WO2003074177A3 - Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes - Google Patents

Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes Download PDF

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Publication number
WO2003074177A3
WO2003074177A3 PCT/US2003/004169 US0304169W WO03074177A3 WO 2003074177 A3 WO2003074177 A3 WO 2003074177A3 US 0304169 W US0304169 W US 0304169W WO 03074177 A3 WO03074177 A3 WO 03074177A3
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WO
WIPO (PCT)
Prior art keywords
preparation
molecular sieves
catalyst compositions
conversion processes
elements
Prior art date
Application number
PCT/US2003/004169
Other languages
French (fr)
Other versions
WO2003074177A2 (en
Inventor
Doron Levin
James C Vartuli
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/215,511 external-priority patent/US6906232B2/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Priority to AU2003216248A priority Critical patent/AU2003216248B2/en
Priority to CA2477428A priority patent/CA2477428C/en
Priority to KR10-2004-7013378A priority patent/KR20040089679A/en
Priority to EA200401061A priority patent/EA007871B1/en
Priority to EP03743673A priority patent/EP1478464A2/en
Priority to JP2003572681A priority patent/JP2005518930A/en
Publication of WO2003074177A2 publication Critical patent/WO2003074177A2/en
Publication of WO2003074177A3 publication Critical patent/WO2003074177A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates (SAPO compounds)
    • B01J35/19—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/54—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J35/60—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/83—Aluminophosphates (APO compounds)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene. The catalyst composition comprises a molecular sieve and at least one oxide of a metal selected from Group 3 of the Periodic Table of Elements, the Lanthanide series of elements and the Actinide series of elements.
PCT/US2003/004169 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes WO2003074177A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2003216248A AU2003216248B2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
CA2477428A CA2477428C (en) 2002-02-28 2003-02-10 Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
KR10-2004-7013378A KR20040089679A (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
EA200401061A EA007871B1 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
EP03743673A EP1478464A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
JP2003572681A JP2005518930A (en) 2002-02-28 2003-02-10 Molecular sieve compositions, their catalysts, their production and use in conversion processes

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US36096302P 2002-02-28 2002-02-28
US60/360,963 2002-02-28
US36601202P 2002-03-20 2002-03-20
US60/366,012 2002-03-20
US37469702P 2002-04-22 2002-04-22
US60/374,697 2002-04-22
US10/215,511 2002-08-09
US10/215,511 US6906232B2 (en) 2002-08-09 2002-08-09 Molecular sieve compositions, catalysts thereof, their making and use in conversion processes

Publications (2)

Publication Number Publication Date
WO2003074177A2 WO2003074177A2 (en) 2003-09-12
WO2003074177A3 true WO2003074177A3 (en) 2003-12-31

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PCT/US2003/003951 WO2003074175A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
PCT/US2003/004153 WO2003074176A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
PCT/US2003/004169 WO2003074177A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes

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PCT/US2003/003951 WO2003074175A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
PCT/US2003/004153 WO2003074176A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes

Country Status (11)

