CN1286640C - 硬涂层薄膜、层压有硬涂层薄膜的基材以及设置有该薄膜和基材的图像显示装置 - Google Patents
硬涂层薄膜、层压有硬涂层薄膜的基材以及设置有该薄膜和基材的图像显示装置 Download PDFInfo
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- CN1286640C CN1286640C CNB028187660A CN02818766A CN1286640C CN 1286640 C CN1286640 C CN 1286640C CN B028187660 A CNB028187660 A CN B028187660A CN 02818766 A CN02818766 A CN 02818766A CN 1286640 C CN1286640 C CN 1286640C
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Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/416—Reflective
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
Description
试样编号 | 固化性树脂 | 表面弹性模量×厚度3 | 铅笔硬度 | 表面弹性模量 | 膜厚 | 固化收缩率 | 卷曲值 | 尖钢笔划伤 | 开裂性 | |
(混合质量比) | KPa·mm3 | GPa | μm | 体积% | 1/m | mm | ||||
1 | 比较例 | 二季戊四醇六丙烯酸酯(日本化药(株)制造) | 7 | 2H | 6.8 | 10 | 21 | 5以下 | 200g | 30以下 |
2 | 本发明 | 184 | 4H | 6.8 | 30 | 25 | 300g以上 | 100 | ||
3 | 本发明 | 662 | 5H | 6.8 | 46 | 33 | 300g以上 | 140 | ||
4 | 比较例 | 850 | 5H | 6.8 | 50 | 60 | 300g以上 | 200 | ||
5 | 比较例 | 季戊四醇四丙烯酸酯(日本化药(株)制造) | 21 | 3H | 6.2 | 15 | 20 | 10 | 200g | 40 |
6 | 本发明 | 167 | 4H | 6.2 | 30 | 20 | 300g以上 | 90 | ||
7 | 本发明 | 565 | 5H | 6.2 | 45 | 25 | 300g以上 | 120 | ||
8 | 比较例 | 775 | 5H | 6.2 | 50 | 50 | 300g以上 | 160 | ||
9 | 比较例 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造) | 20 | 3H | 6.0 | 15 | 19 | 15 | 200g | 50 |
10 | 本发明 | 162 | 4H | 6.0 | 30 | 25 | 300g以上 | 100 | ||
11 | 本发明 | 547 | 5H | 6.0 | 45 | 30 | 300g以上 | 120 | ||
12 | 比较例 | 750 | 5H | 6.0 | 50 | 50 | 300g以上 | 150 | ||
13 | 比较例 | 1290K(聚氨酯丙烯酸酯グイセル化学工业(株)制造) | 23 | 2H | 6.8 | 15 | 10 | 5以下 | 250g | 30以下 |
14 | 本发明 | 244 | 4H | 6.8 | 33 | 7 | 300g以上 | 30以下 | ||
15 | 本发明 | 579 | 5H | 6.8 | 44 | 15 | 300g以上 | 30以下 | ||
16 | 比较例 | 850 | 5H | 6.8 | 50 | 21 | 300g以上 | 40 | ||
17 | 比较例 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造)/聚缩水甘油甲基丙烯酸酯*混合物(75/25质量比) | 6 | 2H | 5.8 | 10 | 13 | 5以下 | 200g | 30以下 |
18 | 本发明 | 157 | 4H | 5.8 | 30 | 5以下 | 300g以上 | 30以下 | ||
19 | 本发明 | 529 | 5H | 5.8 | 45 | 5以下 | 300g以上 | 40 | ||
20 | 比较例 | 二季戊四醇六丙烯酸酯(日本化药(株)制造)/氧化铝分散物*混合物(75/25质量比) | 15 | 3H | 8.9 | 12 | 15 | 5以下 | 80 | 100 |
21 | 本发明 | 139 | 4H | 8.9 | 25 | 15 | 100 | 150 | ||
22 | 本发明 | 382 | 5H | 8.9 | 35 | 20 | 130 | 200以上 | ||
23 | 比较例 | 811 | 5H | 8.9 | 45 | 25 | 130 | 200以上 | ||
24 | 比较例 | UV6300(聚氨酯丙烯酸酯,日本合成化学工业(株)制造) | 10 | 2H | 4.6 | 13 | 12 | 5以下 | 200g | 40 |
25 | 本发明 | 181 | 4H | 4.6 | 34 | 8 | 300g以上 | 50 | ||
26 | 本发明 | 366 | 4H | 4.6 | 43 | 10 | 300g以上 | 50 | ||
27 | 本发明 | 575 | 4H | 4.6 | 50 | 15 | 300g以上 | 100 | ||
28 | 比较例 | ビスコ-ト#230(二丙烯酸己二酯;大阪有机化学工业(株)制造) | 14 | 2H | 4.2 | 15 | 18 | 5以下 | 150g | 50 |
29 | 本发明 | 66 | 4H | 4.2 | 25 | 10 | 200g | 100 |
试样编号 | 固化性树脂 | 表面弹性模量×厚度3 | 铅笔硬度 | 表面弹性模量 | 膜厚 | 固化收缩率 | 卷曲值 | 尖钢笔划伤 | 开裂性 | |
