CN1301327A - 利用烃类原料生产电能、蒸汽和二氧化碳的工艺 - Google Patents

利用烃类原料生产电能、蒸汽和二氧化碳的工艺 Download PDF

Info

Publication number
CN1301327A
CN1301327A CN98814162A CN98814162A CN1301327A CN 1301327 A CN1301327 A CN 1301327A CN 98814162 A CN98814162 A CN 98814162A CN 98814162 A CN98814162 A CN 98814162A CN 1301327 A CN1301327 A CN 1301327A
Authority
CN
China
Prior art keywords
gas
unit
steam
turbine
technology
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN98814162A
Other languages
English (en)
Other versions
CN1116501C (zh
Inventor
H·O·弗杰尔霍格
H·R·尼尔森
W·索伊兹
M·塞格尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Equinor ASA
Original Assignee
Norsk Hydro ASA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Norsk Hydro ASA filed Critical Norsk Hydro ASA
Publication of CN1301327A publication Critical patent/CN1301327A/zh
Application granted granted Critical
Publication of CN1116501C publication Critical patent/CN1116501C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/064—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle in combination with an industrial process, e.g. chemical, metallurgical
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/26—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension
    • F02C3/28—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension using a separate gas producer for gasifying the fuel before combustion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/04—Gas-turbine plants providing heated or pressurised working fluid for other apparatus, e.g. without mechanical power output
    • F02C6/10—Gas-turbine plants providing heated or pressurised working fluid for other apparatus, e.g. without mechanical power output supplying working fluid to a user, e.g. a chemical process, which returns working fluid to a turbine of the plant
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/0445—Selective methanation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

本发明涉及一种利用烃类原料来生产电能、蒸汽和二氧化碳的工艺,所述的二氧化碳为浓缩的形式,该工艺包括:在一个空气驱动的自热反应器(ATR)单元中形成合成气体、对形成的合成气体进行热量交换以产生蒸汽、在一个一氧化碳转移反应器单元和二氧化碳分离单元中处理至少一部分合成气体以形成浓缩的二氧化碳和贫的含氢气体,所述气体的至少一部分在一个联成循环气轮机中燃烧而产生电能,其中,来自于所述气轮机单元的空气被供应至ATR单元,来自于气轮机的废气进行热交换而形成蒸汽,所述的蒸汽与上游产生的蒸汽一起用来在蒸汽气轮机中产生基本无CO2的电能。所述蒸汽可被输送到气轮机来稀释含氢气体混合物。该工艺可与生产合成气体产品如甲醇和/或氨气的工艺联合使用。可在燃料电池中利用来自于二氧化碳去除单元的一部分气体。

