CN1693324A - 反光膜用丙烯酸树脂的制备方法 - Google Patents
反光膜用丙烯酸树脂的制备方法 Download PDFInfo
- Publication number
- CN1693324A CN1693324A CN 200510040631 CN200510040631A CN1693324A CN 1693324 A CN1693324 A CN 1693324A CN 200510040631 CN200510040631 CN 200510040631 CN 200510040631 A CN200510040631 A CN 200510040631A CN 1693324 A CN1693324 A CN 1693324A
- Authority
- CN
- China
- Prior art keywords
- acrylic acid
- acid monomer
- chain
- transfer agent
- extraordinary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims description 47
- 239000011347 resin Substances 0.000 title claims description 13
- 229920005989 resin Polymers 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims description 29
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 26
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 15
- -1 R 2Be H Chemical group 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 13
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 12
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 12
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 12
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- 230000009466 transformation Effects 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical group [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 8
- 150000002576 ketones Chemical class 0.000 claims description 8
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- UBLAMKHIFZBBSS-UHFFFAOYSA-N 3-Methylbutyl pentanoate Chemical compound CCCCC(=O)OCCC(C)C UBLAMKHIFZBBSS-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000003556 assay Methods 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 235000019439 ethyl acetate Nutrition 0.000 claims description 5
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 5
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 5
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims description 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 229940117955 isoamyl acetate Drugs 0.000 claims description 3
- 229940119545 isobornyl methacrylate Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229920005906 polyester polyol Polymers 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 8
- 239000012948 isocyanate Substances 0.000 abstract description 5
- 150000002513 isocyanates Chemical class 0.000 abstract description 5
- 239000004925 Acrylic resin Substances 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 210000000160 tapetum lucidum Anatomy 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100406317A CN100366650C (zh) | 2005-06-17 | 2005-06-17 | 反光膜用丙烯酸树脂的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100406317A CN100366650C (zh) | 2005-06-17 | 2005-06-17 | 反光膜用丙烯酸树脂的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1693324A true CN1693324A (zh) | 2005-11-09 |
CN100366650C CN100366650C (zh) | 2008-02-06 |
Family
ID=35352467
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2005100406317A Active CN100366650C (zh) | 2005-06-17 | 2005-06-17 | 反光膜用丙烯酸树脂的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100366650C (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100427518C (zh) * | 2007-02-16 | 2008-10-22 | 南京夜视丽精细化工有限责任公司 | 反光布用阻燃丙烯酸树脂 |
CN101792566B (zh) * | 2010-01-29 | 2011-09-28 | 晋江市夜视明反光材料有限公司 | 一种定向反光膜表层材料制备方法 |
CN103044615A (zh) * | 2013-01-17 | 2013-04-17 | 焦作瑞福莱反光材料有限公司 | 一种反光膜用羟基丙烯酸树脂及其制备方法 |
CN103360930A (zh) * | 2013-07-01 | 2013-10-23 | 东莞东萌化工有限公司 | 一种高硬度抗鼓筋的pu水晶透底漆涂料及底漆 |
CN106699954A (zh) * | 2015-07-20 | 2017-05-24 | 潘盈 | 一种用于3d打印的uv固化丙烯酸树脂的制备方法 |
CN109400789A (zh) * | 2018-10-12 | 2019-03-01 | 浙江龙游道明光学有限公司 | 一种反光膜用丙烯酸共聚物的制备方法 |
CN115215960A (zh) * | 2022-06-29 | 2022-10-21 | 苏州赫伯特电子科技有限公司 | 一种用于热固性树脂开窗的可去除材料及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1059921A (zh) * | 1990-09-11 | 1992-04-01 | 周建明 | 一种透明保护涂料的组成、制造方法及用途 |
WO1995026281A2 (en) * | 1994-03-24 | 1995-10-05 | Minnesota Mining And Manufacturing Company | Retroreflective license plate and method for making same |
-
2005
- 2005-06-17 CN CNB2005100406317A patent/CN100366650C/zh active Active
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100427518C (zh) * | 2007-02-16 | 2008-10-22 | 南京夜视丽精细化工有限责任公司 | 反光布用阻燃丙烯酸树脂 |
CN101792566B (zh) * | 2010-01-29 | 2011-09-28 | 晋江市夜视明反光材料有限公司 | 一种定向反光膜表层材料制备方法 |
CN103044615A (zh) * | 2013-01-17 | 2013-04-17 | 焦作瑞福莱反光材料有限公司 | 一种反光膜用羟基丙烯酸树脂及其制备方法 |
CN103360930A (zh) * | 2013-07-01 | 2013-10-23 | 东莞东萌化工有限公司 | 一种高硬度抗鼓筋的pu水晶透底漆涂料及底漆 |
CN106699954A (zh) * | 2015-07-20 | 2017-05-24 | 潘盈 | 一种用于3d打印的uv固化丙烯酸树脂的制备方法 |
CN109400789A (zh) * | 2018-10-12 | 2019-03-01 | 浙江龙游道明光学有限公司 | 一种反光膜用丙烯酸共聚物的制备方法 |
CN115215960A (zh) * | 2022-06-29 | 2022-10-21 | 苏州赫伯特电子科技有限公司 | 一种用于热固性树脂开窗的可去除材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN100366650C (zh) | 2008-02-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1693324A (zh) | 反光膜用丙烯酸树脂的制备方法 | |
CN105062375B (zh) | 一种紫外光固化的液态光学透明胶及其制备方法与应用 | |
CN103044615B (zh) | 一种反光膜用羟基丙烯酸树脂及其制备方法 | |
CN1872931A (zh) | 一种用于液晶显示器金属销钉粘接的紫外线固化胶粘剂 | |
CN101619116B (zh) | 一种热塑性含氟丙烯酸树脂及其制备方法 | |
CN101864204A (zh) | 一种高性能汽车车灯反射镜专用紫外光固化真空镀膜底漆 | |
CN1935870A (zh) | 一种低苯乙烯含量耐高温环氧乙烯基酯树脂的合成工艺 | |
CN114015075B (zh) | 一种基于纤维素自组装调控的强韧、透明水凝胶的制备方法 | |
CN103554334A (zh) | 内增塑单体改性丙烯酸酯/无机纳米复合乳液及其制备方法 | |
CN102190759A (zh) | 一种聚酯改性氟丙烯酸树脂、制备方法及其涂料 | |
CN1793196A (zh) | 一种高韧性环氧乙烯基酯树脂合成工艺 | |
GB2148908A (en) | Process for the preparation of high impact strength moulding compositions | |
DE59806774D1 (de) | Verfahren zur Herstellung von wässrigen Dispersionen als Grundierung für Heisssiegelkleber | |
CN105408437A (zh) | 由多阶段乳液聚合制备用于保护膜的压敏胶粘剂分散体 | |
CN1632022A (zh) | 一种核壳结构的水性磨光油 | |
CN111995954A (zh) | 一种高段差贴合胶的制作方法 | |
CN111154049B (zh) | 一种耐温可增稠光固化环氧乙烯基酯树脂及其制备方法 | |
CN103562236B (zh) | 固化性树脂组合物、其固化物、层叠体及该层叠体的制造方法 | |
JP2000319475A (ja) | 耐衝撃性樹脂組成物、その製造方法、および、その成形品 | |
CN102952227A (zh) | 涂料用的具有重涂性的热固性丙烯酸树脂及其制备方法 | |
CN1072684C (zh) | 一种有机硅改性的丙烯酸树脂的制备方法 | |
CN103554804B (zh) | 高强级亚克力反光膜支撑层树脂的制备方法 | |
CN106916247A (zh) | Pmma预聚体及其制备方法和应用 | |
CN101067724A (zh) | 具有星型结构四官能团丙烯酸酯光固化树脂及其合成方法 | |
CN1171917C (zh) | 聚甲基丙烯酸甲酯模塑料的制造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Changzhou Hua R Sheng Reflective Material Co., Ltd. Assignor: Lu Yajian Contract fulfillment period: 2008.4.27 to 2014.4.27 contract change Contract record no.: 2008320000818 Denomination of invention: Process for preparing propenoic acid resin for reflectorized film Granted publication date: 20080206 License type: Exclusive license Record date: 20081012 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.4.27 TO 2014.4.27; CHANGE OF CONTRACT Name of requester: CHANGZHOU HUARISHENG GLISTENING MATERIALS CO., LTD Effective date: 20081012 |
|
ASS | Succession or assignment of patent right |
Owner name: CHANGZHOU HUA R SHENG REFLECTIVE MATERIAL CO., LTD Free format text: FORMER OWNER: LU YAJIAN Effective date: 20110104 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20110104 Address after: 213144 Jiangsu Province, Changzhou city Wujin District Zou broad road No. 18 Changzhou huarsheng reflective material Co., Ltd. Patentee after: Changzhou Hua R Sheng Reflective Material Co., Ltd. Address before: 213144 Jiangsu Province, Changzhou city Wujin District Zou broad road No. 18 Changzhou huarsheng reflective material Co., Ltd. Patentee before: Lu Yajian |
|
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: 213144 Jiangsu Province, Changzhou city Wujin District Zou Yue Yang Road, No. 8 Patentee after: Changzhou Hua R Sheng Reflective Material Co., Ltd. Address before: 213144 Jiangsu Province, Changzhou city Wujin District Zou broad road No. 18 Changzhou huarsheng reflective material Co., Ltd. Patentee before: Changzhou Hua R Sheng Reflective Material Co., Ltd. |
|
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: 213144 Jiangsu province Changzhou City Zhonglou District Zou Yue Yang Road, No. 8 Patentee after: Changzhou Hua R Sheng Reflective Material Co., Ltd. Address before: 213144 Jiangsu Province, Changzhou city Wujin District Zou Yue Yang Road, No. 8 Patentee before: Changzhou Hua R Sheng Reflective Material Co., Ltd. |