CN1771218B - 在双酚a生产中回收苯酚的方法 - Google Patents
在双酚a生产中回收苯酚的方法 Download PDFInfo
- Publication number
- CN1771218B CN1771218B CN200480009711.XA CN200480009711A CN1771218B CN 1771218 B CN1771218 B CN 1771218B CN 200480009711 A CN200480009711 A CN 200480009711A CN 1771218 B CN1771218 B CN 1771218B
- Authority
- CN
- China
- Prior art keywords
- phenol
- obtains
- exchange resin
- dihydroxyphenyl propane
- fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title abstract description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 54
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 36
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 36
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 25
- 239000011593 sulfur Substances 0.000 claims abstract description 24
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 24
- -1 amine compound Chemical class 0.000 claims abstract description 23
- 238000005406 washing Methods 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims abstract description 5
- 239000012141 concentrate Substances 0.000 claims abstract 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 238000004821 distillation Methods 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000002425 crystallisation Methods 0.000 claims description 8
- 238000006482 condensation reaction Methods 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- 239000006210 lotion Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 2
- 238000009833 condensation Methods 0.000 abstract description 2
- 230000005494 condensation Effects 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 230000002411 adverse Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000004048 modification Effects 0.000 description 12
- 238000012986 modification Methods 0.000 description 12
- 239000002994 raw material Substances 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 231100000989 no adverse effect Toxicity 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229960003151 mercaptamine Drugs 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- XKWQAXGDFYIFMB-UHFFFAOYSA-N 2-aminopyridine-3-thiol Chemical compound NC1=NC=CC=C1S XKWQAXGDFYIFMB-UHFFFAOYSA-N 0.000 description 1
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001020 rhythmical effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- GLQWRXYOTXRDNH-UHFFFAOYSA-N thiophen-2-amine Chemical class NC1=CC=CS1 GLQWRXYOTXRDNH-UHFFFAOYSA-N 0.000 description 1
- DKGYESBFCGKOJC-UHFFFAOYSA-N thiophen-3-amine Chemical compound NC=1C=CSC=1 DKGYESBFCGKOJC-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/74—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP108698/2003 | 2003-04-14 | ||
| JP2003108698A JP4615831B2 (ja) | 2003-04-14 | 2003-04-14 | ビスフェノールａの製造におけるフェノールの回収方法 |
| PCT/JP2004/005239 WO2004092102A1 (ja) | 2003-04-14 | 2004-04-13 | ビスフェノールaの製造におけるフェノールの回収方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1771218A CN1771218A (zh) | 2006-05-10 |
| CN1771218B true CN1771218B (zh) | 2010-05-26 |
Family
ID=33295895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200480009711.XA Expired - Fee Related CN1771218B (zh) | 2003-04-14 | 2004-04-13 | 在双酚a生产中回收苯酚的方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP4615831B2 (ja) |
| CN (1) | CN1771218B (ja) |
| TW (1) | TW200508187A (ja) |
| WO (1) | WO2004092102A1 (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2637311C2 (ru) * | 2012-07-13 | 2017-12-04 | Идемицу Козан Ко., Лтд. | Способ получения бисфенола а |
| CN105669388B (zh) * | 2016-03-08 | 2018-09-28 | 江苏常青树新材料科技有限公司 | 一种亚磷酸一苯二异辛酯生产装置上苯酚与异辛醇混合物的分离回收工艺 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4912263A (en) * | 1987-08-19 | 1990-03-27 | Bayer Aktiengesellschaft | Ionic exchangers modified with thiazolines |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2962441B2 (ja) * | 1991-10-11 | 1999-10-12 | 千代田化工建設株式会社 | 着色性の低いビスフェノールａの製造方法 |
| JPH06340564A (ja) * | 1993-06-01 | 1994-12-13 | Chiyoda Corp | ビスフェノールａの製造方法 |
| JPH09176069A (ja) * | 1995-12-26 | 1997-07-08 | Nippon Steel Chem Co Ltd | ビスフェノール類の製造方法 |
| JPH11246458A (ja) * | 1998-02-26 | 1999-09-14 | Mitsubishi Chemical Corp | ビスフェノールの製造方法 |
| JP2001199919A (ja) * | 2000-01-18 | 2001-07-24 | Idemitsu Petrochem Co Ltd | ビスフェノールａの製造方法 |
| JP2001335522A (ja) * | 2000-05-25 | 2001-12-04 | Mitsubishi Chemicals Corp | ビスフェノールの製造方法 |
| JP4689059B2 (ja) * | 2001-02-28 | 2011-05-25 | 出光興産株式会社 | ビスフェノールａの製造方法 |
-
2003
- 2003-04-14 JP JP2003108698A patent/JP4615831B2/ja not_active Expired - Fee Related
-
2004
- 2004-04-13 WO PCT/JP2004/005239 patent/WO2004092102A1/ja active Application Filing
- 2004-04-13 CN CN200480009711.XA patent/CN1771218B/zh not_active Expired - Fee Related
- 2004-04-14 TW TW093110379A patent/TW200508187A/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4912263A (en) * | 1987-08-19 | 1990-03-27 | Bayer Aktiengesellschaft | Ionic exchangers modified with thiazolines |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004092102A1 (ja) | 2004-10-28 |
| JP4615831B2 (ja) | 2011-01-19 |
| TW200508187A (en) | 2005-03-01 |
| JP2004315387A (ja) | 2004-11-11 |
| TWI324145B (ja) | 2010-05-01 |
| CN1771218A (zh) | 2006-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100526 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |