CN1879239B - 电池用负极活性物质材料、电池用负极罐、电池用负极锌板、锰干电池及其制造方法 - Google Patents
电池用负极活性物质材料、电池用负极罐、电池用负极锌板、锰干电池及其制造方法 Download PDFInfo
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- CN1879239B CN1879239B CN200480032815.2A CN200480032815A CN1879239B CN 1879239 B CN1879239 B CN 1879239B CN 200480032815 A CN200480032815 A CN 200480032815A CN 1879239 B CN1879239 B CN 1879239B
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- zinc
- battery
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- bismuth
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- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 196
- 239000011701 zinc Substances 0.000 title claims abstract description 196
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 188
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000011572 manganese Substances 0.000 title claims abstract description 67
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims description 43
- 238000004519 manufacturing process Methods 0.000 title claims description 38
- 239000007773 negative electrode material Substances 0.000 title abstract description 35
- 230000007797 corrosion Effects 0.000 claims abstract description 110
- 238000005260 corrosion Methods 0.000 claims abstract description 110
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000010949 copper Substances 0.000 claims abstract description 43
- 229910052802 copper Inorganic materials 0.000 claims abstract description 42
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 34
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 33
- 239000010941 cobalt Substances 0.000 claims abstract description 33
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 22
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 93
- 229910052797 bismuth Inorganic materials 0.000 claims description 90
- 239000002245 particle Substances 0.000 claims description 77
- 229910052751 metal Inorganic materials 0.000 claims description 47
- 239000002184 metal Substances 0.000 claims description 47
- 239000011777 magnesium Substances 0.000 claims description 43
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 35
- 229910052749 magnesium Inorganic materials 0.000 claims description 35
- 238000002425 crystallisation Methods 0.000 claims description 32
- 230000008025 crystallization Effects 0.000 claims description 32
- 239000011149 active material Substances 0.000 claims description 26
- 238000003490 calendering Methods 0.000 claims description 26
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 22
- 229910052726 zirconium Inorganic materials 0.000 claims description 22
- 229910052788 barium Inorganic materials 0.000 claims description 16
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052712 strontium Inorganic materials 0.000 claims description 16
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 16
- 238000005520 cutting process Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 description 148
- 239000003792 electrolyte Substances 0.000 description 76
- 230000000052 comparative effect Effects 0.000 description 75
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 62
