CN1250688C - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
- Publication number
- CN1250688C CN1250688C CN01821492.4A CN01821492A CN1250688C CN 1250688 C CN1250688 C CN 1250688C CN 01821492 A CN01821492 A CN 01821492A CN 1250688 C CN1250688 C CN 1250688C
- Authority
- CN
- China
- Prior art keywords
- composition
- surfactant system
- detergent composition
- lime
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 239000003599 detergent Substances 0.000 title claims abstract description 25
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 30
- 239000000344 soap Substances 0.000 claims abstract description 10
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 9
- 239000004615 ingredient Substances 0.000 claims abstract description 3
- -1 hydroxypropyl Chemical group 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 14
- 150000005215 alkyl ethers Chemical class 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 241000282326 Felis catus Species 0.000 claims description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 125000001165 hydrophobic group Chemical group 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 abstract description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 23
- 229910021536 Zeolite Inorganic materials 0.000 description 15
- 239000010457 zeolite Substances 0.000 description 15
- 239000004094 surface-active agent Substances 0.000 description 13
- 239000007844 bleaching agent Substances 0.000 description 11
- 229910000323 aluminium silicate Inorganic materials 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 102000004190 Enzymes Human genes 0.000 description 9
- 108090000790 Enzymes Proteins 0.000 description 9
- 239000013543 active substance Substances 0.000 description 9
- 238000004061 bleaching Methods 0.000 description 9
- 238000005660 chlorination reaction Methods 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 238000007046 ethoxylation reaction Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 108091005804 Peptidases Proteins 0.000 description 6
- 102000035195 Peptidases Human genes 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229940115440 aluminum sodium silicate Drugs 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000429 sodium aluminium silicate Substances 0.000 description 4
