CN1260263C - 两性聚氨酯树脂的制备方法以及由该方法获得的两性聚氨酯树脂及树脂组合物 - Google Patents
两性聚氨酯树脂的制备方法以及由该方法获得的两性聚氨酯树脂及树脂组合物 Download PDFInfo
- Publication number
- CN1260263C CN1260263C CNB021282358A CN02128235A CN1260263C CN 1260263 C CN1260263 C CN 1260263C CN B021282358 A CNB021282358 A CN B021282358A CN 02128235 A CN02128235 A CN 02128235A CN 1260263 C CN1260263 C CN 1260263C
- Authority
- CN
- China
- Prior art keywords
- compound
- urethane resin
- amphoteric urethane
- preparation
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims description 105
- 229920005749 polyurethane resin Polymers 0.000 title claims description 6
- 239000011342 resin composition Substances 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 215
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 203
- -1 polysiloxane Polymers 0.000 claims abstract description 160
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 50
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 43
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 32
- 229920005862 polyol Polymers 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 25
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims abstract description 24
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 23
- 150000003077 polyols Chemical class 0.000 claims abstract description 18
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 15
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 8
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 31
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 30
- 238000006276 transfer reaction Methods 0.000 claims description 20
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 17
- 239000007795 chemical reaction product Substances 0.000 claims description 14
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 12
- 229920005906 polyester polyol Polymers 0.000 claims description 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 229960004418 trolamine Drugs 0.000 claims description 7
- 229920005604 random copolymer Polymers 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 239000005062 Polybutadiene Substances 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 229920001610 polycaprolactone Polymers 0.000 claims description 5
- 239000004632 polycaprolactone Substances 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 5
- 239000002537 cosmetic Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 78
- 239000007864 aqueous solution Substances 0.000 description 69
- 230000000052 comparative effect Effects 0.000 description 66
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 30
- 229920005989 resin Polymers 0.000 description 21
- 239000011347 resin Substances 0.000 description 21
- 239000006260 foam Substances 0.000 description 19
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 238000005406 washing Methods 0.000 description 17
- 229920001451 polypropylene glycol Polymers 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 239000000499 gel Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000000443 aerosol Substances 0.000 description 10
- 239000000865 liniment Substances 0.000 description 10
- 229940040145 liniment Drugs 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 239000003380 propellant Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000003648 hair appearance Effects 0.000 description 6
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229940058015 1,3-butylene glycol Drugs 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- ARSRBNBHOADGJU-UHFFFAOYSA-N 7,12-dimethyltetraphene Chemical compound C1=CC2=CC=CC=C2C2=C1C(C)=C(C=CC=C1)C1=C2C ARSRBNBHOADGJU-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VFZRZRDOXPRTSC-UHFFFAOYSA-N DMBA Natural products COC1=CC(OC)=CC(C=O)=C1 VFZRZRDOXPRTSC-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-MRTMQBJTSA-N Isoborneol Natural products C1C[C@@]2(C)[C@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-MRTMQBJTSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000012973 diazabicyclooctane Substances 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 2
- 229960005082 etohexadiol Drugs 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003863 metallic catalyst Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- WOGVOIWHWZWYOZ-UHFFFAOYSA-N 1,1-diisocyanatoethane Chemical compound O=C=NC(C)N=C=O WOGVOIWHWZWYOZ-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 description 1
- NKFNBVMJTSYZDV-UHFFFAOYSA-N 2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCO NKFNBVMJTSYZDV-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- UZPWKTCMUADILM-UHFFFAOYSA-N 3-methylcyclohexene Chemical compound CC1CCCC=C1 UZPWKTCMUADILM-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000006474 Theobroma bicolor Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- HNDLTSNUZCYNRL-UHFFFAOYSA-N hexadecan-5-ol Chemical compound CCCCCCCCCCCC(O)CCCC HNDLTSNUZCYNRL-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
Description
实施例和比较例的发型固定剂泡沫 | 重量% | |
X成分 | 实施例和比较例的两性聚氨酯树脂水溶液 | 2.5a) |
去离子水 | 78.5 | |
聚氧乙烯月桂基醚 | 0.5 | |
可可油脂肪酸二乙醇酰胺 | 0.5 | |
乙醇 | 10.0 | |
Y成分 | 抛射剂 | 8.0 |
实施例 | ||||||||||||
1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | |
固定性能 | A | A | A | A | A | A | A | A | A | A | A | A |
质地 | A | A | A | A | A | A | A | A | A | A | A | A |
洗发性能 | B | B | B | B | B | B | B | B | A | A | A | A |
手感 | B | B | B | B | B | B | A | A | B | B | A | A |
铺展性 | A | A | A | A | A | A | A | A | A | A | A | A |
储存稳定性 | A | A | A | A | A | A | A | A | A | A | A | A |
比较例 | |||||||||
1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | |
固定性能 | A | C | C | C | C | C | C | A | A |
质地 | A | A | A | A | A | A | A | A | A |
洗发性能 | B | B | B | B | B | B | B | B | B |
手感 | C | B | B | B | B | B | B | A | A |
铺展性 | C | A | A | A | A | A | A | C | C |
储存稳定性 | - | D | D | D | D | D | D | A | A |
实施例和比较例的发型固定剂凝胶 | 重量% | |
X成分 | 增稠剂b) | 1.5a) |
三乙醇胺 | 1.1 | |
乙醇 | 10.0 | |
丙二醇 | 0.5 | |
1,3-丁二醇 | 0.5 | |
去离子水 | 50.0 | |
Y成分 | 实施例或比较例各自的两性聚氨酯树脂水溶液 | 2.5a) |
去离子水 | 33.9 |
实施例和比较例的发型固定剂气雾剂 | 重量% | |
X成分 | 实施例或比较例各自的两性聚氨酯树脂水溶液 | 2.5a) |
去离子水 | 8.0 | |
二辛基硫代琥珀酸钠 | 0.5 | |
丙二醇 | 0.1 | |
1,3-丁二醇 | 0.3 | |
乙醇 | 48.6 | |
Y成分 | 抛射剂 | 40.0 |
实施例和比较例的发型固定剂泵喷射剂 | 重量% |
实施例或比较例各自的两性聚氨酯树脂水溶液 | 2.5a) |
去离子水 | 85.5 |
二辛基硫代琥珀酸钠 | 0.5 |
鲸蜡醇 | 0.5 |
十八烷醇 | 0.5 |
丙二醇 | 0.5 |
乙醇 | 10.0 |
抗菌剂 | 适量 |
Claims (12)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP194685/01 | 2001-06-27 | ||
JP2001194685A JP4688351B2 (ja) | 2001-06-27 | 2001-06-27 | 両性ウレタン樹脂の製造方法、その製造方法で得られる両性ウレタン樹脂及び樹脂組成物 |
JP194685/2001 | 2001-06-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1406996A CN1406996A (zh) | 2003-04-02 |
CN1260263C true CN1260263C (zh) | 2006-06-21 |
Family
ID=19032776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB021282358A Expired - Fee Related CN1260263C (zh) | 2001-06-27 | 2002-06-27 | 两性聚氨酯树脂的制备方法以及由该方法获得的两性聚氨酯树脂及树脂组合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US6646092B2 (zh) |
EP (1) | EP1275672B1 (zh) |
JP (1) | JP4688351B2 (zh) |
CN (1) | CN1260263C (zh) |
AU (1) | AU783970B2 (zh) |
BR (1) | BR0203347A (zh) |
DE (1) | DE60207154T2 (zh) |
MX (1) | MXPA02006419A (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1303124C (zh) * | 2004-01-30 | 2007-03-07 | 香港理工大学 | 水基嵌段聚氨酯、其制法及由其制备的防水、保暖、透湿性材料 |
US20070185003A1 (en) * | 2006-01-18 | 2007-08-09 | Invista North America S.A.R.L. | Non-textile polymer compositions and methods |
JP5463612B2 (ja) * | 2006-09-28 | 2014-04-09 | 横浜ゴム株式会社 | ウレタンエマルジョン |
JP4450427B2 (ja) * | 2007-11-13 | 2010-04-14 | 株式会社資生堂 | 皮膚化粧料 |
DE102008006004B3 (de) * | 2008-01-25 | 2009-08-27 | Bayer Materialscience Ag | Thermoplastische Polyurethane und deren Verwendung |
CN101225150B (zh) * | 2008-01-28 | 2010-06-09 | 浙江大学 | 水分散有机硅-聚氨酯嵌段共聚物的合成方法及应用 |
CN101225226B (zh) * | 2008-01-28 | 2010-11-24 | 浙江大学 | 水分散蒙脱土/有机硅嵌段聚氨酯纳米复合材料的制备方法及用途 |
EP2113546A1 (en) | 2008-04-28 | 2009-11-04 | Schlumberger Holdings Limited | Swellable compositions for borehole applications |
EP2495270B1 (en) | 2009-10-30 | 2014-10-01 | Mitsubishi Chemical Corporation | Polyester polyol, polyurethane utilizing the polyester polyol and process for production thereof, and polyurethane molded article |
JP5269855B2 (ja) * | 2010-10-28 | 2013-08-21 | 株式会社 資生堂 | 化粧料 |
JP2014520919A (ja) * | 2011-07-08 | 2014-08-25 | 江蘇博特新材料有限公司 | 水分散両性ポリウレタン、調製方法及びそのコンクリート靱性増強への応用 |
US20140364552A1 (en) * | 2011-12-09 | 2014-12-11 | Dic Corporation | Aqueous resin composition comprising film-forming aid, and steel sheet surface treatment agent containing the same |
CN105237721A (zh) * | 2015-09-17 | 2016-01-13 | 合肥思敬齐化工材料有限责任公司 | 一种高附着力水性聚氨酯树脂的制备方法 |
CN105175671A (zh) * | 2015-09-17 | 2015-12-23 | 合肥思敬齐化工材料有限责任公司 | 一种阴阳离子型聚氨酯树脂及其制备方法 |
KR20210024162A (ko) * | 2018-06-28 | 2021-03-04 | 닛토덴코 가부시키가이샤 | 방오성 폴리머 복합재 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3509810C1 (de) * | 1985-03-19 | 1986-05-15 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung von Polyurethanformteilen |
DE69401230T3 (de) | 1993-04-06 | 2006-02-16 | National Starch And Chemical Investment Holding Corp., Wilmington | Verwendung von Polyurethanen, die funktionelle Carboxylatogruppe enthalt, zur Haarfestigung |
JP3673880B2 (ja) * | 1996-05-29 | 2005-07-20 | 大日本インキ化学工業株式会社 | 水性樹脂水分散体及びその製造方法 |
JP2950778B2 (ja) * | 1996-07-30 | 1999-09-20 | 日本エヌエスシー株式会社 | 両性ポリウレタン樹脂水分散体の製造方法 |
JP3972409B2 (ja) * | 1997-05-22 | 2007-09-05 | チッソ株式会社 | コーティング樹脂組成物、及びその硬化方法 |
JP4165669B2 (ja) | 1998-02-09 | 2008-10-15 | 日本エヌエスシー株式会社 | 化粧品用樹脂組成物およびその製法 |
DE19821731A1 (de) * | 1998-05-14 | 1999-11-18 | Basf Ag | Kosmetisches Mittel |
JP4165676B2 (ja) * | 1998-12-22 | 2008-10-15 | 日本エヌエスシー株式会社 | 化粧品用樹脂組成物およびその製法、それを用いた化粧品 |
JP4165675B2 (ja) * | 1998-12-22 | 2008-10-15 | 日本エヌエスシー株式会社 | 化粧品用樹脂組成物およびその製法、それを用いた化粧品 |
WO2002009658A1 (en) | 2000-04-13 | 2002-02-07 | National Starch And Chemical Investiment Holding Corporation | Cosmetic resin composition |
JP4199353B2 (ja) * | 1998-12-24 | 2008-12-17 | シンジーテック株式会社 | 基材上に多孔質被覆層を形成するための方法 |
JP2000198920A (ja) * | 1999-01-06 | 2000-07-18 | Nippon Nsc Ltd | 水に分散が容易な新規なポリイソシアネ―ト組成物 |
