CN1325833C - 耐热绝缘复合物、含该复合物的基物、和其制备方法 - Google Patents
耐热绝缘复合物、含该复合物的基物、和其制备方法 Download PDFInfo
- Publication number
- CN1325833C CN1325833C CNB038167778A CN03816777A CN1325833C CN 1325833 C CN1325833 C CN 1325833C CN B038167778 A CNB038167778 A CN B038167778A CN 03816777 A CN03816777 A CN 03816777A CN 1325833 C CN1325833 C CN 1325833C
- Authority
- CN
- China
- Prior art keywords
- insulation composite
- heat
- insulated substrate
- heat resistant
- resistant insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 110
- 239000002131 composite material Substances 0.000 title claims abstract description 99
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 90
- 239000011230 binding agent Substances 0.000 claims abstract description 52
- 239000011159 matrix material Substances 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims description 76
- 230000004224 protection Effects 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 8
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 101
- 239000010410 layer Substances 0.000 description 34
- 239000000853 adhesive Substances 0.000 description 29
- 239000000835 fiber Substances 0.000 description 29
- 230000001070 adhesive effect Effects 0.000 description 28
- 239000003381 stabilizer Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 19
- 238000005187 foaming Methods 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 12
- 229920005992 thermoplastic resin Polymers 0.000 description 12
- 238000000576 coating method Methods 0.000 description 11
- 239000008187 granular material Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- 239000004005 microsphere Substances 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000006260 foam Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- -1 microballoon Substances 0.000 description 7
- 239000010451 perlite Substances 0.000 description 7
- 235000019362 perlite Nutrition 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910021485 fumed silica Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000012783 reinforcing fiber Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000004964 aerogel Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000005373 porous glass Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000784 Nomex Polymers 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920005822 acrylic binder Polymers 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 description 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000004763 nomex Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002480 polybenzimidazole Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000010456 wollastonite Substances 0.000 description 2
- 229910052882 wollastonite Inorganic materials 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000219492 Quercus Species 0.000 description 1
- 235000016976 Quercus macrolepis Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B2001/7691—Heat reflecting layers or coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Thermal Insulation (AREA)
- Building Environments (AREA)
- Insulating Bodies (AREA)
Abstract
本发明提供一种耐热绝缘复合物,它包括(a)绝缘基层和(b)热反射层,该绝缘基层包括中空非多孔颗粒和基体粘结剂,热反射层包括红外反射剂和保护粘结剂,其中耐热绝缘复合物具有导热性约50mW/(m·K)或更低。本发明还提供一种制备耐热绝缘复合物的方法。
Description
技术领域
本发明涉及耐热绝缘复合物和其制备方法。
背景技术
各种材料已与粘结剂体系一起用于提供填充颗粒的粘结剂型绝缘材料。例如,气凝胶已与含水粘结剂结合提供具有良好隔热和隔音性能的绝缘材料,然而,这些体系通常不提供足够的耐久性和耐热性,因此其配料中仅限于不渗透气凝胶颗粒的疏水孔。此外,该气凝胶物质趋于比其它颗粒类型更昂贵。其它物质如微球、perlite、粘土和各种其它颗粒填料已与粘结剂结合用于提供绝缘材料。一些绝缘材料已与膨胀(例如形成烧焦)层结合使用以提供一定程度的耐热性。
然而,仍然需要一种提供良好的隔热和/或隔音性能以及耐久性和耐热性,并且对其配料和用途具有低成本和适应性的绝缘制品。本发明提供这样的制品,以及制备该制品的方法。本发明的这些和其它优点,以及另外的发明特点,将通过这里提供的描述显而易见。
发明内容
本发明提供一种耐热绝缘复合物,包括、基本组成为或组成为(a)绝缘基层,它包括、基本组成为或组成为中空非多孔颗粒、基体粘结剂和非必要的发泡剂,和(b)热反射层,它包括、基本组成为或组成为保护粘结剂和红外反射剂,其中耐热绝缘复合物具有导热性约50mW/(m·K)或更低。还提供一种制备耐热绝缘复合物的方法,它包括、基本组成为或组成为(a)在基材上设置绝缘基层,它包括、基本组成为或组成为中空非多孔颗粒、基体粘结剂和非必要的发泡剂,和(b)在绝缘基层表面上涂布热反射层,该热反射层包括、基本组成为或组成为保护粘结剂和热反射剂,其中耐热绝缘复合物具有导热性约50mW/(m·K)或更低。本发明提供一种基物,该基物包括上述耐热绝缘复合物。
具体实施方式
耐热绝缘复合物
本发明的耐热绝缘复合物包括、基本组成为或组成为(a)绝缘基层,它包括、基本组成为或组成为中空非多孔颗粒、基体粘结剂和非必要的发泡剂,和(b)热反射层,它包括、基本组成为或组成为保护粘结剂和红外反射剂,其中耐热绝缘复合物具有导热性约50mW/(m·K)或更低。
本发明可使用任何合适类型的材料,包括称为微球体、微泡沫体、微微球、煤胞(microspheres,microbubbles,microballoons,cenospheres)和本领域通常使用的其它术语的材料。术语″非多孔″,本发明中是指中空颗粒的壁不以任何明显程度让基体粘结剂进入颗粒内部空间。术语“明显程度”是指将增加中空非多孔颗粒或绝缘复合物的导热性的量。该中空非多孔颗粒由任何合适材料(包括有机材料和无机材料)构成,优选由具有相当低导热性的材料形成。有机材料包括例如偏氯乙烯/丙烯腈材料、酚类材料、脲醛树脂材料、聚苯乙烯材料或热塑性树脂。无机材料包括例如玻璃、二氧化硅、二氧化钛、氧化铝、石英、飞灰和陶瓷材料。此外,耐热绝缘复合物可包括上述任何一类型的中空非多孔颗粒(例如无机和有机中空非多孔颗粒)的混合物。中空颗粒的内部空间一般将包括气体如空气(即中空颗粒可包括包覆气体的非多孔材料的壳)。合适的中空颗粒可市购。合适的中空非多孔颗粒的例子包括ScotchliteTM玻璃微球和ZeeospheresTM陶瓷微球(制造商都是3M,Inc.)。合适的中空非多孔颗粒还包括EXPANCEL微球(制造商为AkzoNobel),,其由包覆气体的热塑性树脂微球构成。
中空非多孔颗粒的尺寸将部分取决于耐热绝缘复合物的厚度。对于本发明,术语“颗粒尺寸”和“粒径”作为同义词使用。通常,较大的颗粒提供更好的热均匀;然而,这些颗粒应比耐热绝缘复合物(即耐热绝缘复合物的绝缘基层)的厚度更小以使基体粘结剂围绕颗粒并形成基体。对于大多数应用,合适地使用具有平均粒径(按重量计)约5mm或更低(例如约0.01-5mm)的中空非多孔颗粒。通常,这些颗粒将具有平均粒径(按重量计)约0.001mm或更大(例如约0.005mm或更大,或约0.01mm或更大)。这些颗粒优选具有平均粒径(按重量计)约3mm或更低(例如约0.015-3mm,约0.02-3mm或约0.1-3mm)或约2mm或更低(例如约0.015-2mm,约0.02-2mm,约0.5-2mm或约1-1.5mm)。
