298267A1 (en) | 2007-12-27 |
| CN101123314B (zh) | 2012-05-09 |
| JP4981542B2 (ja) | 2012-07-25 |
| JP2008010423A (ja) | 2008-01-17 |
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