Country Link
EP (3) EP1478462A2 (en)
JP (3) JP2005518930A (en)
KR (3) KR20040089679A (en)
CN (3) CN1298427C (en)
AU (3) AU2003212993A1 (en)
BR (1) BR0308011A (en)
CA (2) CA2477432A1 (en)
EA (3) EA007871B1 (en)
MY (2) MY140018A (en)
TW (3) TWI265824B (en)
WO (3) WO2003074175A2 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1478462A2 (en) * 2002-02-28 2004-11-24 ExxonMobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US7074739B2 (en) 2002-11-19 2006-07-11 Exxonmobil Chemical Patents Inc. Multi-component molecular sieve catalyst compositions and their use in aromatics reactions
US6951830B2 (en) 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US7404891B2 (en) 2004-03-29 2008-07-29 Exxonmobil Chemical Patents Inc. Heat recovery technique for catalyst regenerator flue gas
US7166757B2 (en) * 2004-07-30 2007-01-23 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
WO2007021394A2 (en) * 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
CN101003018A (en) * 2006-01-20 2007-07-25 中国石油天然气股份有限公司 Heterogenous catalysis solid alkali catalyst, and its preparing method and use
US7335621B2 (en) 2006-04-19 2008-02-26 Exxonmobil Chemical Patents Inc. Catalyst compositions and preparation thereof
JP4710744B2 (en) * 2006-07-18 2011-06-29 トヨタ自動車株式会社 Method for producing composite metal oxide
US7595275B2 (en) 2006-08-15 2009-09-29 Exxonmobil Chemical Patents Inc. Catalyst compositions and their synthesis
CN101239878B (en) * 2007-02-07 2010-05-19 中国石油化工股份有限公司 Method for increasing yield of ethylene and propylene from olefin with four carbon or above
CN101239866B (en) * 2007-02-07 2010-12-01 中国石油化工股份有限公司 Method for producing ethylene and propylene from oxygen-containing compounds
CA2578494A1 (en) * 2007-02-14 2008-08-14 Nova Chemicals Corporation Catalytic cracking of ethers to 1-olefins
EP2022565A1 (en) * 2007-07-06 2009-02-11 Casale Chemicals S.A. Process for preparing silicoaluminoposphate (SAPO) molecular sieves, catalysts containing said sieves and catalytic dehydration processes using said catalysts
WO2009021726A1 (en) * 2007-08-13 2009-02-19 Saudi Basic Industries Corporation Process for converting aliphatic oxygenates to aromatics
DE102007059129A1 (en) * 2007-12-07 2009-06-10 Süd-Chemie AG Catalyst with increased olefin selectivity for the conversion of oxygenates to olefins
EP2268400A1 (en) * 2008-04-04 2011-01-05 Petr Vasiliev Zeolite catalyst zeolite secondary structure
JP5818133B2 (en) * 2011-05-20 2015-11-18 国立大学法人東京工業大学 Olefin production catalyst and olefin production method
CN102344328B (en) * 2011-07-25 2014-03-12 浙江大学 Semi-continuous method for converting methyl alcohol into propylene by using moving bed technology
CN104718025B (en) * 2012-10-15 2017-05-10 三菱瓦斯化学株式会社 Method for producing catalyst for use in production of methylamine compound, and method for producing methylamine compound
UA112832C2 (en) * 2013-05-07 2016-10-25 Сінтос С.А. METHOD OF OBTAINING 1,3-BUTADIEN
CN107661774B (en) * 2016-07-27 2020-11-03 中国科学院大连化学物理研究所 Catalyst and method for preparing low-carbon olefin by directly converting synthesis gas
CN107661773B (en) * 2016-07-29 2020-08-04 中国科学院大连化学物理研究所 Method for preparing liquid fuel and co-producing low-carbon olefin by directly converting catalyst and synthesis gas
CN108568311B (en) * 2017-03-07 2021-03-23 中国科学院大连化学物理研究所 Catalyst and method for preparing ethylene by directly converting synthesis gas
KR102326358B1 (en) * 2017-04-27 2021-11-12 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 In situ production method and reaction process of catalyst for producing at least one of toluene, P-xylene and light olefins
CN109939667B (en) * 2018-01-26 2021-01-05 中国科学院大连化学物理研究所 Catalyst and method for preparing low-carbon olefin by directly converting synthesis gas
CN109939722B (en) * 2018-01-26 2021-05-25 中国科学院大连化学物理研究所 Organic base modified composite catalyst and method for preparing ethylene by hydrogenation of carbon monoxide
US20210370276A1 (en) * 2018-10-30 2021-12-02 Exxonmobil Chemical Patents Inc. Group 1 Metal Ion Content of Microporous Molecular Sieve Catalysts
CN111346664B (en) * 2018-12-24 2022-11-15 中国石油化工股份有限公司 Modified vanadium-silicon molecular sieve, preparation method thereof and thioether oxidation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998029370A1 (en) * 1996-12-31 1998-07-09 Exxon Chemical Patents Inc. Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts
EP0967011A2 (en) * 1998-06-26 1999-12-29 Mitsubishi Gas Chemical Company, Ltd. Catalysts and methods for producing methylamines
WO2001064340A1 (en) * 2000-03-01 2001-09-07 Exxonmobil Chemical Patents Inc. Thorium-containing sapo molecular sieve for producing olefins

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4465889A (en) * 1982-07-02 1984-08-14 Summit Gas Systems Pte. Ltd. Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor
US4781816A (en) 1987-10-19 1988-11-01 Phillips Petroleum Company Cracking process
US6040264A (en) * 1996-04-04 2000-03-21 Exxon Chemical Patents Inc. Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion
US6423879B1 (en) * 1997-10-02 2002-07-23 Exxonmobil Oil Corporation Selective para-xylene production by toluene methylation
US6388156B1 (en) * 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
US6448197B1 (en) * 2000-07-13 2002-09-10 Exxonmobil Chemical Patents Inc. Method for making a metal containing small pore molecular sieve catalyst
WO2002005952A2 (en) * 2000-07-13 2002-01-24 Uop Llc Attrition resistant catalyst for light olefin production
CA2369318A1 (en) * 2002-01-28 2003-07-28 Universite Concordia Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins
EP1478462A2 (en) * 2002-02-28 2004-11-24 ExxonMobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998029370A1 (en) * 1996-12-31 1998-07-09 Exxon Chemical Patents Inc. Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts
EP0967011A2 (en) * 1998-06-26 1999-12-29 Mitsubishi Gas Chemical Company, Ltd. Catalysts and methods for producing methylamines
WO2001064340A1 (en) * 2000-03-01 2001-09-07 Exxonmobil Chemical Patents Inc. Thorium-containing sapo molecular sieve for producing olefins

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