DE102004014621A1 - Organische Verbindungen mit Kern-Schale-Struktur - Google Patents
Organische Verbindungen mit Kern-Schale-Struktur Download PDFInfo
- Publication number
- DE102004014621A1 DE102004014621A1 DE102004014621A DE102004014621A DE102004014621A1 DE 102004014621 A1 DE102004014621 A1 DE 102004014621A1 DE 102004014621 A DE102004014621 A DE 102004014621A DE 102004014621 A DE102004014621 A DE 102004014621A DE 102004014621 A1 DE102004014621 A1 DE 102004014621A1
- Authority
- DE
- Germany
- Prior art keywords
- chains
- compounds according
- core
- linear
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011258 core-shell material Substances 0.000 title claims abstract description 10
- 150000002894 organic compounds Chemical class 0.000 title description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 94
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000004065 semiconductor Substances 0.000 claims abstract description 19
- 238000002360 preparation method Methods 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims description 22
- -1 n-decyl Chemical group 0.000 claims description 20
- 230000037230 mobility Effects 0.000 claims description 16
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- 229920000587 hyperbranched polymer Polymers 0.000 claims description 7
- 238000010653 organometallic reaction Methods 0.000 claims description 7
- 230000005669 field effect Effects 0.000 claims description 6
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical class O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 238000005577 Kumada cross-coupling reaction Methods 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 238000006069 Suzuki reaction reaction Methods 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 230000001268 conjugating effect Effects 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 239000002904 solvent Substances 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000000412 dendrimer Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229920000736 dendritic polymer Polymers 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 229920002098 polyfluorene Polymers 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 3
- 101000801643 Homo sapiens Retinal-specific phospholipid-transporting ATPase ABCA4 Proteins 0.000 description 3
- 102100033617 Retinal-specific phospholipid-transporting ATPase ABCA4 Human genes 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000001246 bromo group Chemical group Br* 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000005442 molecular electronic Methods 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229920000412 polyarylene Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 125000005266 diarylamine group Chemical group 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000006459 hydrosilylation reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- SLIUAWYAILUBJU-UHFFFAOYSA-N pentacene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC=CC=C5C=C4C=C3C=C21 SLIUAWYAILUBJU-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000001226 reprecipitation Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- TWUDEELNCBASSZ-UHFFFAOYSA-N 2-thiophen-2-yl-5-undec-1-enylthiophene Chemical compound S1C(C=CCCCCCCCCC)=CC=C1C1=CC=CS1 TWUDEELNCBASSZ-UHFFFAOYSA-N 0.000 description 1
- IEXFJYKXMZNZPO-UHFFFAOYSA-N 2-thiophen-2-yl-5-undec-10-enylthiophene Chemical compound S1C(CCCCCCCCCC=C)=CC=C1C1=CC=CS1 IEXFJYKXMZNZPO-UHFFFAOYSA-N 0.000 description 1