- 239000000203 mixture Substances 0.000 description 58
- 238000012360 testing method Methods 0.000 description 56
- 239000012535 impurity Substances 0.000 description 35
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 34
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 229910052738 indium Inorganic materials 0.000 description 23
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- 238000012545 processing Methods 0.000 description 20
- 208000037656 Respiratory Sounds Diseases 0.000 description 18
- 235000019270 ammonium chloride Nutrition 0.000 description 17
- 239000011592 zinc chloride Substances 0.000 description 15
- 235000005074 zinc chloride Nutrition 0.000 description 15
- 229910052793 cadmium Inorganic materials 0.000 description 14
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 238000005238 degreasing Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- 238000011835 investigation Methods 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229910052787 antimony Inorganic materials 0.000 description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229920002472 Starch Polymers 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000013527 degreasing agent Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 239000008107 starch Substances 0.000 description 8
- 235000019698 starch Nutrition 0.000 description 8
- 150000003751 zinc Chemical class 0.000 description 8
- 239000007774 positive electrode material Substances 0.000 description 7
- 229920002261 Corn starch Polymers 0.000 description 6
- 244000137852 Petrea volubilis Species 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 6
- 230000008033 biological extinction Effects 0.000 description 6
- 239000008120 corn starch Substances 0.000 description 6
- 229940099112 cornstarch Drugs 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 239000013585 weight reducing agent Substances 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
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- 238000003556 assay Methods 0.000 description 4
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- 238000005516 engineering process Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000565 sealant Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 229920006332 epoxy adhesive Polymers 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
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- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
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- 238000003860 storage Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical class [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000037237 body shape Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
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- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
- H01M4/08—Processes of manufacture
- H01M4/12—Processes of manufacture of consumable metal or alloy electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/42—Alloys based on zinc
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
