DE102005001637A1 - Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien - Google Patents
Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien Download PDFInfo
- Publication number
- DE102005001637A1 DE102005001637A1 DE102005001637A DE102005001637A DE102005001637A1 DE 102005001637 A1 DE102005001637 A1 DE 102005001637A1 DE 102005001637 A DE102005001637 A DE 102005001637A DE 102005001637 A DE102005001637 A DE 102005001637A DE 102005001637 A1 DE102005001637 A1 DE 102005001637A1
- Authority
- DE
- Germany
- Prior art keywords
- block
- copolymer
- weight
- block copolymer
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 229920006300 shrink film Polymers 0.000 title claims abstract description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 title description 8
- 229920001400 block copolymer Polymers 0.000 claims abstract description 55
- 239000000178 monomer Substances 0.000 claims abstract description 26
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- 150000001993 dienes Chemical class 0.000 claims abstract description 12
- 230000009477 glass transition Effects 0.000 claims abstract description 11
- 239000004793 Polystyrene Substances 0.000 claims abstract description 10
- 229920002223 polystyrene Polymers 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 17
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- 239000003999 initiator Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229920006257 Heat-shrinkable film Polymers 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004455 differential thermal analysis Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- ZRLVQFQTCMUIRM-UHFFFAOYSA-N potassium;2-methylbutan-2-olate Chemical compound [K+].CCC(C)(C)[O-] ZRLVQFQTCMUIRM-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005001637A DE102005001637A1 (de) | 2005-01-12 | 2005-01-12 | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
| DE502005006672T DE502005006672D1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
| AT05849213T ATE423168T1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
| CA2591623A CA2591623C (en) | 2005-01-12 | 2005-12-31 | Styrene/butadiene block copolymer mixtures for shrink films |
| JP2007550717A JP4959581B2 (ja) | 2005-01-12 | 2005-12-31 | 収縮フィルム用スチレン／ブタジエンブロックコポリマー混合物 |
| EP05849213A EP1838781B1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
| PL05849213T PL1838781T3 (pl) | 2005-01-12 | 2005-12-31 | Mieszaniny zawierające kopolimer blokowy styren-butadien przeznaczone do folii kurczliwych |
| MX2007008271A MX2007008271A (es) | 2005-01-12 | 2005-12-31 | Mezclas de copolimeros de bloques de estirol/butadieno para peliculas de contraccion. |
| PCT/EP2005/014166 WO2006074819A1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
| BRPI0519833-0A BRPI0519833A2 (pt) | 2005-01-12 | 2005-12-31 | mistura, uso da mesma, e, pelìcula retrátil |
| ES05849213T ES2320365T3 (es) | 2005-01-12 | 2005-12-31 | Mezclas de copolimeros bloque de estireno-butadieno para laminas retractiles. |
| KR1020077018356A KR101235976B1 (ko) | 2005-01-12 | 2005-12-31 | 수축 필름용 스티렌/부타디엔 블록 공중합체 혼합물 |
| CN2005800465239A CN101098929B (zh) | 2005-01-12 | 2005-12-31 | 用于收缩膜的苯乙烯/丁二烯嵌段共聚物混合物 |
| US11/813,742 US9090768B2 (en) | 2005-01-12 | 2005-12-31 | Styrol/butadiene block copolymer mixtures for shrink films |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005001637A DE102005001637A1 (de) | 2005-01-12 | 2005-01-12 | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102005001637A1 true DE102005001637A1 (de) | 2006-07-20 |
Family
ID=36035706
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102005001637A Withdrawn DE102005001637A1 (de) | 2005-01-12 | 2005-01-12 | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
| DE502005006672T Expired - Lifetime DE502005006672D1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE502005006672T Expired - Lifetime DE502005006672D1 (de) | 2005-01-12 | 2005-12-31 | Styrol-butadien-blockcopolymermischungen für schrumpffolien |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9090768B2 (https=) |
| EP (1) | EP1838781B1 (https=) |
| JP (1) | JP4959581B2 (https=) |
| KR (1) | KR101235976B1 (https=) |
| CN (1) | CN101098929B (https=) |
| AT (1) | ATE423168T1 (https=) |
| BR (1) | BRPI0519833A2 (https=) |
| CA (1) | CA2591623C (https=) |
| DE (2) | DE102005001637A1 (https=) |
| ES (1) | ES2320365T3 (https=) |
| MX (1) | MX2007008271A (https=) |
| PL (1) | PL1838781T3 (https=) |
| WO (1) | WO2006074819A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009037115A1 (de) * | 2007-09-14 | 2009-03-26 | Basf Se | Transparente und zähsteife formmassen auf basis von styrol-butadien-blockcopolymermischungen |
| EP2138541A4 (en) * | 2007-03-28 | 2010-05-26 | Denki Kagaku Kogyo Kk | MOLD FOR MD SHRINK AND MD SHRINK FILM |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4911913B2 (ja) * | 2005-04-14 | 2012-04-04 | 旭化成ケミカルズ株式会社 | 共重合体組成物及びそのフィルム |