Description

利用烃类原料生产电能、蒸汽和二氧化碳的工艺
本发明涉及一种利用烃类原料生产电能、蒸汽和浓缩形式的二氧化碳产品的工艺。本发明还包括与所述的工艺相结合选择生产基于合成气体的产品。
电能是在一个与转化厂结合为一体的联合循环电厂中生产出来的，其中气轮机是以含氢气体为燃料。(整体式转化联合循环(IRCC))。这个工艺中的一个主要问题是在氮氧化物排放量最小同时得到最优化的电能和蒸汽的条件下操纵气轮机。
在互联网上的网址为http：/www.hydro.com/konsern/news/eng/1998/980423e.html处公开了一种用来生产电能、蒸汽和浓缩的二氧化碳的工艺。在这个公开文件中描述了这样一种生产工艺，包括：天然气与蒸汽反应而产生含氢气体，所述气体在一个联合循环式气轮机中燃烧而产生电能。
从日本专利申请JP608041中还可进一步了解到利用一种燃烧氢气的涡轮机来生产电能。根据这个申请文件，通过部分氧化所述燃料而使1∶0.5至1∶0.7的摩尔比的天然气和氧气反应来产生氢和一氧化碳。将空气供应到一个压力变动氧气吸附分离器(PSA)中，然后所述氧气被输送到一个自热反应器(ATR)中，在所述的自供热反应器(ATR)中，天然气就被转化为氢和一氧化碳。被转化的气体进入一个转移反应器中，在所述的转移反应器中，一氧化碳转化为二氧化碳。然后气体混合物被引导入一个隔膜分离器中，在所述的隔膜分离器中，氢气从二氧化碳中分离出来。分离出的CO2被冲洗掉，然后排出。基本不含含碳化合物的氢被用于气轮机中来产生电能。这个工艺需要氧气并需要一个动力消耗PSA单元。根据该申请的流程图，天然气必须被减压至接近周围压力才允许添加氧气。在PSA中分离后，必须对氧气进行二次压缩。所有这些额外的压缩均降低了该工艺的效率。
本发明的一个主要目的是提供一种利用烃类原料蒸汽转化的改进的发电的工艺，其中产生的相当一部分CO2以高度浓缩的CO2气流的形式而分离出来且氮氧化物的排放量在常规气轮机接受的水平之内。
本发明的另一个目的是利用在所述电能产生过程中形成的合成气体的至少一部分来生产合成气体产品，特别是氨，甲醇和/或二甲醚。
对于产生电能来说，本发明可与以燃烧烃类原料如天然气为基础的传统电厂相竞争。但是，仅燃烧烃类的一个主要的缺点是二氧化碳的排放，因为燃烧废气只有少量的二氧化碳，目前不能经济地回收。氮氧化物(NOX)的排放根据运行状况的变化而变化，这也构成了一个排放的问题。
在减少二氧化碳和氮氧化物(NOX)的排放时的一个主要的问题在于：获得所需要的排放减少量，而不使发电过程的效率的降低至不可接受的程度。根据上面的要求，在评价基本工艺中的第一步为合成气体的生产步骤。发明人通过考虑不同的工艺发现自热反应器(ATR)可具有多种优点并决定进一步寻找最好的工艺来运行自供热反应器(ATR)。与上面所述的日本专利申请中的教导相反，本申请发明人发现自热反应器(ATR)应该是一个空气驱动反应器，也就是说，该反应器不是一个氧气驱动反应器。ATR的应用从灵活性的角度来讲存在多种优势。这样，运行的压力可根据整体的经济性原则来选择。甲烷减少率(slip)可根据下游单元的操作而变化，最后在ATR中产生的合成气体为适于气体驱动气轮机的较贫气体，并与现存在的大规模联合循环电厂(IRCC)中应用的燃料混合物相当。
适用于该工艺的烃类原料为天然气、石脑油、各种汽油馏分等。通过在ATR之前应用一个预先转化器，原料就会具有较大的灵活性。本发明中优选的原料为天然气。
现在已发现：氮氧化物(NOX)的问题与气轮机的运行条件密切相关。氮氧化物(NOX)的形成与该气轮机中的燃烧温度有关。因此，应当采取适当的措施来控制所述的燃烧温度。为将燃烧温度保持在所需的水平并仍能保持可接受的发电能力，在所述气轮机中燃烧的气体混合物的范围可通过对该工艺的设计来选择。气轮机中的燃烧温度在很大程度上是由燃烧气体的组成决定的。现在已发现空气驱动的ATR可提供一种贫的氢基燃料气体混合物，所述的燃料混合气体与在IGCC厂中应用的气体相当。现在已认识到有利的是在气轮机的空气压缩机排气处为ATR抽取工艺空气及添加至所需的ATR喷射压力。另外，空气的流量也可被调节至满足甲烷减少率的需要及满足在燃气轮机燃烧系统中形成可接受的NOX水平的燃料气体混合物的组成的需要。从气轮机中与空气一起被抽取的氮气作为燃料气体混合物的一种组分而返回至气轮机的部分中去，这样就可极大地保持气轮机中质量流量。
如果需要的话，可向气轮机中喷射适量的蒸汽来减少NOX的形成。对燃烧器的优化设计也可减少NOX的排量。
在本发明的内容范围内，一种可选择的方式为将ATR与一个转化交换器联合使用。现在已发现这种选择可增加对浓缩形式的CO2的回收。
为得到最大的灵活性，基本的发电原理可与以现存的工艺气流为基础的各种产品的生产相结合。这样，一个甲醇单元就可利用来自于ATR的一些合成气体而一个氨设备也可利用在合成气体的移动反应之后而从二氧化碳中分离出来的氢气/氮气的一部分。氨设备需要的唯一的附加单元是一个常规隔膜分离单元和一个处于合成氨反应器上游的甲烷转化装置。
本发明的范围包括：在一个空气驱动ATR单元中形成合成气体、对形成的合成气体进行热量交换，从而产生蒸汽。然后，在一个一氧化碳转移反应器中处理至少一部分冷却的合成气体，所述的一氧化碳转移反应器可以是一个单个的单元或两个一氧化碳转移反应器，其中一个是低温反应器而另一个是高温反应器。所述的气流还进一步在一个二氧化碳单元中进行处理以形成浓缩的二氧化碳流及贫的含氢气体的气流，所述气体的至少一部分在一个联合循环气轮机中燃烧而生成电能。来自于所述气轮机中的空气被供应到ATR单元。对来自于气轮机的废气进行热量交换形成蒸汽而与在上游产生的蒸汽一起在一个蒸汽涡轮机中被用来生产电能。
ATR单元可与一个转化交换器相结合而所述的原料也可在这两个单元中进行分配，输送至ATR中的原料最好占原料总量的50-80％。
在ATR单元的上游可布置一个预先转化器。
在该工艺中产生的一小部分蒸汽可被输送至气轮机来稀释含氢气体，这样就可降低气轮机中的燃烧温度。
来自于气轮机的废气的至少一部分可作为氧气源而被循环输送至ATR或与输送至气轮机的空气相结合。
合成气体的一部分可被用来生产甲烷，这种生产工艺可结合图1而按着上述的各种方式来进行。
来自于二氧化碳分离单元的气体的一部分可被用来生产氨。在这种情况下，将一种流体输送至隔膜分离单元用于分离出氢气，所述的氢气与另一含氢气流相混合，从而使混合的气流中的氮与氢的比例为1∶3。来自于隔膜分离单元的氮气返回至主要的含氢气流中，然后被输送至气轮机。
结合下面的实施例及对附图的描述，下面将对本发明进行进一步的解释和阐述。
图1所示为基本发电原理的一个简化流程图；
图2所示为与一个甲醇设备和/或一个氨设备联合使用的基本原理的简化流程图。
