CN1298427C - 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用 - Google Patents
分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用 Download PDFInfo
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- CN1298427C CN1298427C CNB038047616A CN03804761A CN1298427C CN 1298427 C CN1298427 C CN 1298427C CN B038047616 A CNB038047616 A CN B038047616A CN 03804761 A CN03804761 A CN 03804761A CN 1298427 C CN1298427 C CN 1298427C
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- Prior art keywords
- carbon monoxide
- olefin polymeric
- molecular sieve
- metal oxides
- oxide
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- 239000002808 molecular sieve Substances 0.000 title claims abstract description 99
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- 239000000463 material Substances 0.000 claims description 38
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Classifications
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
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- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
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- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/83—Aluminophosphates (APO compounds)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36096302P | 2002-02-28 | 2002-02-28 | |
| US60/360,963 | 2002-02-28 | ||
| US36601202P | 2002-03-20 | 2002-03-20 | |
| US60/366,012 | 2002-03-20 | ||
| US37469702P | 2002-04-22 | 2002-04-22 | |
| US60/374,697 | 2002-04-22 | ||
| US10/215,511 US6906232B2 (en) | 2002-08-09 | 2002-08-09 | Molecular sieve compositions, catalysts thereof, their making and use in conversion processes |
| US10/215,511 | 2002-08-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1638865A CN1638865A (zh) | 2005-07-13 |
| CN1298427C true CN1298427C (zh) | 2007-02-07 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038068079A Expired - Fee Related CN1327964C (zh) | 2002-02-28 | 2003-02-10 | 包括分子筛的催化剂组合物、其制备及在转化方法中的应用 |
| CNB038082659A Expired - Fee Related CN100335172C (zh) | 2002-02-28 | 2003-02-10 | 分子筛组合物、催化剂、其制备方法及在转化过程中的应用 |
| CNB038047616A Expired - Fee Related CN1298427C (zh) | 2002-02-28 | 2003-02-10 | 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用 |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038068079A Expired - Fee Related CN1327964C (zh) | 2002-02-28 | 2003-02-10 | 包括分子筛的催化剂组合物、其制备及在转化方法中的应用 |
| CNB038082659A Expired - Fee Related CN100335172C (zh) | 2002-02-28 | 2003-02-10 | 分子筛组合物、催化剂、其制备方法及在转化过程中的应用 |
Country Status (11)
| Country | Link |
|---|---|
| EP (3) | EP1478464A2 (de) |
| JP (3) | JP2005518929A (de) |
| KR (3) | KR20040091080A (de) |
| CN (3) | CN1327964C (de) |
| AU (3) | AU2003212993A1 (de) |
| BR (1) | BR0308011A (de) |
| CA (2) | CA2477432A1 (de) |
| EA (3) | EA007872B1 (de) |
| MY (2) | MY139847A (de) |
| TW (3) | TWI306780B (de) |
| WO (3) | WO2003074175A2 (de) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003212993A1 (en) * | 2002-02-28 | 2003-09-16 | Exxonmobil Chemical Patents Inc. | Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes |
| US7074739B2 (en) * | 2002-11-19 | 2006-07-11 | Exxonmobil Chemical Patents Inc. | Multi-component molecular sieve catalyst compositions and their use in aromatics reactions |
| US6951830B2 (en) | 2003-08-05 | 2005-10-04 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst compositions, their production and use in conversion processes |
| US7404891B2 (en) * | 2004-03-29 | 2008-07-29 | Exxonmobil Chemical Patents Inc. | Heat recovery technique for catalyst regenerator flue gas |