- QPLXKJDNPNYSNJ-UHFFFAOYSA-N 3-propan-2-yloxydioxaborolane Chemical compound CC(C)OB1CCOO1 QPLXKJDNPNYSNJ-UHFFFAOYSA-N 0.000 description 1
- QZBIZUWOLRZGEJ-UHFFFAOYSA-N 5-bromo-2-hexyl-2-thiophen-2-yl-3h-thiophene Chemical compound C=1C=CSC=1C1(CCCCCC)CC=C(Br)S1 QZBIZUWOLRZGEJ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241000531908 Aramides Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000005620 boronic acid group Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- VDYIOWXZMNKCHN-UHFFFAOYSA-N ethyl(trimethyl)stannane Chemical group CC[Sn](C)(C)C VDYIOWXZMNKCHN-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- FVIZARNDLVOMSU-UHFFFAOYSA-N ginsenoside K Natural products C1CC(C2(CCC3C(C)(C)C(O)CCC3(C)C2CC2O)C)(C)C2C1C(C)(CCC=C(C)C)OC1OC(CO)C(O)C(O)C1O FVIZARNDLVOMSU-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229920000301 poly(3-hexylthiophene-2,5-diyl) polymer Polymers 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920000553 poly(phenylenevinylene) Polymers 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920003257 polycarbosilane Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical group CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 description 1
- CPRPKIMXLHBUGA-UHFFFAOYSA-N triethyltin Chemical group CC[Sn](CC)CC CPRPKIMXLHBUGA-UHFFFAOYSA-N 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000002061 vacuum sublimation Methods 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/002—Dendritic macromolecules
- C08G83/003—Dendrimers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Thin Film Transistor (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Silicon Polymers (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004014621A DE102004014621A1 (de) | 2004-03-25 | 2004-03-25 | Organische Verbindungen mit Kern-Schale-Struktur |
| EP05005344A EP1580217A1 (de) | 2004-03-25 | 2005-03-11 | Makromolekulare Verbindungen mit Kern-Schale-Struktur |
| MXPA05003055A MXPA05003055A (es) | 2004-03-25 | 2005-03-18 | Compuestos macromoleculares con estructura de nucleo-corteza. |
| CA002502085A CA2502085A1 (en) | 2004-03-25 | 2005-03-22 | Macromolecular compounds with a core-shell structure |
| KR1020050024394A KR101196112B1 (ko) | 2004-03-25 | 2005-03-24 | 코어-셀 구조를 갖는 거대분자 화합물 |
| RU2005108309/04A RU2397995C9 (ru) | 2004-03-25 | 2005-03-24 | Макромолекулярные соединения с ядерно-оболочечной структурой, способы их получения, их применение в качестве полупроводников в электронном функциональном элементе и в качестве электронного функционального элемента |
| US11/088,434 US7402651B2 (en) | 2004-03-25 | 2005-03-24 | Macromolecular compounds with a core-shell structure |
| TW094109033A TWI368626B (en) | 2004-03-25 | 2005-03-24 | Macromolecular compounds with a core-shell structure |
| CN2005100627625A CN1673247B (zh) | 2004-03-25 | 2005-03-25 | 具有芯-壳结构的高分子化合物 |
| JP2005088777A JP4920194B2 (ja) | 2004-03-25 | 2005-03-25 | コア−シェル構造を有する高分子化合物 |
| HK06103633.1A HK1083512B (en) | 2004-03-25 | 2006-03-22 | Macromolecular compounds with a core-shell structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004014621A DE102004014621A1 (de) | 2004-03-25 | 2004-03-25 | Organische Verbindungen mit Kern-Schale-Struktur |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102004014621A1 true DE102004014621A1 (de) | 2005-10-13 |
Family
ID=34854048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102004014621A Withdrawn DE102004014621A1 (de) | 2004-03-25 | 2004-03-25 | Organische Verbindungen mit Kern-Schale-Struktur |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7402651B2 (enExample) |
