BR9810820A - Processo aperfeiçoado para a hidrocianação em fase lìquida de compostos diolefìnicos, processo aperfeiçoado para a isomerização de uma 2-alquil-3-monoalquenonitrila não-conjugada, ligante de fosfito multidentado e composição precursora de catálise - Google Patents

Processo aperfeiçoado para a hidrocianação em fase lìquida de compostos diolefìnicos, processo aperfeiçoado para a isomerização de uma 2-alquil-3-monoalquenonitrila não-conjugada, ligante de fosfito multidentado e composição precursora de catálise

Info

Publication number
BR9810820A
BR9810820A BR9810820-4A BR9810820A BR9810820A BR 9810820 A BR9810820 A BR 9810820A BR 9810820 A BR9810820 A BR 9810820A BR 9810820 A BR9810820 A BR 9810820A
Authority
BR
Brazil
Prior art keywords
improved process
isomerization
liquid phase
alkyl
catalyst precursor
Prior art date
Application number
BR9810820-4A
Other languages
English (en)
Other versions
BR9810820B1 (pt
Inventor
Thomas Foo
James Michael Garner
Wilson Tam
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of BR9810820A publication Critical patent/BR9810820A/pt
Publication of BR9810820B1 publication Critical patent/BR9810820B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO APERFEIçOADO PARA A HIDROCIANAçãO EM FASE LìQUIDA DE COMPOSTOS DIOLEFìNICOS, PROCESSO APERFEIçOADO PARA A ISOMERIZAçãO DE UMA 2-ALQUIL-3-MONOALQUENONITRILA NãO-CONJUGADA, LIGANTE DE FOSFITO MULTIDENTADO E COMPOSIçãO PRECURSORA DE CATáLISE" A presente invenção se refere a um processo de fase líquida aperfeiçoado, útil para a hidrocianação de compostos diolefínicos, a fim de produzir nitrilas acíclicas não-conjugadas e para o processo de fase líquida de isomerização das nitrilas em, entre outros, nitrilas lineares 3- e/ou 4-monoalqueno. O melhoramento envolve a condução do processo na presença de níquel de valência zero e ligante de fosfito multidentado. São também descritos ligantes inovadores de fosfito multidentados e composições precursoras de catálise fabricados a partir deles.
BRPI9810820-4A 1997-07-29 1998-07-23 processo aperfeiçoado para a hidrocianação em fase lìquida de compostos diolefìnicos, processo aperfeiçoado para a isomerização de uma 2-alquil-3-monoalquenonitrila não-conjugada, ligante de fosfito multidentado e composição precursora de catálise. BR9810820B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5402397P 1997-07-29 1997-07-29
PCT/US1998/015198 WO1999006357A1 (en) 1997-07-29 1998-07-23 Hydrocyanation of diolefins and isomerization of nonconjugated 2-alykl-3-monoalkenenitriles

Publications (2)

Publication Number Publication Date
BR9810820A true BR9810820A (pt) 2000-07-25
BR9810820B1 BR9810820B1 (pt) 2010-06-01

Family

ID=21988284

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9810820-4A BR9810820B1 (pt) 1997-07-29 1998-07-23 processo aperfeiçoado para a hidrocianação em fase lìquida de compostos diolefìnicos, processo aperfeiçoado para a isomerização de uma 2-alquil-3-monoalquenonitrila não-conjugada, ligante de fosfito multidentado e composição precursora de catálise.

Country Status (14)

Country Link
US (2) US5981772A (pt)
EP (1) EP1000021B1 (pt)
JP (1) JP2002509550A (pt)
KR (1) KR100545279B1 (pt)
CN (2) CN1255415C (pt)
BR (1) BR9810820B1 (pt)
CA (1) CA2291443A1 (pt)
DE (1) DE69808481T2 (pt)
HK (1) HK1029983A1 (pt)
ID (1) ID23785A (pt)
MY (1) MY125853A (pt)
TW (1) TW527339B (pt)
WO (1) WO1999006357A1 (pt)
ZA (1) ZA986369B (pt)

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CN1265093A (zh) 2000-08-30
DE69808481D1 (de) 2002-11-07
ZA986369B (en) 2000-01-17
KR100545279B1 (ko) 2006-01-24
EP1000021B1 (en) 2002-10-02
CN1117728C (zh) 2003-08-13
ID23785A (id) 2000-05-11
WO1999006357A1 (en) 1999-02-11
DE69808481T2 (de) 2003-07-10
US5981772A (en) 1999-11-09
KR20010022366A (ko) 2001-03-15
EP1000021A1 (en) 2000-05-17
HK1029983A1 (en) 2001-04-20
MY125853A (en) 2006-08-30
BR9810820B1 (pt) 2010-06-01
US6120700A (en) 2000-09-19
CA2291443A1 (en) 1999-02-11
CN1255415C (zh) 2006-05-10
JP2002509550A (ja) 2002-03-26
TW527339B (en) 2003-04-11
CN1515576A (zh) 2004-07-28

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