用于本发明的中空非多孔颗粒具有窄分子量分布。例如中空非多孔颗粒具有这样的颗粒尺寸分布,即至少约95%的颗粒(按重量计)具有粒径约5mm或更低(例如约0.01-5mm),优选约3mm或更低(例如约0.01-3mm,约0.015-3mm,约0.02-3mm或约0.1-3mm)或甚至约2mm或更低(例如约0.01-2mm,约0.015-2mm,约0.02-2mm,约0.5-2mm或约1-1.5mm)。这些颗粒合适地为球形。同时,该中空非多孔颗粒可具有双模态颗粒尺寸分布,其中该双模态颗粒尺寸的平均颗粒尺寸可为上述平均颗粒尺寸中的任何一种。双模态颗粒尺寸分布的平均颗粒尺寸的比例为至少约8∶1,如至少约10∶1或甚至至少约12∶1。
任何量的中空非多孔颗粒可用于耐热具有复合物中,例如,该耐热绝缘复合物(即耐热绝缘复合物的绝缘基层)可包括总约5-99vol.%的中空非多孔颗粒,按绝缘基层的总液体/固体体积计。该绝缘基层的总液体/固体体积可通过测量绝缘基层的合并的液体和固体组分(例如中空非多孔颗粒、粘结剂、发泡剂等)的体积确定。
若将绝缘基层(例如绝缘基层的基体粘结剂)发泡,则绝缘基层的总液体/固体组分的体积为发泡前合并的液体和固体组分的体积。当然,随着中空非多孔颗粒的比例升高,绝缘基层的导热性降低,由此产生增强的热绝缘性能;然而,绝缘基层的机械强度和完整性随中空非多孔颗粒的比例升高而降低,原因在于使用的基体粘结剂的相对量降低。因此通常需要在绝缘基层中使用约50-95vol.%,更优选约75-90vol.%的中空非多孔颗粒。
耐热绝缘复合物的绝缘基层可包括任何合适的基体粘结剂。该基体粘结剂就为含水或不含水粘结剂,尽管含水粘结剂因其使用容易性是优选的。这里使用的术语这里使用的术语含水粘结剂是指处于润湿或干燥状态的含水粘结剂(例如在含水粘结剂已干燥或固化前后,其中粘结剂可不再包括水的状态),即使粘结剂在干燥或固化后不能分散或溶于含水粘结剂中。优选的含水粘结剂是在干燥后提供耐水粘结剂组合物的那些。适宜的非水性基体粘结剂包括丙烯酸酯类、环氧类、丁醛类粘结剂、聚氧化乙烯粘结剂、醇酸树脂、聚酯、不饱和聚酯、和其它非水性粘结剂。合适的含水基体粘结剂包括例如丙烯酸类粘结剂、含硅氧烷的粘结剂、酚类粘结剂、乙酸乙烯酯粘结剂、乙烯-乙酸乙烯酯粘结剂、苯乙烯-丙烯酸酯粘结剂、苯乙烯-丁二烯粘结剂、聚乙烯醇粘结剂和聚氯乙烯粘结剂,和丙烯酰胺粘结剂,及其混合物和共聚物。该粘结剂可单独使用或与合适交联剂的组合。优选的含水粘结剂为含水丙烯酸类粘结剂。基体粘结剂,不管是含水的或非水性的,可单独使用,或与适宜的交联剂组合使用。
耐热绝缘复合物的绝缘基层可包括任何量的含水粘结剂。例如气绝缘基层可包括1-95vol.%的基体粘结剂,按绝缘基层的总液体/固体体积计。当然,随着基体粘结剂的比例升高,中空非多孔颗粒的比例必然降低,结果绝缘基层的导热性增加。因此,使用保持所需量的机械强度的尽可能少的基体粘结剂是适宜的。对于大多数应用,绝缘基层包括约1-50vol.%的基体粘结剂,或约5-25vol.%的基体粘结剂,或甚至约5-10vol.%的基体粘结剂。
绝缘基层可包括不透明剂,它降低绝缘基层的导热性。合适的不透明剂可使用(包括但不限于)炭黑、碳纤维、二氧化钛或改性含碳组分,如WO96/18456A2中描述。
绝缘基层除了基体粘结剂和非多孔颗粒外,优选包括发泡剂。不需要受到任何理论约束下,据信该发泡剂增强了基体与中空非多孔颗粒之间的粘结力。此外,据信发泡剂改进基体粘结剂的流变性能(例如可用于喷雾涂布),特别是在加入中空非多孔颗粒前或后,通过搅拌或混合(例如起泡)合并的基体粘结剂和发泡剂使基体粘结剂发泡,尽管可在不将粘结剂发泡下使用发泡剂。此外,可有利地使用发泡的粘结剂,以提供具有比非发泡基层低的密度的发泡绝缘基层。
尽管使用的发泡剂可通过搅拌或混合使基体粘结剂发泡,当然,该粘结剂可使用其它方法,在使用或不使用发泡剂下发泡。例如,该基体粘结剂可用压缩空气或推进剂发泡,或可将粘结剂通过喷嘴(例如形成高剪切或湍流的喷嘴)使其发泡。
任何合适的发泡剂可用于绝缘基层中。合适的发泡剂包括但不限于泡沫增强表面活性剂(例如非离子、阳离子、阴离子和两性离子表面活性剂),以及其它可市购的泡沫增强剂,或其混合物。该发泡剂应存在足够的量以使基体粘结剂发泡,若需要这种发泡。优选使用约0.1-5wt.%,例如约0.5-2wt%的发泡剂。
该绝缘基层还包括增强纤维。这些增强纤维还可对绝缘基层提供额外的机械强度,并因此提供绝缘复合物额外的机械强度。可使用任何合适类型的纤维,如玻璃纤维、氧化铝、磷酸钙矿物棉、硅灰石、陶瓷、纤维素、碳、棉花、聚酰胺、聚苯并咪唑、聚芳酰胺、丙烯酸类、酚类、聚酯、聚乙烯、PEEK、聚丙烯和其它聚烯烃类型,或其混合物。优选的纤维为耐热和耐火的纤维,如不具有可呼吸片断的纤维。纤维还可为反射红外辐射的纤维类型,如碳纤维、金属化纤维、或其它合适的红外反射材料的纤维。这些纤维可为任何合适长度的单股,其可通过例如将纤维与绝缘基层的其它组分喷涂到基材上(例如通过在喷涂前将纤维与绝缘基层的一种或多种其它组分混合,或通过单独将纤维喷涂在基材上)施用。此外,该纤维可纤维网或编织网形式,例如可将其涂于基材上,并将绝缘基层的其它组分喷涂、刷涂或以其它方式涂于纤维网或编织网上。可施用足够量的纤维,以对其中将使用耐热绝缘复合物的特定应用提供所需量的机械强度。该纤维的存在量通常为约0.1-50wt.%,合适地约0.5-20wt.%,如约1-10wt.%,按绝缘基层的重量计。
绝缘基层可具有任何所需厚度。包括较厚绝缘基层的耐热绝缘复合物具有较大的隔热和/或隔音性能;然而,本发明的耐热绝缘复合物可使用相当薄的绝缘基层,同时仍然提供优良的隔热和/或隔音性能。对于大多数应用,厚度约1-15mm,例如约2-6mm的绝缘基层提供足够的绝缘。
该绝缘基层的导热性将部分取决于用于提供绝缘基层的特殊配方。优选配制绝缘基层以在干燥后具有导热性约50mW/(m·K)或更低。配制的绝缘基层在干燥后应具有导热性约45mW/(m·K)或更低,更优选约mW/(m·K)或更低,或甚至约40mW/(m·K)或更低(例如约35mW/(m·K))。
类似地,该绝缘基层在干燥后的密度部分取决于用于提供绝缘基层的特定配方。优选配制绝缘基层以在干燥后具有密度约0.5g/cm3或更低,优选约0.1g/cm3或更低,最优选约0.08g/cm3或更低(例如约0.05g/cm3或更低)。
耐热绝缘复合物的热反射层包括保护粘结剂。散热反射层赋予绝缘复合物较高的机械强度和/或保护基层不会因一种或多种环境因素(例如热、潮湿、磨损、冲击等)造成的降解。保护粘结剂可为耐热绝缘复合物将暴露其下的特定条件(例如热、应力、潮湿等)的任何合适粘结剂。因此粘结剂的选取将部分取决于耐热绝缘复合物所需的特殊性能。该保护粘结剂可与绝缘基层的基体粘结剂相同或不同。合适的粘结剂的例子包括含水和非水天然和合成粘结剂。这些粘结剂的例子包括如上所述的适用于绝缘基层的任何含水粘结剂以及非水粘结剂。优选的粘结剂为含水粘结剂,如含水丙烯酸类粘结剂。特别优选的是自交联粘结剂,如自交联丙烯酸类粘结剂。热反射层可含有中空非多孔颗粒,优选基本上无或完全无空非多孔颗粒。基本上中空非多孔颗粒是指热反射层合约20vol.%或更低、如约10vol.%或更低,或甚至约5vol.%或更低(例如约1vol.%或更低)的中空非多孔颗粒。
红外反射试剂可为反射或不阻止红外辐射的任何化合物或组合物,包括不透明剂如含碳物质(例如炭黑)、碳纤维、二氧化钛(金红石),尖晶石颜料,以及金属和非金属颗粒,颜料和纤维,及其混合物。优选的红外反射剂包括金属颗粒、颜料和糊料,如铝、不锈钢、黄铜,铜/锌合金和铜/铬合金。特别优选铝颗粒、颜料和糊料。为防止红外反射剂在保护粘结剂中沉降,热反射层有利地包括抗沉降剂。合适的抗沉降剂包括市购的煅制金属氧化物、粘土和金属悬浮试剂。特别优选的抗沉降试剂是煅制金属氧化物如煅制二氧化硅,和粘土如hectorites。该热反射层还可包括润湿剂,如非发泡表面活性剂。
热反射层的优选配料包括增强纤维。该增强纤维可对热反射层提供额外的机械强度,并因此提供绝缘复合物额外的机械强度。可使用任何合适类型的纤维,如玻璃纤维、氧化铝、磷酸钙、矿物棉、硅灰石、陶瓷、纤维素、碳、棉花、聚酰胺、聚苯并咪唑、聚芳酰胺、丙烯酸类、酚类、聚酯、聚乙烯、PEEK、聚丙烯和其它聚烯烃类型,或其混合物。优选的纤维为耐热和耐火的,如不具有可呼吸部分的纤维。纤维还可为反射红外辐射的纤维类型,并且可与上述红外反射剂一起使用或代替上述红外反射剂。例如可使用碳纤维或金属化纤维,它们同时提供增强性能和红外反射性能。这些纤维可为任何合适长度的单股,其可通过例如将纤维与热反射层的其它组分喷涂到绝缘基层上(例如通过在喷涂前将纤维与热反射层的一种或多种其它组分混合,或通过单独将纤维喷涂在绝缘基层上)施用。此外,该纤维可纤维网或编织网形式,例如可将其涂于绝缘基层上,并将热反射层的其它组分喷涂、刷涂或以其它方式涂于纤维网或编织网上。可施用足够量的纤维,以对其中将使用绝缘复合物的特定应用提供所需量的机械强度。该纤维的存在量通常为约0.1-50wt.%,合适地约1-20wt.%,如约2-10wt.%,按热反射层的重量计。
热反射层的厚度将部分取决于保护程度和所需的强度。尽管热反射层可为任何厚度,但通常需要保持耐热绝缘复合物的厚度最小,并由此将热反射层的厚度降至所需的最小量以提供特定应用的足够保护量。通常,可通过约1mm厚或更低的热反射层提供足够的保护。
该耐热绝缘复合物的导热性将部分取决于用于提供绝缘基层的特殊配方。尽管热反射层的配方具有一些影响。合适地配制耐热绝缘复合物以在干燥后具有导热性约50mW/(m·K)或更低。优选配制耐热绝缘复合物以在干燥后应具有导热性约45mW/(m·K)或更低,更优选约42mW/(m·K)或更低,或甚至约40mW/(m·K)或更低(例如约35mW/(m·K))。
这里用于描述本发明绝缘复合物的术语“耐热性”是指该绝缘复合物在高热条件下基本上不降解。本发明中认为绝缘复合物耐热的含义是,该复合物暴露于高热条件下1小时后,该绝缘复合物保持原质量的至少约85%,优选至少约90%,更优选至少约95%,或甚至至少约98%或所有其原质量。具体地,高耐热条件按如下设置:使用250W加热元件(IRB,由EdmundBilhier GmbH,Germany制造),这些元件与热空气鼓风机(HG3002LCD,由Steinel GmbH,Germany制造)连接,其具有围绕该装置排列的铝板,由此形成洞道。将该绝缘复合物在距离加热元件约20mm处(保护层面对加热元件)暴露于高热条件下,其中热空气鼓风机(在完全鼓风设定和最低热设定下)在加热元件与绝缘复合物之间提供连续空气流。该耐热绝缘复合物在这些条件下不会出现肉眼可见的降解。
当该耐热绝缘复合物在特定可燃性分级条件下使用时,例如当将其暴露于明火焰或特别高温条件下时,该绝缘复合物需要包括合适的阻燃剂。阻燃剂可包括在绝缘复合物的绝缘基层和/或热反射层中。合适的阻燃剂包括氢氧化铝、氢氧化镁、多磷酸铵和各种含磷物质,和其它可市购的阻燃剂和膨胀剂。
耐热绝缘复合物(例如绝缘复合物的绝缘基层和/或热反射)还可包括其它组分,如本领域已知的各种添加剂。这些添加剂的例子包括流变控制剂和增稠剂,如煅制二氧化硅、聚丙烯酸酯、聚羧酸、纤维素聚合物,以及天然树胶、淀粉和糊精。其它添加剂包括溶剂和助溶剂,以及蜡、表面活性剂、固化和交联剂。