图1显示了实现本发明的一个例子。气态的烃类原料如天然气作为气流1供应，在气流1穿过管道2之前被加热和压缩，然后被传送至一个饱和器3中，在饱和器3中，所述气流1与工艺水4和通过管线4b供应的经脱盐工艺的补充水相混合。然后至少部分用水饱和的烃类原料，作为流体5而输送入ATR单元6中。压缩空气通过管道7而供应到ATR单元6中。一个预先转化器可选择性地布置在ATR的上游。这样将增加烃类原料的灵活性。然后就可允许使用含量更多较重的烃类原料。空气供给29的至少一部分可从燃气气轮机的空气压缩器处来供应并被增压至必要的喷射压力。所述的单元6也可以是包括有一个ATR和一个转化交换器的组合单元。应供应到各个单元中的烃类原料的量可在一个较宽的范围内变化。进入ATR的实际分配量为原料的50-80％而其余部分则分配至转化交换器中。来自于ATR单元6的合成气体8在作为流体11而被供应到一个转移转化器单元12之前在一个锅炉(蒸汽发生器)9中冷却。所述的转移转化器单元可包含两个常规一氧化碳转移反应器即一个低温(LT)反应器和一个高温(HT)反应器或仅包含一个单个的一氧化碳转移反应器。将产生的气体混合物13冷却，在单元14中将冷凝水除去，然后将产生的气体混合物作为流体15供应到一个CO2吸收器16中，CO2和吸收物质就从吸收器16中通过管道18而供应到一个解吸器19中。作为流体20b的补偿吸收物质被供应到单元19中。再生吸附物质如一种胺溶液可通过管道20而循环至吸收器16。在单元22中将CO2流21中的水除去。来自于单元22和14的工艺水可循环供应至饱和器3。高度浓缩的CO2流可被压缩并通过管道23的输送而作进一步的应用，例如可作为油田或气田的喷射气体。来自于CO2吸收器16的气流17主要包含氢和氮及少量的CO、CO2、CH4。流体17然后就被用作联合循环燃气轮机24的燃料，空气25也供应到所述的燃气轮机24中。蒸汽10也可选择性地被供应到气轮机24中来减少NOX。可在一个燃料电池中利用至少一部分流体17来产生直流电。如果电能是用于电解作用，则采用这种选择性电能就不需要整流器。气轮机24产生的废气26与蒸汽发生器27中的水进行热交换，来自于蒸汽发生器的蒸汽在气流31被供应至发电机32之前在热交换器30中被过热，蒸汽10也被供应到发电机32中。废气28可被循环至转化器单元6或与空气供给25混合输送至气轮机24。
图2中，一个合成氨设备和一个甲醇合成设备在图1中所示的基本工艺中结合为一体。这种联合工艺可包括所述的两个设备或包括其中之一。合成气体34可来自于流体11并被供应到一个甲醇合成装置35。未转化的合成气体37可被循环至合成气体流11处而生成的甲醇产品则通过管道36排出。所述的合成气体34作为另一选择可在一个气体分离隔膜单元中进行处理而除去氢和二氧化碳而作为原料以供应至甲醇合成装置。该原料也从流体23中得到额外的二氧化碳的供应。来自于所述隔膜分离单元的其他部分则重新循环至流体11。
用于氨合成的原料可来自于管道17。一股侧流体38首先被输送至气体隔膜分离单元40而将氢42供应到管道39中，从而将H2和N2的比例调整为3∶1，然后在甲烷化单元43中处理气体混合物，再后在氨合成装置44产生氨45。来自于隔膜分离单元40的氮通过管道41而被循环输送至进料17而进入氢燃气轮机24。
实施例1
该实施例显示了在图1中所示的生产工艺中，本发明在发电量、效率及作为浓缩气流的二氧化碳的回收方面的效果。该实施例还显示了与同样利用一个初级一次级转化器生产合成气体的工艺相比，所述工艺生产的效率、浓缩二氧化碳的回收及生产的全部能量的情况。该示范性的例子显示了废气循环至ATR的效果，另外该例子还显示出将ATR与一个转化交换器结合的效果。在下面的表格中所述的结合为ATR-RE结合。在下表中将根据本发明的工艺与利用次级和初级转化器SR/PR的组合而生产合成气体的工艺进行了比较。在表中，进入到转化器单元中的蒸汽和碳的摩尔比称为：蒸汽∶碳。
表1
以ATR为基础两个一氧化碳转移反应器 以ATR为基础一个一氧化碳转移反应器 使用ATR废气循环不进行冷却 使用ATR废气循环冷却温度30℃ 使用ATR废气循环，不进行冷却，减少工艺蒸汽 使  用ATR-RE  即ATR和转化器的结合 SR/PR，两个一氧化碳转移反应器
天然气LVH(MW)  823.2  823.2  823.2  823.2  823.2  823.2  882.71
蒸汽∶碳 2.0∶1  2.0∶1  2.6∶1  2.6∶1  2.0∶1  3.2∶1 2.8∶1
作为气轮机燃料的燃气组成
CH4COCO2H2N2Ar  0.01750.00520.00060.56110.41060.0049  0.01730.01180.00060.54760.40550.0048  0.00950.00240.00050.42160.55920.0067  0.0170.00280.00050.40150.57130.0069  0.01090.00390.00050.42820.57570.0069  0.00230.00340.00070.62720.36210.0043  0.03280.00380.0010.76970.18460.0021
气体流量kmol/hr  17.176  17.390  23.648  23.148  22.971  17.641  15.520
功率．MW气轮机  287.42  287.87  298.82  295.25  298.39  302.03  289.77
功率．MW蒸汽  139.54  137.9  143.64  135.28  154.38  113.10 149.11
功率．MWExp.comp  4.34  4.34  4.34  4.34  4.34  4.34  4.46
功率．MW空气压缩机 33.82  33.82  80.66  61.12  80.64  30.61  12.55
总功率．MW  397.48  396.29  366.14  373.75  376.47  388.86  430.79
效率％  48.3  48.1  44.5  45.4  45.7  46.9  48.8
 CO2回收率％  88.8  85.7  91.7  87.3  90.3  95.8  84.5
从上面的结果可以看出，根据本发明的生产工艺可回收产生的CO2的95.8％。该结果还显示出在发明的内容范围内，生产的效率、电力功率及CO2的量根据运行条件的变化而变化，该工艺具有很大的灵活性。形成的NOX通常为输送至气轮机的气体中的氢所占的百分比的函数。
本发明提供了一种生产清洁的二氧化碳的工艺，所生产的二氧化碳适合作为在油田中进行注射的驱动气。这样，IRCC工厂就可以以最少的二氧化碳排量而运行。另外，该工艺还提供了一种以氢为基础的贫的燃料混合气体，该混合气体适宜于在目前的燃气轮机工艺中进行燃烧。当仅需要减少NOX的量时，可向燃气轮机输送气体混合物用蒸汽进行适度稀释。

