CN1229318C - 实现多相催化反应,尤其加氢甲酰化反应的方法 - Google Patents
实现多相催化反应,尤其加氢甲酰化反应的方法 Download PDFInfo
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- CN1229318C CN1229318C CNB001087991A CN00108799A CN1229318C CN 1229318 C CN1229318 C CN 1229318C CN B001087991 A CNB001087991 A CN B001087991A CN 00108799 A CN00108799 A CN 00108799A CN 1229318 C CN1229318 C CN 1229318C
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Classifications
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- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
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- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 | 5 |
时空收率[t/(m3·h)] | 0.98 | 1.39 | 1.23 | 1.00 | 0.71 |
B值 | 13.16 | 13.34 | 13.16 | 13.16 | 8.06 |
起始原料 | |||||
CO | 22.79 | 16.99 | 28.24 | 23.92 | 12.73 |
H2 | 21.28 | 15.87 | 26.38 | 22.87 | 11.89 |
N2 | 0.12 | 0.09 | 0.15 | 0.10 | 0.07 |
丙烯 | 51.49 | 35.57 | 31.13 | 36.01 | 33.45 |
丙烷 | 0.17 | 0.12 | 0.10 | 0.11 | 0.11 |
产物 | |||||
CO | 2.15 | 2.09 | 2.08 | 0.66 | 2.11 |
H2 | 0.89 | 0.93 | 0.98 | 0.37 | 0.97 |
丙烯 | 3.35 | 6.73 | 3.04 | 3.45 | 4.00 |
异丁醛 | 0.24 | 0.51 | 0.53 | 0.39 | 0.20 |
正丁醛 | 5.46 | 11.03 | 9.82 | 6.19 | 4.66 |
异丁醇 | <0.01 | <0.01 | <0.01 | <0.01 | <0.01 |
正丁醇 | 0.07 | 0.07 | 0.07 | 0.06 | 0.07 |
2-乙基己醛 | 0.09 | 0.03 | 0.08 | <0.01 | 0.02 |
2-乙基己烯醛 | 0.26 | 0.19 | 0.18 | <0.01 | 0.09 |
尾气 | |||||
CO | 9.50 | 3.06 | 13.23 | 13.72 | 6.81 |
H2 | 8.45 | 1.46 | 9.97 | 10.82 | 3.59 |
N2 | 0.29 | 0.10 | 0.09 | 0.10 | 0.16 |
丙烯 | 37.37 | 13.56 | 17.72 | 19.47 | 36.93 |
丙烷 | 0.17 | 0.10 | 0.17 | 0.10 | 0.09 |
异丁醛 | 0.24 | 0.16 | 0.15 | 0.18 | 0.14 |
正丁醛 | 4.59 | 3.13 | 2.72 | 2.62 | 2.56 |
实施例 | 6 | 7 |
时空收率[t/(m3·h)] | 1.06 | 1.04 |
B值 | 12.12 | 12.12 |
丙烯转化率 | 93.70% | 92.33% |
合成气转化率 | 92.09% | 90.27% |
进料起始原料 | ||
CO | 10.41 | 10.23 |
H2 | 9.56 | 9.63 |
N2 | 0.07 | 0.07 |
丙烯 | 12.42 | 12.43 |
丙烷 | 0.07 | 0.07 |
产物 | ||
CO | 1.27 | 1.65 |
H2 | 0.24 | 0.39 |
丙烯 | 0.58 | 0.73 |
异丁醛 | 0.86 | 0.77 |
正丁醛 | 8.04 | 8.24 |
异丁醇 | <0.001 | <0.001 |
正丁醇 | 0.13 | 0.11 |
2-乙基己醛 | 0.15 | 0.12 |
2-乙基己烯醛 | 0.29 | 0.18 |
尾气 | ||
CO | 0.18 | 0.09 |
H2 | 0.09 | 0.05 |
N2 | 0.01 | 0.01 |
丙烯 | 0.10 | 0.09 |
丙烷 | 0.003 | 0.002 |
通过次数 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
总转化率% | 19.1 | 36.9 | 49.8 | 59.8 | 68.5 | 76.5 | 82.9 | 86.8 |
高沸物 | 0 | 0.37 | 0.28 | 2.1 | 2.65 | 4.29 | 4.59 | 4.62 |
总选择性% | 85.1 | 89.1 | 91.7 | 92.1 | 92.4 | 92.8 | 93.1 | 92.9 |
总时空收率[t/(m3·h)] | 0.748 | 0.743 | 0.689 | 0.619 | 0.568 | 0.521 | 0.486 | 0.444 |
B值 | 14.26 | 14.26 | 14.26 | 14.26 | 14.26 | 14.26 | 14.26 | 14.26 |
实施例 | 0 |
时空收率[t/(m3·h)] | 0.05 |
B值 | 13.96 |
起始原料 | |
CO | 11.38 |
H2 | 10.52 |
N2 | 0.05 |
1-癸烯 | 7.12 |
产物 | |
1-癸烯 | 6.67 |
十一醛 | 0.34 |
2-甲基癸醛 | 0.11 |
尾气 | |
CO | 10.36 |
H2 | 9.89 |
N2 | 0.05 |
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19925384.6 | 1999-06-02 | ||