制备耐热绝缘复合物的方法
本发明进一步提供一种制备耐热绝缘复合物的方法,该方法包括、基本组成为或组成为:(a)在基物上设置绝缘基层,该基层包括、基本组成为或组成为中空非多孔颗粒、基体粘结剂、和非必要的发泡剂,和(b)将包括保护粘结剂红外反射剂的热反射层涂于绝缘基层表面,其中耐热绝缘复合物具有导热性约50 mW/(m·K)或更低。按照此方法制备的耐热绝缘复合物的各种元素为前面描述的。
绝缘基层可通过任何合适的方法提供。例如,例如可将中空非多孔颗粒与基体粘结剂通过任何合适的方法混合制备含颗粒的粘结剂组合物,然后例如通过将含颗粒的粘结剂组合物刷涂或喷涂于基物上的将其施于基物上。
然而,绝缘基层优选通过下面的方法提供:(a)提供一种粘结剂组合物,它包括、基本组成为或组成为基体粘结剂和发泡剂,(b)搅拌粘结剂组合物以提供发泡的粘结剂组合物,(c)将该发泡的粘结剂组合物与中空非多孔颗粒混合提供含颗粒的粘结剂组合物,和(d)将该含颗粒的粘结剂组合物涂于基材上以提供绝缘基层。
此外,该绝缘基层通过如下方法提供:(a)提供一种粘结剂组合物,它包括、基本组成为或组成为基体粘结剂和非必要的发泡剂;(b)提供一种颗粒组合物,它包括、基本组成为或组成为中空非多孔颗粒;和(c)将该粘结剂组合物和颗粒组合物同时涂于基材上,其中将粘结剂组合物与颗粒组合物混合以提供绝缘基层。
该颗粒组合物包括、基本组成为或组成为如上所述的中空非多孔颗粒和非必要的合适载体。根据本发明,可将粘结剂组合物和/或颗粒组合物(例如一起或分别)通过任一合适的方法,例如通过将该粘结剂组合物和/或颗粒组合物或其组分一起同时涂于基物上。术语“同时涂布”是指将颗粒组合物和粘结剂组合物同时分别输送到基物上,其中在输送过程中将颗粒组合物和粘结剂组合物混合(例如在流路中或基物表面上混合)。这可通过例如将颗粒组合物和粘结剂组合物同时喷涂于基物上完成,由此将颗粒组合物和粘结剂组合物通过单独的流路输送。这些流路可在喷涂装置内连接,这样可将混合的颗粒-粘结剂组合物输送到基物上,或流路可完全分离,这样将颗粒组合物和粘结剂组合物在相应的组合物到达基物时才混合。
通过按此方式将粘结剂组合物与中空非多孔颗粒混合,可提供具有合适性能的含颗粒粘结剂组合物。在不希望受任何特殊理论束缚下,根据本发明生产的含颗粒粘结剂组合物呈现降低中空非多孔颗粒从组合物中分离的趋势。此外,本发明方法可使用高的颗粒与粘结剂的比例,如此含颗粒粘结剂组合物的热性能并降低组合物的密度。此外,本发明的方法提供一种可喷涂的含颗粒粘结剂组合物,使该组合物在应用中具有适应性。中空非多孔颗粒、粘结剂组合物和发泡剂为前面描述的。
尽管优选可通过搅拌或混合使粘结剂单独或与发泡剂组合发泡,但也可以使用其它方法发泡。例如粘结剂可用压缩空气或推进剂发泡,或可将粘结剂通过喷嘴(例如产生高剪切或湍流的喷嘴)发泡。
耐热绝缘复合物的热反射层可通过任何合适的方法涂于绝缘基层的表面。该热反射层的组分为前面描述的。优选将该热反射层的组分混合以提供热反射涂料组合物,然后将其通过任何合适的方法例如通过刷涂或喷涂涂于绝缘基层的表面上。
尽管可将粘合剂或偶联剂用于使热反射层与绝缘基层粘结,但根据本发明并不需要这些粘合剂,因为绝缘基层或热反射层中的粘结剂可提供所需的粘结力。优选在绝缘基层为润湿的时将热反射层涂于绝缘基层上,但也可在绝缘基层干燥后涂布。该耐热绝缘复合物(例如绝缘复合物的绝缘基层和/或热反射层)可在环境条件或加热下例如在烘箱中干燥。
应用和最终用途
本发明的耐热绝缘复合物及其制备方法当然可用于任何合适的目的。然而,本发明的耐热绝缘复合物特别适用于要求绝缘的应用,在该应用模式中提供热稳定性、机械强度和/或柔韧性。例如,按照优选的配料,特别是可喷涂的配料,耐热绝缘复合物可用于耐高温的绝缘表面,并且特别适用于通过常规方法保护困难或费用高的表面。这些应用的例子包括机动车辆和装置的各种部件,如发动机部件、防火墙、油罐、转向柱、承油盘、中继线和备用轮胎,或机动车或装置的任何其它部件。该耐热绝缘复合物特别适用于机动车底部的绝缘,特别是作为接近排气系统的部件的保护。当然,本发明的耐热绝缘复合物可用于在很多其它应用中提供绝缘。例如该耐热绝缘复合物可用于使管道、壁和加热或冷却导管绝缘。尽管耐热绝缘复合物的优选配料可为可喷涂的配料,但该耐热绝缘复合物和也可挤出或模塑以提供绝缘制品如瓦片、嵌板或各种成型制品。为此,本发明还提供一种基物,如前面描述的任何一种,它包括本发明的耐热绝缘复合物,以及使基物绝缘的方法,该方法包括使用耐热绝缘复合物、或其制备方法或用途中的任何一种。
下面的实施例进一步说明本发明,当然不以任何方式限制其范围。
实施例1
本实施例说明本发明耐热绝缘复合物的制备和性能。
按如下制备含颗粒的粘结剂组合物(样品1A),将200g含水丙烯酸酯粘结剂(LEFASOLTM 168/1,制造商Lefatex Chemie GmbH,Germany)、1.7g发泡剂(HOSTAPURTMOSB,制造商Clariant GmbH,Germany)和30g多磷酸铵阻燃剂(ExoLITTM AP420,制造商Clariant GmbH,Germany)在常规混合器中混合。将该粘结剂组合物混合至获得3dm3发泡组合物。然后在搅拌下慢慢加入100g中空非多孔玻璃微球(B23/500,制造商3M,Inc.,Minnesota),以保持体积3dm3,由此提供含颗粒的粘结剂组合物(样品1A)。
按与样品1A相同的方式制备另外两种含颗粒的粘结剂组合物(样品1B和1C),不同的是用perlite (StaubexTM,制造商Deutsche Perlite GmbH,Germany)和沥青化perlite(ThermoperlTM,制造商Deutsche Perlite GmbH,Germany)代替玻璃微球。
将各组合物用刮刀涂于具有深度1.5cm的25cm×25cm框架上。将该框架衬上铝箔。将该组合物在130℃下干燥2小时。将该组合物冷却后,从框架中切割出20cm×20cm样品,各样品的导热性用LAMBDACONTROLTM A50导热仪器(制造商Hesto Elektronik GmbH,Germany)在上压盘温度36℃和下压盘温度10℃下测量。样品的密度用各样品的重量除以其尺寸测定。结果在表1中给出。
表1
样品 | 颗粒 | 密度(g/cm3) | 导热性(mW·m-1·K-1) | 观察 |
1A | 玻璃微球 | 0.08 | 42 | 复合物为白色柔软和自支撑的 |
1B | perlite | 0.11 | 53 | 复合物为刚性且易碎,在颗粒之间存在很大的空隙 |
1C | 沥青化的perlite | 0.17 | 63 | 复合物为刚性且易碎,在颗粒之间存在很大的空隙 |
这些结果说明,可在本发明耐热绝缘复合物中用作绝缘基层的含颗粒粘结剂组合物与使用其它颗粒材料的组合物相比,提供较低的导热性和较低的密度。同时,含该颗粒的粘结剂组合物与其它复合物相比不容易破碎和刚性较低。
将含颗粒的粘结剂组合物作为绝缘基层涂于基材上,在其上涂布热反射涂料以形成耐热绝缘复合物。例如可通过将58g含水丙烯酸酯粘结剂(WORLEECRYLTM1218,制造商Worlee Chemie GmbH,Germany)与22.6g煅制二氧化硅抗沉降剂(CAB-O-SPERSETM,制造商Cabot Corporation,Massachusetts)和作为红外反射剂的19.4g铝颜料糊料(STAPATM HydroxalWH 24n.l.,制造商Eckart GmbH,Germany).制备热反射涂料组合物。将该组合物用磁搅拌器轻轻混合。混合后,优选在绝缘基层干燥前,例如通过喷涂至约1mm厚将该涂料组合物涂于绝缘基层上。
与不存在热反射涂层的相同绝缘基层相比,如此制备的含颗粒绝缘复合物提供优良的耐热性,同时保持低导热性和低密度。
实施例2
本实施例说明本发明耐热绝缘复合物的制备和性能。
按如下制备含颗粒的基体粘结剂组合物(样品2A):将200g含水丙烯酸粘结剂(LEFASOLTM 168/1,制造商Lefatex Chemie GmbH,Germany)、1.2g发泡剂(HOSTAPURTMOSB,制造商Clariant GmbH,Germany)和10g水在Oakes发泡器(购自E.T.Oakes Corporation,Hauppauge,New York)中,在转子-定子速度约1000rpm、泵速约25%容量和空气流速约2.4dm3/min下混合。然后用常规混合器慢慢加入15g中空非多孔热塑性树脂微球(EXPANCEL091 DE 40 d30微球,制造商Akzo Nobel)以保持混合物体积,由此提供含颗粒粘结剂组合物。
按与上面样品2A相同的方式制备第二种含颗粒的粘结剂组合物(样品2B),不同的是用中空非多孔热塑性树脂微球和中空非多孔玻璃微球的混合物代替单独中空非多孔热塑性树脂微球。特别的,该混合物由38.3g中空非多孔热塑性树脂微球(具体地,,5g EXPANCEL091 DE 40 d30微球和33.3g EXPANCEL551WE 40 d36微球,制造商都是Akzo Nobel))和45g中空非多孔玻璃微球(B23/500玻璃微球,制造商3M,Minneapolis,MN)组成。各种类型的中空非多孔颗粒包括相同的量,按总中空非多孔颗粒组合物的体积计。此外,样品2B中中空非多孔颗粒的体积百分比与样品2A中的相同。
将各组合物用刮刀涂于具有深度约1.5cm的25cm×25cm铝箔衬里框架上。将该组合物在130℃下干燥2小时。将该组合物冷却后,从框架中切割出20cm×20cm样品,各样品的导热性用LAMBDACONTROLTM A50导热仪器(制造商Hesto Elektronik GmbH,Germany)在上压盘温度36℃和下压盘温度10℃下测量。样品的密度用各样品的重量除以其尺寸测定。结果在表2中给出。
表2
样品 | 颗粒 | 密度(g/cm3) | 导热性(mW·m-1·K-1) | 观察 |
2A | 热塑性树脂微球 | 0.059 | 34.2 | 复合物为浅黄色和自支撑的 |
2B | 热塑性树脂微球和玻璃微球 | 0.066 | 39.7 | 复合物为刚性且稍微发碎。 |
这些结果说明,可在本发明耐热绝缘复合物中用作绝缘基层的含颗粒粘结剂组合物提供低导热性和低密度。
实施例3
本实施例说明本发明的绝缘复合物的耐热性。
按如下制备热反射涂料组合物,将58g含水丙烯酸酯粘结剂(WORLEECRYLTM1218,制造商Worlee Chemie GmbH,Germany)与22.6g煅制二氧化硅抗沉降剂(CAB-O-SPERSETM,制造商Cabot Corporation,Massachusetts)和作为抗红外反射剂的19.4g铝颜料糊料(STAPATMHydroxal WH 24n.l.,制造商Eckart GmbH,Germany)混合。将该混合物用磁搅拌器慢慢混合。
然后将该热反射涂料组合物涂于实施例2的含颗粒粘结剂组合物(样品2A和2B)上使其具有厚度约1mm,由此获得具有绝缘基层和热反射层的绝缘复合物(分别为样品3A和3B)。将该热反射涂料组合物也涂于第三种含颗粒组合物上得到第三种绝缘复合物(样品3C)。该第三种含颗粒组合物按与样品2A相同的方式制备,但中空非多孔热塑性树脂微球的量和类型不同(使用100g EXPANCEL551 WE 40 d36 179.2微球(购自Akzo Nobel))。