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 235000013599 spices Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 150000004965 peroxy acids Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 108090000787 Subtilisin Proteins 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000002797 proteolythic effect Effects 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 1
- OQNZFMZDPKAMHH-UHFFFAOYSA-N 1-methoxyethane-1,1,2-tricarboxylic acid Chemical class COC(C(O)=O)(C(O)=O)CC(O)=O OQNZFMZDPKAMHH-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- CYOSZPKSDURROM-UHFFFAOYSA-N CCOC(NC)(OCC)OCC Chemical compound CCOC(NC)(OCC)OCC CYOSZPKSDURROM-UHFFFAOYSA-N 0.000 description 1
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- 102220536955 Dynein axonemal intermediate chain 4_C33W_mutation Human genes 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 108010044467 Isoenzymes Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IFVNATVJZVXOFC-UHFFFAOYSA-N OC(CCC(O)=O)=O.OC(CCC(O)=O)=O.O.O Chemical compound OC(CCC(O)=O)=O.OC(CCC(O)=O)=O.O.O IFVNATVJZVXOFC-UHFFFAOYSA-N 0.000 description 1
- BLSKPZCBDOVSEF-UHFFFAOYSA-N O[PH2]=O.OC(=O)C=C Chemical compound O[PH2]=O.OC(=O)C=C BLSKPZCBDOVSEF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical group OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- JRZCGMGYTDEOII-UHFFFAOYSA-N butanedioic acid;2-sulfobutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CC(C(O)=O)S(O)(=O)=O JRZCGMGYTDEOII-UHFFFAOYSA-N 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000001007 flame atomic emission spectroscopy Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 125000005544 phthalimido group Chemical group 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Abstract
一种洗涤剂组合物，其含有：(a)至少(5)wt%的耐钙性的非皂阴离子表面活性剂体系，其含有α-烯烃磺酸盐；(b)至少(0.1)wt%的阳离子表面活性剂体系，(a)∶(b)的重量比为(17∶3)-(9∶10)，优选(3∶1)-(1∶1)；和(c)余量为其它可能存在的各洗涤剂成分。
Description
技术领域
本发明涉及一种衣用洗涤剂组合物，其可配成例如颗粒、片剂或液体组合物。
发明背景
用于手洗的常规衣用洗涤剂粉末包含大量阴离子表面活性剂，最通常为烷基苯磺酸盐。阴离子表面活性剂被认为很理想地合于手洗，因为其兼具针对各种污迹的优异去污性和高泡性。
然而，对于手洗来说，即使是高浓度的阴离子表面活性剂，也需要改善这种产品对油污的去除性能。
GB-A-1 570 128公开的洗涤剂组合物含有4-40wt％的对镁敏感的表面活性剂(例如，烷基醚硫酸盐、乙氧基化非离子表面活性剂、氧化胺)、13-40wt％的硅酸钠，以及5-50wt％的对镁有选择性去污力的助洗剂(例如沸石、柠檬酸钠、次氮基三乙酸盐或方解石/碳酸盐)。
