CN1231487C - 金属茂和烯烃聚合催化剂 - Google Patents

金属茂和烯烃聚合催化剂 Download PDF

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Publication number
CN1231487C
CN1231487C CNB988031299A CN98803129A CN1231487C CN 1231487 C CN1231487 C CN 1231487C CN B988031299 A CNB988031299 A CN B988031299A CN 98803129 A CN98803129 A CN 98803129A CN 1231487 C CN1231487 C CN 1231487C
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dihydroindeno
methyl
indol
formula
group
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Expired - Fee Related
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Chinese (zh)
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CN1249756A (zh
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I·E·尼范特埃弗
V·V·巴格罗夫
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Spherilene SRL
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Spherilene SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/58—[b]- or [c]-condensed
    • C07D209/70—[b]- or [c]-condensed containing carbocyclic rings other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
CNB988031299A 1997-11-12 1998-11-04 金属茂和烯烃聚合催化剂 Expired - Fee Related CN1231487C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97119778 1997-11-12
EP97119778.5 1997-11-12

Publications (2)

Publication Number Publication Date
CN1249756A CN1249756A (zh) 2000-04-05
CN1231487C true CN1231487C (zh) 2005-12-14

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US (2) US6451724B1 (https=)
EP (1) EP0952978B1 (https=)
JP (1) JP4540755B2 (https=)
KR (1) KR100583931B1 (https=)
CN (1) CN1231487C (https=)
AR (1) AR016150A1 (https=)
AU (1) AU1870999A (https=)
BR (1) BR9807103A (https=)
CA (1) CA2277127A1 (https=)
DE (1) DE69810894T2 (https=)
ES (1) ES2190131T3 (https=)
HU (1) HUP0001331A2 (https=)
ID (1) ID22914A (https=)
IL (1) IL130713A0 (https=)
MY (1) MY132919A (https=)
NO (1) NO993398L (https=)
PL (1) PL334470A1 (https=)
TR (1) TR199901908T1 (https=)
WO (1) WO1999024446A1 (https=)
ZA (1) ZA9810179B (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107325034A (zh) * 2017-06-23 2017-11-07 浙江华海药业股份有限公司 一种制备罗匹尼罗二聚物的方法
CN105745301B (zh) * 2013-11-20 2020-04-21 东进世美肯株式会社 新型发光化合物以及包含其的有机发光元件

Families Citing this family (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU1870999A (en) * 1997-11-12 1999-05-31 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation
DE19903306A1 (de) * 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
BR0014616A (pt) 1999-09-22 2002-06-18 Basell Technology Co Bv Sistema catalìtico e processo para a polimerização de olefinas
US6232260B1 (en) 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
ES2239665T3 (es) * 2000-01-18 2005-10-01 Basell Polyolefine Gmbh Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos.
DE60103702T2 (de) 2000-02-24 2005-06-23 Basell Polyolefine Gmbh Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
JP2004516365A (ja) 2000-12-22 2004-06-03 バセル ポリオレフィン イタリア エス．ピー．エー． 多孔性ポリマーの製造方法およびそれから得られるポリマー
DE60135311D1 (de) 2000-12-22 2008-09-25 Basell Polyolefine Gmbh Katalysatorkomponente fur die polymerisation von olefinen
US6414162B1 (en) 2001-04-05 2002-07-02 Equistar Chemicals, Lp Bimetallic catalysts for olefin polymerization
US6579957B2 (en) 2001-04-11 2003-06-17 Equistar Chemicals, Lp Single-site catalysts based on anionic thiopyran dioxide ligands
JP2004530689A (ja) 2001-05-15 2004-10-07 バセル ポリオレフィン ジーエムビーエイチ シクロペンタジエン誘導体の合成
US6541583B2 (en) * 2001-05-17 2003-04-01 Equistar Chemicals, Lp Polypropylene preparation
US7417006B2 (en) 2001-05-21 2008-08-26 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
US6759361B2 (en) * 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
US6583242B2 (en) 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
US6440889B1 (en) * 2001-08-15 2002-08-27 Equistar Chemicals, Lp Amine elimination process for making single-site catalysts
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
ATE412016T1 (de) 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
US6908972B2 (en) 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
US6630547B1 (en) 2002-06-11 2003-10-07 Equistar Chemicals, Lp Use of silanes to control molecular weight in olefin polymerizations
AU2003242663A1 (en) * 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
RU2308470C2 (ru) * 2002-06-26 2007-10-20 Базелль Полиолефин Италия С.П.А. Ударопрочные полиолефиновые композиции
US6737487B2 (en) * 2002-07-30 2004-05-18 Equistar Chemicals, Lp Polyolefin block copolymers
AU2003248919A1 (en) 2002-08-02 2004-02-23 Equistar Chemicals, Lp Catalysts and process for making polyolefins
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US6841500B2 (en) * 2002-12-03 2005-01-11 Equistar Chemicals, Lp Bimetallic indenoindolyl catalysts
US6683150B1 (en) 2002-12-19 2004-01-27 Equistar Chemicals, Lp High molecular weight polypropylene process
US20040176241A1 (en) * 2003-03-04 2004-09-09 Sandor Nagy Benzoindenoindolyl metal catalysts for olefin polymerization
US6693155B1 (en) 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
EP1613668B1 (en) 2003-04-17 2012-08-08 Basell Poliolefine Italia S.r.l. Gas-phase olefin polymerization process
US6794468B1 (en) 2003-05-12 2004-09-21 Equistar Chemicals, Lp Olefin polymerization process
US6995216B2 (en) 2003-06-16 2006-02-07 Equistar Chemicals, Lp Process for manufacturing single-site polyolefins
US6998451B2 (en) * 2003-07-01 2006-02-14 Equistar Chemicals, Lp Olefin polymerization process
CN101163723B (zh) 2003-07-04 2010-12-22 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
US6933353B2 (en) * 2003-07-07 2005-08-23 Equistar Chemicals, Lp Olefin polymerization process
US6818713B1 (en) 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
US6939930B2 (en) * 2003-09-09 2005-09-06 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight
US6958377B2 (en) * 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
EP1735355B1 (en) 2004-03-12 2010-09-29 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
BRPI0508155A (pt) 2004-03-12 2007-08-07 Basell Polyolefine Gmbh sistema catalìtico para a polimerização de olefinas
EP1723184A1 (en) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
US6995220B2 (en) 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
DE102004027332A1 (de) 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
WO2006005648A1 (en) * 2004-07-13 2006-01-19 Basell Polyolefine Gmbh Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom
US6967231B1 (en) 2004-09-23 2005-11-22 Equistar Chemicals, Lp Olefin polymerization process
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
EP1814922A1 (en) * 2004-11-22 2007-08-08 Basell Polyolefine GmbH Propylene based terpolymers
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
US7230056B2 (en) * 2005-07-01 2007-06-12 Equistar Chemicals, Lp Catalyst preparation method
US7196147B2 (en) 2005-07-01 2007-03-27 Equistar Chemicals, Lp Olefin polymerization process with improved operability and polymer properties
US7538173B2 (en) * 2005-11-21 2009-05-26 Equistar Chemicals Lp Polyolefin compositions
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
US7423098B2 (en) * 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US7638584B2 (en) * 2006-06-20 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7638586B2 (en) 2006-09-26 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US8475898B2 (en) 2007-08-29 2013-07-02 Equistar Chemicals, Lp Polyolefin resin blends for crack-resistant pipe
US7666961B2 (en) * 2007-09-04 2010-02-23 Equistar Chemicals, Lp Olefin polymerization process
US7781549B2 (en) * 2007-09-04 2010-08-24 Equistar Chemicals, Lp Olefin polymerization process
US7655740B2 (en) * 2007-09-04 2010-02-02 Equistar Chemicals, Lp Olefin polymerization process
US7723451B2 (en) * 2007-09-04 2010-05-25 Equistar Chemicals, Lp Olefin polymerization process
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8084557B2 (en) 2007-12-18 2011-12-27 Basell Polyolefine Gmbh Gas-phase process for the polymerization of alpha-olefins
BRPI0908411B1 (pt) * 2008-02-29 2018-10-30 Basell Poliolefine Italia Srl composições de poliolefinas
US7776974B2 (en) * 2008-04-30 2010-08-17 Equistar Chemicals, Lp Olefin polymerization process
US7671151B2 (en) * 2008-05-21 2010-03-02 Equistar Chemicals, Lp Olefin polymerization process
US7816478B2 (en) * 2008-09-03 2010-10-19 Equistar Chemicals, Lp Polyethylene thick film and process for preparing polyethylene
US20100129924A1 (en) * 2008-11-21 2010-05-27 Sandor Nagy Quality assurance method for olefin polymerization catalysts
DE102010033548A1 (de) * 2010-08-05 2012-02-09 Merck Patent Gmbh Materialien für elektronische Vorrichtungen
KR101623485B1 (ko) 2013-08-01 2016-05-23 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
KR101644113B1 (ko) * 2013-10-18 2016-07-29 주식회사 엘지화학 혼성 담지 메탈로센 촉매
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
KR101705340B1 (ko) * 2014-06-03 2017-02-09 주식회사 엘지화학 폴리올레핀의 제조 방법 및 이로부터 제조된 폴리올레핀
KR101703274B1 (ko) * 2014-08-12 2017-02-22 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
WO2016024818A1 (ko) * 2014-08-12 2016-02-18 주식회사 엘지화학 메탈로센 화합물， 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
KR101784463B1 (ko) 2014-10-06 2017-10-11 주식회사 엘지화학 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법
RU2640045C1 (ru) 2014-10-13 2017-12-26 ЭлДжи КЕМ, ЛТД. Сополимер этилен/1-гексен или этилен/1-бутен, обладающий отличными технологическими свойствами и сопротивлением разрастанию трещин под действием факторов окружающей среды
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
JP6511061B2 (ja) 2015-01-28 2019-05-08 エルジー・ケム・リミテッド メタロセン化合物、これを含む触媒組成物およびこれを用いるオレフィン系重合体の製造方法
EP3138847B1 (en) 2015-01-28 2020-01-15 LG Chem, Ltd. Metallocene compound, catalyst composition containing same, and method for preparing polyolefin using same
CN105985383B (zh) * 2015-02-06 2019-09-03 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
WO2016124157A1 (zh) * 2015-02-06 2016-08-11 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
CN105985368B (zh) * 2015-02-06 2020-03-10 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
CN107636029B (zh) 2015-04-20 2020-05-22 埃克森美孚化学专利公司 包含氟化载体的催化剂组合物及其使用方法
CN114685703A (zh) 2015-04-20 2022-07-01 埃克森美孚化学专利公司 包含氟化物化的载体的催化剂组合物及其使用方法
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
CN107922527A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
EP3344385A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS ON SOUND
US10059788B2 (en) 2016-04-29 2018-08-28 Exxonmobil Chemical Patents Inc. Organoaluminum activators on clays
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
KR102072697B1 (ko) 2016-12-09 2020-02-03 주식회사 엘지화학 가공성 및 기계적 물성이 우수한 에틸렌/1-헥센 공중합체
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
WO2019203676A1 (en) * 2018-04-16 2019-10-24 Arlanxeo Netherlands B.V. Metal complex comprising amidine and indole fused cyclopentadienyl ligands
WO2022071744A1 (ko) * 2020-09-29 2022-04-07 주식회사 엘지화학 시공성 및 가공성이 우수한 에틸렌/1-헥센 공중합체
CN116425774A (zh) * 2021-12-30 2023-07-14 中国石油天然气股份有限公司 一种稀土金属配合物及其制备方法和应用
CN115400797B (zh) * 2022-08-19 2024-09-27 中国科学院山西煤炭化学研究所 含杂原子的茂金属催化剂体系及催化α-烯烃齐聚的方法
CN119431465B (zh) * 2023-08-01 2025-12-02 中国石油化工股份有限公司 茂金属化合物、催化剂组合物、烯烃聚合方法和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3714148A (en) * 1968-10-15 1973-01-30 Sumitomo Chemical Co Process for preparing dibenzazocine derivatives and salts thereof
DE3007725A1 (de) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
IT1256259B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
PL188107B1 (pl) 1996-11-15 2004-12-31 Montell Technology Company Bv Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
AU1870999A (en) * 1997-11-12 1999-05-31 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation
US6232260B1 (en) * 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105745301B (zh) * 2013-11-20 2020-04-21 东进世美肯株式会社 新型发光化合物以及包含其的有机发光元件
CN107325034A (zh) * 2017-06-23 2017-11-07 浙江华海药业股份有限公司 一种制备罗匹尼罗二聚物的方法

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