BR9712273A - Ferrocelinas quirais - Google Patents
Ferrocelinas quiraisInfo
- Publication number
- BR9712273A BR9712273A BR9712273-4A BR9712273A BR9712273A BR 9712273 A BR9712273 A BR 9712273A BR 9712273 A BR9712273 A BR 9712273A BR 9712273 A BR9712273 A BR 9712273A
- Authority
- BR
- Brazil
- Prior art keywords
- chiral
- ferrocellins
- quirais
- ferrocenila
- ferrocenyls
- Prior art date
Links
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/32—Oxygen atoms
- C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/18—Gold
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Catalysts (AREA)
- Soft Magnetic Materials (AREA)
Abstract
Patente de Invenção:<B>"FERROCENILA QUIRAIS"<D>. A invenção refere-se a ferrocenilas quirais de fórmula (I) na qual R~ a~ é -P(R~ 10~R~ 11~) ou -SR~ 12~; R~ b~ é -P(R'~ 10~R'~ 11~), -SR'~ 12~, -CH=NR~ 12~, -CH~ 2~-NH-R~ 12~ ou -CH~ 2~-O-P(R~ 10~R~ 11~); e os outros substituintes são conforme definido na reivindicação 1, as quais podem ser como ligantes para catalisadores de metal de transição em reações enantiosseletivas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH244196 | 1996-10-07 | ||
CH244096 | 1996-10-07 | ||
PCT/EP1997/005480 WO1998015565A1 (en) | 1996-10-07 | 1997-10-06 | Chiral ferrocenyls |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9712273A true BR9712273A (pt) | 1999-08-31 |
Family
ID=25690448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9712273-4A BR9712273A (pt) | 1996-10-07 | 1997-10-06 | Ferrocelinas quirais |
Country Status (13)
Country | Link |
---|---|
US (1) | US6133464A (pt) |
EP (1) | EP0929560B1 (pt) |
JP (1) | JP4043051B2 (pt) |
AT (1) | ATE211479T1 (pt) |
AU (1) | AU4944197A (pt) |
BR (1) | BR9712273A (pt) |
CA (1) | CA2263715C (pt) |
CZ (1) | CZ292412B6 (pt) |
DE (1) | DE69709883T2 (pt) |
ES (1) | ES2170942T3 (pt) |
HU (1) | HU222691B1 (pt) |
IL (1) | IL129329A (pt) |
WO (1) | WO1998015565A1 (pt) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1006199A1 (en) | 1998-12-03 | 2000-06-07 | Kreatech Biotechnology B.V. | Applications with and methods for producing selected interstrand crosslinks in nucleic acid |
US6562989B2 (en) | 2000-08-07 | 2003-05-13 | Yale University | Catalyst for aromatic C—O, C—N, and C—C bond formation |
US20040030199A1 (en) * | 2002-01-29 | 2004-02-12 | Maughon Robert R. | Process for reducing alpha-haloketones to secondary alpha-haloalcohols |
US6620954B1 (en) * | 2002-03-25 | 2003-09-16 | Eastman Chemical Company | Phosphinometallocenylamides as novel ligands for asymmetric catalysis |
GB0400717D0 (en) * | 2004-01-14 | 2004-02-18 | Stylacats Ltd | Ferrocene derivatives |
GB0400719D0 (en) * | 2004-01-14 | 2004-02-18 | Stylacats Ltd | Ligands for use in homogeneous catalysis |
GB0400720D0 (en) | 2004-01-14 | 2004-02-18 | Stylacats Ltd | Novel ferrocene-based phosphorus chiral phosphines |
DE102010001364B4 (de) * | 2010-01-29 | 2014-10-16 | Technische Universität Chemnitz | Neue P,O-Ferrocene, deren Herstellung und Verwendung in katalytischen Reaktionen |
JP6455893B2 (ja) | 2013-03-11 | 2019-01-23 | ラトガース,ザ ステート ユニバーシティ オブ ニュー ジャージー | 不斉転換のための有機金属の触媒作用 |
CN103772441B (zh) * | 2013-12-26 | 2016-08-17 | 浙江中山化工集团股份有限公司 | 一种(s)-1-二茂铁基乙基二甲胺转化为(r)-1-二茂铁基乙基二甲胺的合成方法 |
US9308527B2 (en) * | 2014-03-17 | 2016-04-12 | Eastman Chemical Company | Phosphorous compounds useful as ligands and compositions and methods regarding them |
CN104761518B (zh) * | 2014-12-01 | 2017-05-24 | 青岛科技大学 | 一种离子液体条件下不对称氢化合成d‑泛内酯的方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0496699B1 (de) * | 1991-01-25 | 1995-04-26 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diphosphine und deren Verwendung als Hydrierkatalysatoren |
EP0496700B1 (de) * | 1991-01-25 | 1996-03-06 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diophoshine und deren Verwendung als Hydrierkatalysatoren |
DE59309554D1 (de) * | 1992-04-02 | 1999-06-10 | Novartis Ag | Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
SG42938A1 (en) * | 1993-02-26 | 1997-10-17 | Ciba Geigy Ag | Ferrocenc diphosphines as ligands for homogeneous catalysts |
EP0646590B1 (de) * | 1993-10-01 | 1999-08-25 | Novartis AG | Mit Fluoralkyl substituierte Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
DE59605736D1 (de) * | 1995-02-24 | 2000-09-21 | Novartis Ag | Silylierte Ferrocenyldiphosphine, an anorganische oder polymere organische Träger gebundene silylierte Ferrocenyldiphosphine sowie Metallkomplexe davon, ihre Herstellung und Verwendung |
EP0820460B1 (en) * | 1995-04-11 | 1999-07-28 | Novartis AG | Dihalogenated ferrocenes and processes for the preparation thereof |
HRP960295A2 (en) * | 1995-07-06 | 1997-08-31 | Ciba Geigy Ag | Process for the hydrogenation of imines in the presence of immobilized iridium-diphosphine catalysts |
-
1997
- 1997-10-06 BR BR9712273-4A patent/BR9712273A/pt not_active Application Discontinuation
- 1997-10-06 JP JP51716698A patent/JP4043051B2/ja not_active Expired - Fee Related
- 1997-10-06 AU AU49441/97A patent/AU4944197A/en not_active Abandoned
- 1997-10-06 CA CA002263715A patent/CA2263715C/en not_active Expired - Fee Related
- 1997-10-06 AT AT97912121T patent/ATE211479T1/de not_active IP Right Cessation
- 1997-10-06 IL IL12932997A patent/IL129329A/xx not_active IP Right Cessation
- 1997-10-06 EP EP97912121A patent/EP0929560B1/en not_active Expired - Lifetime
- 1997-10-06 HU HU9904186A patent/HU222691B1/hu not_active IP Right Cessation
- 1997-10-06 CZ CZ19991178A patent/CZ292412B6/cs not_active IP Right Cessation
- 1997-10-06 WO PCT/EP1997/005480 patent/WO1998015565A1/en active IP Right Grant
- 1997-10-06 US US09/254,527 patent/US6133464A/en not_active Expired - Fee Related
- 1997-10-06 DE DE69709883T patent/DE69709883T2/de not_active Expired - Lifetime
- 1997-10-06 ES ES97912121T patent/ES2170942T3/es not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2263715A1 (en) | 1998-04-16 |
WO1998015565A1 (en) | 1998-04-16 |
CZ292412B6 (cs) | 2003-09-17 |
DE69709883T2 (de) | 2002-08-29 |
ES2170942T3 (es) | 2002-08-16 |
EP0929560A1 (en) | 1999-07-21 |
CZ117899A3 (cs) | 1999-07-14 |
CA2263715C (en) | 2007-05-01 |
AU4944197A (en) | 1998-05-05 |
JP2001501638A (ja) | 2001-02-06 |
IL129329A0 (en) | 2000-02-17 |
ATE211479T1 (de) | 2002-01-15 |
HUP9904186A2 (hu) | 2000-04-28 |
JP4043051B2 (ja) | 2008-02-06 |
IL129329A (en) | 2003-05-29 |
HU222691B1 (hu) | 2003-09-29 |
HUP9904186A3 (en) | 2001-11-28 |
US6133464A (en) | 2000-10-17 |
EP0929560B1 (en) | 2002-01-02 |
DE69709883D1 (de) | 2002-02-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25A | Requested transfer of rights approved |
Owner name: SYNGENTA PARTICIPATIONS AG (CH) Free format text: TRANSFERIDO DE: NOVARTIS AG |
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B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFERIMENTO DO PRESENTE PEDIDO, UMA VEZ QUE O MESMO NAO ATENDE AOS REQUISITOS DE SUFICIENCIA DESCRITIVA, DEFINICAO CLARA E PRECISA DA MATERIA OBJETO DE PROTECAO E ATIVIDADE INVENTIVA, DE ACORDO COM OS ARTIGOS 8O,13,24 E 25 DA LPI |
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B12B | Appeal against refusal [chapter 12.2 patent gazette] |