JP-A-09 087 690公开了一种用于机洗的高堆积密度的粒状洗涤剂组合物，其含有阴离子表面活性剂(5-40wt％)，加上乙氧基化非离子表面活性剂(1-15wt％)、沸石(10-40wt％)以及晶体和无定形的硅酸钠(0.5-10wt％)。阴离子表面活性剂任选包含α-烯烃磺酸盐(在一些例子中高达10wt％)。
WO-A-97/43366涉及的洗涤剂组合物含0.5-60wt％的阴离子表面活性剂和0.01-30wt％的阳离子表面活性剂。在该文献中举例的组合物中，阴离子表面活性剂的含量一般为组合物的约10-15wt％，阳离子表面活性剂的量为约1-4wt％。在某些例子中，阴离子表面活性剂组分包含少量的烷基醚硫酸盐表面活性剂，其一般为组合物总量的0.76-2.5wt％。
在WO-A-98/01521中公开了含有少量烷基醚硫酸盐阴离子表面活性剂(高达～1.75wt％)的组合物，以及在一种情况下含有少量沸石(1.5wt％)的组合物。然而，这些组合物是喷雾干燥的，因此其含有大量硫酸钠，硫酸钠是一种非碱性的非官能化水溶性盐(电解质)。
JP-A-62 218499公开了其它喷雾干燥的组合物，其硫酸钠含量高并且包含α-烯烃硫酸盐阴离子表面活性剂，以及12wt％或15wt％的沸石助洗剂。
WO-A-00/40682公开的组合物含有超过40％的阴离子表面活性剂体系，至少某些所述体系含有耐钙性的表面活性剂，例如α-烯烃磺酸盐或烷基醚硫酸盐。含耐钙性的表面活性剂的例子不含磷酸盐或铝硅酸盐助洗剂，否则磷酸盐的含量非常高。
我们的英国专利申请9925961.6也公开了含5-30wt％的α-烯烃磺酸盐的组合物。这些都基于方解石/碳酸盐助洗剂体系。
其它含耐钙性的表面活性剂的组合物公开在US-A-6,010,996、GB-A-2309706、US-A-5,415,812、US-A-4,265,777和US-A-4,970,017中。
仍需要含有强助洗剂，即磷酸盐或铝硅酸盐助洗剂，但其含量较低，却仍然对各种水硬度都通用的组合物，本发明满足了这一需要。
发明的限定
本发明提供了一种洗涤剂组合物，其含有：
(a)至少5wt％的耐钙性的非皂阴离子表面活性剂体系，其含有α-烯烃磺酸盐和烷基醚硫酸盐；
(b)至少0.1wt％的阳离子表面活性剂体系，其中(a)∶(b)的重量比为3∶1-1∶1；和
(c)余量为其它可能存在的各洗涤剂成分。
发明详述
本发明组合物基于混合的耐钙性的阴离子表面活性剂体系，加上中等含量的磷酸盐和/或铝硅酸盐助洗剂。
在一种实施方案中，粉末洗涤剂组合物的组分(a)和(b)被包含在单独的颗粒中，各颗粒都不含另一种组分。
阴离子表面活性剂体系(a)
本发明组合物包含至少5wt％的耐钙性的阴离子表面活性剂，其含有α-烯烃磺酸盐。一般地，这一耐钙性的阴离子表面活性剂体系含量的上限为75wt％。然而，优选阴离子表面活性剂体系的存在量基于组合物总重为15-70wt％，更优选2-60wt％，尤其为30-50wt％。
阴离子表面活性剂对钙离子的稳定性可通过改进的Hart法(Witkes等人，J.Ind.Encl.Chem.29，1234-1239(1937))在微量滴定板中进行测定。用钙离子溶液滴定表面活性剂溶液。在室温下摇动一分钟后，混浊的出现显示不溶性钙沉淀物开始形成。
如这里所指，“耐钙性的”表面活性剂是一种表面活性剂浓度为0.4g/L(在离子强度为0.040M的1∶1盐溶液中)、钙浓度高达20°FH(法国硬度)，即200ppm的钙时不沉淀的表面活性剂。
本发明组合物所用的基本非皂的耐钙性的阴离子表面活性剂是α-烯烃磺酸盐和烷基醚硫酸盐。
有利地，烷基醚硫酸盐的存在量可少于α-烯烃磺酸盐的存在量。
优选的表面活性剂体系含有重量比为5∶1-15∶1的α-烯烃磺酸盐和烷基醚硫酸盐。
除α-烯烃磺酸和烷基醚硫酸盐的组合外，可单独或与这些或其它耐钙性的阴离子表面活性剂结合使用的其它耐钙性的阴离子表面活性剂是烷基乙氧基羧酸盐表面活性剂(例如Shell出品的Neodox(商标))、脂肪酸酯磺酸盐(例如Stepan出品的FAES MC-48和ML-40)、烷基二甲苯磺酸盐、二烷基磺基丁二酸盐、脂肪酸酯磺酸盐、烷基酰胺硫酸盐、sorpholipids、烷基糖苷硫酸盐和饱和或不饱和脂肪酸的碱金属(例如钠)盐。
也可存在一种以上的其它阴离子表面活性剂。例如，其可以选自一种或多种烷基苯磺酸盐、伯和仲烷基硫酸盐。
当希望避免烷基苯磺酸盐表面活性剂的不耐钙性时，则阴离子表面活性剂体系可以包含(优选占阴离子表面活性剂总量的70wt％或更多的)一种或多种耐钙性的非皂阴离子表面活性剂，或仅由其组成。
阳离子表面活性剂体系
本发明组合物包含至少0.1wt％的阳离子表面活性剂体系。一般地，该阳离子表面活性剂体系可占组合物总量的高达15wt％。然而，优选其占组合物的0.5-5wt％。
优选的阳离子表面活性剂类型包括具有下式的那些：
R1R2R3R4N+X-
其中
R1是疏水基团，(优选)C12-14烷基，或衍生自椰油；
R2、R3或R4独立地是羟乙基、羟丙基或C1-4烷基(例如Me、Et)；
X-增溶阳离子，优选Cl-、Br-或MeSO4-。
具体的例子是：
| R1 | R2、R3、R4 | |
