CN1298822C - 含钼－硫的添加剂 - Google Patents
含钼－硫的添加剂 Download PDFInfo
- Publication number
- CN1298822C CN1298822C CNB031453694A CN03145369A CN1298822C CN 1298822 C CN1298822 C CN 1298822C CN B031453694 A CNB031453694 A CN B031453694A CN 03145369 A CN03145369 A CN 03145369A CN 1298822 C CN1298822 C CN 1298822C
- Authority
- CN
- China
- Prior art keywords
- additive
- molybdenum
- compound
- sulphur
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000654 additive Substances 0.000 title claims abstract description 190
- 230000000996 additive effect Effects 0.000 title claims abstract description 115
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 44
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims description 43
- 229910052750 molybdenum Inorganic materials 0.000 title claims description 38
- 239000011733 molybdenum Substances 0.000 title claims description 33
- 239000005864 Sulphur Substances 0.000 title claims description 30
- 239000000203 mixture Substances 0.000 claims abstract description 96
- 238000000034 method Methods 0.000 claims abstract description 69
- 239000010687 lubricating oil Substances 0.000 claims abstract description 66
- 150000001875 compounds Chemical class 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 46
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical class [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000376 reactant Substances 0.000 claims abstract description 16
- 239000003446 ligand Substances 0.000 claims abstract description 13
- 239000011541 reaction mixture Substances 0.000 claims abstract description 10
- -1 molybdenum-sulphur compound Chemical class 0.000 claims description 59
- 239000003921 oil Substances 0.000 claims description 36
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 21
- 239000000446 fuel Substances 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 9
- 239000002360 explosive Substances 0.000 claims description 5
- ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical class [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 13
- 230000007797 corrosion Effects 0.000 abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 abstract description 8
- 239000011593 sulfur Substances 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000005078 molybdenum compound Substances 0.000 abstract 1
- 150000002752 molybdenum compounds Chemical class 0.000 abstract 1
- 238000009877 rendering Methods 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 15
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 230000027455 binding Effects 0.000 description 12
- 238000009739 binding Methods 0.000 description 12
- 239000010949 copper Substances 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 150000001450 anions Chemical class 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000012990 dithiocarbamate Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000002199 base oil Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052711 selenium Inorganic materials 0.000 description 4
- 239000011669 selenium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000003016 phosphoric acids Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000012044 organic layer Substances 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 108010021119 Trichosanthin Proteins 0.000 description 1
- NUHGWJBSSKVFDO-UHFFFAOYSA-N [K].OP(O)(S)=S Chemical compound [K].OP(O)(S)=S NUHGWJBSSKVFDO-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical class NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000010688 mineral lubricating oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000008427 organic disulfides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 238000003969 polarography Methods 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/18—Esters of dithiocarbamic acids
- C07C333/20—Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/09—Complexes with metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/20—Colour, e.g. dyes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/26—Two-strokes or two-cycle engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02078011.0 | 2002-07-08 | ||
| EP02078011 | 2002-07-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1472292A CN1472292A (zh) | 2004-02-04 |
| CN1298822C true CN1298822C (zh) | 2007-02-07 |
Family
ID=30129222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031453694A Expired - Lifetime CN1298822C (zh) | 2002-07-08 | 2003-07-08 | 含钼－硫的添加剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7309680B2 (enExample) |
