CN1267460C - 催化组合物、其制备方法、聚合体系和制备加聚物的方法 - Google Patents

催化组合物、其制备方法、聚合体系和制备加聚物的方法 Download PDF

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Publication number
CN1267460C
CN1267460C CNB2004100641613A CN200410064161A CN1267460C CN 1267460 C CN1267460 C CN 1267460C CN B2004100641613 A CNB2004100641613 A CN B2004100641613A CN 200410064161 A CN200410064161 A CN 200410064161A CN 1267460 C CN1267460 C CN 1267460C
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metal
title complex
atoms metal
alkyl
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Chinese (zh)
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CN1597709A (zh
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B·L·古达尔
J·L·佩托夫
沈瀚
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Rohm and Haas Co
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Rohm and Haas Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
CNB2004100641613A 2003-08-21 2004-08-20 催化组合物、其制备方法、聚合体系和制备加聚物的方法 Expired - Fee Related CN1267460C (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US49687303P 2003-08-21 2003-08-21
US60/496,873 2003-08-21
US55924304P 2004-04-02 2004-04-02
US60/559,243 2004-04-02
US10/857,330 US7087687B2 (en) 2003-08-21 2004-05-28 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US10/857,330 2004-05-28

Publications (2)

Publication Number Publication Date
CN1597709A CN1597709A (zh) 2005-03-23
CN1267460C true CN1267460C (zh) 2006-08-02

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CNB2004100641613A Expired - Fee Related CN1267460C (zh) 2003-08-21 2004-08-20 催化组合物、其制备方法、聚合体系和制备加聚物的方法

Country Status (6)

Country Link
US (1) US7087687B2 (cg-RX-API-DMAC10.html)
EP (1) EP1508577A1 (cg-RX-API-DMAC10.html)
JP (1) JP2005068424A (cg-RX-API-DMAC10.html)
KR (1) KR100560061B1 (cg-RX-API-DMAC10.html)
CN (1) CN1267460C (cg-RX-API-DMAC10.html)
TW (1) TWI262196B (cg-RX-API-DMAC10.html)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7172986B2 (en) * 2004-06-14 2007-02-06 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7199074B2 (en) * 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7595369B2 (en) * 2004-11-10 2009-09-29 Lg Chem, Ltd. Method of polymerizing cyclic olefins and vinyl olefins, copolymer produced by the method and optical anisotropic film comprising the same
US7749934B2 (en) * 2005-02-22 2010-07-06 Rohm And Haas Company Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7435701B2 (en) * 2005-05-27 2008-10-14 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7635739B2 (en) 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
JP4855740B2 (ja) * 2005-09-01 2012-01-18 株式会社クラレ 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
KR100882315B1 (ko) * 2006-04-28 2009-02-10 주식회사 엘지화학 루이스 산을 이용한 α-올레핀-아크릴레이트-노보넨 3원공중합체 제조방법 및 이에 의해 제조된 공중합체
MY157264A (en) * 2006-11-14 2016-05-31 Univation Tech Llc Catalyst systems and polymerization processes
US20080118570A1 (en) * 2006-11-20 2008-05-22 Zhi Liu Polymer coated drug-ion exchange resins and methods
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
CA2620852A1 (en) 2007-02-28 2008-08-28 Rohm And Haas Company A porous linear polymer composition and method of making same
JP5016512B2 (ja) 2007-02-28 2012-09-05 ローム アンド ハース カンパニー 実質的に線状のコポリマーおよびその製造方法
JP5111145B2 (ja) 2007-02-28 2012-12-26 ローム アンド ハース カンパニー 非環式脂肪族オレフィンの重合
CA2620884C (en) * 2007-02-28 2011-07-12 Rohm And Haas Company Composition and method for preparing copolymers of polar and non-polar olefins substantially free of free radical intiated polymer
FR2937643B1 (fr) * 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires
JP5738097B2 (ja) * 2010-09-10 2015-06-17 昭和電工株式会社 ノルボルネン系重合体の製造方法
TWI507432B (zh) * 2010-10-26 2015-11-11 Showa Denko Kk A method for producing a catalyst for the polymerization of bentonite units and a method for producing bentonite-based polymers
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材
KR101576718B1 (ko) 2011-05-09 2015-12-10 릴라이언스 인더스트리즈 리미티드 프로필렌 중합용 질소 함유 외부 공여체 시스템
JP5575702B2 (ja) * 2011-05-20 2014-08-20 株式会社クラレ ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用
WO2014157583A1 (ja) 2013-03-27 2014-10-02 日本ポリエチレン株式会社 極性基含有オレフィン共重合体、多元系極性基含有オレフィン共重合体及びオレフィン系樹脂組成物並びにそれを利用する接着剤、積層体
CN103360544B (zh) * 2013-07-26 2015-07-01 宁波工程学院 降冰片烯类、丙烯酸酯类和戊烯类共聚用催化剂及共聚方法
WO2019089715A1 (en) * 2017-10-31 2019-05-09 Dow Global Technologies, Llc Catalyst systems comprising carborane cocatalysts
CN113877551B (zh) * 2021-10-25 2023-12-29 湖北科技学院 重金属和放射性金属离子吸附材料及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) * 1970-07-13 1974-12-15 Способ получения линейных полимеров
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
DE69325757T2 (de) 1992-09-21 1999-12-30 Montell Technology Co. B.V., Hoofddorp Polymerisationsverfahren
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) * 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US5929181A (en) * 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
EP0988331B1 (en) * 1997-06-09 2004-09-01 Promerus LLC Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US6111041A (en) * 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US6593440B2 (en) * 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US7087691B2 (en) * 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
WO1999014222A1 (en) * 1997-09-15 1999-03-25 The Dow Chemical Company Bimetallic complexes and polymerization catalysts therefrom
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
AU4826399A (en) * 1998-07-01 2000-01-24 B.F. Goodrich Company, The Polycyclic copolymer compositions
KR20000011466A (ko) * 1998-07-08 2000-02-25 고사이 아끼오 전이금속화합물,올레핀중합촉매성분,올레핀중합촉매및올레핀폴리머의제조방법
KR20010072084A (ko) 1998-07-27 2001-07-31 간디 지오프레이 에이치. 중합반응법
CN1847270B (zh) * 1998-10-05 2012-05-09 普罗米鲁斯有限责任公司 含聚合催化剂前体的组合物
AU3115500A (en) * 1998-12-09 2000-06-26 B.F. Goodrich Company, The In mold addition polymerization of norbornene-type monomers using group 10 metal complexes
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
MXPA02011811A (es) * 2000-05-31 2003-05-14 Du Pont Polimerizacion de olefinas.
US6541585B2 (en) 2000-05-31 2003-04-01 E. I. Du Pont De Nemours And Company Polymerization of olefins
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) * 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) * 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Also Published As

Publication number Publication date
JP2005068424A (ja) 2005-03-17
TWI262196B (en) 2006-09-21
KR20050020725A (ko) 2005-03-04
TW200514795A (en) 2005-05-01
US7087687B2 (en) 2006-08-08
KR100560061B1 (ko) 2006-03-13
EP1508577A1 (en) 2005-02-23
US20050043494A1 (en) 2005-02-24
CN1597709A (zh) 2005-03-23

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