Claims (11)

1．一种利用烃类原料来生产电能、蒸汽和浓缩形式的二氧化碳的工艺，该工艺包括：在一个空气驱动的自热反应器(ATR)单元中形成合成气体、对形成的合成气体进行热量交换而产生蒸汽、在一个一氧化碳转移反应器单元和二氧化碳分离单元中处理至少一部分合成气体以形成浓缩的二氧化碳和贫含氢气体，所述含氢气体的至少一部分在一个联合循环气轮机中燃烧而产生电能，其中，来自于所述气轮机单元的空气被供应至ATR单元，对来自于气轮机的废气进行热量交换而形成蒸汽，所述的蒸汽与上游产生的蒸汽一起被用来在蒸汽气轮机中产生基本无CO2的电能。
2．根据权利要求1所述的工艺，该工艺包括利用一个转化器单元，所述转化器单元包括一个与转化交换器结合的ATR。
3．根据权利要求1所述的工艺，其中包括，烃类原料的50-80％被供应到ATR而剩余的原料被供应到转化交换器。
4．根据权利要求1所述的工艺，该工艺包括利用一个布置在ATR单元之前的预先转化器。
5．根据权利要求1所述的工艺，该工艺包括利用一个单个的一氧化碳转移反应器单元。
6．根据权利要求1所述的工艺，该工艺包括将蒸汽供给到燃气轮机来稀释包含有氢气的气体混合物。
7．根据权利要求1所述的工艺，该工艺包括来自于燃气轮机的废气被循环至ATR单元。
8．根据权利要求1所述的工艺，该工艺包括将来自于燃气轮机的废气的至少一部分与供应到所述燃气轮机中的空气相结合。
9．根据权利要求1所述的工艺，该工艺包括利用合成气体的一部分来生产甲醇而其余部分的合成气体在用于生成电能之前在下游单元中进行进一步的处理。
10．根据权利要求1所述的工艺，该工艺包括：利用来自于二氧化碳去除单元的含氢气体的一部分来生产氨，包括在一个隔膜单元中分离所述气体而将氮和氢的比例调节至生成氨气的条件，并将分离出的氮气返回至主含氢气流中，其中，所述包含的氮和氢的比例为1∶3的气流在合成氨之前在一个甲烷转化单元中处理。
11．根据权利要求1所述的工艺，该工艺包括：将来自于二氧化碳去除单元的含氢气体的一部分进行输送而用作为燃料供给燃料电池用来生产电能。
CN98814162A 1998-07-13 1998-07-13 利用烃类原料生产电能、蒸汽和二氧化碳的工艺 Expired - Fee Related CN1116501C (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/NO1998/000213 WO2000003126A1 (en) 1998-07-13 1998-07-13 Process for generating electric energy, steam and carbon dioxide from hydrocarbon feedstock