| (i)氯化烷基羟乙基二甲基铵，HoeS3996(现在以Praepagen HY出售)(Clariant prev.Hoechst出品) | C12 | 2甲基、1羟乙基 |
| (ii)氯化烷基二羟乙基甲基铵，Bis-AQA型(Clariant出品)，例如EthoquadC/12型(AKZO-Nobel) | C12 | 1甲基、2羟乙基 |
| (iii)氯化烷基三甲基铵，Arquad型(例如Arquad C33W) | ＜C16，优选C12 | 3甲基 |
阳离子表面活性剂的限定也包括QMEA(季铵化单乙醇胺)或QTEA(季铵化三乙醇胺)。可能由于用表面活性剂酸(即LAS酸、脂肪酸、链烷烃磺酸＝SAS酸等)就地中和MEA或TEA而引起季铵化：
| R1 | R2、R3、R4 | |
| (iv)氯化单羟乙基铵季铵化的MEA羟乙基 | H | 2H，1 |
| (v)氯化三羟乙基铵季铵化的TEA | 1羟乙基 | 1H，2羟乙基 |
胺的外观为水状液体。可将它们应用于生产粉末的浆料中(作为部分替代苛性钠的碱)，或者应用于后配料颗粒添加剂中，并且作为中和表面活性剂酸后的反离子而存在。
(vi)APA Quats：氯化烷基酰氨基-正亚丙基二甲基(季)铵(烷基-CON(X)-(CH2)3NH+(CH3)2Cl-，其中X＝H或Me，Et，Pr或更高级烷基)
APA Quats C12-C14-CON(X)(CH2)3 2甲基
(vii)氯化醇三乙氧基二甲基铵(烷基(EO)nN+(CH3)3Cl-，其中n为1-10)
(viii)Esterquats：氯化单或二(椰油基亚乙基)羟乙基甲基铵(椰油基(CH2)2N+(CH3)(CH2CH2OH)CH3SO4-)
(viii)氯化苄基二甲基椰油烷基铵(例如R(CH3)2N+CH2C6H5Cl-等)，AKZO-Nobel出品，例如Arquad DMCB-80、DMHTB-75Arquad M2HTB-80)
(ix)氯化椰油苄基-(乙氧基化(2)-铵(例如Ethoquad C12/B))
(x)乙氧基化季盐(单烷基乙氧基化物)，即氯化单烷基甲基[乙氧基化(n)]铵
-例如Ethoquat 18/12，即十八烷基甲基[乙氧基化(2)]；Ethoquad18/25；Ethoquad C/12、C/25；Ethoquad 0/12，即油烯基甲基[乙氧基化(2)]；Ethoquad C/12硝酸盐，即硝酸椰油甲基[乙氧基化(2)]铵；Ethoquad T/12，即氯化牛油烷基甲基[乙氧基化(2)]铵。
任选的其它表面活性剂
如果希望，也可包含非离子表面活性剂。优选，这些物质的含量总计占组合物重量的0.1-7wt％。更优选0.5-4wt％，尤其是0.9-3wt％。
优选的非离子表面活性剂是平均乙氧基化度为2-12，更优选3-10的脂肪醇。优选，该脂肪醇是C10-C16，更优选C12-C15的。
助洗剂
本发明组合物在用作洗衣用组合物时通常也包含一种或多种助洗剂。在该组合物中，助洗剂的总量一般为组合物总重的5-80wt％，优选10-60wt％。在一个实施方案中，助洗剂的量为组合物总重的0-80wt％，优选0-45wt％。
可存在的无机助洗剂包括碳酸钠，如果希望，其可与用于碳酸钙的晶种结合使用，如GB-A-1 437 950中公开的；晶体和无定形铝硅酸盐，例如GB-A-1 473 201中公开的沸石、GB-A-1 473 202中公开的无定形铝硅酸盐以及GB-A-1 470 250中公开的混合的晶体/无定形铝硅酸盐；以及BP-A-164 514中公开的层状硅酸盐。无机磷酸盐助洗剂，例如正磷酸钠、焦磷酸钠和三聚磷酸钠也适用于本发明。
本发明组合物优选包含碱金属、优选钠的铝硅酸盐助洗剂。铝硅酸钠的一般加入量为10-70wt％(按无水物重量计)，优选25-50wt％。
当铝硅酸盐是沸石时，其最高量为19wt％。
所述碱金属铝硅酸盐可以是晶体或无定形的，或其混合物，具有通式：0.8-1.5 Na2O.Al2O3.0.8-6 SiO2。
这些物质含有一些结合水，并且要求其具有的钙离子交换能力为至少50mg CaO/g。优选的铝硅酸钠包含1.5-3.5个SiO2单元(在上式中)。无定形物质和晶体物质都可以通过硅酸钠和铝酸钠的反应容易地制备出来，如文献中的充分描述。在例如GB 1 429 143(Procter& Gamble)中描述了适合的晶体铝硅酸钠离子交换助洗剂。优选的这类铝硅酸钠是众所周知的市售沸石A和X，及其混合物。
所述沸石可以是市售的沸石4A，其现在被广泛地用于衣用洗涤剂粉末。然而，根据本发明的优选实施方案，加入本发明组合物的沸石助洗剂是铝最多的沸石P(沸石MAP)，如EP-A-384 070描述和要求权利的。沸石MAP被定义为沸石P型的碱金属铝硅酸盐，其硅与铝的比例不超过1.33，优选为0.90-1.33，更优选为0.90-1.20。
特别优选的是沸石MAP，其硅与铝的比例不超过1.07，更优选约1.00。沸石MAP的钙结合量一般为至少150mg CaO/g无水物质。
可以存在的有机助洗剂包括聚羧酸盐聚合物，如聚丙烯酸盐、丙烯酸/马来酸共聚物和丙烯酸亚膦酸盐；单体聚羧酸盐，如柠檬酸盐、葡糖酸盐、氧联二琥珀酸盐、甘油单-、二-和三琥珀酸盐、羧甲氧基琥珀酸盐、羧甲氧基丙二酸盐、二吡啶甲酸盐、羟乙基亚氨基二乙酸盐、烷基-和烯基丙二酸盐和琥珀酸盐；以及磺化的脂肪酸盐。这些列出的物质不是穷举的。
特别优选的有机助洗剂是柠檬酸盐，其适合的用量为5-30wt％，优选10-25wt％；以及丙烯酸聚合物，更特别是丙烯酸/马来酸共聚物，其适合的用量为0.5-15wt％，优选1-10wt％。
无机和有机助洗剂都优选以碱金属盐，特别是钠盐形式存在。
漂白剂
本发明的洗衣用组合物也可以适当地含有漂白体系。织物洗涤组合物可能希望包含过氧漂白化合物，例如能在水溶液中产生过氧化氢的无机过酸盐或有机过酸。
适用的过氧漂白化合物包括有机过氧化物，如过氧化脲；和无机过酸盐，如碱金属过硼酸盐、过碳酸盐、过磷酸盐、过硅酸盐和过硫酸盐。优选的无机过酸盐是过硼酸钠一水合物和四水合物，以及过碳酸钠。
特别优选的是过碳酸钠，其具有抵御由湿气引起的失稳效应的保护层。具有含偏硼酸钠和硅酸钠的保护层的过碳酸钠公开在GB-A-2123 044中。
过氧漂白化合物适合的存在量为0.1-35wt％，优选0.5-25wt％。该过氧漂白化合物可以与漂白活化剂(漂白剂前体)结合使用，以便改善在低洗涤温度下的漂白作用。漂白剂前体适合的存在量为0.1-8wt％，优选0.5-5wt％。
优选的漂白剂前体是过羧酸前体，更特别是过乙酸前体和过壬酸前体。适用于本发明的特别优选的漂白剂前体是N，N，N′，N′-四乙酰乙二胺(TAED)和壬酰氧基苯磺酸钠(SNOBS)。公开在美国专利4,751,015和US-A-4,818,426以及EP-A402 971中的新型季铵和季鏻漂白剂前体，和公开在EP-A-284 292和EP-A-303 520中的阳离子漂白剂前体也使人感兴趣。
可用过氧酸补充或替代所述漂白体系。这种过酸的例子出现在US-A-4,686,063和US-A-5,397,501中。优选的例子是描述在EP-A-325 288、EP-A-349 940、DE-A-382 3172和EP-A-325 289中的酰亚氨基过氧羧酸类过酸。特别优选的例子是苯二甲酰亚氨基过氧己酸(PAP)。这种过酸适合的存在量为0.1-12％，优选0.5-10％。
也可存在漂白稳定剂(过渡金属螯合剂)。适当的漂白稳定剂包括乙二胺四乙酸(EDTA)、聚膦酸盐如Dequest(商标)，以及非磷酸盐稳定剂如EDDS(乙二胺二琥珀酸)。这些漂白稳定剂也可用于去污，特别是在漂白物质含量低或不含漂白物质的产品中。
特别优选的漂白体系含有过氧漂白化合物(优选过碳酸钠，任选与漂白活化剂结合使用)和过渡金属漂白催化剂，如EP-A-458 397、EP-A-458 398和EP-A-509 787中描述并要求权利的。
酶
本发明的洗衣用组合物也可包含一种或多种酶。适当的酶包括可用于加入洗涤剂组合物中的蛋白酶、淀粉酶、纤维素酶、氧化酶、过氧化物酶和脂肪酶。优选的蛋白水解酶(蛋白酶)是催化激活的蛋白质物质，其在水解反应中降解或改变作为织物污迹存在的污迹蛋白质的类型。它们可以是任何适合的来源，如植物、动物、细菌或酵母源的。
可以得到各种质量和来源并在4-12的各pH值范围内具有活性的蛋白水解酶或蛋白酶，并可用于本发明。适合的蛋白水解酶的例子是从枯草芽孢杆菌、地衣芽孢杆菌的特定菌株中获得的枯草杆菌蛋白酶，如Gist Brocades N.V.，Delft，Holland提供的市售枯草杆菌蛋白酶Maxatase(商标)和Novo Industri A/S，Copenhagen，Denmark提供的Alcalase(商标)。
特别适合的是从在8-12的pH值范围内始终具有最大活性的芽孢杆菌属菌株中获得的蛋白酶，它可市购，如以注册商品名Esperase(商标)和Savinase(商标)购自Novo Industri A/S。GB 1 243 785描述了这些酶及其同功酶的制备。其它市售的蛋白酶是Kazusase(商标，从日本的Showa-Denko获得)、Optimase(商标，从西德汉诺威的Miles Kali-Chemie获得)，以及Superase(商标，从美国的Pfizer获得)。
通常使用颗粒形的去污酶，其用量为约0.1-3.0wt％。然而，可以使用任何适合外形的酶。
其它任选的次要成分
本发明组合物可以含有碱金属碳酸盐，优选碳酸钠，以便增加去污力并易于加工。碳酸钠适合的存在量为1-60wt％，优选2-40wt％。然而含有少量或不含碳酸钠的组合物也落入本发明的范围内。
粉末流动性可通过加入粉末表面活性剂来改善，例如加入脂肪酸(或脂肪酸皂)、糖、丙烯酸酯或丙烯酸酯/马来酸酯共聚物、或硅酸钠。一种优选的粉末表面活性剂是脂肪酸皂，其适合的存在量为1-5wt％。
可以存在于本发明组合物中的其它物质包括硅酸钠；抗再沉积剂，如纤维素聚合物；无机盐，如硫酸钠；根据需要而定的泡沫控制剂或助泡剂；染料；彩色斑饰物；香料；泡沫控制剂；荧光增白剂和去偶合剂。这些列出的物质不是穷举的。
制备组合物
本发明组合物可以通过任何适合的方法制备。
制备路径的选择部分取决于所包含的表面活性剂的稳定性或热敏性，以及其应用形式。
例如α-烯烃磺酸盐是通用的，并可为粉末、膏状和溶液形式。
烷基醚硫酸盐对热较敏感、易于水解并可以为浓的(例如约70％性物质的)含水膏状物质或更稀的(例如28.5wt％)溶液。