然后将各绝缘复合物放在设计的仪器中以测定绝缘复合物的耐热性。具体地,该仪器包括250W加热元件(IRB,由EdmundBilhier GmbH,Germany制造),这些元件与热空气鼓风机(HG3002 LCD,由Steinel GmbH,Germany制造)连接,其具有围绕该装置排列的薄铝板,由此形成洞道。将该绝缘复合物在距离加热元件(热反射层面对加热元件)约20mm处暴露于高热条件下约30分钟,同时热空气鼓风机(在完全鼓风设定和最低热设定下)在加热元件与绝缘复合物之间提供连续空气流。在整个测试中监测该绝缘复合物的背面(即热反射层和加热元件反面)温度以确定最大忍耐温度。这些测量结果在下表3中给出。
表3
样品 | 颗粒 | 背面温度(℃) |
3A | 热塑性树脂微球 | 27 |
3B | 热塑性树脂微球和玻璃 | 25 |
微球 | ||
3C | 热塑性树脂微球 | 28 |
这些结果证明本发明的绝缘复合物耐热并且在高热条件下显示良好的热绝缘性能。
这里引用的所有参考文献(包括公开出版物、专利申请和专利)按照与各自单独和具体引入的相同程度引入,并且其整体内容这里引入作为参考。
描述本发明的上下文(特别是下面权利要求上下文)中使用的术语“a”、“an”和“the”和类似的指代词应解释为同时覆盖单数和复数,除非另有说明或通过上下文明显相反。术语“包含、“具有”和“包括”应解释为开放式的(意即“包括、但不限于”),除非另有说明。这里数值范围的叙述仅起到分别针对落入该范围的各分离值的缩写方法的作用,除非另有说明,各分离的值包括在说明书中,与单独引用的一样。这里描述的方法可以任何合适的顺序进行,除非另有说明或通过上下文明显相反。这里给出的任一和所有实施例或示例性语言(如“例如”)的使用仅用于更好地说明本发明而不对本发明的范围施加任何限制,除非另有说明。说明书中的语言不应解释为是表示作为实施本发明基本的任何不要求保护的元素。
这里描述了本发明的优选实施方案,包括发明人已知的实施本发明的最佳方式。在阅读说明书后,那些优选实施方案的各种变化对本领域熟练技术人员变得显而易见的。发明人预期本领域熟练技术人员可合适地使用这些变化,发明人将通过不同于这里描述的具体实施方案的其它方式实施本发明。因此,本发明包括专利法允许的所附权利要求中引用的主题的各种改进和等同物。此外,除非另有说明或与上下文明显相反,在其所有变化中的上述元素的任何组合都包括在本发明中。
Claims (11)
1. 一种耐热绝缘复合物,包括绝缘基层和热反射层,特征在于
(a)该绝缘基层包括中空非多孔颗粒和基体粘结剂,和
(b)该热反射层包括红外反射剂和保护粘结剂,
且其中耐热绝缘复合物具有导热性50mW/(m·K)或更低。
2.权利要求1的耐热绝缘复合物,其中绝缘基层包括5-99vol.%的中空非多孔颗粒。
3.权利要求1-2任何一项的耐热绝缘复合物,其中绝缘基层的厚度为1-10mm。
4.权利要求1-2任何一项的耐热绝缘复合物,其中绝缘基层在干燥后具有密度0.5g/cm3或更低。
5.权利要求1-2任何一项的耐热绝缘复合物,其中热反射层的厚度为1mm或更低。
6.一种基物,特征在于该基物包括权利要求1-5任何一项的耐热绝缘复合物。
7.权利要求6的基物,其中基物为机动车或装置的部件。
8.权利要求6或7的基物,其中基物为机动车的底部或其部件。
9.一种制备耐热绝缘复合物的方法,包括:(a)在基物上设置绝缘基层,该基层包括中空非多孔颗粒和基体粘结剂,和(b)将包括保护粘结剂和红外反射剂的热反射层涂于绝缘基层表面,其中耐热绝缘复合物具有导热性50mW/(m·k)或更低。
10.权利要求9的方法,其中绝缘基层通过喷涂涂于基物上。
11.权利要求9-10任何一项的方法,其中热反射层通过喷涂涂于绝缘基层表面。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38096702P | 2002-05-15 | 2002-05-15 | |
US60/380,967 | 2002-05-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1668871A CN1668871A (zh) | 2005-09-14 |
CN1325833C true CN1325833C (zh) | 2007-07-11 |
Family
ID=32176363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038167778A Expired - Fee Related CN1325833C (zh) | 2002-05-15 | 2003-05-15 | 耐热绝缘复合物、含该复合物的基物、和其制备方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20050025952A1 (zh) |
EP (1) | EP1511959A2 (zh) |
JP (1) | JP4559229B2 (zh) |
CN (1) | CN1325833C (zh) |
AU (1) | AU2003299511B2 (zh) |
RU (1) | RU2303744C2 (zh) |
WO (1) | WO2004037533A2 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI761013B (zh) * | 2020-12-31 | 2022-04-11 | 金門化工有限公司 | 防火阻熱樹脂組成物及防火阻熱層 |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8132382B2 (en) * | 2004-06-17 | 2012-03-13 | Certainteed Corporation | Insulation containing heat expandable spherical additives, calcium acetate, cupric carbonate, or a combination thereof |
US20050281979A1 (en) * | 2004-06-17 | 2005-12-22 | Toas Murray S | Loose fill insulation product having phase change material therein |
WO2006024010A2 (en) * | 2004-08-24 | 2006-03-02 | Aspen Aerogels, Inc. | Aerogel-based vehicle thermalmanagement systems and methods |
US20060057351A1 (en) * | 2004-09-10 | 2006-03-16 | Alain Yang | Method for curing a binder on insulation fibers |
US20060123723A1 (en) * | 2004-12-09 | 2006-06-15 | Weir Charles R | Wall finishing panel system |
US8003028B2 (en) * | 2005-07-26 | 2011-08-23 | The Boeing Company | Composite of aerogel and phase change material |
DE102006039261A1 (de) * | 2006-08-22 | 2008-03-06 | Lanxess Deutschland Gmbh | Zugerichtetes Leder |
US20090239429A1 (en) | 2007-03-21 | 2009-09-24 | Kipp Michael D | Sound Attenuation Building Material And System |
US8445101B2 (en) * | 2007-03-21 | 2013-05-21 | Ashtech Industries, Llc | Sound attenuation building material and system |
CN101688393A (zh) * | 2007-03-21 | 2010-03-31 | 阿什工业技术有限责任公司 | 结合微粒基质的实用材料 |
US7953247B2 (en) * | 2007-05-21 | 2011-05-31 | Snap-On Incorporated | Method and apparatus for wheel alignment |
US8591677B2 (en) | 2008-11-04 | 2013-11-26 | Ashtech Industries, Llc | Utility materials incorporating a microparticle matrix formed with a setting agent |
DE202009010576U1 (de) | 2009-08-05 | 2009-10-29 | Peter-Lacke Gmbh | Beschichtung für ein Trägerteil |
DE102010029513A1 (de) * | 2010-05-31 | 2011-02-24 | Wacker Chemie Ag | Dämmung mit Schichtaufbau |
FI2598459T3 (fi) * | 2010-07-30 | 2023-04-19 | Rockwool As | Menetelmä aerogeeliä sisältävän komposiitin valmistamiseksi |
CN101967046B (zh) * | 2010-09-14 | 2012-12-05 | 陈西才 | 一种天然彩玉外墙外隔热保温层涂料的配方及生产方法 |
RU2462331C2 (ru) * | 2010-09-15 | 2012-09-27 | Государственное образовательное учреждение высшего профессионального образования "Пермский государственный технический университет" | Способ получения композиционного материала на основе карбосилицида титана и титанового пористо-волокнистого компонента |
CN102454228A (zh) * | 2010-10-19 | 2012-05-16 | 叶福春 | 一种复合型酚醛保温板 |
FR2975691B1 (fr) * | 2011-05-26 | 2014-02-07 | Electricite De France | Materiau super-isolant a pression atmospherique a base d'aerogel |