Publications (2)

Publication Number Publication Date
CN1301327A true CN1301327A (zh) 2001-06-27
CN1116501C CN1116501C (zh) 2003-07-30

Family

ID=19907882

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98814162A Expired - Fee Related CN1116501C (zh) 1998-07-13 1998-07-13 利用烃类原料生产电能、蒸汽和二氧化碳的工艺

Country Status (23)

Country Link
US (1) US6505467B1 (zh)
EP (1) EP1105625B1 (zh)
JP (1) JP4190151B2 (zh)
CN (1) CN1116501C (zh)
AT (1) ATE249572T1 (zh)
AU (1) AU744197B2 (zh)
BR (1) BR9815946A (zh)
CA (1) CA2337394C (zh)
CZ (1) CZ294769B6 (zh)
DE (1) DE69818111T2 (zh)
DK (1) DK1105625T3 (zh)
EE (1) EE04622B1 (zh)
ES (1) ES2206972T3 (zh)
HU (1) HU222969B1 (zh)
ID (1) ID28247A (zh)
IL (1) IL140627A (zh)
NO (1) NO319178B1 (zh)
NZ (1) NZ509572A (zh)
PL (1) PL195221B1 (zh)
RU (1) RU2213051C2 (zh)
SK (1) SK286791B6 (zh)
TR (1) TR200100067T2 (zh)
WO (1) WO2000003126A1 (zh)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100338180C (zh) * 2001-10-05 2007-09-19 国际壳牌研究有限公司 烃生产工艺中的发电系统
CN100389251C (zh) * 2005-05-27 2008-05-21 北京化工大学 一种燃气动力循环系统及循环方法
CN101910381A (zh) * 2008-01-07 2010-12-08 通用电气公司 有利于代用天然气的产生的方法和设备
CN102234547A (zh) * 2010-04-26 2011-11-09 通用电气公司 用于整合气化组合循环动力系统的水煤气变换反应器系统
CN102482080A (zh) * 2009-05-26 2012-05-30 约翰内斯堡金山大学 用于生产合成气的碳吸收系统
CN102637886A (zh) * 2006-12-16 2012-08-15 克里斯多佛·J·帕皮雷 由碳氢化合物沉积物发电同时捕获二氧化碳
CN101098826B (zh) * 2004-11-16 2012-10-10 乔治洛德方法研究和开发液化空气有限公司 联合生产氢和二氧化碳的方法和设备