铋添加量 | 添加成分和添加量 | 腐蚀损耗量 | 腐蚀损耗量均方差值 | |
实施例A1 | 0.10 | - | 3.8 | 0.0147 |
实施例A2 | 0.20 | - | 2.4 | 0.0110 |
实施例A3 | 0.30 | - | 2.0 | 0.00567 |
实施例A4 | 0.40 | - | 1.6 | 0.00267 |
实施例A5 | 0.50 | - | 1.3 | 0.00667 |
实施例A6 | 0.70 | - | 1.1 | 0.00567 |
比较例A1 | - | - | 12.0 | 1.10 |
比较例A2 | 0.05 | - | 5.8 | 1.14 |
比较例A3 | 1.00 | - | 1.1 | 0.00400 |
比较例A4 | - | In0.10 | 21.0 | 7.10 |
参照例A1 | - | Pb0.40 | 4.2 | 0.00187 |
实施例A7 | 0.20 | Mg0.0003 | 2.4 | 0.0107 |
实施例A8 | 0.20 | Mg0.001 | 2.5 | 0.00967 |
实施例A9 | 0.20 | Mg0.003 | 2.6 | 0.0107 |
实施例A10 | 0.20 | Zr0.001 | 2.3 | 0.00800 |
实施例A11 | 0.20 | Zr0.05 | 2.2 | 0.00800 |
实施例A12 | 0.20 | Sr0.001 | 2.8 | 0.0160 |
实施例A13 | 0.20 | Sr0.05 | 3.1 | 0.0107 |
实施例A14 | 0.20 | Ba0.001 | 3.0 | 0.0627 |
实施例A15 | 0.20 | Ba0.05 | 3.9 | 0.311 |
铋添加量 | 添加元素和添加量 | 制罐时的材料温度 | 罐底厚度平均值 | 罐底厚度均方差值 | 产生的裂纹数 | |
比较例A6 | 0.30 | - | 91 | 0.53 | 6.93E-4 | 0 |
实施例A18 | 0.30 | - | 118 | 0.50 | 0.267E-4 | 0 |
实施例A19 | 0.30 | - | 153 | 0.50 | 0.178E-4 | 0 |
实施例A20 | 0.30 | - | 211 | 0.50 | 0.278E-4 | 0 |
比较例A7 | 0.30 | - | 232 | 0.50 | 0.233E-4 | 1 |
比较例A8 | 0.30 | Mg0.001 | 94 | 0.52 | 2.68E-4 | 0 |
实施例A21 | 0.30 | Mg0.001 | 111 | 0.50 | 0.233E-4 | 0 |
实施例A22 | 0.30 | Mg0.001 | 156 | 0.50 | 0.178E-4 | 0 |
实施例A23 | 0.30 | Mg0.001 | 252 | 0.50 | 0.456E-4 | 0 |
比较例A9 | 0.30 | Mg0.001 | 278 | 0.50 | 0.233E-4 | 2 |
比较例A10 | 0.30 | Mg0.003 | 94 | 0.52 | 2.94E-4 | 0 |
实施例A24 | 0.30 | Mg0.003 | 110 | 0.50 | 0.267E-4 | 0 |
实施例A25 | 0.30 | Mg0.003 | 154 | 0.50 | 0.100E-4 | 0 |
实施例A26 | 0.30 | Mg0.003 | 256 | 0.50 | 0.400E-4 | 0 |
比较例A11 | 0.30 | Mg0.003 | 274 | 0.50 | 0.456E-4 | 2 |
比较例A12 | 0.30 | Zr0.001 | 92 | 0.51 | 2.54E-4 | 0 |
实施例A27 | 0.30 | Zr0.001 | 113 | 0.50 | 0.233E-4 | 0 |
实施例A28 | 0.30 | Zr0.001 | 152 | 0.50 | 0.222E-4 | 0 |
实施例A29 | 0.30 | Zr0.001 | 255 | 0.50 | 0.233E-4 | 0 |
比较例A13 | 0.30 | Zr0.001 | 275 | 0.50 | 0.278E-4 | 3 |
比较例A14 | 0.30 | Zr0.05 | 93 | 0.51 | 2.67E-4 | 0 |
实施例A30 | 0.30 | Zr0.05 | 110 | 0.50 | 0.278E-4 | 0 |
实施例A31 | 0.30 | Zr0.05 | 153 | 0.50 | 0.178E-4 | 0 |
实施例A32 | 0.30 | Zr0.05 | 254 | 0.50 | 0.267E-4 | 0 |
比较例A15 | 0.30 | Zr0.05 | 271 | 0.50 | 0.900E-4 | 4 |
参照例A3 | - | Pb0.40 | 255 | 0.50 | 0.267E-4 | 0 |
铋添加量 | 添加成分和添加量 | 腐蚀损耗量 | 腐蚀损耗量均方差值 | |
实施例A62 | 0.10 | - | 3.9 | 0.0150 |
实施例A63 | 0.20 | - | 2.3 | 0.0112 |
实施例A64 | 0.30 | - | 1.9 | 0.00572 |
实施例A65 | 0.40 | - | 1.7 | 0.00268 |
实施例A66 | 0.50 | - | 1.4 | 0.00681 |
实施例A67 | 0.70 | - | 1.2 | 0.00601 |
比较例A24 | - | - | 12.5 | 1.18 |
比较例A25 | 0.05 | - | 6.0 | 1.15 |
比较例A26 | 1.00 | - | 1.2 | 0.00412 |
比较例A27 | - | In0.10 | 22.2 | 7.50 |
参照例A7 | - | Pb0.40 | 4.5 | 0.00190 |
实施例A68 | 0.20 | Mg0.0003 | 2.3 | 0.0118 |
实施例A69 | 0.20 | Mg0.003 | 2.4 | 0.0090 |
实施例A70 | 0.20 | Mg0.03 | 3.8 | 0.0181 |
实施例A71 | 0.20 | Zr0.001 | 2.4 | 0.009 |
实施例A72 | 0.20 | Zr0.05 | 2.1 | 0.007 |
实施例A73 | 0.20 | Sr0.001 | 2.7 | 0.0172 |
实施例A74 | 0.20 | Sr0.05 | 3.0 | 0.0118 |
实施例A75 | 0.20 | Ba0.001 | 3.2 | 0.0712 |
实施例A76 | 0.20 | Ba0.05 | 3.7 | 0.391 |
铋添加量 | 添加元素和添加量 | 压延时的材料温度 | 产生的裂纹数 | |
比较例A28 | 0.30 | - | 99 | 0 |
实施例A77 | 0.30 | - | 121 | 0 |
实施例A78 | 0.30 | - | 161 | 0 |
