CO6950487A2 - Transposición catalítica de beckmann de fase de gas líquido de oximas para producir lactamas - Google Patents

Transposición catalítica de beckmann de fase de gas líquido de oximas para producir lactamas

Info

Publication number
CO6950487A2
CO6950487A2 CO14089762A CO14089762A CO6950487A2 CO 6950487 A2 CO6950487 A2 CO 6950487A2 CO 14089762 A CO14089762 A CO 14089762A CO 14089762 A CO14089762 A CO 14089762A CO 6950487 A2 CO6950487 A2 CO 6950487A2
Authority
CO
Colombia
Prior art keywords
beckmann
oximes
gas phase
liquid gas
transposition
Prior art date
Application number
CO14089762A
Other languages
English (en)
Spanish (es)
Inventor
Alan B Levy
Robert Raja
Matthew E Potter
Original Assignee
Honeywell Int Inc
Univ Southampton
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell Int Inc, Univ Southampton filed Critical Honeywell Int Inc
Publication of CO6950487A2 publication Critical patent/CO6950487A2/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates [SAPO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54Phosphates, e.g. APO or SAPO compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D201/00Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02Preparation of lactams
    • C07D201/04Preparation of lactams from or via oximes by Beckmann rearrangement
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D223/00Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08Oxygen atoms
    • C07D223/10Oxygen atoms attached in position 2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D225/00Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
    • C07D225/02Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05Nuclear magnetic resonance [NMR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10Infrared [IR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
CO14089762A 2011-10-28 2014-04-28 Transposición catalítica de beckmann de fase de gas líquido de oximas para producir lactamas CO6950487A2 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161628419P 2011-10-28 2011-10-28
US13/658,495 US8772476B2 (en) 2011-10-28 2012-10-23 Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams

Publications (1)

Publication Number Publication Date
CO6950487A2 true CO6950487A2 (es) 2014-05-20

Family

ID=48168483

Family Applications (1)

Application Number Title Priority Date Filing Date
CO14089762A CO6950487A2 (es) 2011-10-28 2014-04-28 Transposición catalítica de beckmann de fase de gas líquido de oximas para producir lactamas

Country Status (11)

Country Link
US (3) US8772476B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP2771317B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (2) JP6243340B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR102002197B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN104039760B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CO (1) CO6950487A2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2856699T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN2014DN03074A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX354802B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2609779C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO2013063244A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4136000B2 (ja) * 1994-06-03 2008-08-20 三井化学株式会社 殺虫性テトラヒドロフラン系化合物
US8772476B2 (en) * 2011-10-28 2014-07-08 Honeywell International Inc. Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
US20160167030A1 (en) * 2014-12-16 2016-06-16 University Of Southampton Hierarchical aluminophosphates as catalysts for the beckmann rearrangement

