CN1720208A - 醇的制备方法 - Google Patents
醇的制备方法 Download PDFInfo
- Publication number
- CN1720208A CN1720208A CNA2003801049354A CN200380104935A CN1720208A CN 1720208 A CN1720208 A CN 1720208A CN A2003801049354 A CNA2003801049354 A CN A2003801049354A CN 200380104935 A CN200380104935 A CN 200380104935A CN 1720208 A CN1720208 A CN 1720208A
- Authority
- CN
- China
- Prior art keywords
- aldehyde
- hydrogenation
- alcohol
- distillation
- hydrogenation catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 44
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 82
- 238000004821 distillation Methods 0.000 claims abstract description 54
- 239000003054 catalyst Substances 0.000 claims abstract description 53
- 238000000746 purification Methods 0.000 claims abstract description 26
- 238000006356 dehydrogenation reaction Methods 0.000 claims abstract description 6
- 150000001299 aldehydes Chemical class 0.000 claims description 91
- 238000002360 preparation method Methods 0.000 claims description 15
- 230000009466 transformation Effects 0.000 claims description 12
- 238000007037 hydroformylation reaction Methods 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 6
- 238000005882 aldol condensation reaction Methods 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 239000000047 product Substances 0.000 description 61
- 238000009835 boiling Methods 0.000 description 55
- 239000000203 mixture Substances 0.000 description 26
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 20
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 241000282326 Felis catus Species 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 229960004279 formaldehyde Drugs 0.000 description 4
- 235000019256 formaldehyde Nutrition 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- NDFKTBCGKNOHPJ-AATRIKPKSA-N (E)-hept-2-enal Chemical compound CCCC\C=C\C=O NDFKTBCGKNOHPJ-AATRIKPKSA-N 0.000 description 3
- PYLMCYQHBRSDND-UHFFFAOYSA-N 2-ethyl-2-hexenal Chemical compound CCCC=C(CC)C=O PYLMCYQHBRSDND-UHFFFAOYSA-N 0.000 description 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- NDFKTBCGKNOHPJ-UHFFFAOYSA-N hex-2-enal Natural products CCCCC=CC=O NDFKTBCGKNOHPJ-UHFFFAOYSA-N 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 3
- MMFCJPPRCYDLLZ-CMDGGOBGSA-N (2E)-dec-2-enal Chemical compound CCCCCCC\C=C\C=O MMFCJPPRCYDLLZ-CMDGGOBGSA-N 0.000 description 2
- LGYNIFWIKSEESD-UHFFFAOYSA-N 2-ethylhexanal Chemical compound CCCCC(CC)C=O LGYNIFWIKSEESD-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- MMFCJPPRCYDLLZ-UHFFFAOYSA-N dec-2-enal Natural products CCCCCCCC=CC=O MMFCJPPRCYDLLZ-UHFFFAOYSA-N 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- PIYDVAYKYBWPPY-UHFFFAOYSA-N heptadecanal Chemical compound CCCCCCCCCCCCCCCCC=O PIYDVAYKYBWPPY-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000001149 thermolysis Methods 0.000 description 2
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 2
- WTPYRCJDOZVZON-UHFFFAOYSA-N 3,5,5-Trimethylhexanal Chemical compound O=CCC(C)CC(C)(C)C WTPYRCJDOZVZON-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- -1 C20 acetal Chemical class 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- LQKRYVGRPXFFAV-UHFFFAOYSA-N Phenylmethylglycidic ester Chemical compound CCOC(=O)C1OC1(C)C1=CC=CC=C1 LQKRYVGRPXFFAV-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical compound CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
粗壬醇溶液 | 实施例1 | 比较例1 | 比较例2 | |
氢化催化剂的含量 | - | - | 1160ppm | 1160ppm |
压力 | - | 60mmHgA | 60mmHgA | 60mmHgA |
气氛 | - | 氮气 | 氮气 | 氮气 |