实施例A79 | 0.30 | - | 222 | 0 |
比较例A29 | 0.30 | - | 241 | 2 |
比较例A30 | 0.30 | Mg0.003 | 95 | 0 |
实施例A80 | 0.30 | Mg0.003 | 113 | 0 |
实施例A81 | 0.30 | Mg0.003 | 161 | 0 |
实施例A82 | 0.30 | Mg0.003 | 255 | 0 |
比较例A31 | 0.30 | Mg0.003 | 281 | 4 |
比较例A32 | 0.30 | Mg0.03 | 96 | 0 |
实施例A83 | 0.30 | Mg0.03 | 112 | 0 |
实施例A84 | 0.30 | Mg0.03 | 161 | 0 |
实施例A85 | 0.30 | Mg0.03 | 261 | 0 |
比较例A33 | 0.30 | Mg0.03 | 281 | 3 |
比较例A34 | 0.30 | Zr0.001 | 95 | 0 |
实施例A86 | 0.30 | Zr0.001 | 114 | 0 |
实施例A87 | 0.30 | Zr0.001 | 156 | 0 |
实施例A88 | 0.30 | Zr0.001 | 261 | 0 |
比较例A35 | 0.30 | Zr0.001 | 282 | 5 |
比较例A36 | 0.30 | Zr0.05 | 94 | 0 |
实施例A89 | 0.30 | Zr0.05 | 112 | 0 |
实施例A90 | 0.30 | Zr0.05 | 163 | 0 |
实施例A91 | 0.30 | Zr0.05 | 255 | 0 |
比较例A37 | 0.30 | Zr0.05 | 273 | 7 |
参照例A8 | - | Pb0.40 | 265 | 0 |
铋添加量(Mg添加量) | 平均粒径 | 标准误差 | 腐蚀损耗量 | 制罐时的材料温度 | 裂纹产生数 | 寿命相对值 | |
参照例B1 | Pb0.2 | 30.3 | 1.17 | 4.8 | 180 | 0 | 100 |
参照例B2 | In0.01 | 26.7 | 1.23 | 21.0 | 210 | 3 | 66 |
实施例B1 | 0.1 | 20.6 | 0.92 | 3.8 | 162 | 0 | 101 |
实施例B2 | 0.3 | 12.7 | 0.049 | 2.0 | 211 | 0 | 101 |
实施例B3 | 0.3 | 12.7 | 0.049 | 2.0 | 230 | 1 | 101 |
实施例B4 | 0.5 | 10.8 | 0.033 | 1.3 | 203 | 0 | 101 |
实施例B5 | 0.7 | 7.8 | 0.023 | 1.1 | 182 | 0 | 102 |
实施例B6 | 0.8 | 7.7 | 0.033 | 1.1 | 118 | 0 | 101 |
实施例B7 | 0.3(Mg0.0003) | 12.9 | 0.067 | 2.0 | 158 | 0 | 100 |
实施例B8 | 0.3(Mg0.003) | 12.6 | 0.071 | 2.1 | 155 | 0 | 100 |
实施例B9 | 0.3(Mg0.03) | 12.4 | 0.072 | 2.0 | 154 | 0 | 101 |
比较例B1 | 0.3(Mg0.04) | - | - | - | 155 | 17 | - |
比较例B2 | - | 48.2 | 1.33 | 12.0 | 155 | 0 | 69 |
铋添加量(Mg添加量) | 平均粒径 | 标准误差 | 腐蚀损耗量 | 压延时的材料温度 | 裂纹产生数 | 寿命相对值 | |
参照例B3 | Pb0.2 | 30.1 | 1.20 | 4.9 | 181 | 0 | 100 |
参照例B4 | In0.01 | 25.7 | 1.31 | 21.2 | 212 | 7 | 71 |
实施例B10 | 0.1 | 20.1 | 1.00 | 3.9 | 171 | 0 | 100 |
实施例B11 | 0.3 | 12.8 | 0.051 | 2.2 | 213 | 0 | 101 |
实施例B12 | 0.5 | 11.2 | 0.033 | 1.4 | 212 | 0 | 100 |
实施例B13 | 0.7 | 8.1 | 0.021 | 1.2 | 190 | 0 | 101 |
实施例B14 | 0.8 | 7.9 | 0.041 | 1.3 | 119 | 0 | 101 |
实施例B15 | 0.3(Mg0.0003) | 12.8 | 0.061 | 2.1 | 161 | 0 | 100 |
实施例B16 | 0.3(Mg0.003) | 12.7 | 0.078 | 2.5 | 167 | 0 | 100 |
实施例B17 | 0.3(Mg0.03) | 12.5 | 0.073 | 2.2 | 168 | 0 | 101 |
比较例B3 | 0.3(Mg0.04) | - | - | - | 169 | 9 | - |
比较例B4 | - | 49.1 | 1.41 | 13.5 | 160 | 0 | 75 |
例 | Bi质量浓度(质量%) | 平均结晶粒径(μm) | 标准误差(S.E.M) | O/I比 | 腐蚀损耗量(mg) | 材料硬度(HV) |
实施例C1 | 0.08 | 24.8 | 0.95 | 1.40 | 4.0 | 40 |
实施例C2 | 0.1 | 21.1 | 0.92 | 1.41 | 3.8 | 40 |
实施例C3 | 0.3 | 12.7 | 0.049 | 1.15 | 2.0 | 41 |
实施例C4 | 0.7 | 7.8 | 0.023 | 1.04 | 1.1 | 41 |
比较例C1 | 0.05 | 40.3 | 1.15 | 1.67 | 5.8 | 32 |
例 | Pb质量浓度(质量%) | 平均结晶粒径(μm) | 标准误差(S.E.M) | O/I比 | 腐蚀损耗量(mg) | 材料硬度(HV) |
比较例C2 | 0.2 | 30.3 | 1.17 | 1.52 | 4.8 | 44 |
比较例C3 | 0.4 | 14.8 | 1.58 | 1.46 | 4.2 | 45 |
例 | Bi质量浓度(质量%) | 平均结晶粒径(μm) | 标准误差(S.E.M) | 腐蚀损耗量(mg) | 材料硬度(HV) |
实施例C13 | 0.08 | 25.1 | 1.00 | 5.1 | 43 |
实施例C14 | 0.1 | 21.3 | 0.98 | 3.3 | 45 |
实施例C15 | 0.3 | 12.8 | 0.061 | 2.1 | 42 |
实施例C16 | 0.7 | 8.1 | 0.031 | 1.0 | 43 |
比较例C8 | 0.05 | 45.6 | 1.28 | 6.1 | 35 |
例 | Pb质量浓度(质量%) | 平均结晶粒径(μm) | 标准误差(S.E.M) | 腐蚀损耗量(mg) | 材料硬度(HV) |
比较例C9 | 0.2 | 30.5 | 1.21 | 5.1 | 41 |