在任何场合，可以在如下所述加工步骤后加入各种成分，如酶、漂白成分、螯合剂、聚合物和香料，这些成分传统上是分别加入的(例如酶作为颗粒进行后加料，香料进行喷涂)。
适合的方法包括：
(1)将主要成分滚筒干燥，任选随后进行造粒或将其它成分后加料；
(2)在高速混合机/成粒机例如Fukae(商标)FS系列混合器中，将全部成分、优选与至少一种糊状表面活性剂一起进行非塔造粒，以便使表面活性剂糊中的水可以起粘合剂的作用；
(3)在高速/中速成粒机联合作用大，在膜式急骤干燥机/蒸发器或流化床成粒机中进行非塔造粒。
实施例
通过下列非限定性的实施例进一步举例说明本发明，除非另有说明，其中的份数和百分数都按重量计算。
| A | 1 | B | 2 | C | |
| AOS | 5 | 10 | 5 | 10 | 9.2 |
| LAS | 10 | 10 | |||
| SLES(3E0) | 5 | 5 | |||
| 醇7E0乙氧基化非离子 | 2 | 2 | |||
| 阳离子Praegen HY | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 |
| Na2CO3 | 25 | 25 | 25 | 25 | 25 |
| STP | 35 | 35 | 35 | 35 | 35 |
| 酶 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 |
| SCMC | 2 | 2 | 2 | 2 | 2 |
| 荧光增白剂 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| 香料 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| 水&杂质 | 余量，至100％ | ||||
去污力试验
实施例1-2是本发明。实施例A-C是对比实施例。在定量试验中，实施例1-2显示出显著优越的去脂/油污力。
Claims (8)
1.一种洗涤剂组合物，其含有：
(a)至少5wt％的耐钙性的非皂阴离子表面活性剂体系，其含有α-烯烃磺酸盐和烷基醚硫酸盐；
(b)至少0.1wt％的阳离子表面活性剂体系，其中(a)∶(b)的重量比为3∶1-1∶1；和
(c)余量为其它任选存在的各洗涤剂成分。
2.权利要求1的洗涤剂组合物，其含有至少15wt％的阴离子表面活性剂体系(a)。
3.权利要求2的洗涤剂组合物，其中的阴离子表面活性剂体系含有占阴离子表面活性剂总量的至少70wt％的耐钙性的非皂阴离子表面活性剂。
4.前述权利要求任一项的洗涤剂组合物，其中耐钙性的非皂阴离子表面活性剂体系(a)含有重量比为5∶1-15∶1的α-烯烃磺酸盐和烷基醚硫酸盐。
5.权利要求1的洗涤剂组合物，其含有0.5-5wt％的阳离子表面活性剂体系。
6.权利要求1的洗涤剂组合物，其中阳离子表面活性剂体系含有一种或多种选自下式化合物的阳离子表面活性剂：
R1R2R3R4N+X-
其中R1是疏水基；
R2、R3和R4独立地选自羟乙基、羟丙基和C1-4烷基；X-是增溶阳离子。
7.权利要求1的组合物，其含有0-45wt％的助洗剂。
8.权利要求1的粉末洗涤剂组合物，其中组分(a)和(b)被包含在单独的颗粒中，各颗粒都不含另一种组分。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0031823.8A GB0031823D0 (en) | 2000-12-29 | 2000-12-29 | Detergent compositions |
| GB0031823.8 | 2000-12-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1533425A CN1533425A (zh) | 2004-09-29 |
| CN1250688C true CN1250688C (zh) | 2006-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN01821492.4A Expired - Fee Related CN1250688C (zh) | 2000-12-29 | 2001-12-13 | 洗涤剂组合物 |
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| Country | Link |
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| US (1) | US6730649B2 (zh) |
| EP (1) | EP1346018B1 (zh) |
| CN (1) | CN1250688C (zh) |
| AT (1) | ATE282682T1 (zh) |
| BR (1) | BR0116619B1 (zh) |
| CA (1) | CA2431538C (zh) |
| DE (1) | DE60107289T2 (zh) |
| ES (1) | ES2228976T3 (zh) |
| GB (1) | GB0031823D0 (zh) |
| WO (1) | WO2002053693A1 (zh) |