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6669744B2 (en) 1998-04-14 2003-12-30 Air Products And Chemicals, Inc. Process and apparatus for the production of synthesis gas
GB0025150D0 (en) 2000-10-13 2000-11-29 Air Prod & Chem A process and apparatus for the production of synthesis gas
EP1138096B1 (en) * 1998-10-14 2010-10-06 IdaTech, LLC Fuel processing system
CA2352626A1 (fr) 2001-07-12 2003-01-12 Co2 Solution Inc. Couplage d'une pile a hydrogene a un bioreacteur enzymatique de transformation et sequestration du co2
US20030162846A1 (en) 2002-02-25 2003-08-28 Wang Shoou-L Process and apparatus for the production of synthesis gas
NO20023050L (no) 2002-06-21 2003-12-22 Fleischer & Co Fremgangsmåte samt anlegg for utf degree relse av fremgangsmåten
GB0314813D0 (en) * 2003-06-25 2003-07-30 Johnson Matthey Plc Reforming process
US7163758B2 (en) * 2003-06-27 2007-01-16 Hce, Llc Integrated plasma fuel cell process
US20040265651A1 (en) * 2003-06-27 2004-12-30 Meyer Steinberg Combined-Cycle Energy, Carbon and Hydrogen Production Process
DE10355494B4 (de) * 2003-11-27 2009-12-03 Enerday Gmbh System und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat
US7024800B2 (en) * 2004-07-19 2006-04-11 Earthrenew, Inc. Process and system for drying and heat treating materials
US7685737B2 (en) 2004-07-19 2010-03-30 Earthrenew, Inc. Process and system for drying and heat treating materials
US7024796B2 (en) * 2004-07-19 2006-04-11 Earthrenew, Inc. Process and apparatus for manufacture of fertilizer products from manure and sewage
US7694523B2 (en) * 2004-07-19 2010-04-13 Earthrenew, Inc. Control system for gas turbine in material treatment unit
US20070084077A1 (en) * 2004-07-19 2007-04-19 Gorbell Brian N Control system for gas turbine in material treatment unit
US20060149423A1 (en) * 2004-11-10 2006-07-06 Barnicki Scott D Method for satisfying variable power demand
FR2881417B1 (fr) * 2005-02-01 2007-04-27 Air Liquide Procede de production de gaz de synthese a faible emission de dioxyde de carbone
DE102005012902A1 (de) * 2005-03-21 2006-09-28 Steag Saar Energie Ag Kraftwerksanlage
DE102005021981B3 (de) * 2005-05-12 2006-10-26 Mtu Cfc Solutions Gmbh Verfahren zum Betrieb einer Brennstoffzellenanordnung und Brennstoffzellenanordnung
JP4855730B2 (ja) * 2005-07-29 2012-01-18 株式会社東芝 水素製造システム
US20070130831A1 (en) * 2005-12-08 2007-06-14 General Electric Company System and method for co-production of hydrogen and electrical energy
US20070163316A1 (en) * 2006-01-18 2007-07-19 Earthrenew Organics Ltd. High organic matter products and related systems for restoring organic matter and nutrients in soil
US7610692B2 (en) * 2006-01-18 2009-11-03 Earthrenew, Inc. Systems for prevention of HAP emissions and for efficient drying/dehydration processes
US7632476B2 (en) * 2006-03-09 2009-12-15 Praxair Technology, Inc. Method of recovering carbon dioxide from a synthesis gas stream
BRPI0709156B1 (pt) 2006-03-24 2016-08-02 Virent Energy Systems Inc método para fabricar hidrocarbonetos e hidrocarbonetos oxigenados, hidrocarbonetos lineares ou ramificados de c2 a c36
US9605522B2 (en) * 2006-03-29 2017-03-28 Pioneer Energy, Inc. Apparatus and method for extracting petroleum from underground sites using reformed gases
US7506685B2 (en) * 2006-03-29 2009-03-24 Pioneer Energy, Inc. Apparatus and method for extracting petroleum from underground sites using reformed gases
EP1944268A1 (en) * 2006-12-18 2008-07-16 BP Alternative Energy Holdings Limited Process
US7650939B2 (en) * 2007-05-20 2010-01-26 Pioneer Energy, Inc. Portable and modular system for extracting petroleum and generating power
US8616294B2 (en) 2007-05-20 2013-12-31 Pioneer Energy, Inc. Systems and methods for generating in-situ carbon dioxide driver gas for use in enhanced oil recovery
US20090173081A1 (en) * 2008-01-07 2009-07-09 Paul Steven Wallace Method and apparatus to facilitate substitute natural gas production
US20090173080A1 (en) * 2008-01-07 2009-07-09 Paul Steven Wallace Method and apparatus to facilitate substitute natural gas production
US8272216B2 (en) * 2008-02-22 2012-09-25 Toyota Jidosha Kabushiki Kaisha Method for converting solar thermal energy
US8375725B2 (en) * 2008-03-14 2013-02-19 Phillips 66 Company Integrated pressurized steam hydrocarbon reformer and combined cycle process
JP5365037B2 (ja) * 2008-03-18 2013-12-11 トヨタ自動車株式会社 水素生成装置、アンモニア燃焼内燃機関、及び燃料電池
US8450536B2 (en) * 2008-07-17 2013-05-28 Pioneer Energy, Inc. Methods of higher alcohol synthesis
DE102008048062B3 (de) * 2008-09-19 2010-04-08 Forschungszentrum Jülich GmbH IGCC-Kraftwerk mit Rauchgasrückführung und Spülgas
FR2941937B1 (fr) * 2009-02-09 2011-08-19 Inst Francais Du Petrole Procede de production d'hydrogene avec captation totale du co2, et reduction du methane non converti
ATE539459T1 (de) * 2009-02-12 2012-01-15 Electro Power Systems Spa Elektrischer brennstoffzellen-ersatzgenerator mit einem kompakten verteilerkörper
EP2233433A1 (en) 2009-03-24 2010-09-29 Hydrogen Energy International Limited Process for generating electricity and for sequestering carbon dioxide
EP2233430A1 (en) 2009-03-24 2010-09-29 Hydrogen Energy International Limited Process for generating hydrogen and carbon dioxide
EP2233432A1 (en) 2009-03-24 2010-09-29 Hydrogen Energy International Limited Plant for generating electricity and for sequestrating carbon dioxide
CN101880046A (zh) * 2009-05-05 2010-11-10 中村德彦 复合设备
US7937948B2 (en) * 2009-09-23 2011-05-10 Pioneer Energy, Inc. Systems and methods for generating electricity from carbonaceous material with substantially no carbon dioxide emissions
JP5495749B2 (ja) * 2009-12-10 2014-05-21 三菱重工業株式会社 水素製造設備および発電プラント
US8590490B2 (en) * 2010-02-18 2013-11-26 King Fahd Univ. Of Petroleum & Minerals Carbon-free fire tube boiler
WO2011118031A1 (ja) * 2010-03-26 2011-09-29 トヨタ自動車株式会社 内燃機関の燃焼制御装置
IT1399300B1 (it) * 2010-04-19 2013-04-16 Luminari Impianto integrato a scarico zero per la produzione di elettricita' e idrogeno, con cattura della co2, recupero di calore e con disponibilita' di acqua da destinare al riscaldamento di edifici.
US9062525B2 (en) * 2011-07-07 2015-06-23 Single Buoy Moorings, Inc. Offshore heavy oil production
US20130127163A1 (en) 2011-11-17 2013-05-23 Air Products And Chemicals, Inc. Decarbonized Fuel Generation
ES2439620B1 (es) * 2012-01-23 2015-01-05 Fundación Centro De Innovación Y Desarrollo Tecnológico Proceso para la obtención de energía eléctrica a partir de combustión de carbón, horno de reducción de co2, dos turbinas y un motor de gas
US9377202B2 (en) 2013-03-15 2016-06-28 General Electric Company System and method for fuel blending and control in gas turbines
US9382850B2 (en) 2013-03-21 2016-07-05 General Electric Company System and method for controlled fuel blending in gas turbines
RU2524317C1 (ru) * 2013-03-27 2014-07-27 Геннадий Павлович Барчан Способ преобразования энергии с регенерацией энергоносителей в циклическом процессе теплового двигателя
US10113448B2 (en) * 2015-08-24 2018-10-30 Saudi Arabian Oil Company Organic Rankine cycle based conversion of gas processing plant waste heat into power
RU2725983C2 (ru) * 2017-01-17 2020-07-08 Андрей Владиславович Курочкин Автотермический реактор
CN108331625B (zh) * 2017-12-29 2019-10-25 华中科技大学 一种利用天然气电厂排烟汽化潜热的发电系统
IT202100010631A1 (it) 2021-04-27 2022-10-27 Energean Italy S P A Processo per produrre idrogeno da una materia prima idrocarburica.
WO2023180114A1 (en) * 2022-03-21 2023-09-28 Topsoe A/S Process for co-producing ammonia and methanol with reduced carbon
WO2023217804A1 (en) * 2022-05-12 2023-11-16 Topsoe A/S Process and plant for producing synthesis gas