RU2475897C1 (ru) * | 2011-07-06 | 2013-02-20 | Открытое акционерное общество "Энергия" | Способ изготовления тепловой изоляции для теплового литиевого источника тока |
RU2012100941A (ru) * | 2012-01-11 | 2013-07-20 | Юрий Николаевич Дубов | Способ применения полимерного материала |
US9976687B2 (en) | 2012-05-18 | 2018-05-22 | Saprex, Llc | Breathable multi-component exhaust insulation system |
CN102702982A (zh) * | 2012-05-24 | 2012-10-03 | 浙江东化实业有限公司 | 全粒面皮革抛光补伤膏 |
US9388515B2 (en) | 2012-09-28 | 2016-07-12 | Saprex, Llc | Heat curable composite textile |
JP5727986B2 (ja) * | 2012-10-31 | 2015-06-03 | ニチハ株式会社 | 建築板及びその製造方法 |
SK6703Y1 (sk) * | 2012-12-31 | 2014-03-04 | Rusnak Matej | Hmota na povrchovĂş Ăşpravu a jej pouĹľitie |
KR101583651B1 (ko) * | 2013-03-07 | 2016-01-08 | 주식회사 아모그린텍 | 단열재용 코어 및 그의 제조방법과 이를 이용한 슬림형 단열재 |
JP6369849B2 (ja) * | 2013-12-11 | 2018-08-08 | 関西ペイント株式会社 | 断熱塗材、断熱建材及び建築物改修方法 |
DE102014222851A1 (de) * | 2014-11-10 | 2016-05-12 | BSH Hausgeräte GmbH | No-Frost-Kältegerät |
JP6281551B2 (ja) * | 2015-09-30 | 2018-02-21 | マツダ株式会社 | エンジン燃焼室の断熱構造 |
RU2633386C2 (ru) * | 2016-03-15 | 2017-10-12 | Акционерное общество АО "Энергия" | Способ изготовления супертонкой тепловой изоляции для теплового источника тока |
DK3443254T3 (da) * | 2016-04-15 | 2024-03-18 | Saprex Llc | Kompositisoleringssystem |
US10570308B2 (en) * | 2016-07-08 | 2020-02-25 | Akzo Nobel Coatings International B.V. | Heat insulating coating composition, method for applying such coating composition and kit of parts comprising such coating composition |
WO2018033218A1 (de) * | 2016-08-19 | 2018-02-22 | Wacker Chemie Ag | Wärmedämmverbundsystem |
RU176949U1 (ru) * | 2016-10-10 | 2018-02-02 | Александр Валерьевич Бояринцев | Устройство теплоизоляции резервуаров, цистерн, емкостей, танкеров и оборудования (хранения, транспортировки и переработки жидкостей) с использованием теплоизоляционного покрытия на основе полых микросфер, предотвращающее теплопотери и конденсатообразование |
DE102016121807A1 (de) * | 2016-11-14 | 2018-05-17 | Joint Stock Company Railway Research Institute | Solarstrahlung-reflektierende Beschichtung und deren Verwendung |
WO2018094339A1 (en) | 2016-11-18 | 2018-05-24 | Saprex, Llc | Composite insulation system |
DE102016226064A1 (de) * | 2016-12-22 | 2018-06-28 | Kautex Textron Gmbh & Co. Kg | Hohlkörper umfassend eine Wand aus einem mehrschichtigen thermoplastischen Kunststoff sowie Verfahren zu dessen Herstellung |
CN109137537B (zh) * | 2018-09-10 | 2020-03-27 | 钟金榜 | 封闭多孔复合材料、隔热材料、隔音材料、其制造方法 |
RU2722596C1 (ru) * | 2019-04-08 | 2020-06-02 | Шахурин Иван Александрович | Связующая композиция для получения изоляционного композитного материала и изоляционный композитный материал |
CN110077063A (zh) * | 2019-04-25 | 2019-08-02 | 上海驰纺材料科技有限公司 | 一种基于气凝胶的高保暖纺织复合材料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5631097A (en) * | 1992-08-11 | 1997-05-20 | E. Khashoggi Industries | Laminate insulation barriers having a cementitious structural matrix and methods for their manufacture |
US5641584A (en) * | 1992-08-11 | 1997-06-24 | E. Khashoggi Industries | Highly insulative cementitious matrices and methods for their manufacture |
US5665442A (en) * | 1992-08-11 | 1997-09-09 | E. Khashoggi Industries | Laminated sheets having a highly inorganically filled organic polymer matrix |
Family Cites Families (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3249463A (en) * | 1962-09-21 | 1966-05-03 | Interchem Corp | Acrylic latex coating composition and book cover material made therefrom |
US4001379A (en) * | 1968-04-27 | 1977-01-04 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of making superfine amorphous high structural silicic acid |
US4003981A (en) * | 1968-04-27 | 1977-01-18 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of making superfine amorphous high structure silicic acid |
US3634288A (en) * | 1969-04-16 | 1972-01-11 | Nalco Chemical Co | Preparation of hydrophobic silica sol for use as antifoaming agent |
US3868299A (en) * | 1969-09-04 | 1975-02-25 | Bayer Ag | Insulating glass unit containing absorbent mixture |
GB1298701A (en) * | 1969-11-12 | 1972-12-06 | Foseco Int | Heat-insulating antipiping compounds |
US3874944A (en) * | 1969-12-31 | 1975-04-01 | Polaroid Corp | Diffusion transfer processes employing permanent laminate film units |
US3716431A (en) * | 1970-05-14 | 1973-02-13 | Vistron Corp | Process for preparing striped sheet material continuously |
GB1350661A (en) * | 1970-06-10 | 1974-04-18 | Micropore International Ltd | Thermal insulating materials |
US3869297A (en) * | 1970-06-15 | 1975-03-04 | Chevron Res | Aluminum coatings based on clay-emulsified asphalts |
US3775351A (en) * | 1970-10-28 | 1973-11-27 | C Sachs | Production of polymer-inorganic foam |
US3869334A (en) * | 1971-06-10 | 1975-03-04 | Micropore Insulation Limited | Insulating materials |