DE19925384A DE19925384A1 (de) | 1999-06-02 | 1999-06-02 | Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Hydroformylierungen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1276364A CN1276364A (zh) | 2000-12-13 |
CN1229318C true CN1229318C (zh) | 2005-11-30 |
Family
ID=7910094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB001087991A Expired - Fee Related CN1229318C (zh) | 1999-06-02 | 2000-06-01 | 实现多相催化反应,尤其加氢甲酰化反应的方法 |
Country Status (20)
Country | Link |
---|---|
US (1) | US6492564B1 (zh) |
EP (1) | EP1057524B1 (zh) |
JP (1) | JP2001026566A (zh) |
KR (1) | KR100648847B1 (zh) |
CN (1) | CN1229318C (zh) |
AR (1) | AR024268A1 (zh) |
AT (1) | ATE387954T1 (zh) |
BR (1) | BR0002178B1 (zh) |
CA (1) | CA2310516C (zh) |
DE (2) | DE19925384A1 (zh) |
ES (1) | ES2301458T3 (zh) |
ID (1) | ID26185A (zh) |
MX (1) | MXPA00001215A (zh) |
MY (1) | MY125133A (zh) |
PL (1) | PL199506B1 (zh) |
RO (1) | RO121180B1 (zh) |
RU (1) | RU2266894C2 (zh) |
SG (1) | SG86401A1 (zh) |
TW (1) | TW537930B (zh) |
ZA (1) | ZA200002740B (zh) |
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- 1999-06-02 DE DE19925384A patent/DE19925384A1/de not_active Withdrawn
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- 2000-02-03 MX MXPA00001215A patent/MXPA00001215A/es active IP Right Grant
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- 2000-06-01 KR KR1020000029965A patent/KR100648847B1/ko not_active IP Right Cessation
- 2000-06-01 CN CNB001087991A patent/CN1229318C/zh not_active Expired - Fee Related
- 2000-06-02 ID IDP20000468D patent/ID26185A/id unknown
- 2000-06-02 US US09/585,425 patent/US6492564B1/en not_active Expired - Lifetime
- 2000-06-02 AR ARP000102744A patent/AR024268A1/es not_active Application Discontinuation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11412083B2 (en) | 2016-03-14 | 2022-08-09 | Robert Bosch Gmbh | Portable keypanel for intercom system |
Also Published As
Publication number | Publication date |
---|---|
US6492564B1 (en) | 2002-12-10 |
ZA200002740B (en) | 2000-12-11 |
DE50015005D1 (de) | 2008-04-17 |
AR024268A1 (es) | 2002-09-25 |
TW537930B (en) | 2003-06-21 |
MXPA00001215A (es) | 2002-04-24 |
RO121180B1 (ro) | 2007-01-30 |
ES2301458T3 (es) | 2008-07-01 |
CN1276364A (zh) | 2000-12-13 |
RU2266894C2 (ru) | 2005-12-27 |
BR0002178A (pt) | 2001-01-02 |
KR20010049467A (ko) | 2001-06-15 |
SG86401A1 (en) | 2002-02-19 |
PL340362A1 (en) | 2000-12-04 |
ID26185A (id) | 2000-12-07 |
EP1057524A2 (de) | 2000-12-06 |
ATE387954T1 (de) | 2008-03-15 |
EP1057524B1 (de) | 2008-03-05 |
MY125133A (en) | 2006-07-31 |
BR0002178B1 (pt) | 2010-10-19 |
CA2310516C (en) | 2010-02-09 |
JP2001026566A (ja) | 2001-01-30 |
EP1057524A3 (de) | 2002-04-17 |
CA2310516A1 (en) | 2000-12-02 |
KR100648847B1 (ko) | 2006-11-24 |
PL199506B1 (pl) | 2008-09-30 |
DE19925384A1 (de) | 2000-12-07 |
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