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193259A (en) * 1979-05-24 1980-03-18 Texaco Inc. Process for the generation of power from carbonaceous fuels with minimal atmospheric pollution
AU638543B2 (en) * 1990-02-09 1993-07-01 Mitsubishi Jukogyo Kabushiki Kaisha Process for purifying high-temperature reducing gases and integrated coal gasification combined cycle power generation plant
GB9105095D0 (en) * 1991-03-11 1991-04-24 H & G Process Contracting Improved clean power generation
MY118075A (en) * 1996-07-09 2004-08-30 Syntroleum Corp Process for converting gas to liquids
US6106110A (en) 1996-10-09 2000-08-22 Nocopi Technologies, Inc. Secure thermal ink jet printing composition and substrate and method and apparatus utilizing same
AU2752300A (en) * 1999-02-03 2000-08-25 Texaco Development Corporation Utilizing purge gas from ammonia synthesis
US6314715B1 (en) * 1999-06-03 2001-11-13 General Electric Co. Modified fuel gas turbo-expander for oxygen blown gasifiers and related method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100338180C (zh) * 2001-10-05 2007-09-19 国际壳牌研究有限公司 烃生产工艺中的发电系统
CN101098826B (zh) * 2004-11-16 2012-10-10 乔治洛德方法研究和开发液化空气有限公司 联合生产氢和二氧化碳的方法和设备
CN100389251C (zh) * 2005-05-27 2008-05-21 北京化工大学 一种燃气动力循环系统及循环方法
CN102637886A (zh) * 2006-12-16 2012-08-15 克里斯多佛·J·帕皮雷 由碳氢化合物沉积物发电同时捕获二氧化碳
CN102637886B (zh) * 2006-12-16 2014-10-15 克里斯多佛·J·帕皮雷 由碳氢化合物沉积物发电同时捕获二氧化碳
CN101910381A (zh) * 2008-01-07 2010-12-08 通用电气公司 有利于代用天然气的产生的方法和设备
US8528343B2 (en) 2008-01-07 2013-09-10 General Electric Company Method and apparatus to facilitate substitute natural gas production
CN101910381B (zh) * 2008-01-07 2014-03-12 通用电气公司 有利于代用天然气的产生的方法和设备
CN102482080A (zh) * 2009-05-26 2012-05-30 约翰内斯堡金山大学 用于生产合成气的碳吸收系统
CN102234547A (zh) * 2010-04-26 2011-11-09 通用电气公司 用于整合气化组合循环动力系统的水煤气变换反应器系统