US3812886A (en) * | 1972-07-05 | 1974-05-28 | Midwesco Enterprise Inc | Cryogenic insulation |
US3816154A (en) * | 1973-05-18 | 1974-06-11 | Goury T Mc | Silica gel flatting agent |
US3830666A (en) * | 1973-06-12 | 1974-08-20 | Us Army | Insulation application |
DE2359611C3 (de) * | 1973-11-30 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von durch Harze auf Isocyanatbasis gebundenen Füllstoffen |
JPS5325856B2 (zh) * | 1974-02-06 | 1978-07-29 | ||
DE2414478C3 (de) * | 1974-03-26 | 1978-07-13 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Aerogelartige strukturierte Kieselsäure und Verfahren zu ihrer Herstellung |
US4038077A (en) * | 1974-04-04 | 1977-07-26 | Polaroid Corporation | Process comprising diffusion transfer silver image removal |
US3955034A (en) * | 1974-06-24 | 1976-05-04 | Nasa | Three-component ceramic coating for silica insulation |
US3953646A (en) * | 1974-06-24 | 1976-04-27 | Nasa | Two-component ceramic coating for silica insulation |
US3968281A (en) * | 1974-07-15 | 1976-07-06 | Sybron Corporation | Filter molded heating and/or insulating member |
GB1540825A (en) * | 1975-02-27 | 1979-02-14 | Ici Ltd | Paint compositions |
DE2613099B2 (de) * | 1975-03-28 | 1981-04-30 | Dai Nippon Toryo Co., Ltd., Osaka | Wäßrige Dispersionsbeschichtungsmassen |
US4146585A (en) * | 1977-03-02 | 1979-03-27 | Union Carbide Corporation | Process for preparing silane grafted polymers |
US4209566A (en) * | 1977-07-18 | 1980-06-24 | General Electric Company | Method of improving the electrical properties of polymeric insulations containing polar additives, and the improved polymeric insulation product thereof |
DE2750903C2 (de) * | 1977-11-14 | 1982-12-09 | Basf Farben + Fasern Ag, 2000 Hamburg | Verwendung eines Beschichtungsmittels auf der Basis von Acrylatpolymerisaten für verschiedene Anwendungszwecke, insbesondere im Bautenbereich |
GB1603972A (en) * | 1978-02-15 | 1981-12-02 | Reed K J | Transfer sheets with releasable layers |
US4332852A (en) * | 1978-03-29 | 1982-06-01 | Kennecott Corporation | Conditioned colloidal silica post impregnant to prevent binder migration in the production of insulation articles comprising randomly oriented refractory fibers |
US4322460A (en) * | 1978-04-24 | 1982-03-30 | The Boeing Company | Sprayable polyester coating |
US4381716A (en) * | 1978-06-05 | 1983-05-03 | Hastings Otis | Insulating apparatus and composite laminates employed therein |
US4218502A (en) * | 1978-06-19 | 1980-08-19 | Minnesota Mining And Manufacturing Company | Intumescable fire-retardant products |
JPS557428A (en) * | 1978-06-30 | 1980-01-19 | Yuasa Battery Co Ltd | Multilayer heat insulator |
JPS55161150A (en) * | 1979-06-01 | 1980-12-15 | Tajima Roofing Co | Heattinsulating asphalt waterproof board laying method thereof |
FR2461690B1 (fr) * | 1979-07-19 | 1985-08-16 | Europ Propulsion | Materiau d'isolation thermique a haute temperature et son procede de fabrication |
CA1171570A (en) * | 1979-10-13 | 1984-07-24 | Hans Kummermehr | Thermal insulating body and process for making same |
ZA807224B (en) * | 1979-12-07 | 1982-01-27 | Dunlop Ltd | Foam composites |
US4346149A (en) * | 1980-05-19 | 1982-08-24 | Gulfko Incorporated | Water based aluminum paint |
GB2081246B (en) * | 1980-07-25 | 1984-03-14 | Rolls Royce | Thermal barrier coating composition |
JPS57140814A (en) * | 1981-02-23 | 1982-08-31 | Japan Steel Works Ltd:The | Heat insulation method for heated metallic material |
US4396661A (en) * | 1981-08-20 | 1983-08-02 | Subtex, Inc. | Refractory coated and dielectric coated flame resistant insulating fabric composition |
US4492779A (en) * | 1981-12-07 | 1985-01-08 | Thiokol Corporation | Aramid polymer and powder filler reinforced elastomeric composition for use as a rocket motor insulation |
GB2118201B (en) * | 1982-01-12 | 1986-03-05 | Otsuka Kagaku Yakuhin | Heat-insulating refractory material |
US4391873A (en) * | 1982-01-19 | 1983-07-05 | The United States Of America As Represented By The Department Of Energy | High temperature thermal insulating composite |
US4507165A (en) * | 1982-09-15 | 1985-03-26 | Hercules Incorporated | Elastomer insulation compositions for rocket motors |
US4461867A (en) * | 1982-09-27 | 1984-07-24 | General Electric Company | Composition for promoting adhesion of curable silicones to substrates |
US4501841A (en) * | 1983-02-03 | 1985-02-26 | Hercules Incorporated | Elastomeric insulating materials for rocket motors |
US4504532A (en) * | 1983-02-03 | 1985-03-12 | Hercules Incorporated | Phenolic blast tube insulators for rocket motors |
US4504565A (en) * | 1984-04-17 | 1985-03-12 | Markem Corporation | Radiation imageable compositions containing hollow ceramic microspheres |
US4582873A (en) * | 1984-05-21 | 1986-04-15 | Ppg Industries, Inc. | Process for producing aqueous dispersions, internally silylated and dispersed polyurethane resins, and surfaces containing same |
