CS209536B2 - Catalytic system for polymerization and copolymerization of diolefins - Google Patents

Catalytic system for polymerization and copolymerization of diolefins Download PDF

Info

Publication number
CS209536B2
CS209536B2 CS781135A CS113580A CS209536B2 CS 209536 B2 CS209536 B2 CS 209536B2 CS 781135 A CS781135 A CS 781135A CS 113580 A CS113580 A CS 113580A CS 209536 B2 CS209536 B2 CS 209536B2
Authority
CS
Czechoslovakia
Prior art keywords
polymerization
halogen
component
mmol
compound
Prior art date
Application number
CS781135A
Other languages
Czech (cs)
English (en)
Inventor
Ugo Pedretti
Gabriele Lugli
Sergio Poggio
Alessandro Mazzei
Original Assignee
Anic Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic Spa filed Critical Anic Spa
Publication of CS209536B2 publication Critical patent/CS209536B2/cs

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
CS781135A 1977-08-01 1978-08-01 Catalytic system for polymerization and copolymerization of diolefins CS209536B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2637777A IT1085663B (it) 1977-08-01 1977-08-01 Procedimento per la polimerizzazione e copolimerizzazione di diolefine e mezzi adatti allo scopo

Publications (1)

Publication Number Publication Date
CS209536B2 true CS209536B2 (en) 1981-12-31

Family

ID=11219355

Family Applications (2)

Application Number Title Priority Date Filing Date
CS781135A CS209536B2 (en) 1977-08-01 1978-08-01 Catalytic system for polymerization and copolymerization of diolefins
CS785060A CS209535B2 (en) 1977-08-01 1978-08-01 Method of polymerization and copolymerization of diolefins

Family Applications After (1)

Application Number Title Priority Date Filing Date
CS785060A CS209535B2 (en) 1977-08-01 1978-08-01 Method of polymerization and copolymerization of diolefins

Country Status (24)