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3503958A (en) 1964-10-29 1970-03-31 Mobil Oil Corp Molecular rearrangement of oximes
DE1545789A1 (de) 1965-02-10 1969-10-02 Bayer Ag Verfahren zum Herstellen von Lactamen
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4499327A (en) * 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
IT1187661B (it) 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
US4873325A (en) * 1986-06-25 1989-10-10 Uop Process for the production of amides
JP3066047B2 (ja) 1990-08-03 2000-07-17 中外製薬株式会社 新規なビタミンd▲下3▼誘導体
DE4125457A1 (de) 1991-08-01 1993-02-04 Bayer Ag Verfahren zur herstellung von n-substituierten lactamen
KR100224333B1 (ko) 1991-11-27 1999-10-15 고오사이 아끼오 ε-카프로락탐의 제조방법
US5242676A (en) 1992-05-11 1993-09-07 Mobil Oil Corp. Selective surface dealumination of zeolites using dicarboxylic acid
US5292880A (en) 1992-05-11 1994-03-08 Mobil Oil Corporation Synthesis of caprolactam using catalysts
JPH06256304A (ja) 1993-03-04 1994-09-13 Sumitomo Chem Co Ltd ε−カプロラクタムの製法
JPH09291074A (ja) 1996-04-26 1997-11-11 Sumitomo Chem Co Ltd ε−カプロラクタムの製造方法
WO1998054092A1 (en) * 1997-05-29 1998-12-03 Exxon Chemical Patents Inc. Preparation of zeolite-bound fau structure type zeolite and use thereof
US6331500B1 (en) * 1997-08-25 2001-12-18 California Institute Of Technology Functionalized molecular sieves
JP2001072658A (ja) 1999-06-28 2001-03-21 Mitsubishi Chemicals Corp アミド化合物の製造方法
JP2001072657A (ja) 1999-06-28 2001-03-21 Mitsubishi Chemicals Corp アミド化合物の製造方法
TW526172B (en) 1999-06-30 2003-04-01 Sumitomo Chemical Co A process for producing pentacyl-type crystalline zeolites and a process for producing ε-caprolactam using the same
IT1314001B1 (it) 1999-11-19 2002-12-03 Enichem Spa Metodo per la rimozione del templante da zeoliti sintetiche
IT1314263B1 (it) 1999-12-03 2002-12-06 Enichem Spa Processo per la preparazione di catalizzatori zeolitici.
AU4880401A (en) * 2000-04-21 2001-11-07 Mitsubishi Chemical Corporation Process for producing amide compound
US6531595B2 (en) 2000-09-29 2003-03-11 Sumitomo Chemical Company, Limited Method for producing ε-caprolactam and reactor for the method
CN1322927A (zh) 2001-03-05 2001-11-21 叶声羽 大热水量的电热水器及槓杆式上水自动装置
JP4433795B2 (ja) 2001-09-12 2010-03-17 旭化成ケミカルズ株式会社 ラクタムの製造方法
ITMI20012470A1 (it) 2001-11-23 2003-05-23 Enichem Spa Procediemnto per la preparazione di vitalizzatori zeolitici di tipo mfi
JP3969078B2 (ja) 2001-12-12 2007-08-29 住友化学株式会社 ペンタシル型ゼオライトの製造方法およびε−カプロラクタムの製造方法
US6946553B2 (en) 2002-02-27 2005-09-20 Sumitomo Chemical Company, Limited Process for producing ε-caprolactam and catalyst for the production
US7326332B2 (en) * 2003-09-25 2008-02-05 Exxonmobil Chemical Patents Inc. Multi component catalyst and its use in catalytic cracking
US20070112189A1 (en) 2003-11-17 2007-05-17 Takuji Ikeda High silica cds-1 zeolite
JP4461926B2 (ja) 2004-06-30 2010-05-12 住友化学株式会社 ゼオライトの製造方法及びε−カプロラクタムの製造方法
GB2450711A (en) 2007-07-03 2009-01-07 Univ Southampton An aluminophosphate based redox catalyst
JP2010047499A (ja) 2008-08-20 2010-03-04 Univ Of Tokyo ε−カプロラクタムの製造方法及びペンタシル型ゼオライトの製造方法
DE102008060340A1 (de) 2008-12-03 2010-06-10 Wolfgang F. Prof. Dr. Hölderich Herstellung von Lactamen und Carbonsäureamide durch Beckmann-Umlagerung von Oximen in Gegenwart von Nb-Katalysatoren
GB0900198D0 (en) 2009-01-07 2009-02-11 Univ Southampton Ammoximation process
CN102050464B (zh) 2009-10-30 2012-07-25 中国石油化工股份有限公司 硅分子筛的合成方法
GB2475740B (en) * 2009-11-30 2017-06-07 Johnson Matthey Plc Catalysts for treating transient NOx emissions
JP2012066977A (ja) 2010-09-27 2012-04-05 Sumitomo Chemical Co Ltd ゼオライトの製造方法及びε−カプロラクタムの製造方法
JP2012158501A (ja) 2011-02-02 2012-08-23 Sumitomo Chemical Co Ltd ゼオライトの製造方法及びε−カプロラクタムの製造方法
CN102188989B (zh) 2011-03-24 2013-08-07 中国天辰工程有限公司 一种流化床催化剂及制备方法
CN102432032B (zh) 2011-09-16 2013-05-15 湖南大学 一种纳米全硅分子筛及其制备方法与应用
US8772476B2 (en) * 2011-10-28 2014-07-08 Honeywell International Inc. Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams

Also Published As

Publication number Publication date
MX2014005018A (es) 2014-07-09
RU2014121157A (ru) 2015-12-10
US8772476B2 (en) 2014-07-08
EP2771317A1 (en) 2014-09-03
EP2771317B1 (en) 2020-12-09
BR112014010194A2 (pt) 2017-06-13
US20150306586A1 (en) 2015-10-29
US9221762B2 (en) 2015-12-29
RU2609779C2 (ru) 2017-02-03
WO2013063244A1 (en) 2013-05-02
IN2014DN03074A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2015-05-15
JP2015501321A (ja) 2015-01-15
ES2856699T3 (es) 2021-09-28
US9662643B2 (en) 2017-05-30
JP6243340B2 (ja) 2017-12-06
EP2771317A4 (en) 2015-10-07
CN104039760B (zh) 2018-03-09
BR112014010194A8 (pt) 2017-06-20
KR102002197B1 (ko) 2019-07-19
US20130109851A1 (en) 2013-05-02
JP2017200906A (ja) 2017-11-09
MX354802B (es) 2018-03-22
KR20150000863A (ko) 2015-01-05
US20150126732A1 (en) 2015-05-07
CN104039760A (zh) 2014-09-10
US20160279622A9 (en) 2016-09-29

Similar Documents

Publication Publication Date Title
IL269207B (en) Purification of immunoglobulin hetero-dimers
IL262055B (en) Synthesis of lactams
DK2553229T3 (da) Selektiv katalytisk reduktion ved elektrolyse af urinstof
BR112013033063A2 (pt) conversão catalítica de biomassa
EP2925327A4 (en) ANTICONVULSIVE EFFECT OF STEROIDS
BR112014000445A2 (pt) usos de inibidores de hsp90 marcados
BR112013032184A2 (pt) conversão catalítica zeolítica de alcoóis para hidrocarbonetos
BR112013020016A2 (pt) método de purificação de um gás
PT2604625T (pt) Geração de moléculas de ligação
PL2757107T3 (pl) Sposób syntezy w fazie stałej liraglutydu
EP2742051A4 (en) AMORPHIC FORM OF DOLUTEGRAVIR
EP2812279A4 (en) LIQUID PHASE SYNTHESIS OF TRISILYLAMINE
PL2665692T3 (pl) Katalityczne fluorowanie w fazie gazowej
EP2721153A4 (en) SYNTHETIC GENCLUSTERS
DK3590517T3 (da) Heteroaryl-ketonkondenserede azadecalin som modulatorer af glucocorticoidreceptorer
EP2831021A4 (en) METHOD FOR OXIDATIVE DEHYDRATION WITH IMPROVED CONTROLLABILITY FOR THE PREPARATION OF BUTADIENE
PL2665693T3 (pl) Fluorowanie katalityczne w fazie gazowej
BR112012005542A2 (pt) processo para polimerização em fase gasosa de olefinas
SG11201400462YA (en) Inner phase thickened water-in-oil cosmetic composition
BR112014003878A2 (pt) síntese de r-bifenilalaninol
EP2794908A4 (en) Light-activated chemical bleaching of dyes
DK2931847T3 (da) Conversion of triacylglyceride-containing oils to hydrocarbons
BRDI7105200S (pt) Configuração aplicada em vaporizador sublingual de produtos fluidos
EP2893977A4 (en) COSELECTIVE METHANIZATION CATALYST
SG11201406111YA (en) Purification of succinic acid

Legal Events

Date Code Title Description
FG Application granted