| JP (2) | JP5435834B2 (enExample) |
| CN (1) | CN1298822C (enExample) |
| AT (1) | ATE352604T1 (enExample) |
| CA (1) | CA2432993A1 (enExample) |
| DE (1) | DE60311362T2 (enExample) |
| MX (1) | MXPA03005852A (enExample) |
| SG (1) | SG121781A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102510866A (zh) * | 2009-09-30 | 2012-06-20 | 雪佛龙奥伦耐有限责任公司 | 具有低残留活性硫的硫化钼酰胺络合物和添加剂组合物的制备 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060025315A1 (en) * | 2004-07-30 | 2006-02-02 | Rebecca Oldfield | Method for lubricating surfaces |
| EP1803799A4 (en) | 2004-10-19 | 2012-09-05 | Nippon Oil Corp | LUBRICANT FORMULA AND ANTIOXIDANT FORMULA |
| US7074381B1 (en) * | 2005-06-13 | 2006-07-11 | Infineum International Limited | Process for producing ammonium polythiomolybdate |
| JP5175462B2 (ja) * | 2006-09-04 | 2013-04-03 | 出光興産株式会社 | 内燃機関用潤滑油組成物 |
| KR101267758B1 (ko) * | 2006-10-07 | 2013-05-23 | 게케엔 드리펠린 인터나쇼날 게엠베하 | 두 개 이상의 여러 가지 몰리브덴 화합물을 포함하여 등속 조인트에서 사용하기 위한 그리스 조성물 |
| WO2008040381A1 (en) * | 2006-10-07 | 2008-04-10 | Gkn Driveline International Gmbh | Grease composition for use in constant velocity joints comprising at least one tri-nuclear molybdenum compound |
| WO2008040383A1 (en) * | 2006-10-07 | 2008-04-10 | Gkn Driveline International Gmbh | Grease composition for use in constant velocity joints comprising at least one tri-nuclear molybdenum compound and a urea derivative thickener |
| JP5468728B2 (ja) | 2007-05-29 | 2014-04-09 | 出光興産株式会社 | 内燃機関用潤滑油組成物 |
| US8183189B2 (en) * | 2009-09-30 | 2012-05-22 | Chevron Oronite Company Llc | Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur |
| US20110237474A1 (en) | 2010-03-25 | 2011-09-29 | R.T. Vanderbilt Company, Inc. | Ultra Low Phosphorus Lubricant Compositions |
| CN104471041A (zh) | 2012-06-06 | 2015-03-25 | 范德比尔特化学品有限责任公司 | 节油润滑油 |
| US20150147012A1 (en) * | 2013-11-27 | 2015-05-28 | Emerson Climate Technologies, Inc. | Bearing performance for compressors using high energy refrigerants with sulfur-based oil additives |
| JP2015063564A (ja) * | 2014-12-26 | 2015-04-09 | シェブロン・オロナイト・カンパニー・エルエルシー | 硫化モリブデンアミド錯体の製造および残留活性硫黄の少ない添加剤組成物 |
| CN105133002B (zh) * | 2015-08-29 | 2017-07-21 | 西北有色金属研究院 | 一种十三硫代钼酸铵晶体的制备方法 |
| US10883046B2 (en) | 2017-02-02 | 2021-01-05 | Nanoco 2D Materials Limited | Synthesis of luminescent 2D layered materials using an amine-met al complex and a slow sulfur-releasing precursor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888945A (en) * | 1996-12-13 | 1999-03-30 | Exxon Research And Engineering Company | Method for enhancing and restoring reduction friction effectiveness |
| WO1999031113A1 (en) * | 1997-12-12 | 1999-06-24 | Infineum Usa L.P. | Method for the preparation of trinuclear molybdenum-sulfur compounds and their use as lubricant additives |
| CN1319648A (zh) * | 2000-03-29 | 2001-10-31 | 英菲诺姆国际有限公司 | 润滑剂添加剂的制造 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3509051A (en) | 1964-08-07 | 1970-04-28 | T R Vanderbilt Co Inc | Lubricating compositions containing sulfurized oxymolybdenum dithiocarbamates |
| NL131940C (enExample) | 1965-10-28 | |||
| DE2508713C3 (de) | 1975-02-28 | 1979-04-12 | Adolf Schmids Erben Ag, Bern | Verfahren zur Aufarbeitung von gebrauchtem Mineralöl |
| US4289635A (en) | 1980-02-01 | 1981-09-15 | The Lubrizol Corporation | Process for preparing molybdenum-containing compositions useful for improved fuel economy of internal combustion engines |
| FR2484442B1 (fr) * | 1980-02-01 | 1985-11-22 | Lubrizol Corp | Procede de preparation de compositions contenant du molybdene utiles pour une meilleure economie du combustible des moteurs a combustion interne |
| WO1985004896A1 (en) | 1984-04-16 | 1985-11-07 | The Lubrizol Corporation | Additives for lubricants and functional fluids which exhibit improved performance and method for preparing same |
| JP3659598B2 (ja) * | 1995-02-15 | 2005-06-15 | 旭電化工業株式会社 | 硫化オキシモリブデンジチオカーバメートの製造方法 |
| FR2735785B1 (fr) | 1995-06-22 | 1997-08-08 | Chavet Bernard | Procede de raffinage d'huiles usagees par traitement alcalin |
| US6043200A (en) * | 1995-07-31 | 2000-03-28 | Exxon Chemical Patents, Inc. | Oleaginous compositions |
| WO1997023587A1 (en) * | 1995-12-22 | 1997-07-03 | Japan Energy Corporation | Lubricating oil for internal combustion engines |
| US6232276B1 (en) * | 1996-12-13 | 2001-05-15 | Infineum Usa L.P. | Trinuclear molybdenum multifunctional additive for lubricating oils |