Country Link
US (1) US4429089A (pt)
JP (1) JPS5440890A (pt)
AR (1) AR223650A1 (pt)
AU (1) AU519419B2 (pt)
BE (1) BE869438A (pt)
BR (1) BR7804950A (pt)
CA (1) CA1113915A (pt)
CS (2) CS209536B2 (pt)
DD (1) DD137592A5 (pt)
DE (1) DE2833721C2 (pt)
EG (1) EG13467A (pt)
ES (1) ES472634A1 (pt)
FR (1) FR2399447A1 (pt)
GB (1) GB2002003B (pt)
IE (1) IE47219B1 (pt)
IN (1) IN150161B (pt)
IT (1) IT1085663B (pt)
MX (1) MX151421A (pt)
NL (1) NL186449C (pt)
PL (1) PL208756A1 (pt)
PT (1) PT68360A (pt)
TR (1) TR20144A (pt)
YU (1) YU39510B (pt)
ZA (1) ZA784294B (pt)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1223396A (en) * 1981-06-29 1987-06-23 Tooru Shibata Process for producing conjugated diene polymer
IT1140452B (it) * 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
CA1212932A (en) * 1982-04-01 1986-10-21 Derek K. Jenkins Polymerisation of conjugated dienes
JPS5945337A (ja) * 1982-09-07 1984-03-14 Japan Synthetic Rubber Co Ltd 生強度の改良されたポリブタジエンゴム組成物
JPS6084338A (ja) * 1983-10-14 1985-05-13 Japan Synthetic Rubber Co Ltd 新規なジエン系ポリマ−組成物
JPS60108410A (ja) * 1983-11-18 1985-06-13 Japan Synthetic Rubber Co Ltd 熱可塑性樹脂の製造方法
US4791086A (en) * 1984-01-30 1988-12-13 Phillips Petroleum Company Olefin polymerization
US4699962A (en) * 1984-01-30 1987-10-13 Phillips Petroleum Company Olefin polymerization
US4575538A (en) * 1984-12-20 1986-03-11 Phillips Petroleum Company Olefin polymerization
JPS61128971U (pt) * 1985-01-31 1986-08-13
IT1186747B (it) * 1985-07-01 1987-12-16 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene
EP0304088B1 (en) * 1987-08-19 1993-01-27 Asahi Kasei Kogyo Kabushiki Kaisha A prepolymerization process for producing a conjugated diene compound prepolymer solution
US5238891A (en) * 1989-06-15 1993-08-24 Phillips Petroleum Company Olefin polymerization catalyst and process
JPH07104118B2 (ja) * 1990-12-19 1995-11-13 ダイキンプラント株式会社 クロスフロー型クーリングタワーにおけるファンモータの起動保護機構
US5403904A (en) * 1993-05-27 1995-04-04 Amoco Corporation Process for preparation of telechelic difunctional unsaturated oligomers or polymers by acyclic olefin metathesis
US5519101A (en) * 1993-05-27 1996-05-21 Amoco Corporation Process for preparation of unsaturated oligomers or polymers by acyclic olefin metathesis
US5512635A (en) * 1993-05-27 1996-04-30 Amoco Corporation Process for preparing linear monofunctional and telechelic difunctional polymers and compositions obtained thereby
US5405815A (en) * 1993-06-17 1995-04-11 The Goodyear Tire & Rubber Company Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
US5914377A (en) * 1995-04-04 1999-06-22 Bayer Ag Method for the production of diene rubbers in the gas phase
US6018007A (en) 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
DE19746266A1 (de) 1997-10-20 1999-04-22 Bayer Ag Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen
US6197713B1 (en) 1997-12-19 2001-03-06 Bridgestone Corporation Use of Lewis acids for the breakdown of gelatinous rare earth compounds in hydrocarbon solutions
US6441107B1 (en) * 1998-12-18 2002-08-27 Union Carbide Chemicals & Plastics Technology Corporation Molecular weight control of gas phase polymerized polybutadiene when using a rare earth catalyst
US6767927B1 (en) * 1999-04-26 2004-07-27 Rhodia Rare Earths Inc. Synthesis of stable solutions of rare earth tris (organophosphate) in hydrocarbon solvents
DE19919870A1 (de) * 1999-04-30 2000-11-02 Bayer Ag Verfahren zur Suspensions-Polymerisation von konjugierten Dienen
DE10115106A1 (de) * 2001-03-27 2002-10-10 Bayer Ag Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren
US9226876B2 (en) * 2001-10-19 2016-01-05 The Goodyear Tire & Rubber Company Rubber for baby bottle nipples, pacifiers, and syringe plungers
US6699813B2 (en) 2001-11-07 2004-03-02 Bridgestone Corporation Lanthanide-based catalyst composition for the manufacture of polydienes
US6780948B2 (en) 2002-03-28 2004-08-24 The Goodyear Tire & Rubber Company Synthesis of polyisoprene with neodymium catalyst
US7586548B2 (en) * 2002-12-02 2009-09-08 Sony Corporation Stand-by power supply shutdown at power on
KR100553249B1 (ko) 2003-05-15 2006-02-20 금호석유화학 주식회사 고 1,4-시스 폴리부타디엔-폴리우레탄 공중합체 및 그 제조방법
JP4467258B2 (ja) 2003-06-25 2010-05-26 株式会社ブリヂストン ブタジエン系重合体及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ
JP4651921B2 (ja) * 2003-07-17 2011-03-16 株式会社ブリヂストン 空気入りタイヤ
US7008899B2 (en) * 2003-08-11 2006-03-07 Bridgestone Corporation Lanthanide-based catalyst composition for producing cis-1,4-polydienes
US7094849B2 (en) * 2003-12-15 2006-08-22 Bridgestone Corporation Bulk polymerization process for producing polydienes
US7091150B2 (en) * 2003-12-19 2006-08-15 The Goodyear Tire & Rubber Company Synthetic polyisoprene rubber
WO2007021215A1 (en) 2005-08-12 2007-02-22 Otkrytoe Aktsionernoe Obschestvo 'efremovsky Zavod Sinteticheskogo Kauchuka' Method for producing cis-1,4 diene rubber, catalyst, rubber
RU2415875C2 (ru) 2005-12-05 2011-04-10 Джей Эс Эр КОРПОРЕЙШН Способ получения конъюгированного диенового полимера, конъюгированный диеновый полимер и каучуковая композиция
CN101600736B (zh) * 2006-12-27 2012-11-07 Jsr株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物
WO2008156788A2 (en) 2007-06-18 2008-12-24 Bridgestone Corporation Polymers functionalized with halosilanes containing an amino group
KR100970767B1 (ko) 2007-12-12 2010-07-16 금호석유화학 주식회사 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
US7825201B2 (en) * 2007-12-31 2010-11-02 Bridgestone Corporation Process for producing polydienes
US8623975B2 (en) 2009-06-24 2014-01-07 Bridgestone Corporation Process for producing polydienes
KR101194401B1 (ko) * 2009-12-09 2012-10-25 금호석유화학 주식회사 골프공 코어의 제조용 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔
JP6204646B2 (ja) * 2012-09-19 2017-09-27 旭化成株式会社 変性共役ジエン系重合体の製造方法及び変性共役ジエン系重合体、並びに変性共役ジエン系重合体組成物
TWI639502B (zh) * 2013-03-13 2018-11-01 日商宇部興產股份有限公司 共軛二烯聚合用觸媒及使用該觸媒之共軛二烯聚合物、改質共軛二烯聚合物、其等之製造方法、輪胎用橡膠組成物、及橡膠皮帶用橡膠組成物
US11767388B1 (en) 2019-09-18 2023-09-26 The Goodyear Tire & Rubber Company Silicon-functionalized rubber
EP3838932B1 (en) 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB865248A (en) 1956-12-28 1961-04-12 Hoechst Ag Process for the polymerisation of olefines
US3394156A (en) 1960-03-07 1968-07-23 Monsanto Co Titanium amide borohydrides and chlorides
US3297667A (en) * 1963-02-28 1967-01-10 Union Carbide Corp Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes
DE1257431B (de) * 1965-02-03 1967-12-28 Snam Spa Verfahren zur Polymerisation von Butadien
US3541063A (en) * 1967-12-29 1970-11-17 Goodyear Tire & Rubber Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds
US3641188A (en) * 1968-05-08 1972-02-08 Atlantic Richfield Co Process for polymerizing olefins
GB1294725A (en) * 1969-03-27 1972-11-01 Goodyear Tire & Rubber Polymerization of diolefins
FR2071811A5 (pt) 1969-11-07 1971-09-17 Snam Progetti
US3657205A (en) * 1970-09-03 1972-04-18 Goodyear Tire & Rubber Preparation of high 1 4-polypentadienes
US3676411A (en) 1970-12-17 1972-07-11 Goodyear Tire & Rubber Ternary catalyst systems for the polymerization of conjugated diolefins
IT971308B (it) 1972-11-29 1974-04-30 Snam Progetti Processo per la polimerizzazion e di composti insaturi

Also Published As

Publication number Publication date
CS209535B2 (en) 1981-12-31
IE47219B1 (en) 1984-01-25
NL7808104A (nl) 1979-02-05
FR2399447B1 (pt) 1982-06-18
TR20144A (tr) 1980-09-26
BR7804950A (pt) 1979-03-13
MX151421A (es) 1984-11-15
DD137592A5 (de) 1979-09-12
PT68360A (en) 1978-08-01
GB2002003B (en) 1982-02-24
JPS6213363B2 (pt) 1987-03-26
DE2833721C2 (de) 1985-02-21
YU39510B (en) 1984-12-31
AU519419B2 (en) 1981-12-03
IE781551L (en) 1979-02-01
ES472634A1 (es) 1979-02-16
BE869438A (fr) 1979-02-01
AR223650A1 (es) 1981-09-15
FR2399447A1 (fr) 1979-03-02
GB2002003A (en) 1979-02-14
CA1113915A (en) 1981-12-08
EG13467A (en) 1981-12-31
DE2833721A1 (de) 1979-02-08
JPS5440890A (en) 1979-03-31
PL208756A1 (pl) 1979-03-12
IN150161B (pt) 1982-08-07
IT1085663B (it) 1985-05-28
YU185378A (en) 1982-10-31
US4429089A (en) 1984-01-31
NL186449B (nl) 1990-07-02
NL186449C (nl) 1990-12-03
AU3831978A (en) 1980-01-31
ZA784294B (en) 1979-07-25

Similar Documents

Publication Publication Date Title
CS209536B2 (en) Catalytic system for polymerization and copolymerization of diolefins
US4444903A (en) Process for polymerizing conjugate diolefins, and means suitable for this purpose
JP4339434B2 (ja) ルイス酸を使用する非粘稠な希土類化合物の炭化水素中溶液及びその製造方法
RU2515980C2 (ru) Способ получения полидиенов полимеризацией в объеме
US4663405A (en) Molecular weight modifier for use with lanthanide and actinide catalysts
KR20010024933A (ko) 지연 음이온 중합 방법
JP4208346B2 (ja) 共役ジエンの重合における有機亜鉛及び希土類触媒系
EP1055659B1 (en) Process for the preparation of neodymium neodecanoate and use thereof as catalytic component for the solution polymerisation of butadiene
US4525549A (en) Process for preparing conjugate diolefins, and means suitable for this purpose
KR100292790B1 (ko) 란타노이드계의 할로겐화 착염과 불포화 단량체의 중합반응에서 이들의 용도
WO2020160000A1 (en) Method for producing polydienes with reduced cold flow
RU2345092C1 (ru) Способ получения катализатора полимеризации бутадиена и сополимеризации бутадиена с изопреном
EP0344888B1 (en) Liquid telechelic polymers having high 1,4-diene structure
GB2245576A (en) A method of preparing homopolymers of conjugate dienes and copolymers of conjugate dienes with other dienes or vinyl aromatic compounds
JP3992365B2 (ja) クロロプレン系重合体の製造方法及びその重合触媒
RU2432365C1 (ru) Способ получения катализатора (со)полимеризации бутадиена
RU2267355C2 (ru) Способ получения катализатора полимеризации бутадиена и сополимеризации бутадиена с сопряженными диенами
CN115246913A (zh) 一种立构嵌段聚异戊二烯及其制备方法
SU297192A1 (ru) Способ получения карбоцепных сополимеров
WO2021133819A1 (en) Polymerization processes for the production of cis-1,4-polydienes
CN115210272A (zh) 用于生产改性聚二烯的方法、实施方案
WO2021133818A1 (en) Polymerization processes for the production of cis-1,4-polydienes
PL116837B1 (en) Catalytic system for polymerization or copolymerizationof diolefines
RU2268894C1 (ru) Способ получения катализатора полимеризации и сополимеризации сопряженных диеновых углеродов
MXPA00007698A (en) Method for retarded anionic polymerization