CN1243763C - 茂金属化合物的制备方法 - Google Patents

茂金属化合物的制备方法 Download PDF

Info

Publication number
CN1243763C
CN1243763C CNB99800037XA CN99800037A CN1243763C CN 1243763 C CN1243763 C CN 1243763C CN B99800037X A CNB99800037X A CN B99800037XA CN 99800037 A CN99800037 A CN 99800037A CN 1243763 C CN1243763 C CN 1243763C
Authority
CN
China
Prior art keywords
group
metal element
ind
methyl
indenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB99800037XA
Other languages
English (en)
Chinese (zh)
Other versions
CN1255925A (zh
Inventor
L·雷斯科尼
D·巴尔波尼
G·普里尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Spherilene SRL
Original Assignee
Spherilene SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene SRL filed Critical Spherilene SRL
Publication of CN1255925A publication Critical patent/CN1255925A/zh
Application granted granted Critical
Publication of CN1243763C publication Critical patent/CN1243763C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
CNB99800037XA 1998-01-14 1999-01-14 茂金属化合物的制备方法 Expired - Fee Related CN1243763C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98200077 1998-01-14
EP98200077.0 1998-01-14

Publications (2)

Publication Number Publication Date
CN1255925A CN1255925A (zh) 2000-06-07
CN1243763C true CN1243763C (zh) 2006-03-01

Family

ID=8233295

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB99800037XA Expired - Fee Related CN1243763C (zh) 1998-01-14 1999-01-14 茂金属化合物的制备方法

Country Status (8)

Country Link
US (1) US6191294B1 (OSRAM)
EP (1) EP0979232B1 (OSRAM)
JP (1) JP4208265B2 (OSRAM)
KR (1) KR20000076111A (OSRAM)
CN (1) CN1243763C (OSRAM)
CA (1) CA2283880A1 (OSRAM)
DE (1) DE69903388T2 (OSRAM)
WO (1) WO1999036427A1 (OSRAM)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002505713A (ja) * 1998-04-21 2002-02-19 モンテル テクノロジー カンパニー ビーブイ α−オレフィンとのエチレンコポリマーの製造方法
IL142979A0 (en) 1998-11-18 2002-04-21 Basell Technology Co Bv Methylene bridged metallocenes as olefin-polymerization-catalyst components
KR20010072229A (ko) 1999-06-04 2001-07-31 간디 지오프레이 에이치. 티타늄 착물의 제조 방법
ATE430753T1 (de) * 2000-01-18 2009-05-15 Basell Polyolefine Gmbh Ligand für einen metallocenkatalysator für die polymerisation von propylen und dessen herstellungsverfahren
EP1381618B1 (en) 2001-04-10 2008-05-07 Basell Polyolefine GmbH Process for the production of monohalide or dihalide metallocene compounds
WO2002100909A1 (en) 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
DE60210089T2 (de) 2001-06-22 2006-10-19 Basell Polyolefine Gmbh Metallocene, verwendung in katalysatoren für olefinpolymerisation
WO2003008496A1 (en) * 2001-07-17 2003-01-30 Basell Polyolefine Gmbh Multistep process for the (co)polymerization of olefins
ES2268126T3 (es) 2001-11-30 2007-03-16 Basell Polyolefine Gmbh Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno.
DE10200422A1 (de) * 2002-01-08 2003-07-17 Basell Polyolefine Gmbh Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen
EP1470140B1 (en) * 2002-01-08 2008-03-12 Basell Polyolefine GmbH Preparation of silicon-bridged metallocene compounds
EP1539843B1 (en) 2002-09-06 2009-10-14 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7176158B2 (en) * 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
US6693155B1 (en) * 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
ATE471332T1 (de) 2003-05-08 2010-07-15 Basell Polyolefine Gmbh Verfahren zur herstellung von halogenidmetallocenverbindungen
BRPI0414762A (pt) 2003-09-29 2006-11-28 Basell Polyolefine Gmbh processo para a isomerização de compostos metalocênicos
CN101245084B (zh) * 2007-02-14 2013-02-20 中国石油天然气股份有限公司 含膦取代乙烯基茂金属催化剂及其制备方法和应用
US8076259B2 (en) * 2007-10-04 2011-12-13 Basell Polyolefine Gmbh Process for the preparation of catalyst paste and products thereof
EP2328906A1 (en) 2008-08-25 2011-06-08 Basell Polyolefine GmbH Preparation of ansa metallocene compounds
MX362816B (es) 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
US20110082323A1 (en) * 2009-10-06 2011-04-07 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
JP6038375B1 (ja) * 2016-06-29 2016-12-07 ポリプラスチックス株式会社 触媒の製造方法
KR102073252B1 (ko) 2016-12-05 2020-02-04 주식회사 엘지화학 올레핀 공중합체 합성용 촉매 조성물 및 올레핀 공중합체의 제조 방법
KR102765043B1 (ko) * 2018-05-16 2025-02-07 주식회사 엘지화학 테트라하이드로인덴 유도체로부터 메탈로센 화합물을 제조하는 방법
KR102398899B1 (ko) * 2019-11-29 2022-05-17 디엘케미칼 주식회사 낮은 점도 알파-올레핀 올리고머 및 이의 제조방법
CN115485311B (zh) 2020-02-24 2024-12-06 埃克森美孚化学专利公司 用于生产乙烯叉基封端的聚α-烯烃的柄型-双(茚-2-基)催化剂

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
ATE147761T1 (de) * 1990-06-22 1997-02-15 Exxon Chemical Patents Inc Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation
IT1256259B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
WO1996019488A1 (en) 1994-12-21 1996-06-27 Exxon Chemical Patents Inc. A method of preparing high purity racemic metallocene alkyls and use thereof
IL127229A0 (en) 1997-03-29 1999-09-22 Montell Technology Company Bv Metallocenes and catalysts for polymerization of olefins

Also Published As

Publication number Publication date
EP0979232B1 (en) 2002-10-09
CA2283880A1 (en) 1999-07-22
CN1255925A (zh) 2000-06-07
JP2001516367A (ja) 2001-09-25
JP4208265B2 (ja) 2009-01-14
DE69903388T2 (de) 2003-06-18
WO1999036427A1 (en) 1999-07-22
EP0979232A1 (en) 2000-02-16
KR20000076111A (ko) 2000-12-26
DE69903388D1 (de) 2002-11-14
US6191294B1 (en) 2001-02-20

Similar Documents

Publication Publication Date Title
CN1243763C (zh) 茂金属化合物的制备方法
CN1075819C (zh) 金属茂、其制备方法和它作为催化剂的应用
CN1075076C (zh) 金属茂化合物及其制法和在烯烃聚合催化剂中的应用
CN1058015C (zh) 双环戊二烯基二烯配合物
CN1042340C (zh) 制备乙烯共聚物的方法
CN1374973A (zh) 用于烯烃聚合的催化剂体系及方法
CN1052736C (zh) 无定形丙烯聚合物的制备方法
CN1226894A (zh) 金属茂和烯烃聚合催化剂
JP3986441B2 (ja) モノハライドまたはジハライドメタロセン化合物の製造方法
CN1278265A (zh) 制备富烯金属配合物的方法
CN1422287A (zh) 类似盐的化合物,其制备和其在制备聚烯烃催化剂体系中的用途
EP1102778B1 (en) Process for the preparation of titanium complexes
CN100349910C (zh) 用于制备金属茂的含有至少一个氟硅氧烷取代基的配体
CN1447816A (zh) 外消旋金属茂配合物的选择性制备方法
CN1217891C (zh) 亚甲基桥接双环戊二烯基化合物的制备方法
US20070043228A1 (en) Process for the production of halide metallocene compounds
CN1950384A (zh) 外消旋选择性制备柄型金属茂的方法
CN1960998A (zh) 柄型金属茂的内消旋选择性合成
JP2006503910A (ja) 部分的に水素化されたラセミ体のａｎｓａ−メタロセン錯体の製造方法
CN1860124A (zh) 金属茂化合物的异构化方法
CN1643002A (zh) 非金属茂、其制备方法和其在烯烃聚合中的应用
CN1345325A (zh) 制备钛络合物的方法
HK1033758A (en) Method for producing fulvene metal complexes
CN1346359A (zh) 携带二齿双阴离子配体的过渡金属烷基络合物的制备
CN1703418A (zh) 外消旋－二有机甲硅烷基双(2－甲基苯并[e]茚基)锆化合物的外消旋选择性合成

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20060301

Termination date: 20100222