(混合质量比) | KPa·mm3 | GPa | μm | 体积% | 1/m | mm | ||||
30 | 本发明 | 180 | 4H | 4.2 | 35 | 25 | 200g | 120 | ||
31 | 本发明 | 383 | 4H | 4.2 | 45 | 30 | 250g | 150 | ||
32 | 比较例 | EHPA3150(环氧侧基脂环式环氧树脂;ダイセル化学工业(株)制造) | 27 | 2H | 3.4 | 20 | 2 | 5以下 | 100g | 30以下 |
33 | 本发明 | 218 | 4H | 3.4 | 40 | 5以下 | 120g | 30以下 | ||
34 | 本发明 | 425 | 4H | 3.4 | 50 | 5以下 | 150g | 30以下 | ||
35 | 比较例 | 二季戊四醇六丙烯酸酯(日本化药(株)制造)/氧化铝分散物**混合物(70/30质量比) | 10 | 3H | 9.8 | 10 | 10 | 5以下 | 50g以下 | 150 |
36 | 本发明 | 78 | 4H | 9.8 | 20 | 10 | 50g以下 | 200以上 | ||
37 | 本发明 | 420 | 5H | 9.8 | 35 | 15 | 50g以下 | 200以上 | ||
38 | 比较例 | 893 | 6H | 9.8 | 45 | 20 | 50g以下 | 200以上 | ||
1t | 比较例 | 二季戊四醇六丙烯酸酯(日本化药(株)制造) | 7 | H | 6.8 | 10 | 21 | 5以下 | 200g | 30以下 |
2t | 本发明 | 184 | 4H | 6.8 | 30 | 20 | 300g以上 | 80 | ||
3t | 本发明 | 662 | 4H | 6.8 | 46 | 30 | 300g以上 | 120 | ||
4t | 比较例 | 850 | 4H | 6.8 | 50 | 45 | 300g以上 | 150 | ||
13t | 比较例 | 1290K(聚氨酯丙烯酸酯;ダイセル化学工业(株)制造) | 23 | H | 6.8 | 15 | 10 | 5以下 | 250g | 30以下 |
14t | 本发明 | 244 | 4H | 6.8 | 33 | 5以下 | 300g以上 | 30以下 | ||
15t | 本发明 | 579 | 4H | 6.8 | 44 | 10 | 300g以上 | 30以下 | ||
16t | 比较例 | 850 | 4H | 6.8 | 50 | 15 | 300g以上 | 30以下 |
试样编号 | 固化性树脂 | 表面弹性模量×厚度3 | 铅笔硬度 | 表面弹性模量 | 膜厚 | 固化收缩率 | 卷曲值 | 卷曲湿度差 | I/0值 | 吸湿量 | 开裂性 |
(混合质量比) | KPa·mm3 | GPa | μm | 体积% | 1/m | |80%-10%| | 质量% | mm | |||
3 | 二季戊四醇六丙烯酸酯(日本化药(株)制造) | 662 | 5H | 6.8 | 46 | 21 | 33 | 28 | 0.93 | 3.5 | 140 |
7 | 季戊四醇四丙烯酸酯(日本化药(株)制造) | 565 | 5H | 6.2 | 45 | 20 | 25 | 26 | 0.86 | 3.2 | 120 |
11 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造) | 547 | 5H | 6.0 | 45 | 19 | 30 | 19 | 0.72 | 2.5 | 120 |
19 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造)/聚缩水甘油甲基丙烯酸酯*混合物(75/25质量比) | 529 | 5H | 5.8 | 45 | 13 | 5以下 | 18 | 0.71 | 2.2 | 40 |
40 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造)/聚缩水甘油甲基丙烯酸酯*混合物(50/50质量比) | 492 | 4H | 5.4 | 45 | 11 | 5以下 | 17 | 0.69 | 2.0 | 30以下 |
41 | 三羟甲基丙烷三丙烯酸酯(日本化药(株)制造)/聚缩水甘油甲基丙烯酸酯*混合物(25/75质量比) | 487 | 4H | 5.0 | 46 | 8 | 5以下 | 14 | 0.68 | 1.9 | 30以下 |
42 | 季戊四醇六丙烯酸酯(日本化药(株)制造)/セロキサイド2021P(环氧树脂;ダイセル化学工业(株)制造)(75/25) | 467 | 4H | 4.8 | 46 | 10 | 5以下 | 18 | 0.66 | 1.8 | 30以下 |
43 | 季戊四醇六丙烯酸酯(日本化药(株)制造)/EHPA3150(环氧侧基脂环式环氧树脂:ダイセル化学工业(株)制造)(70/30) | 501 | 5H | 5.5 | 45 | 13 | 5以下 | 20 | 0.79 | 2.6 | 40 |
试样编号 | 表面反射率 | 橡皮擦痕 | 防污性 | 耐伤性 | 铅笔硬度 | |
44 | 附带有防污性防反射层的硬涂层PET薄膜 | 1.5% | ○ | ○ | 60来回 | 5H |
45 | 硬涂层PET薄膜 | 6% | ○ | △ | 100来同 | 5H |
46 | 附带有防污性防反射层的PET薄膜 | 1.6% | × | ○ | 5来回 | H |
47 | 仅有PET薄膜 | 6% | ○ | × | 1来回 | H |
试样编号 | 图像显示装置 | 薄膜 | 画面的易见性 | 指纹擦拭性 | 尖钢笔划伤 | 耐伤性 |
48 | PDP板 | 44 | ○ | ○ | 300g以上 | 60来回 |
49 | ″ | 46 | ○ | ○ | 50g以下 | 5来回 |
50 | ″ | 没有 | × | △ | 300g以上 | 100来回以上 |
51 | ゲ-ムボ-イ | 44 | ○ | ○ | 300g以上 | 60来回 |