Also Published As

Publication number Publication date
JP2002520533A (ja) 2002-07-09
HUP0102620A3 (en) 2002-04-29
RU2213051C2 (ru) 2003-09-27
CZ20004883A3 (en) 2001-06-13
CA2337394A1 (en) 2000-01-20
WO2000003126A1 (en) 2000-01-20
IL140627A (en) 2004-06-01
HUP0102620A2 (hu) 2001-11-28
ID28247A (id) 2001-05-10
TR200100067T2 (tr) 2001-05-21
DE69818111D1 (de) 2003-10-16
ES2206972T3 (es) 2004-05-16
NZ509572A (en) 2003-10-31
IL140627A0 (en) 2002-02-10
DE69818111T2 (de) 2004-06-03
BR9815946A (pt) 2001-02-28
JP4190151B2 (ja) 2008-12-03
DK1105625T3 (da) 2004-01-26
AU8753898A (en) 2000-02-01
CA2337394C (en) 2006-07-04
PL195221B1 (pl) 2007-08-31
EP1105625B1 (en) 2003-09-10
NO20006618D0 (no) 2000-12-22
CZ294769B6 (cs) 2005-03-16
AU744197B2 (en) 2002-02-21
PL345658A1 (en) 2002-01-02
EE200100019A (et) 2002-06-17
NO20006618L (no) 2000-12-22
HU222969B1 (hu) 2004-01-28
EP1105625A1 (en) 2001-06-13
SK286791B6 (sk) 2009-05-07
CN1116501C (zh) 2003-07-30
EE04622B1 (et) 2006-04-17
NO319178B1 (no) 2005-06-27
ATE249572T1 (de) 2003-09-15
SK392001A3 (en) 2001-08-06
US6505467B1 (en) 2003-01-14

Similar Documents

Publication Publication Date Title
CN1116501C (zh) 利用烃类原料生产电能、蒸汽和二氧化碳的工艺
US8669294B2 (en) Syngas production through the use of membrane technologies
CN101208263B (zh) 制氢系统和方法
RU2436974C2 (ru) УСОВЕРШЕНСТВОВАННЫЕ СИСТЕМЫ И СПОСОБЫ ДЛЯ СНИЖЕНИЯ ВЫБРОСОВ NOx
CN1654312B (zh) 用于氢电联产的系统和方法
CN100549389C (zh) 二氧化碳分离的发电系统和方法
Medrano et al. Thermodynamic analysis of a membrane-assisted chemical looping reforming reactor concept for combined H2 production and CO2 capture
US20070130957A1 (en) Systems and methods for power generation and hydrogen production with carbon dioxide isolation
US20030046867A1 (en) Hydrogen generation
CN100503790C (zh) 双燃料重整化工系统生产化工产品的方法
US10329149B2 (en) Energetically enhanced reforming process
JP2003183202A (ja) メタノールの製造方法および装置
CN114843551B (zh) 一种燃料处理器及制氢方法
Gaudernack et al. Natural gas utilisation without CO2 emissions
WO1999041188A1 (en) Process for producing electrical power and steam
JPH11246877A (ja) ガス化ガスからの合成プラント
MXPA01000346A (en) Process for generating electric energy, steam and carbon dioxide from hydrocarbon feedstock
TW202319334A (zh) 氫製造結合co2捕捉的方法
JP2000095505A (ja) 水素の製造方法及び製造装置

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: STATOIL ASA

Free format text: FORMER OWNER: NORSK HYDRO A.S

Effective date: 20140313

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20140313

Address after: Stavanger

Patentee after: Statoil ASA

Address before: Oslo

Patentee before: Norsk Hydro A. S. A

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030730

Termination date: 20130713