| US7166757B2 (en) | 2004-07-30 | 2007-01-23 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
| WO2007021394A2 (en) * | 2005-08-18 | 2007-02-22 | Exxonmobil Chemical Patents Inc. | Catalytic conversion of oxygenates to olefins |
| CN101003018A (zh) * | 2006-01-20 | 2007-07-25 | 中国石油天然气股份有限公司 | 一种多相催化固体碱催化剂及其制备方法和应用 |
| US7335621B2 (en) | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
| JP4710744B2 (ja) * | 2006-07-18 | 2011-06-29 | トヨタ自動車株式会社 | 複合金属酸化物の製造方法 |
| US7595275B2 (en) | 2006-08-15 | 2009-09-29 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their synthesis |
| CN101239878B (zh) * | 2007-02-07 | 2010-05-19 | 中国石油化工股份有限公司 | 碳四及其以上烯烃增产乙烯、丙烯的方法 |
| CN101239866B (zh) * | 2007-02-07 | 2010-12-01 | 中国石油化工股份有限公司 | 含氧化合物生产乙烯、丙烯的方法 |
| CA2578494A1 (en) * | 2007-02-14 | 2008-08-14 | Nova Chemicals Corporation | Catalytic cracking of ethers to 1-olefins |
| EP2022565A1 (de) * | 2007-07-06 | 2009-02-11 | Casale Chemicals S.A. | Verfahren zur Herstellung molekularer Silicoaluminophosphat-Molekularsiebe, Katalysatoren mit besagten Sieben und katalytische Dehydrierungsprozesse mit besagten Katalysatoren |
| WO2009021727A1 (en) * | 2007-08-13 | 2009-02-19 | Saudi Basic Industries Corporation | Catalyst composition and process for converting aliphatic oxygenates to aromatics |
| DE102007059129A1 (de) * | 2007-12-07 | 2009-06-10 | Süd-Chemie AG | Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen |
| CA2719905A1 (en) * | 2008-04-04 | 2009-10-08 | Petr Vasiliev | Zeolite catalyst zeolite secondary structure |
| JP5818133B2 (ja) * | 2011-05-20 | 2015-11-18 | 国立大学法人東京工業大学 | オレフィン製造用触媒及びオレフィンの製造方法 |
| CN102344328B (zh) * | 2011-07-25 | 2014-03-12 | 浙江大学 | 一种使用移动床技术将甲醇转化为丙烯的半连续方法 |
| JP6065014B2 (ja) * | 2012-10-15 | 2017-01-25 | 三菱瓦斯化学株式会社 | メチルアミン類製造用触媒の製造方法及びメチルアミン類の製造方法 |
| RU2612975C1 (ru) * | 2013-05-07 | 2017-03-14 | Синтос С.А. | Способ получения 1,3-бутадиена |
| CN107661774B (zh) * | 2016-07-27 | 2020-11-03 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
| CN107661773B (zh) * | 2016-07-29 | 2020-08-04 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法 |
| CN108568311B (zh) * | 2017-03-07 | 2021-03-23 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制乙烯的方法 |
| WO2018195865A1 (zh) * | 2017-04-27 | 2018-11-01 | 中国科学院大连化学物理研究所 | 制甲苯、对二甲苯、低碳烯烃中至少一种的催化剂的原位制备方法及反应工艺 |
| CN109939722B (zh) * | 2018-01-26 | 2021-05-25 | 中国科学院大连化学物理研究所 | 一种有机碱修饰的复合催化剂及一氧化碳加氢制乙烯的方法 |
| CN109939667B (zh) * | 2018-01-26 | 2021-01-05 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
| KR20210068595A (ko) * | 2018-10-30 | 2021-06-09 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 마이크로다공성 분자체 촉매의 1족 금속 이온 함량 |
| CN111346664B (zh) * | 2018-12-24 | 2022-11-15 | 中国石油化工股份有限公司 | 改性钒硅分子筛及其制备方法以及硫醚氧化方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4465889A (en) * | 1982-07-02 | 1984-08-14 | Summit Gas Systems Pte. Ltd. | Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor |
| WO1998029370A1 (en) * | 1996-12-31 | 1998-07-09 | Exxon Chemical Patents Inc. | Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts |
| WO2000069796A1 (en) * | 1999-05-14 | 2000-11-23 | Exxon Chemical Patents Inc. | Direct selective synthesis of para-xylene |
| WO2002005952A2 (en) * | 2000-07-13 | 2002-01-24 | Uop Llc | Attrition resistant catalyst for light olefin production |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4781816A (en) | 1987-10-19 | 1988-11-01 | Phillips Petroleum Company | Cracking process |
| US6040264A (en) * | 1996-04-04 | 2000-03-21 | Exxon Chemical Patents Inc. | Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion |
| US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