US4567228A (en) * | 1984-05-21 | 1986-01-28 | Ppg Industries, Inc. | Aqueous dispersion, internally silylated and dispersed polyurethane resins, and surfaces containing same |
US4583623A (en) * | 1984-10-18 | 1986-04-22 | Allied Corporation | Heat shield element for a brake |
US5041321A (en) * | 1984-11-02 | 1991-08-20 | The Boeing Company | Fiberformed ceramic insulation and method |
AU579188B2 (en) * | 1985-09-06 | 1988-11-17 | Kabushiki Kaisha Osaka Packing Seizosho | Silica molding and process for its production |
US4745139A (en) * | 1987-02-09 | 1988-05-17 | Pdi, Inc. | Elastomeric coatings containing glass bubbles |
FR2613708B1 (fr) * | 1987-04-13 | 1990-10-12 | Rhone Poulenc Chimie | Silice de precipitation hydrophobe, son procede de preparation et son application au renforcement des elastomeres silicones |
US4805244A (en) * | 1988-01-25 | 1989-02-21 | Scott Walter B | Heat shield insert |
US5175975A (en) * | 1988-04-15 | 1993-01-05 | Midwest Research Institute | Compact vacuum insulation |
US5098938A (en) * | 1989-03-03 | 1992-03-24 | Savin Roland R | Coating composition exhibiting improved resistance to environmental attack |
US5888393A (en) * | 1989-07-18 | 1999-03-30 | The Boeing Company | Microparticle enhanced fibrous ceramic baffle for cryogenic liquid containers |
US5108817A (en) * | 1990-04-30 | 1992-04-28 | Lydall, Inc. | Multi-component heat shield |
US5114818A (en) * | 1990-06-27 | 1992-05-19 | Xerox Corporation | Heat shielded electrostatographic imaging members |
DE4038784A1 (de) * | 1990-12-05 | 1992-06-11 | Basf Ag | Verbundschaumstoffe mit niedriger waermeleitfaehigkeit |
US5188981A (en) * | 1991-05-28 | 1993-02-23 | Ford Motor Company | Molded article with integral heat shield |
US5196455A (en) * | 1991-05-30 | 1993-03-23 | Tremco Incorporated | Self-leveling sealant composition and method relating thereto |
US5221596A (en) * | 1991-09-03 | 1993-06-22 | Motorola, Inc. | Method of forming a retrograde photoresist profile |
US5300807A (en) * | 1992-01-22 | 1994-04-05 | The United States Of America As Represented By The Secretary Of The Army | Thin film detector and method of manufacture |
FR2697446B1 (fr) * | 1992-11-03 | 1994-12-02 | Aquasource | Procédé de traitement d'un fluide contenant des matières en suspension et en solution, par utilisation de membranes de séparation. |
ATE167462T1 (de) * | 1992-07-23 | 1998-07-15 | Owens Corning Fiberglass Corp | Silicium- oder siliciumdioxid-substrat mit modifizierter oberfläche und verfahren zu dessen herstellung |
US5453310A (en) * | 1992-08-11 | 1995-09-26 | E. Khashoggi Industries | Cementitious materials for use in packaging containers and their methods of manufacture |
US5783126A (en) * | 1992-08-11 | 1998-07-21 | E. Khashoggi Industries | Method for manufacturing articles having inorganically filled, starch-bound cellular matrix |
BR9307447A (pt) * | 1992-11-12 | 1999-06-01 | Crosfield Joseph & Sons | Sílica amorfa processo para a fabricação da mesma tintas e lacas tixotrópicas e uso da sílica |
EP0678068A4 (en) * | 1992-11-25 | 1998-04-01 | Khashoggi E Ind | CONNECTIONS WITH A HIGH INORGANIC PART. |
US5424111A (en) * | 1993-01-29 | 1995-06-13 | Farbstein; Malcolm N. | Thermally broken insulating glass spacer with desiccant |
US5603759A (en) * | 1993-02-11 | 1997-02-18 | Indresco Inc. | Stable, cement-bonded, overhead sprayed insulating mixes and resultant linings |
JP2568472B2 (ja) * | 1993-04-16 | 1997-01-08 | 日本ピラー工業株式会社 | 耐熱性複合部材およびその成形体 |
US5652278A (en) * | 1993-06-22 | 1997-07-29 | Imperial Chemical Industries Plc | Microvoid polyurethane materials |
JP2557604B2 (ja) * | 1993-08-17 | 1996-11-27 | 東レ・ダウコーニング・シリコーン株式会社 | 碍 子 |
DE4422912A1 (de) * | 1994-06-30 | 1996-01-11 | Hoechst Ag | Xerogele, Verfahren zu ihrer Herstellung, sowie ihre Verwendung |
EP0781196A4 (en) * | 1994-09-06 | 1998-02-25 | Thermacell Tech Inc | INSULATING MICROBALLS AND METHOD FOR THE PRODUCTION THEREOF |
US5601897A (en) * | 1994-10-17 | 1997-02-11 | Owens-Corning Fiberglass Technology Inc. | Vacuum insulation panel having carbonized asphalt coated glass fiber filler |
JPH08127739A (ja) * | 1994-10-31 | 1996-05-21 | Riboole:Kk | 耐火断熱性塗材 |
KR100368851B1 (ko) * | 1994-12-21 | 2003-05-12 | 캐보트 코포레이션 | 한층이상의섬유웹과에어로겔입자로이루어진복합체및이의제조방법 |
US5527411A (en) * | 1995-03-31 | 1996-06-18 | Owens-Corning Fiberglas Technology, Inc. | Insulating modular panels incorporating vacuum insulation panels and methods for manufacturing |
US5600930A (en) * | 1995-04-10 | 1997-02-11 | Drucker; Ernest R. | Construction system using lightweight fire-resistant panels |
US5591505A (en) * | 1995-06-07 | 1997-01-07 | Owens-Corning Fiberglas Technology, Inc. | Fibrous insulation product having inorganic binders |
US5753305A (en) * | 1995-11-16 | 1998-05-19 | Texas Instruments Incorporated | Rapid aging technique for aerogel thin films |