| US6358894B1 (en) * | 1996-12-13 | 2002-03-19 | Infineum Usa L.P. | Molybdenum-antioxidant lube oil compositions |
| KR100516268B1 (ko) * | 1996-12-13 | 2005-09-20 | 엑손 리써치 앤드 엔지니어링 컴파니 | 유기 몰리브덴 착체를 함유하는 윤활유 조성물 |
| US6110878A (en) * | 1997-12-12 | 2000-08-29 | Exxon Chemical Patents Inc | Lubricant additives |
| US5895779A (en) * | 1998-03-31 | 1999-04-20 | Exxon Chemical Patents Inc | Lubricating oil having improved fuel economy retention properties |
| GB9813070D0 (en) * | 1998-06-17 | 1998-08-19 | Exxon Chemical Patents Inc | Lubricant compositions |
| US6074993A (en) * | 1999-10-25 | 2000-06-13 | Infineuma Usa L.P. | Lubricating oil composition containing two molybdenum additives |
| US6528463B1 (en) * | 2000-03-23 | 2003-03-04 | Ethyl Corporation | Oil soluble molybdenum compositions |
| DE60117311T2 (de) * | 2000-03-29 | 2006-08-03 | Infineum International Ltd., Abingdon | Organische Molybdänkomplexe enthaltende Schmiermittelzusammensetzungen |
| US6953771B2 (en) * | 2001-03-23 | 2005-10-11 | Infineon International Limited | Lubricant compositions |
| US6852679B2 (en) * | 2002-02-20 | 2005-02-08 | Infineum International Ltd. | Lubricating oil composition |
-
2003
- 2003-06-20 CA CA002432993A patent/CA2432993A1/en not_active Abandoned
- 2003-06-24 DE DE60311362T patent/DE60311362T2/de not_active Expired - Lifetime
- 2003-06-24 AT AT03253981T patent/ATE352604T1/de not_active IP Right Cessation
- 2003-06-26 MX MXPA03005852A patent/MXPA03005852A/es active IP Right Grant
- 2003-07-01 US US10/611,228 patent/US7309680B2/en not_active Expired - Lifetime
- 2003-07-07 JP JP2003192694A patent/JP5435834B2/ja not_active Expired - Lifetime
- 2003-07-08 CN CNB031453694A patent/CN1298822C/zh not_active Expired - Lifetime
- 2003-07-08 SG SG200303962A patent/SG121781A1/en unknown
-
2013
- 2013-10-10 JP JP2013212733A patent/JP5620559B2/ja not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888945A (en) * | 1996-12-13 | 1999-03-30 | Exxon Research And Engineering Company | Method for enhancing and restoring reduction friction effectiveness |
| WO1999031113A1 (en) * | 1997-12-12 | 1999-06-24 | Infineum Usa L.P. | Method for the preparation of trinuclear molybdenum-sulfur compounds and their use as lubricant additives |
| CN1319648A (zh) * | 2000-03-29 | 2001-10-31 | 英菲诺姆国际有限公司 | 润滑剂添加剂的制造 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102510866A (zh) * | 2009-09-30 | 2012-06-20 | 雪佛龙奥伦耐有限责任公司 | 具有低残留活性硫的硫化钼酰胺络合物和添加剂组合物的制备 |
| CN102510866B (zh) * | 2009-09-30 | 2016-02-03 | 雪佛龙奥伦耐有限责任公司 | 具有低残留活性硫的硫化钼酰胺络合物和添加剂组合物的制备 |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03005852A (es) | 2005-01-10 |
| US7309680B2 (en) | 2007-12-18 |
| ATE352604T1 (de) | 2007-02-15 |
| SG121781A1 (en) | 2006-05-26 |
| DE60311362D1 (de) | 2007-03-15 |
| JP2014005474A (ja) | 2014-01-16 |
| JP5620559B2 (ja) | 2014-11-05 |
| JP5435834B2 (ja) | 2014-03-05 |
| DE60311362T2 (de) | 2007-11-08 |
| CA2432993A1 (en) | 2004-01-08 |
| US20040132627A1 (en) | 2004-07-08 |
| CN1472292A (zh) | 2004-02-04 |
| JP2004051985A (ja) | 2004-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1298822C (zh) | 含钼－硫的添加剂 | |
| CN1195765C (zh) | 油溶性钼组合物 | |
| CN1228426C (zh) | 润滑剂添加剂的制备 | |
| US7615520B2 (en) | Additives and lubricant formulations for improved antioxidant properties | |
| JP5414649B2 (ja) | 摩擦調整をもたらす添加剤および潤滑剤調合物 | |
| EP2271652B1 (en) | Preparation of a molybdenum amide additive composition and lubricating oil compositions containing same | |
| JP2002508384A (ja) | 三核モリブデン−イオウ化合物の製造方法及びそれらの潤滑剤用添加剤としての使用 | |
| CN1417310A (zh) | 润滑油组合物 | |
| JP2004068021A (ja) | 低リン量潤滑油で潤滑にした内燃機関の摩耗を低減する方法および組成物 | |
| JP2007169635A (ja) | 向上した耐摩耗特性を有する添加剤および潤滑剤配合物 | |
| EP3334810B1 (en) | Additive for lubricant compositions comprising a sulfur-containing and a sulfur-free organomolybdenum compound, and a triazole | |
| CN1252049C (zh) | 含烷硫基和羟基取代基的二硫代氨基甲酸酯 | |
| CA2773647C (en) | Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur | |
| CN103987822B (zh) | 后处理过的钼酰胺添加剂组合物和含有它的润滑油组合物的制备 | |
| CN1896203A (zh) | 改进润滑油组合物中高碱性清净剂与其它添加剂相容性的方法 | |
| US8183189B2 (en) | Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur | |
| CN1315495A (zh) | 润滑剂组合物 | |
| CN1301260C (zh) | 作为摩擦改性剂的有机钼配合物 | |
| CN1497043A (zh) | 润滑油组合物 | |
| EP1382659B1 (en) | Process for making molybdenum-sulfur additives containing little unreacted sulfur and additives obtained by the process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20070207 |
|
| CX01 | Expiry of patent term |