| JP4221532B2 (ja) * | 1998-06-26 | 2009-02-12 | 三菱瓦斯化学株式会社 | メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法 |
| WO2001064340A1 (en) * | 2000-03-01 | 2001-09-07 | Exxonmobil Chemical Patents Inc. | Thorium-containing sapo molecular sieve for producing olefins |
| US6448197B1 (en) * | 2000-07-13 | 2002-09-10 | Exxonmobil Chemical Patents Inc. | Method for making a metal containing small pore molecular sieve catalyst |
| CA2369318A1 (en) * | 2002-01-28 | 2003-07-28 | Universite Concordia | Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins |
| AU2003212993A1 (en) * | 2002-02-28 | 2003-09-16 | Exxonmobil Chemical Patents Inc. | Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes |
-
2003
- 2003-02-10 AU AU2003212993A patent/AU2003212993A1/en not_active Abandoned
- 2003-02-10 AU AU2003216248A patent/AU2003216248B2/en not_active Ceased
- 2003-02-10 WO PCT/US2003/003951 patent/WO2003074175A2/en active Application Filing
- 2003-02-10 EP EP03743673A patent/EP1478464A2/de not_active Withdrawn
- 2003-02-10 CN CNB038068079A patent/CN1327964C/zh not_active Expired - Fee Related
- 2003-02-10 WO PCT/US2003/004169 patent/WO2003074177A2/en active Application Filing
- 2003-02-10 EP EP03743671A patent/EP1478462A2/de not_active Withdrawn
- 2003-02-10 CN CNB038082659A patent/CN100335172C/zh not_active Expired - Fee Related
- 2003-02-10 WO PCT/US2003/004153 patent/WO2003074176A2/en active Application Filing
- 2003-02-10 CA CA002477432A patent/CA2477432A1/en not_active Abandoned
- 2003-02-10 KR KR10-2004-7013377A patent/KR20040091080A/ko active IP Right Grant
- 2003-02-10 AU AU2003225560A patent/AU2003225560B2/en not_active Ceased
- 2003-02-10 EA EA200401101A patent/EA007872B1/ru not_active IP Right Cessation
- 2003-02-10 JP JP2003572680A patent/JP2005518929A/ja not_active Withdrawn
- 2003-02-10 EA EA200401102A patent/EA007873B1/ru not_active IP Right Cessation
- 2003-02-10 CA CA2477428A patent/CA2477428C/en not_active Expired - Fee Related
- 2003-02-10 KR KR10-2004-7013384A patent/KR20040089680A/ko not_active Application Discontinuation
- 2003-02-10 JP JP2003572679A patent/JP2005518928A/ja not_active Withdrawn
- 2003-02-10 CN CNB038047616A patent/CN1298427C/zh not_active Expired - Fee Related
- 2003-02-10 JP JP2003572681A patent/JP2005518930A/ja active Pending
- 2003-02-10 EA EA200401061A patent/EA007871B1/ru not_active IP Right Cessation
- 2003-02-10 KR KR10-2004-7013378A patent/KR20040089679A/ko not_active Application Discontinuation
- 2003-02-10 BR BR0308011-0A patent/BR0308011A/pt not_active IP Right Cessation
- 2003-02-10 EP EP03709038A patent/EP1478461A2/de not_active Withdrawn
- 2003-02-14 TW TW092103144A patent/TWI306780B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103154A patent/TWI265825B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103148A patent/TWI265824B/zh not_active IP Right Cessation
- 2003-02-21 MY MYPI20030610A patent/MY139847A/en unknown
- 2003-02-21 MY MYPI20030609A patent/MY140018A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4465889A (en) * | 1982-07-02 | 1984-08-14 | Summit Gas Systems Pte. Ltd. | Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor |
| WO1998029370A1 (en) * | 1996-12-31 | 1998-07-09 | Exxon Chemical Patents Inc. | Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts |
| WO2000069796A1 (en) * | 1999-05-14 | 2000-11-23 | Exxon Chemical Patents Inc. | Direct selective synthesis of para-xylene |
| WO2002005952A2 (en) * | 2000-07-13 | 2002-01-24 | Uop Llc | Attrition resistant catalyst for light olefin production |
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