| EP (1) | EP1580217A1 (enExample) |
| JP (1) | JP4920194B2 (enExample) |
| KR (1) | KR101196112B1 (enExample) |
| CN (1) | CN1673247B (enExample) |
| CA (1) | CA2502085A1 (enExample) |
| DE (1) | DE102004014621A1 (enExample) |
| MX (1) | MXPA05003055A (enExample) |
| RU (1) | RU2397995C9 (enExample) |
| TW (1) | TWI368626B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2054015A1 (de) | 2006-09-06 | 2009-05-06 | Henkel AG & Co. KGaA | Mittel, enthaltend biochinone und betaine |
| DE102011009415A1 (de) | 2011-01-25 | 2012-07-26 | Heraeus Precious Metals Gmbh & Co. Kg | Sternförmige Verbindungen für organische Solarzellen |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7498084B2 (en) * | 2001-09-05 | 2009-03-03 | Sharp Kabushiki Kaisha | Macromolecular structure, functional device having the same, transistor, and display apparatus using the same |
| KR20080096585A (ko) * | 2006-02-16 | 2008-10-30 | 유니버시티 오브 코넥티컷 | 전구체 중합체로부터 유도된 전도성 중합체, 그것의 제조 방법 및 용도 |
| DE102006043039A1 (de) * | 2006-09-14 | 2008-03-27 | H.C. Starck Gmbh | Halbleiterschichten bildende Mischungen von organischen Verbindungen |
| DE102008014158A1 (de) * | 2008-03-14 | 2009-09-17 | H.C. Starck Gmbh | Neue makromolekulare Verbindungen aufweisend eine Kern-Schale-Struktur zur Verwendung als Halbleiter |
| EP2459614B1 (en) * | 2008-09-19 | 2013-06-12 | Merck Patent GmbH | Polymers derived from benzobis(silolothiophene) and their use as organic semiconductors |
| RU2477472C2 (ru) * | 2010-12-24 | 2013-03-10 | Федеральное государственное бюджетное учреждение науки Институт биохимии и физиологии микроорганизмов им. Г.К. Скрябина Российской академии наук (ИБФМ РАН) | Способ определения эффективности биодеградации углеводородов нефти в нативных и загрязненных почвах |
| JP7306313B2 (ja) * | 2020-04-21 | 2023-07-11 | 信越化学工業株式会社 | （ポリ）チオフェン－（ポリ）シロキサンブロックコポリマー及びその製造方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6025462A (en) * | 1997-03-06 | 2000-02-15 | Eic Laboratories, Inc. | Reflective and conductive star polymers |
| DE19711650C1 (de) * | 1997-03-20 | 1998-06-10 | Bayer Ag | Verfahren zur Herstellung SiOH-funktioneller Carbosilan-Dendrimere |
| GB0002936D0 (en) * | 2000-02-09 | 2000-03-29 | Isis Innovation | Improved dendrimers |
| DE60125202T2 (de) | 2000-09-26 | 2007-11-08 | Cambridge Display Technology Ltd. | Polymere und ihre verwendungen |
| US6384172B1 (en) * | 2001-01-02 | 2002-05-07 | Michigan Molecular Institute | Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof |
| DE60144014D1 (de) * | 2001-07-19 | 2011-03-24 | Max Planck Gesellschaft | Chemische Sensoren aus Nanopartikel-Dendrimer-Komposit-Materialen |
| JP2003243660A (ja) * | 2002-02-13 | 2003-08-29 | Fuji Photo Film Co Ltd | 電界効果型トランジスタ |
| JP2004006782A (ja) * | 2002-04-11 | 2004-01-08 | Konica Minolta Holdings Inc | 有機半導体材料、これを用いた有機トランジスタ、電界効果トランジスタ及びスイッチング素子 |
| JP2003324203A (ja) * | 2002-04-30 | 2003-11-14 | Sharp Corp | 静電誘導型トランジスタ |
| JP4277948B2 (ja) * | 2002-07-18 | 2009-06-10 | 東洋合成工業株式会社 | デンドリマーの製造方法及び化合物 |
| JP4277947B2 (ja) * | 2002-07-18 | 2009-06-10 | シャープ株式会社 | デンドリマー及びこれを用いた電子デバイス素子 |
| KR100759818B1 (ko) * | 2002-07-18 | 2007-09-18 | 도요 고세이 고교 가부시키가이샤 | 덴드리머의 제조방법 및 빌딩블록 화합물 및 티오펜계화합물의 제조방법 |
| ATE393186T1 (de) | 2002-09-13 | 2008-05-15 | Starck H C Gmbh | Organische verbindungen mit kern-schale-struktur |
| JP2005075962A (ja) * | 2003-09-02 | 2005-03-24 | Sharp Corp | 超分岐高分子、超分岐高分子組成物、超分岐高分子構造体および電子デバイス素子 |
-
2004
- 2004-03-25 DE DE102004014621A patent/DE102004014621A1/de not_active Withdrawn
