CN1255415C - 用于二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化的多齿亚磷酸酯配体和镍催化剂组合物 - Google Patents

用于二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化的多齿亚磷酸酯配体和镍催化剂组合物 Download PDF

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Publication number
CN1255415C
CN1255415C CNB031368573A CN03136857A CN1255415C CN 1255415 C CN1255415 C CN 1255415C CN B031368573 A CNB031368573 A CN B031368573A CN 03136857 A CN03136857 A CN 03136857A CN 1255415 C CN1255415 C CN 1255415C
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alkyl
formula
hydrocyanation
isomerization
catalyst
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CN1515576A (zh
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T·富
J·M·加纳
W·丹
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INVISTA TECHNOLOGIES R L SA
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNB031368573A 1997-07-29 1998-07-23 用于二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化的多齿亚磷酸酯配体和镍催化剂组合物 Expired - Fee Related CN1255415C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5402397P 1997-07-29 1997-07-29
US60/054023 1997-07-29

Related Parent Applications (1)

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CN98807514A Division CN1117728C (zh) 1997-07-29 1998-07-23 二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化

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CN1515576A CN1515576A (zh) 2004-07-28
CN1255415C true CN1255415C (zh) 2006-05-10

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CNB031368573A Expired - Fee Related CN1255415C (zh) 1997-07-29 1998-07-23 用于二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化的多齿亚磷酸酯配体和镍催化剂组合物
CN98807514A Expired - Fee Related CN1117728C (zh) 1997-07-29 1998-07-23 二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化

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US (2) US5981772A (OSRAM)
EP (1) EP1000021B1 (OSRAM)
JP (1) JP2002509550A (OSRAM)
KR (1) KR100545279B1 (OSRAM)
CN (2) CN1255415C (OSRAM)
BR (1) BR9810820B1 (OSRAM)
CA (1) CA2291443A1 (OSRAM)
DE (1) DE69808481T2 (OSRAM)
ID (1) ID23785A (OSRAM)
MY (1) MY125853A (OSRAM)
TW (1) TW527339B (OSRAM)
WO (1) WO1999006357A1 (OSRAM)
ZA (1) ZA986369B (OSRAM)

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CN113912516B (zh) 2021-10-15 2023-06-27 浙江新和成股份有限公司 一种多齿亚磷酸酯配体在催化合成己二腈中的应用
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WO1999006357A1 (en) 1999-02-11
KR100545279B1 (ko) 2006-01-24
US6120700A (en) 2000-09-19
KR20010022366A (ko) 2001-03-15
TW527339B (en) 2003-04-11
ID23785A (id) 2000-05-11
CN1265093A (zh) 2000-08-30
BR9810820A (pt) 2000-07-25
CA2291443A1 (en) 1999-02-11
CN1515576A (zh) 2004-07-28
HK1029983A1 (en) 2001-04-20
US5981772A (en) 1999-11-09
EP1000021A1 (en) 2000-05-17
DE69808481D1 (de) 2002-11-07
ZA986369B (en) 2000-01-17
DE69808481T2 (de) 2003-07-10
MY125853A (en) 2006-08-30
BR9810820B1 (pt) 2010-06-01
JP2002509550A (ja) 2002-03-26
EP1000021B1 (en) 2002-10-02

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