CN1178964C - 活性、非均相的二齿或三齿配体/过渡金属催化剂 - Google Patents

活性、非均相的二齿或三齿配体/过渡金属催化剂 Download PDF

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Publication number
CN1178964C
CN1178964C CNB008180296A CN00818029A CN1178964C CN 1178964 C CN1178964 C CN 1178964C CN B008180296 A CNB008180296 A CN B008180296A CN 00818029 A CN00818029 A CN 00818029A CN 1178964 C CN1178964 C CN 1178964C
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China
Prior art keywords
catalyst composition
transition metal
components
inorganic oxide
mmol
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB008180296A
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English (en)
Chinese (zh)
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CN1414982A (zh
Inventor
施耕宇
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WR Grace and Co Conn
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WR Grace and Co Conn
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Publication of CN1414982A publication Critical patent/CN1414982A/zh
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Publication of CN1178964C publication Critical patent/CN1178964C/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
CNB008180296A 1999-11-01 2000-10-19 活性、非均相的二齿或三齿配体/过渡金属催化剂 Expired - Fee Related CN1178964C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43180399A 1999-11-01 1999-11-01
US09/431,803 1999-11-01

Publications (2)

Publication Number Publication Date
CN1414982A CN1414982A (zh) 2003-04-30
CN1178964C true CN1178964C (zh) 2004-12-08

Family

ID=23713487

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008180296A Expired - Fee Related CN1178964C (zh) 1999-11-01 2000-10-19 活性、非均相的二齿或三齿配体/过渡金属催化剂

Country Status (13)

Country Link
US (1) US7291575B2 (https=)
EP (1) EP1237954B1 (https=)
JP (2) JP5258077B2 (https=)
KR (1) KR100710963B1 (https=)
CN (1) CN1178964C (https=)
AT (1) ATE315053T1 (https=)
AU (1) AU1096001A (https=)
BR (1) BR0015192B1 (https=)
CA (1) CA2389587C (https=)
DE (1) DE60025386T2 (https=)
MX (1) MXPA02004322A (https=)
SG (1) SG97961A1 (https=)
WO (1) WO2001032723A1 (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1426385B1 (en) 2001-07-23 2012-08-22 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyst for polymerization or copolymerization of olefins, preparation and use of the same
CN101687776B (zh) * 2007-07-04 2015-07-01 三井化学株式会社 过渡金属配位化合物、含有该化合物的烯烃聚合用催化剂以及在该催化剂存在下进行的烯烃聚合物的制造方法
EP2489431B1 (en) 2011-02-16 2013-05-01 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
KR102578006B1 (ko) 2015-05-11 2023-09-12 더블유.알. 그레이스 앤드 캄파니-콘. 개질된 점토, 지지된 메탈로센 중합 촉매의 제조 방법, 제조된 촉매, 및 이의 용도
US10940460B2 (en) 2015-05-11 2021-03-09 W. R. Grace & Co.-Conn. Process to produce modified clay, modified clay produced and use thereof
KR102472153B1 (ko) * 2016-12-30 2022-11-28 사빅 글로벌 테크놀러지스 비.브이. 선택적인 1-헥센 제조용 균질 촉매의 제조 방법
US11285469B2 (en) 2016-12-30 2022-03-29 Sabic Global Technologies B.V. Method for preparation of a catalyst solution for selective 1-hexene production
WO2020128668A1 (en) * 2018-12-17 2020-06-25 King Abdullah University Of Science And Technology Heterogenized ru amine or imine catalysts for hydrogen generation from formic acid

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4234453A (en) * 1976-09-20 1980-11-18 National Petro Chemicals Corporation Olefin polymerization catalyst
US4367992A (en) * 1980-08-07 1983-01-11 Westinghouse Electric Corp. Broaching machine
US4375406A (en) * 1981-01-21 1983-03-01 Chevron Research Company Fibrous clay compositions containing precalcined oxides
US4629712A (en) * 1984-08-17 1986-12-16 Michigan State University Delaminated clay materials
US4637992A (en) 1984-12-17 1987-01-20 Shell Oil Company Intercalated clay compositions
US4716205A (en) * 1985-10-15 1987-12-29 E. I. Du Pont De Nemours And Company Nickel-catalyzed polymerization of ethylene
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4761391A (en) * 1986-06-30 1988-08-02 Union Oil Company Of California Delaminated clays and their use in hydrocarbon conversion processes
US4995964A (en) * 1987-03-05 1991-02-26 Uop Midbarrel hydrocracking process employing rare earth pillared clays
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4904631A (en) * 1988-11-08 1990-02-27 Exxon Chemical Patents, Inc. Supported vanadium catalyst for polymerization of olefins and a process of preparing and using the same
US4981825A (en) * 1989-09-12 1991-01-01 Board Of Trustees Operating Michigan State University Dried metal oxide and clay particle compositions and method for the preparation thereof
US5824297A (en) 1990-06-25 1998-10-20 Oncogene Science, Inc. Tissue-derived tumor growth inhibitors, methods of preparation and uses thereof
US5038811A (en) * 1990-11-26 1991-08-13 Yvonne Johnson Self-opening cuff for crutch
TW218884B (https=) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5399636A (en) * 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5852148A (en) * 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US5438027A (en) * 1991-12-13 1995-08-01 Phillips Petroleum Company Chromium compounds and uses thereof
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5238892A (en) * 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
NL9201482A (nl) * 1992-08-20 1994-03-16 Dsm Nv Epoxidatie Katalysator.
JP3289058B2 (ja) * 1992-09-11 2002-06-04 工業技術院長 酵素を用いたエステル製造方法
US5403799A (en) * 1992-12-21 1995-04-04 W. R. Grace & Co.-Conn. Process upset-resistant inorganic supports for bioremediation
US5395808A (en) 1992-12-21 1995-03-07 W. R. Grace & Co.-Conn. Inorganic supports for bioremediation
US5403809A (en) * 1992-12-21 1995-04-04 W. R. Grace & Co.-Conn. Composite inorganic supports containing carbon for bioremediation
DE69410668D1 (de) * 1993-03-23 1998-07-09 Asahi Chemical Ind Olefinpolymerisationkatalysator mit mehrzähnigem Ligand
US5395805A (en) * 1993-03-25 1995-03-07 Regents Of The University Of California Method for making monolithic metal oxide aerogels
EP0658576B1 (en) * 1993-12-17 1998-07-29 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process
US5629253A (en) * 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US5707913A (en) * 1994-06-15 1998-01-13 Basf Aktiengesellschaft Amidinato catalyst systems for the polymerization of olefins
US5661097A (en) * 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
DE69611554T2 (de) * 1995-02-20 2001-07-05 Tosoh Corp., Shinnanyo Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
DE69701909T2 (de) * 1996-02-23 2000-08-17 Tosoh Corp., Shinnanyo Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator
US5852146A (en) 1996-06-27 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US5807800A (en) * 1997-02-11 1998-09-15 Fina Technology, Inc. Process for producing stereospecific polymers
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
AU8062898A (en) * 1997-06-09 1998-12-30 E.I. Du Pont De Nemours And Company Polymerization of olefins
DE19746280A1 (de) * 1997-10-20 1999-04-22 Basf Ag Verfahren zur Herstellung von geträgerten Übergangsmetallkatalysatoren
US6228792B1 (en) * 1998-02-27 2001-05-08 W. R. Grace & Co.-Conn. Donor-modified olefin polymerization catalysts
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
US6117959A (en) * 1998-09-02 2000-09-12 Eastman Chemical Company Polyolefin catalysts
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6559090B1 (en) * 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6710007B2 (en) * 2001-01-26 2004-03-23 E. I. Du Pont De Nemours And Company Polymerization of olefinic compounds
EP1399491B1 (en) * 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems

Also Published As

Publication number Publication date
KR20020091051A (ko) 2002-12-05
WO2001032723A1 (en) 2001-05-10
JP2011149025A (ja) 2011-08-04
JP5258077B2 (ja) 2013-08-07
BR0015192B1 (pt) 2010-11-03
US7291575B2 (en) 2007-11-06
MXPA02004322A (es) 2002-11-07
EP1237954B1 (en) 2006-01-04
CA2389587A1 (en) 2001-05-10
JP2003513165A (ja) 2003-04-08
DE60025386T2 (de) 2006-09-21
CA2389587C (en) 2010-05-25
KR100710963B1 (ko) 2007-04-24
EP1237954A1 (en) 2002-09-11
BR0015192A (pt) 2003-06-17
CN1414982A (zh) 2003-04-30
SG97961A1 (en) 2003-08-20
AU1096001A (en) 2001-05-14
US20040029719A1 (en) 2004-02-12
ATE315053T1 (de) 2006-02-15
DE60025386D1 (de) 2006-03-30

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Granted publication date: 20041208

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CF01 Termination of patent right due to non-payment of annual fee