-
2005
- 2005-03-11 EP EP05005344A patent/EP1580217A1/de not_active Withdrawn
- 2005-03-18 MX MXPA05003055A patent/MXPA05003055A/es active IP Right Grant
- 2005-03-22 CA CA002502085A patent/CA2502085A1/en not_active Abandoned
- 2005-03-24 TW TW094109033A patent/TWI368626B/zh not_active IP Right Cessation
- 2005-03-24 RU RU2005108309/04A patent/RU2397995C9/ru not_active IP Right Cessation
- 2005-03-24 KR KR1020050024394A patent/KR101196112B1/ko not_active Expired - Fee Related
- 2005-03-24 US US11/088,434 patent/US7402651B2/en not_active Expired - Fee Related
- 2005-03-25 CN CN2005100627625A patent/CN1673247B/zh not_active Expired - Fee Related
- 2005-03-25 JP JP2005088777A patent/JP4920194B2/ja not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2054015A1 (de) | 2006-09-06 | 2009-05-06 | Henkel AG & Co. KGaA | Mittel, enthaltend biochinone und betaine |
| DE102011009415A1 (de) | 2011-01-25 | 2012-07-26 | Heraeus Precious Metals Gmbh & Co. Kg | Sternförmige Verbindungen für organische Solarzellen |
| WO2012100908A1 (en) | 2011-01-25 | 2012-08-02 | Heraeus Precious Metals Gmbh & Co. Kg | Star-shaped compounds for organic solar cells |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200613374A (en) | 2006-05-01 |
| KR20060044667A (ko) | 2006-05-16 |
| RU2397995C9 (ru) | 2011-06-20 |
| CN1673247B (zh) | 2010-10-13 |
| JP2005272846A (ja) | 2005-10-06 |
| MXPA05003055A (es) | 2005-09-28 |
| JP4920194B2 (ja) | 2012-04-18 |
| US20050215760A1 (en) | 2005-09-29 |
| CA2502085A1 (en) | 2005-09-25 |
| US7402651B2 (en) | 2008-07-22 |
| RU2397995C2 (ru) | 2010-08-27 |
| KR101196112B1 (ko) | 2012-10-30 |
| EP1580217A1 (de) | 2005-09-28 |
| HK1083512A1 (en) | 2006-07-07 |
| RU2005108309A (ru) | 2006-09-10 |
| TWI368626B (en) | 2012-07-21 |
| CN1673247A (zh) | 2005-09-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE112009003593T5 (de) | Organische Halbleiter | |
| EP1913797A1 (de) | Elektrolumineszierende polymere und ihre verwendung | |
| EP1398341B1 (de) | Organische Verbindungen mit Kern-Schale-Struktur | |
| DE102011089351A1 (de) | Halbleiterzusammensetzung | |
| DE102004014621A1 (de) | Organische Verbindungen mit Kern-Schale-Struktur | |
| EP1605007B1 (en) | Processes to prepare oligomeric thiophene compounds | |
| DE112006002830T5 (de) | Verfahren zur Herstellung regioregulärer Polymere | |
| EP2066722A2 (de) | Halbleiterschicht bildende oligomere verbindungen | |
| EP2252648A1 (de) | Neue makromolekulare verbindungen aufweisend eine kern-schale-struktur zur verwendung als halbleiter | |
| DE112006002392T5 (de) | Polymer, umfassend eine Einheit, umfassend einen Fluorcyclopentanring kondensiert mit einem aromatischen Ring, und organischer Dünnfilm und organisches Dünnfilmelement, die es beide umfassen | |
| DE10152939B4 (de) | Polythiophene mit hohen Ladungsträgerbeweglichkeiten | |
| DE112006002690T5 (de) | Regioreguläre Polyselenophene | |
| DE10305945A1 (de) | Organische Verbindungen mit Kern-Schale-Struktur | |
| HK1083512B (en) | Macromolecular compounds with a core-shell structure | |
| KR101855404B1 (ko) | 유기반도체 화합물 및 그를 포함하는 유기전자소자 | |
| Reinold | From polythiophenes to functional materials: development of complex architectures through polymer analogous modifications | |
| WO2003106529A1 (de) | Diaryl-doppelbindungssubstituierte poly(arylenvinylenarylene) als halbleitermaterial für organische feld-effekt-transistoren (ofets), herstellung des materials sowie seine verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |