CN1181074C - 制备三亚乙基二胺(teda)的方法 - Google Patents
制备三亚乙基二胺(teda)的方法 Download PDFInfo
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- CN1181074C CN1181074C CNB011456795A CN01145679A CN1181074C CN 1181074 C CN1181074 C CN 1181074C CN B011456795 A CNB011456795 A CN B011456795A CN 01145679 A CN01145679 A CN 01145679A CN 1181074 C CN1181074 C CN 1181074C
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- teda
- metal
- eda
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- 150000005309 metal halides Chemical class 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- PNPIRSNMYIHTPS-UHFFFAOYSA-N nitroso nitrate Chemical compound [O-][N+](=O)ON=O PNPIRSNMYIHTPS-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000004880 oxines Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/08—Bridged systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10061863.4 | 2000-12-12 | ||
| DE10061863A DE10061863A1 (de) | 2000-12-12 | 2000-12-12 | Verfahren zur Herstellung von Triethylendiamin (TEDA) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1362411A CN1362411A (zh) | 2002-08-07 |
| CN1181074C true CN1181074C (zh) | 2004-12-22 |
Family
ID=7666827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011456795A Expired - Fee Related CN1181074C (zh) | 2000-12-12 | 2001-12-12 | 制备三亚乙基二胺(teda)的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6562971B2 (enExample) |
| EP (3) | EP1215211B1 (enExample) |
| JP (3) | JP4319798B2 (enExample) |
| KR (1) | KR20020046226A (enExample) |
| CN (1) | CN1181074C (enExample) |
| AT (2) | ATE304544T1 (enExample) |
| DE (3) | DE10061863A1 (enExample) |
| ES (3) | ES2544744T3 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US6660731B2 (en) * | 2000-09-15 | 2003-12-09 | Vertex Pharmaceuticals Incorporated | Pyrazole compounds useful as protein kinase inhibitors |
| CA2422367C (en) | 2000-09-15 | 2010-05-18 | Vertex Pharmaceuticals Incorporated | Pyrazole compounds useful as protein kinase inhibitors |
| US7473691B2 (en) * | 2000-09-15 | 2009-01-06 | Vertex Pharmaceuticals Incorporated | Pyrazole compounds useful as protein kinase inhibitors |
| EP1345926B1 (en) * | 2000-12-21 | 2006-05-17 | Vertex Pharmaceuticals Incorporated | Pyrazole compounds useful as protein kinase inhibitors |
| MXPA04007697A (es) * | 2002-02-06 | 2004-11-10 | Vertex Pharma | Compuestos de heteroarilo utiles como inhibidores de gsk-3. |
| ATE468336T1 (de) * | 2002-03-15 | 2010-06-15 | Vertex Pharma | Azolylaminoazine als proteinkinasehemmer |
| MY141867A (en) * | 2002-06-20 | 2010-07-16 | Vertex Pharma | Substituted pyrimidines useful as protein kinase inhibitors |
| CN1319968C (zh) | 2002-08-02 | 2007-06-06 | 沃泰克斯药物股份有限公司 | 用作gsk－3的抑制剂的吡唑组合物 |
| WO2004072029A2 (en) * | 2003-02-06 | 2004-08-26 | Vertex Pharmaceuticals Incorporated | Pyrazolopyridazines useful as inhibitors of protein kinases |
| DE10326137A1 (de) * | 2003-06-06 | 2004-12-23 | Basf Ag | Verfahren zur Erhöhung der Schneidhärte eines Formkörpers enthaltend ein kristallines Alumosilikat und Verwendung dieser Formkörper mit erhöhter Schneidhärte in chemischen Syntheseverfahren, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) durch Umsetzung von Ethylendiamin (EDA) und/oder Piperazin (PIP) |
| DE10356184A1 (de) * | 2003-12-02 | 2005-07-07 | Basf Ag | Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung |
| WO2005056547A2 (en) * | 2003-12-04 | 2005-06-23 | Vertex Pharmaceuticals Incorporated | Quinoxalines useful as inhibitors of protein kinases |
| DE102004024274A1 (de) * | 2004-05-15 | 2005-12-01 | Basf Ag | Verfahren zur Herstellung einer Lösung von reinem Triethylendiamin (TEDA) |
| DE102004029544A1 (de) * | 2004-06-18 | 2006-01-05 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) |
| JP2009504771A (ja) * | 2005-08-18 | 2009-02-05 | バーテックス ファーマシューティカルズ インコーポレイテッド | ピラジンキナーゼ阻害剤 |
| SG166827A1 (en) * | 2005-11-03 | 2010-12-29 | Vertex Pharma | Aminopyrimidines useful as kinase inhibitors |
| CA2668429A1 (en) * | 2006-11-02 | 2008-05-15 | Vertex Pharmaceuticals Incorporated | Aminopyridines and aminopyrimidines useful as inhibitors of protein kinases |
| ES2347721T3 (es) * | 2006-12-19 | 2010-11-03 | Vertex Pharmaceuticals, Inc. | Aminopirimidinas utiles como inhibidores de proteina quinasas. |
| ES2374335T3 (es) * | 2007-03-09 | 2012-02-15 | Vertex Pharmaceuticals Incorporated | Aminopirimidinas útiles como inhibidores de proteína quinasas. |
| WO2008112642A1 (en) * | 2007-03-09 | 2008-09-18 | Vertex Pharmaceuticals Incorporated | Aminopyrimidines useful as inhibitors of protein kinases |
| MX2009009592A (es) * | 2007-03-09 | 2009-11-10 | Vertex Pharma | Aminopiridinas utiles como inhibidores de proteinas cinasas. |
| NZ580343A (en) | 2007-04-13 | 2012-03-30 | Vertex Pharma | Aminopyrimidines useful as kinase inhibitors |
| JP5572087B2 (ja) * | 2007-05-02 | 2014-08-13 | バーテックス ファーマシューティカルズ インコーポレイテッド | キナーゼ阻害として有用なアミノピリミジン |
| WO2008137619A2 (en) * | 2007-05-02 | 2008-11-13 | Vertex Pharmaceuticals Incorporated | Thiazoles and pyrazoles useful as kinase inhibitors |
| EP2152696B1 (en) * | 2007-05-02 | 2014-09-24 | Vertex Pharmaceuticals Incorporated | Aminopyrimidines useful as kinase inhibitors |
| JP2010528021A (ja) * | 2007-05-24 | 2010-08-19 | バーテックス ファーマシューティカルズ インコーポレイテッド | キナーゼのインヒビターとして有用なチアゾールおよびピラゾール |
| WO2009018415A1 (en) * | 2007-07-31 | 2009-02-05 | Vertex Pharmaceuticals Incorporated | Process for preparing 5-fluoro-1h-pyrazolo [3, 4-b] pyridin-3-amine and derivatives thereof |
| KR20110050549A (ko) * | 2008-09-03 | 2011-05-13 | 버텍스 파마슈티칼스 인코포레이티드 | 공-결정 및 이를 포함하는 제약 제제 |
| CN102171178B (zh) | 2008-10-06 | 2015-07-29 | 联合碳化化学品及塑料技术公司 | 乙二胺和其它乙撑胺的连续氨基转移 |
| DE102009027791B4 (de) | 2009-07-17 | 2013-02-21 | Basf Se | Zusammensetzung enthaltend Triethylendiamin, Monethylenglykol und Borhydrid |
| WO2013176803A1 (en) * | 2012-05-24 | 2013-11-28 | Archer Daniels Midland Company | Regeneration of catalyst for hydrogenation of sugars |
| WO2015150489A1 (de) * | 2014-04-03 | 2015-10-08 | Basf Se | Herstellung von teda durch umsetzung von einem amingemisch an einem zeolithkatalysator |
| CN104628675B (zh) * | 2015-02-03 | 2016-09-14 | 西安近代化学研究所 | 一种合成哌嗪和三乙烯二胺的方法 |
| CN104841479B (zh) * | 2015-04-15 | 2017-09-08 | 西安近代化学研究所 | 一种复合固体酸胺化催化剂及其制备方法 |
| CN106831794B (zh) * | 2017-01-20 | 2019-03-05 | 万华化学集团股份有限公司 | 一种制备哌嗪和三乙烯二胺的方法 |
| CN110639605B (zh) * | 2018-06-27 | 2021-10-01 | 中国石油化工股份有限公司 | 用于增产一乙醇胺和二乙醇胺的催化剂 |
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| US2937176A (en) | 1956-12-17 | 1960-05-17 | Houdry Process Corp | Preparation of diazabicyclo-octane |
| US3285920A (en) | 1964-01-16 | 1966-11-15 | Jefferson Chem Co Inc | Combination process for producing piperazine and triethylenediamine |
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| JPS4948609A (enExample) * | 1972-09-13 | 1974-05-11 | ||
| JPS5337876B2 (enExample) | 1973-07-19 | 1978-10-12 | ||
| DE2846813A1 (de) | 1978-10-27 | 1980-05-08 | Bayer Ag | Verfahren zur herstellung von 1,4-diazabicyclo-(2,2,2)-octan |
| JPS60260574A (ja) | 1984-04-10 | 1985-12-23 | ユニオン・カ−バイド・コ−ポレ−シヨン | １−アザビシクロ〔２．２．２〕オクタン又は１，４−ジアザビシクロ〔２．２．２〕オクタンの合成 |
| US5041548A (en) * | 1985-12-05 | 1991-08-20 | Idemitsu Kosan Company Limited | Method for the preparation of triethylene diamines |
| EP0263463B1 (de) * | 1986-10-08 | 1992-03-25 | BASF Aktiengesellschaft | Verfahren zur Herstellung von 1,4-Diazabicyclo(2,2,2)-octanen |
| US4804758A (en) | 1986-10-08 | 1989-02-14 | Basf Aktiengesellschaft | Preparation of 1,4-diazabicyclo[2.2.2]octanes |
| JPH0633266B2 (ja) | 1986-11-10 | 1994-05-02 | 出光興産株式会社 | トリエチレンジアミン類の製造方法 |
| US5053374A (en) | 1987-05-01 | 1991-10-01 | Mobil Oil Corporation | Method for preparing a zeolite catalyst bound with a refractory oxide of low acidity |
| DE3735212A1 (de) | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von gemischen aus 1,4-diazabicyclo(2.2.2)-octan und piperazin |
| DE3735214A1 (de) | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von 1,4-diazabicyclo(2.2.2)-octan aus piperazin |
| EP0345330A1 (en) | 1987-12-18 | 1989-12-13 | Union Carbide Corporation | Processes for the production of amines |
| DE3823160A1 (de) | 1988-07-08 | 1990-01-11 | Basf Ag | Verfahren zur herstellung von 1,4-diazabicyclo-2,2,2-octanen |
| DE3903622A1 (de) | 1989-02-08 | 1990-08-09 | Basf Ag | Verfahren zur herstellung von 1,4-diazabicyclo-2,2,2-octan |
| DE3934459A1 (de) * | 1989-10-14 | 1991-04-18 | Bayer Ag | Verfahren zur herstellung von triethylendiamin und piperazin |
| US5194613A (en) * | 1990-09-20 | 1993-03-16 | Union Carbide Chemicals & Plastics Technology Corporation | Catalytic processes for the preparation of bridged nitrogen-containing compounds |
| US5754741A (en) * | 1992-08-10 | 1998-05-19 | Computer Motion, Inc. | Automated endoscope for optimal positioning |
| RU2071475C1 (ru) | 1993-08-31 | 1997-01-10 | Институт катализа им.Г.К.Борескова СО РАН | Способ получения триэтилендиамина |
| RU2114849C1 (ru) | 1996-04-09 | 1998-07-10 | Конструкторско-технологический институт каталитических и адсорбционных процессов на цеолитах "Цеосит" СО РАН | Способ получения триэтилендиамина |
| US5731449A (en) | 1996-09-23 | 1998-03-24 | Air Products And Chemicals, Inc. | Triethylendiamine synthesis with base-treated zeolites as catalysts |
| US5756741A (en) | 1996-11-15 | 1998-05-26 | Air Products And Chemicals, Inc. | Process for the production of triethylenediamine |
| US5741906A (en) | 1996-11-15 | 1998-04-21 | Air Products And Chemicals, Inc. | Production of triethylenediamine using surface acidity deactivated zeolite catalysts |
| DE19723949A1 (de) | 1997-06-06 | 1998-12-10 | Basf Ag | Verfahren zur Regenerierung eines Zeolith-Katalysators |
| US6084096A (en) * | 1998-04-09 | 2000-07-04 | Air Products And Chemicals, Inc. | Triethylenediamine and piperazine synthesis using zeolite catalysts modified with a silicon-containing compound |
| US6350874B1 (en) | 1999-04-01 | 2002-02-26 | Tosoh Corporation | Method for producing triethylenediamines and piperazines |
| DE19930736C2 (de) | 1999-07-05 | 2001-07-05 | Performance Chemicals Handels | Verfahren zur Herstellung von Triethylendiamin unter Einsatz von Ethylendiamin |
-
2000
- 2000-12-12 DE DE10061863A patent/DE10061863A1/de not_active Withdrawn
-
2001
- 2001-06-26 US US09/765,625 patent/US6562971B2/en not_active Expired - Lifetime
- 2001-11-30 DE DE50107448T patent/DE50107448D1/de not_active Expired - Lifetime
- 2001-11-30 EP EP01128600A patent/EP1215211B1/de not_active Expired - Lifetime
- 2001-11-30 AT AT03009383T patent/ATE304544T1/de not_active IP Right Cessation
- 2001-11-30 EP EP03009385.0A patent/EP1359151B1/de not_active Expired - Lifetime
- 2001-11-30 AT AT01128600T patent/ATE297930T1/de not_active IP Right Cessation
- 2001-11-30 EP EP03009383A patent/EP1338598B1/de not_active Expired - Lifetime
- 2001-11-30 DE DE50106512T patent/DE50106512D1/de not_active Expired - Lifetime
- 2001-11-30 ES ES03009385.0T patent/ES2544744T3/es not_active Expired - Lifetime
- 2001-11-30 ES ES01128600T patent/ES2243380T3/es not_active Expired - Lifetime
- 2001-11-30 ES ES03009383T patent/ES2249652T3/es not_active Expired - Lifetime
- 2001-12-12 CN CNB011456795A patent/CN1181074C/zh not_active Expired - Fee Related
- 2001-12-12 KR KR1020010078510A patent/KR20020046226A/ko not_active Withdrawn
- 2001-12-12 JP JP2001378736A patent/JP4319798B2/ja not_active Expired - Fee Related
-
2003
- 2003-02-06 US US10/359,244 patent/US7115742B2/en not_active Expired - Lifetime
-
2008
- 2008-12-10 JP JP2008314160A patent/JP5086230B2/ja not_active Expired - Fee Related
- 2008-12-10 JP JP2008314159A patent/JP2009102347A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP1338598A1 (de) | 2003-08-27 |
| JP5086230B2 (ja) | 2012-11-28 |
| US6562971B2 (en) | 2003-05-13 |
| CN1362411A (zh) | 2002-08-07 |
| JP4319798B2 (ja) | 2009-08-26 |
| JP2009102347A (ja) | 2009-05-14 |
| DE50107448D1 (de) | 2005-10-20 |
| EP1359151A1 (de) | 2003-11-05 |
| JP2002284784A (ja) | 2002-10-03 |
| US20030139598A1 (en) | 2003-07-24 |
| ATE304544T1 (de) | 2005-09-15 |
| DE50106512D1 (de) | 2005-07-21 |
| DE10061863A1 (de) | 2002-06-13 |
| ES2243380T3 (es) | 2005-12-01 |
| EP1338598B1 (de) | 2005-09-14 |
| US20020107394A1 (en) | 2002-08-08 |
| EP1359151B1 (de) | 2015-06-03 |
| ES2544744T3 (es) | 2015-09-03 |
| KR20020046226A (ko) | 2002-06-20 |
| ES2249652T3 (es) | 2006-04-01 |
| US7115742B2 (en) | 2006-10-03 |
| EP1215211A1 (de) | 2002-06-19 |
| EP1215211B1 (de) | 2005-06-15 |
| JP2009102348A (ja) | 2009-05-14 |
| ATE297930T1 (de) | 2005-07-15 |
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