WO2000052083A1 (en) * | 1999-03-03 | 2000-09-08 | Eastman Chemical Company | Silicone polymer diol compositions and condensation polymer/silicone polymer blends |
FR2793409B1 (fr) * | 1999-05-11 | 2004-03-19 | Oreal | Composition cosmetique comprenant une dispersion aqueuse de polymere filmogene et d'organopolysiloxane |
JP4104791B2 (ja) | 1999-08-10 | 2008-06-18 | 日本エヌエスシー株式会社 | 化粧料 |
JP2003012440A (ja) * | 2001-06-27 | 2003-01-15 | Shiseido Co Ltd | 化粧料 |
-
2001
- 2001-06-27 JP JP2001194685A patent/JP4688351B2/ja not_active Expired - Fee Related
-
2002
- 2002-06-26 MX MXPA02006419A patent/MXPA02006419A/es active IP Right Grant
- 2002-06-26 US US10/183,744 patent/US6646092B2/en not_active Expired - Lifetime
- 2002-06-27 EP EP02014020A patent/EP1275672B1/en not_active Expired - Fee Related
- 2002-06-27 DE DE60207154T patent/DE60207154T2/de not_active Expired - Lifetime
- 2002-06-27 AU AU50677/02A patent/AU783970B2/en not_active Ceased
- 2002-06-27 BR BR0203347-0A patent/BR0203347A/pt not_active IP Right Cessation
- 2002-06-27 CN CNB021282358A patent/CN1260263C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU5067702A (en) | 2003-01-02 |
JP2003012760A (ja) | 2003-01-15 |
MXPA02006419A (es) | 2004-08-12 |
US6646092B2 (en) | 2003-11-11 |
DE60207154T2 (de) | 2006-08-10 |
CN1406996A (zh) | 2003-04-02 |
DE60207154D1 (de) | 2005-12-15 |
EP1275672A1 (en) | 2003-01-15 |
US20030088041A1 (en) | 2003-05-08 |
BR0203347A (pt) | 2003-05-27 |
EP1275672B1 (en) | 2005-11-09 |
JP4688351B2 (ja) | 2011-05-25 |
AU783970B2 (en) | 2006-01-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1260263C (zh) | 两性聚氨酯树脂的制备方法以及由该方法获得的两性聚氨酯树脂及树脂组合物 | |
CN1311003C (zh) | 支链聚有机硅氧烷聚合物 | |
CN1206281C (zh) | 两性离子硅氧烷聚合物及由其形成的离子交联聚合物 | |
CN1735728A (zh) | 线性聚氨基和/或聚铵聚硅氧烷共聚物ⅱ | |
CN1735648A (zh) | 线性聚氨基-和/或聚铵聚硅氧烷共聚物ⅰ | |
CN1319512C (zh) | 包含至少一种聚硅氧烷-基聚酰胺的美容组合物 | |
CN1145660C (zh) | 滋发剂组合物及其用途 | |
CN1213721C (zh) | 化妆品组合物 | |
CN1246364C (zh) | 具有聚烷氧基的有机硅化合物 | |
CN1304683C (zh) | 用于处理纤维基底的含氟化合物组合物 | |
CN1196465C (zh) | 含有单甘油化或多甘油化脂肪醇和特定多元醇,用于角蛋白纤维的氧化染色的组合物 | |
CN101043869A (zh) | 毛发化妆品 | |
CN1186004C (zh) | 头发用组合物 | |
CN1575320A (zh) | 硅基季铵官能组合物及其应用 | |
CN1198564C (zh) | 美容产品 | |
CN1653110A (zh) | 蛋白质-硅烷/硅氧烷共聚物、其制备和应用 | |
CN1229412C (zh) | 基于含有氨基甲酸酯和/或脲官能团的低聚物和聚合物的化妆品 | |
CN1098901A (zh) | 提供调理和增光作用的护发组合物 | |
CN1105688A (zh) | 芳族聚碳化二亚胺交联剂 | |
CN1805993A (zh) | 活性的氨基和/或铵基聚硅氧烷化合物 | |
CN1049784A (zh) | 头发调理和定型组合物 | |
CN1178974C (zh) | 水溶性或水分散性聚合物盐 | |
CN1724578A (zh) | 聚酯二醇、丙烯酸系共聚物、聚氨酯组合物和斯潘德克斯纤维 | |
CN1068309C (zh) | 氨基脲衍生物及含其的涂料组合物 | |
CN1926281A (zh) | 有机硅配制剂用于运动服装用纺织品的耐久功能化的用途 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: AKZO NOBEL CO. Free format text: FORMER OWNER: NAT STARCH CHEM INVEST Effective date: 20091106 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20091106 Address after: Holland Arnhem Patentee after: Akzo Nobel N. V. Address before: Delaware Patentee before: National Starch & Chemical Investment Holding Corp |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171219 Address after: Holland Arnhem Patentee after: Akzo Nobel Chemicals International B.V Address before: Holland Arnhem Patentee before: Akzo Nobel N. V. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060621 Termination date: 20210627 |
|
CF01 | Termination of patent right due to non-payment of annual fee |