| ZA (1) | ZA200304104B (zh) |
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| DE10257389A1 (de) * | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Flüssiges saures Waschmittel |
| DE10303130A1 (de) * | 2003-01-28 | 2004-07-29 | Clariant Gmbh | Wässrige Flüssigwaschmittel-Dispersionen |
| CA2583452A1 (en) | 2004-10-08 | 2006-04-20 | The Procter & Gamble Company | Fabric care compositions comprising hueing dye |
| EP1674608A1 (de) * | 2004-12-23 | 2006-06-28 | Clariant International Ltd. | Dispergator für Polyesteroligomere |
| CA2590550A1 (en) * | 2004-12-27 | 2006-07-06 | The Dial Corporation | Liquid laundry detergent containing fabric conditioners |
| US9237972B2 (en) * | 2008-12-16 | 2016-01-19 | Kimberly-Clark Worldwide, Inc. | Liquid surfactant compositions that adhere to surfaces and solidify and swell in the presence of water and articles using the same |
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-
2000
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- 2001-12-13 ZA ZA200304104A patent/ZA200304104B/en unknown
- 2001-12-13 BR BRPI0116619-0A patent/BR0116619B1/pt not_active IP Right Cessation
- 2001-12-13 WO PCT/EP2001/014766 patent/WO2002053693A1/en not_active Application Discontinuation
- 2001-12-13 CN CN01821492.4A patent/CN1250688C/zh not_active Expired - Fee Related
- 2001-12-13 EP EP01991847A patent/EP1346018B1/en not_active Expired - Lifetime
- 2001-12-13 ES ES01991847T patent/ES2228976T3/es not_active Expired - Lifetime
- 2001-12-13 DE DE60107289T patent/DE60107289T2/de not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2002053693A1 (en) | 2002-07-11 |
| EP1346018A1 (en) | 2003-09-24 |
| BR0116619B1 (pt) | 2012-03-20 |
| EP1346018B1 (en) | 2004-11-17 |
| CA2431538C (en) | 2010-10-19 |
| WO2002053693B1 (en) | 2002-09-06 |
| ATE282682T1 (de) | 2004-12-15 |
| DE60107289D1 (de) | 2004-12-23 |
| US20020155974A1 (en) | 2002-10-24 |
| ZA200304104B (en) | 2004-06-23 |
| DE60107289T2 (de) | 2005-05-04 |
| US6730649B2 (en) | 2004-05-04 |
| CA2431538A1 (en) | 2002-07-11 |
| CN1533425A (zh) | 2004-09-29 |
| ES2228976T3 (es) | 2005-04-16 |
| BR0116619A (pt) | 2003-12-23 |
| GB0031823D0 (en) | 2001-02-14 |
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