52 | ″ | 46 | ○ | ○ | 50g以下 | 5来回 |
53 | ″ | 没有 | × | △ | 50g以下 | 1来回 |
Claims (11)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001291250 | 2001-09-25 | ||
JP291250/2001 | 2001-09-25 | ||
JP2001311569 | 2001-10-09 | ||
JP311569/2001 | 2001-10-09 | ||
JP311567/2001 | 2001-10-09 | ||
JP2001311567 | 2001-10-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1558824A CN1558824A (zh) | 2004-12-29 |
CN1286640C true CN1286640C (zh) | 2006-11-29 |
Family
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Family Applications (1)
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CNB028187660A Expired - Lifetime CN1286640C (zh) | 2001-09-25 | 2002-05-01 | 硬涂层薄膜、层压有硬涂层薄膜的基材以及设置有该薄膜和基材的图像显示装置 |
Country Status (5)
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JP (1) | JPWO2003026881A1 (zh) |
KR (1) | KR100905683B1 (zh) |
CN (1) | CN1286640C (zh) |
TW (1) | TWI225159B (zh) |
WO (1) | WO2003026881A1 (zh) |
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-
2002
- 2002-05-01 KR KR1020047003621A patent/KR100905683B1/ko active IP Right Grant
- 2002-05-01 CN CNB028187660A patent/CN1286640C/zh not_active Expired - Lifetime
- 2002-05-01 JP JP2003530497A patent/JPWO2003026881A1/ja active Pending
- 2002-05-01 WO PCT/JP2002/004364 patent/WO2003026881A1/ja active Application Filing
- 2002-05-08 TW TW091109599A patent/TWI225159B/zh not_active IP Right Cessation
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US9926461B2 (en) | 2012-05-31 | 2018-03-27 | Lg Chem, Ltd. | Hard coating film |
US9896597B2 (en) | 2012-05-31 | 2018-02-20 | Lg Chem, Ltd. | Method of preparing hard coating film |
US9765234B2 (en) | 2012-08-23 | 2017-09-19 | Lg Chem, Ltd. | Laminated hard coating film |
US9783698B2 (en) | 2012-08-23 | 2017-10-10 | Lg Chem, Ltd. | Hard coating film |
US9902868B2 (en) | 2012-08-23 | 2018-02-27 | Lg Chem, Ltd. | Hard coating film |
US9909026B2 (en) | 2012-08-23 | 2018-03-06 | Lg Chem, Ltd. | Hard coating film |
US9777186B2 (en) | 2012-08-23 | 2017-10-03 | Lg Chem, Ltd. | Hard coating film |
US10087340B2 (en) | 2012-08-23 | 2018-10-02 | Lg Chem, Ltd. | Hard coating film |
US10280330B2 (en) | 2012-08-23 | 2019-05-07 | Lg Chem, Ltd. | Hard coating film |
US9567479B2 (en) | 2012-08-23 | 2017-02-14 | Lg Chem, Ltd. | Hard coating film |
CN109747235A (zh) * | 2017-11-07 | 2019-05-14 | 财团法人工业技术研究院 | 保护结构以及电子装置 |
Also Published As
Publication number | Publication date |
---|---|
WO2003026881A1 (fr) | 2003-04-03 |
KR100905683B1 (ko) | 2009-07-03 |
KR20040037081A (ko) | 2004-05-04 |
CN1558824A (zh) | 2004-12-29 |
JPWO2003026881A1 (ja) | 2005-01-06 |
TWI225159B (en) | 2004-12-11 |
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