温度 | - | 136℃ | 136℃ | 136℃ |
加热时间 | - | 7小时 | 7小时 | 14小时 |
异壬醛 | 0.0111重量% | 0.0144重量% | 0.1826重量% | 0.322重量% |
高沸点成分1 | 0.709重量% | 0.533重量% | 0.596重量% | 0.706重量% |
高沸点成分2 | 0.452重量% | 0.227重量% | 0.249重量% | 0.109重量% |
高沸点成分3 | 0.171重量% | 0.216重量% | 0.243重量% | 0.109重量% |
高沸点成分4 | 0.011重量% | 0.000重量% | 0.000重量% | 0.000重量% |
全部的高沸点成分 | 1.343重量% | 0.976重量% | 1.087重量% | 1.005重量% |
实施例2 | 比较例3 | |
氢化催化剂的含量 | 14重量ppm | 0.3重量% |
温度 | 140℃ | 140℃ |
2-乙基己醛0分钟后10分钟后60分钟后 | 0重量%0.0072重量%0.0420重量% | 0.0047重量%0.4327重量%0.5680重量% |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP352760/2002 | 2002-12-04 | ||
JP2002352760 | 2002-12-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1720208A true CN1720208A (zh) | 2006-01-11 |
CN1312094C CN1312094C (zh) | 2007-04-25 |
Family
ID=32463243
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003801049354A Expired - Lifetime CN1312094C (zh) | 2002-12-04 | 2003-11-20 | 醇的制备方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7790938B2 (zh) |
KR (1) | KR100878174B1 (zh) |
CN (1) | CN1312094C (zh) |
AU (1) | AU2003302638A1 (zh) |
BR (2) | BR0317023A (zh) |
TW (1) | TWI324991B (zh) |
WO (1) | WO2004050591A1 (zh) |
ZA (1) | ZA200504568B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105001046A (zh) * | 2015-07-09 | 2015-10-28 | 武汉工程大学 | 正壬醇的合成工艺 |
CN111356671A (zh) * | 2017-11-20 | 2020-06-30 | 沙特基础工业全球技术公司 | 从2-乙基己醇工艺的循环流中回收乙基己醇 |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7479576B1 (en) * | 2007-06-27 | 2009-01-20 | H R D Corporation | Method of hydrogenating aldehydes and ketones |
US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
US8344186B2 (en) * | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
US8859827B2 (en) | 2011-11-18 | 2014-10-14 | Celanese International Corporation | Esterifying acetic acid to produce ester feed for hydrogenolysis |
US8748675B2 (en) | 2011-06-16 | 2014-06-10 | Celanese International Corporation | Extractive distillation of crude alcohol product |
US8704012B2 (en) | 2011-06-16 | 2014-04-22 | Celanese International Corporation | Distillation of crude alcohol product using entrainer |
US8829251B2 (en) | 2011-11-18 | 2014-09-09 | Celanese International Corporation | Liquid esterification method to produce ester feed for hydrogenolysis |
US8829249B2 (en) | 2011-11-18 | 2014-09-09 | Celanese International Corporation | Integrated esterification and hydrogenolysis process for producing ethanol |
US8853468B2 (en) | 2011-11-18 | 2014-10-07 | Celanese International Corporation | Vapor esterification method to produce ester feed for hydrogenolysis |
US9024089B2 (en) | 2011-11-18 | 2015-05-05 | Celanese International Corporation | Esterification process using extractive separation to produce feed for hydrogenolysis |
US8748673B2 (en) | 2011-11-18 | 2014-06-10 | Celanese International Corporation | Process of recovery of ethanol from hydrogenolysis process |
US8802901B2 (en) | 2011-11-18 | 2014-08-12 | Celanese International Corporation | Continuous ethyl acetate production and hydrogenolysis thereof |
EP2782890A1 (en) | 2011-11-22 | 2014-10-01 | Celanese International Corporation | Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis |
US9029614B2 (en) | 2011-12-14 | 2015-05-12 | Celanese International Corporation | Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol |
US8742177B2 (en) | 2011-12-28 | 2014-06-03 | Rohm And Haas Company | Catalyst and process to produce branched unsaturated aldehydes |
US8907139B2 (en) | 2011-12-28 | 2014-12-09 | Celanese International Corporation | Process for acetal removal in the purification of a crude ethanol product |
BR112014015584A8 (pt) | 2012-01-06 | 2017-07-04 | Celanese Int Corp | catalisadores de hidrogenação com suportes modificados com cobalto |
US8981164B2 (en) | 2012-01-06 | 2015-03-17 | Celanese International Corporation | Cobalt and tin hydrogenation catalysts |
US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
US8957262B2 (en) | 2012-11-20 | 2015-02-17 | Celanese International Corporation | Olefin hydration for hydrogenation processes |
US9000237B2 (en) | 2012-12-20 | 2015-04-07 | Celanese International Corporation | Ethanol refining process using intermediate reboiler |
US8975450B2 (en) | 2013-03-15 | 2015-03-10 | Celanese International Corporation | Ethanol and ethyl acetate production using an acetic acid and acetic anhydride mixed feed |
US8975451B2 (en) | 2013-03-15 | 2015-03-10 | Celanese International Corporation | Single phase ester feed for hydrogenolysis |
US8926718B2 (en) | 2013-03-15 | 2015-01-06 | Celanese International Corporation | Thermochemically produced ethanol compositions |
US9512054B2 (en) | 2015-02-10 | 2016-12-06 | Eastman Chemical Company | Method for making a high purity alcohol |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2571160A (en) * | 1946-10-25 | 1951-10-16 | Standard Oil Dev Co | Oxo synthesis process |
DE2713434C3 (de) * | 1977-03-26 | 1980-10-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur Herstellung von 2-Äthylhexanol |
US4518809A (en) * | 1981-06-11 | 1985-05-21 | Monsanto Company | Preparation of pentyl nonanols |
JPH0813767B2 (ja) * | 1988-12-16 | 1996-02-14 | 三菱化学株式会社 | アルコールの精製法 |
JPH06122638A (ja) * | 1992-09-24 | 1994-05-06 | Mitsubishi Kasei Corp | アルコールの精製方法 |
JP3509175B2 (ja) | 1994-04-11 | 2004-03-22 | 三菱化学株式会社 | アルコールの精製方法 |
DE19754848C2 (de) * | 1997-12-10 | 2003-06-18 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung von Alkoholen |
US6455743B1 (en) * | 1998-11-27 | 2002-09-24 | Mitsubishi Chemical Corporation | Process for producing alcohols |
CN1237037C (zh) * | 1999-05-07 | 2006-01-18 | 昭和电工株式会社 | 四氟苯甲醛的制备方法 |
CN101142062B (zh) * | 2005-03-18 | 2010-06-16 | 株式会社安川电机 | 机器人用的示教盒、订制方法和使用了它们的机器人系统 |
-
2003
- 2003-11-20 CN CNB2003801049354A patent/CN1312094C/zh not_active Expired - Lifetime
- 2003-11-20 WO PCT/JP2003/014841 patent/WO2004050591A1/ja active Application Filing
- 2003-11-20 AU AU2003302638A patent/AU2003302638A1/en not_active Abandoned
- 2003-11-20 BR BR0317023-3A patent/BR0317023A/pt unknown
- 2003-11-20 BR BRPI0310135-5A patent/BR0310135B1/pt active IP Right Grant
- 2003-11-20 KR KR1020057010226A patent/KR100878174B1/ko active IP Right Grant
- 2003-12-02 TW TW092133826A patent/TWI324991B/zh not_active IP Right Cessation
-
2005
- 2005-06-03 ZA ZA200504568A patent/ZA200504568B/en unknown
- 2005-06-06 US US11/144,621 patent/US7790938B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105001046A (zh) * | 2015-07-09 | 2015-10-28 | 武汉工程大学 | 正壬醇的合成工艺 |
CN111356671A (zh) * | 2017-11-20 | 2020-06-30 | 沙特基础工业全球技术公司 | 从2-乙基己醇工艺的循环流中回收乙基己醇 |
Also Published As
Publication number | Publication date |
---|---|
US20050277793A1 (en) | 2005-12-15 |
TW200413295A (en) | 2004-08-01 |
BR0317023A (pt) | 2005-10-25 |
TWI324991B (en) | 2010-05-21 |
ZA200504568B (en) | 2006-08-30 |
US7790938B2 (en) | 2010-09-07 |
CN1312094C (zh) | 2007-04-25 |
KR20050085396A (ko) | 2005-08-29 |
BR0310135B1 (pt) | 2014-04-29 |
KR100878174B1 (ko) | 2009-01-12 |
WO2004050591A1 (ja) | 2004-06-17 |
AU2003302638A1 (en) | 2004-06-23 |
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