US5723515A (en) * | 1995-12-29 | 1998-03-03 | No Fire Technologies, Inc. | Intumescent fire-retardant composition for high temperature and long duration protection |
US5766686A (en) * | 1996-03-01 | 1998-06-16 | North American Refractories Co. | Spray insulating coating for refractory articles |
DE19702239A1 (de) * | 1997-01-24 | 1998-07-30 | Hoechst Ag | Mehrschichtige Verbundmaterialien, die mindestens eine aerogelhaltige Schicht und mindestens eine Schicht, die Polyethylenterephthalat-Fasern enthält, aufweisen, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
DE19702240A1 (de) * | 1997-01-24 | 1998-07-30 | Hoechst Ag | Mehrschichtige Verbundmaterialien, die mindestens eine aerogelhaltige Schicht und mindestens eine weitere Schicht aufweisen, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
DE19705511C5 (de) * | 1997-02-13 | 2005-07-14 | Faist Automotive Gmbh & Co. Kg | Hitzeschild für Bauteile aus thermoplastischem Kunststoff |
US5928723A (en) * | 1997-04-09 | 1999-07-27 | Cabot Corporation | Progress for producing surface modified metal oxide compositions |
EP0873864B1 (en) * | 1997-04-23 | 2012-04-25 | Mitsubishi Polyester Film Corporation | Polyester film for decorative plates or decorative sheets |
WO1999044851A1 (de) * | 1998-03-04 | 1999-09-10 | Rieter Automotive (International) Ag | Treibstofftank mit integriertem hitzeschild |
US6228476B1 (en) * | 1998-10-30 | 2001-05-08 | Johns Manville International, Inc. | Coated foam insulation and method of making the same |
AU4355599A (en) * | 1998-11-06 | 2000-05-29 | 1334495 Ontario Inc. | Thermally reflective substrate coating |
US6177186B1 (en) * | 1999-04-30 | 2001-01-23 | General Electric Company | Heat reflective, erosion and wear resistant coating mixture, method and coated article |
JP2002068853A (ja) * | 2000-08-28 | 2002-03-08 | Tokai Kogyo Kk | 軽量断熱体およびその製造方法 |
-
2003
- 2003-05-15 CN CNB038167778A patent/CN1325833C/zh not_active Expired - Fee Related
- 2003-05-15 EP EP20030799798 patent/EP1511959A2/en not_active Withdrawn
- 2003-05-15 AU AU2003299511A patent/AU2003299511B2/en not_active Ceased
- 2003-05-15 WO PCT/US2003/015530 patent/WO2004037533A2/en active Application Filing
- 2003-05-15 JP JP2004546673A patent/JP4559229B2/ja not_active Expired - Fee Related
- 2003-05-15 US US10/439,534 patent/US20050025952A1/en not_active Abandoned
- 2003-05-15 RU RU2004136599A patent/RU2303744C2/ru not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5631097A (en) * | 1992-08-11 | 1997-05-20 | E. Khashoggi Industries | Laminate insulation barriers having a cementitious structural matrix and methods for their manufacture |
US5641584A (en) * | 1992-08-11 | 1997-06-24 | E. Khashoggi Industries | Highly insulative cementitious matrices and methods for their manufacture |
US5665442A (en) * | 1992-08-11 | 1997-09-09 | E. Khashoggi Industries | Laminated sheets having a highly inorganically filled organic polymer matrix |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI761013B (zh) * | 2020-12-31 | 2022-04-11 | 金門化工有限公司 | 防火阻熱樹脂組成物及防火阻熱層 |
Also Published As
Publication number | Publication date |
---|---|
AU2003299511B2 (en) | 2008-06-26 |
JP2006501625A (ja) | 2006-01-12 |
JP4559229B2 (ja) | 2010-10-06 |
EP1511959A2 (en) | 2005-03-09 |
RU2004136599A (ru) | 2005-10-27 |
RU2303744C2 (ru) | 2007-07-27 |
CN1668871A (zh) | 2005-09-14 |
US20050025952A1 (en) | 2005-02-03 |
WO2004037533A2 (en) | 2004-05-06 |
AU2003299511A1 (en) | 2004-05-13 |
WO2004037533A3 (en) | 2004-10-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1325833C (zh) | 耐热绝缘复合物、含该复合物的基物、和其制备方法 | |
CN1331588C (zh) | 气凝胶和中空颗粒粘结剂组合物、绝缘复合物和其制备方法 | |
CN1309468C (zh) | 耐热气凝胶绝缘复合材料及其制备方法,气凝胶粘合剂组合物及其制备方法 | |
JP2006504543A5 (zh) | ||
JP4810433B2 (ja) | 断熱層のための組成物 | |
US5948314A (en) | Composition containing an aerogel, method of producing said composition and the use thereof | |
CN104520365B (zh) | 包含气凝胶的聚氨酯复合材料 | |
WO2006005716A2 (en) | Fire retardant composition | |
US20060257639A1 (en) | Insulation having a thermal enhancement material and method of making same | |
KR20080070501A (ko) | 발포수지용 난연 코팅제, 이를 함유하는 폴리스티렌 폼 및그 폼의 제조방법 | |
CA2209562A1 (en) | An inorganic based intumescent system | |
CN103261293B (zh) | 包含纳米多孔颗粒的复合材料 | |
CN110593448A (zh) | 一种保温隔音防火墙体结构 | |
EP1787716A1 (en) | Heat resistant aerogel insulation composite and method for its preparation;aerogel binder composition and method for its preparation | |
CN101903475A (zh) | 用于汽车制造的涂层物料 | |
KR20120116254A (ko) | 준불연성 코팅제 및 이를 포함하는 준불연성 발포 성형품 | |
JP3421509B2 (ja) | 防火付与組成物 | |
JP7504728B2 (ja) | 断熱部材およびその製造方法 | |
AU2003207724A1 (en) | Heat resistant aerogel insulation composite and method for its preparation; aerogel binder composition and method for its preparation | |
JP5564294B2 (ja) | カーテンウォール | |
JP2022038360A (ja) | 断熱部材およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070711 Termination date: 20120515 |