比较例C10 | 0.4 | 16.2 | 1.61 | 4.3 | 43 |
Claims (6)
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JP379003/2003 | 2003-11-07 | ||
JP2003379003 | 2003-11-07 | ||
JP2003431343 | 2003-12-25 | ||
JP431343/2003 | 2003-12-25 | ||
JP2003431344 | 2003-12-25 | ||
JP431344/2003 | 2003-12-25 | ||
PCT/JP2004/016443 WO2005045959A1 (ja) | 2003-11-07 | 2004-11-05 | 電池用負極活物質材料、電池用負極缶、電池用負極亜鉛板、マンガン乾電池、及びその製造方法 |
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CN1879239A CN1879239A (zh) | 2006-12-13 |
CN1879239B true CN1879239B (zh) | 2014-04-09 |
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US (1) | US20070134553A1 (zh) |
EP (1) | EP1691433A4 (zh) |
JP (1) | JP5091408B2 (zh) |
KR (1) | KR100895941B1 (zh) |
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JP5091409B2 (ja) * | 2003-12-25 | 2012-12-05 | 東芝ホームアプライアンス株式会社 | 電池用負極缶、およびこれを用いたマンガン乾電池 |
US20130252083A1 (en) * | 2004-01-13 | 2013-09-26 | John E. Stauffer | Lead-zinc battery |
CN100530775C (zh) * | 2004-10-15 | 2009-08-19 | 东芝电池株式会社 | 锰干电池负极锌材料的制造方法 |
JP2008140748A (ja) * | 2006-12-05 | 2008-06-19 | Matsushita Electric Ind Co Ltd | マンガン乾電池 |
JP2008171762A (ja) * | 2007-01-15 | 2008-07-24 | Matsushita Electric Ind Co Ltd | マンガン乾電池及びマンガン乾電池用負極亜鉛缶 |
US8361651B2 (en) * | 2011-04-29 | 2013-01-29 | Toyota Motor Engineering & Manufacturing North America, Inc. | Active material for rechargeable battery |
US9923242B2 (en) | 2014-01-23 | 2018-03-20 | John E. Stauffer | Lithium bromide battery |
US9666898B2 (en) | 2014-07-22 | 2017-05-30 | John E. Stauffer | Storage battery using a uniform mix of conductive and nonconductive granules in a lithium bromide electrolyte |
US9509017B2 (en) | 2014-07-22 | 2016-11-29 | John E. Stauffer | Lithium storage battery |
EP4130313A4 (en) * | 2020-03-27 | 2023-09-27 | Mitsui Mining & Smelting Co., Ltd. | ZINC SHEET, ACTIVE MATERIAL FOR BATTERY NEGATIVE ELECTRODE USING SUCH SHEET AND METHOD FOR PRODUCING ZINC SHEET |
CN111621793B (zh) * | 2020-07-24 | 2022-05-17 | 山东德瑞防腐材料有限公司 | 一种耐高温锌合金牺牲阳极及其制备方法 |
CN113224300B (zh) * | 2021-04-15 | 2022-07-29 | 淄博火炬能源有限责任公司 | 铅碳电池负极用铅粉的制备方法 |
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JPS62229762A (ja) * | 1986-03-31 | 1987-10-08 | Toshiba Battery Co Ltd | 乾電池用亜鉛缶の製造方法 |
JPS63226880A (ja) * | 1987-03-16 | 1988-09-21 | Fuji Elelctrochem Co Ltd | 無汞化乾電池 |
JP3105115B2 (ja) * | 1993-07-30 | 2000-10-30 | 東芝電池株式会社 | マンガン乾電池 |
JPH0794193A (ja) * | 1993-09-27 | 1995-04-07 | Toshiba Battery Co Ltd | マンガン乾電池 |
JP2000058045A (ja) * | 1998-08-10 | 2000-02-25 | Toshiba Battery Co Ltd | マンガン乾電池 |
GB9913675D0 (en) * | 1999-06-11 | 1999-08-11 | Ever Ready Ltd | Method of preparing zinc alloy foil |
CN100530775C (zh) * | 2004-10-15 | 2009-08-19 | 东芝电池株式会社 | 锰干电池负极锌材料的制造方法 |
JP5055979B2 (ja) * | 2006-11-29 | 2012-10-24 | 井関農機株式会社 | 多条刈コンバインの刈取部 |
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EP1691433A4 (en) | 2007-06-27 |
JPWO2005045959A1 (ja) | 2007-05-24 |
CN1879239A (zh) | 2006-12-13 |
US20070134553A1 (en) | 2007-06-14 |
WO2005045959A1 (ja) | 2005-05-19 |
KR100895941B1 (ko) | 2009-05-07 |
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