| US8545953B2 (en) | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
| DK2152770T3 (da) * | 2007-05-23 | 2011-02-07 | Basf Se | Isotactic polystyrene having reactive groups |
| CN101688038B (zh) * | 2007-07-10 | 2013-01-16 | 巴斯夫欧洲公司 | 阻燃性热塑性模塑组合物 |
| US8349963B2 (en) * | 2007-10-16 | 2013-01-08 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a linear block copolymer |
| US7923392B2 (en) | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a branched block copolymer |
| US7923391B2 (en) | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing crosslinked elastic component formed from a pentablock copolymer |
| US8399368B2 (en) | 2007-10-16 | 2013-03-19 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing a crosslinked elastic component formed from a linear block copolymer |
| JP5481757B2 (ja) * | 2008-06-27 | 2014-04-23 | スティロルーション ゲゼルシャフト ミット ベシュレンクテル ハフツング | 収縮包装フィルム用のスチレンブタジエンブロックコポリマー混合物 |
| US8536279B2 (en) | 2008-12-23 | 2013-09-17 | Styrolution GmbH | Phase-separating block or graft copolymers comprising incompatible hard blocks and moulding compositions having a high stiffness |
| EP2547506A1 (de) | 2010-03-17 | 2013-01-23 | Basf Se | Hohlkörper mit verbesserter barrierewirkung |
| US20110226723A1 (en) * | 2010-03-17 | 2011-09-22 | Basf Se | Hollow body with improved barrier action |
| US10773502B2 (en) * | 2014-08-29 | 2020-09-15 | Gunze Limited | Heat-shrinkable multilayer film and heat-shrinkable label |
| WO2018114569A1 (en) | 2016-12-23 | 2018-06-28 | Ineos Styrolution Group Gmbh | Polymer compositions for shrink-wrap films |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG55445A1 (en) * | 1997-01-07 | 1998-12-21 | Denki Kagaku Kogyo Kabushili K | Block copolymer block copolymer compostion and heat shrinkable films made thereof |
| DE19810141A1 (de) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymermischungen aus Styrolpolymeren |
| DE19914075A1 (de) * | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
| DE10158500A1 (de) * | 2001-11-28 | 2003-06-12 | Basf Ag | Transparente Styrol-Butadien-Blockcopolymermischungen |
| JP4530669B2 (ja) * | 2002-04-25 | 2010-08-25 | 旭化成ケミカルズ株式会社 | ブロック共重合体及びその組成物 |
| JP2004018800A (ja) | 2002-06-20 | 2004-01-22 | Denki Kagaku Kogyo Kk | 熱可塑性樹脂シート |
| TWI287031B (en) * | 2003-05-28 | 2007-09-21 | Nippon Catalytic Chem Ind | Aqueous resin composition and its uses |
-
2005
- 2005-01-12 DE DE102005001637A patent/DE102005001637A1/de not_active Withdrawn
- 2005-12-31 WO PCT/EP2005/014166 patent/WO2006074819A1/de not_active Ceased
- 2005-12-31 CN CN2005800465239A patent/CN101098929B/zh not_active Expired - Fee Related
- 2005-12-31 CA CA2591623A patent/CA2591623C/en not_active Expired - Fee Related
- 2005-12-31 EP EP05849213A patent/EP1838781B1/de not_active Expired - Lifetime
- 2005-12-31 AT AT05849213T patent/ATE423168T1/de not_active IP Right Cessation
- 2005-12-31 ES ES05849213T patent/ES2320365T3/es not_active Expired - Lifetime
- 2005-12-31 JP JP2007550717A patent/JP4959581B2/ja not_active Expired - Fee Related
- 2005-12-31 PL PL05849213T patent/PL1838781T3/pl unknown
- 2005-12-31 DE DE502005006672T patent/DE502005006672D1/de not_active Expired - Lifetime
- 2005-12-31 KR KR1020077018356A patent/KR101235976B1/ko not_active Expired - Fee Related
- 2005-12-31 US US11/813,742 patent/US9090768B2/en not_active Expired - Fee Related
- 2005-12-31 BR BRPI0519833-0A patent/BRPI0519833A2/pt active Search and Examination
- 2005-12-31 MX MX2007008271A patent/MX2007008271A/es active IP Right Grant
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2138541A4 (en) * | 2007-03-28 | 2010-05-26 | Denki Kagaku Kogyo Kk | MOLD FOR MD SHRINK AND MD SHRINK FILM |
| EP2138541B1 (en) | 2007-03-28 | 2017-08-02 | Denka Company Limited | Molding material for md shrink and md shrink film |
| WO2009037115A1 (de) * | 2007-09-14 | 2009-03-26 | Basf Se | Transparente und zähsteife formmassen auf basis von styrol-butadien-blockcopolymermischungen |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007008271A (es) | 2007-09-07 |
| US9090768B2 (en) | 2015-07-28 |
| JP4959581B2 (ja) | 2012-06-27 |
| EP1838781B1 (de) | 2009-02-18 |
| KR20070114125A (ko) | 2007-11-29 |
| EP1838781A1 (de) | 2007-10-03 |
| BRPI0519833A2 (pt) | 2009-03-17 |
| CA2591623A1 (en) | 2006-07-20 |
| ES2320365T3 (es) | 2009-05-21 |
| CN101098929B (zh) | 2011-01-19 |
| US20080269414A1 (en) | 2008-10-30 |
| CA2591623C (en) | 2013-05-07 |
| DE502005006672D1 (de) | 2009-04-02 |
| PL1838781T3 (pl) | 2009-07-31 |
| WO2006074819A1 (de) | 2006-07-20 |
| JP2008527123A (ja) | 2008-07-24 |
| ATE423168T1 (de) | 2009-03-15 |
| CN101098929A (zh) | 2008-01-02 |
| KR101235976B1 (ko) | 2013-02-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |