CN116867762A - 环己烯酮化合物的制造方法 - Google Patents

环己烯酮化合物的制造方法 Download PDF

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Publication number
CN116867762A
CN116867762A CN202280014372.2A CN202280014372A CN116867762A CN 116867762 A CN116867762 A CN 116867762A CN 202280014372 A CN202280014372 A CN 202280014372A CN 116867762 A CN116867762 A CN 116867762A
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CN
China
Prior art keywords
compound
solvent
reaction
isomerization
producing
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Pending
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CN202280014372.2A
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English (en)
Chinese (zh)
Inventor
长滨正树
谷池裕次
井上淳
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API Corp
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API Corp
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Publication of CN116867762A publication Critical patent/CN116867762A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN202280014372.2A 2021-02-19 2022-02-15 环己烯酮化合物的制造方法 Pending CN116867762A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021025335 2021-02-19
JP2021-025335 2021-02-19
PCT/JP2022/005854 WO2022176837A1 (ja) 2021-02-19 2022-02-15 シクロヘキセノン化合物の製造方法

Publications (1)

Publication Number Publication Date
CN116867762A true CN116867762A (zh) 2023-10-10

Family

ID=82931767

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202280014372.2A Pending CN116867762A (zh) 2021-02-19 2022-02-15 环己烯酮化合物的制造方法

Country Status (5)

Country Link
US (1) US20240158328A1 (https=)
EP (1) EP4296254A4 (https=)
JP (1) JPWO2022176837A1 (https=)
CN (1) CN116867762A (https=)
WO (1) WO2022176837A1 (https=)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610121A (en) * 1979-07-05 1981-02-02 Yoshiro Kobayashi Preparation of organic fluorocompound
CN1890204A (zh) * 2003-12-16 2007-01-03 弗门尼舍有限公司 环己烯基烷基或烯基酮的异构化方法
US20180044279A1 (en) * 2015-03-09 2018-02-15 Mitsubishi Gas Chemical Company, Inc. Method for isomerizing bis(aminomethyl)cyclohexane
WO2020213731A1 (ja) * 2019-04-19 2020-10-22 株式会社エーピーアイ コーポレーション （１ｒ，３ｒ）－３－（トリフルオロメチル）シクロヘキサン－１－オール及びその中間体の製造法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5026918A (en) * 1990-04-27 1991-06-25 Petrolite Corporation Synthesis of 2,3,5-trisubstituted-2-cyclopentenones via base induced cyclization of alpha-chloro unsaturated ketones
DE102004035389A1 (de) * 2004-07-21 2006-03-16 Symrise Gmbh & Co. Kg Verbessertes Verfahren zur Herstellung von (E,Z)-7,8-Cyclohexadecen-1-on
JP5478097B2 (ja) * 2008-04-15 2014-04-23 花王株式会社 ２−アルキル−２−シクロアルケン−１−オンの製造方法
CN109937038A (zh) 2016-08-26 2019-06-25 田边三菱制药株式会社 双环式含氮杂环化合物
JP6670971B1 (ja) 2019-08-06 2020-03-25 シィスクエアド アソシエイツ インク 鋼製構造部材の接続金物及び接続構造

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610121A (en) * 1979-07-05 1981-02-02 Yoshiro Kobayashi Preparation of organic fluorocompound
CN1890204A (zh) * 2003-12-16 2007-01-03 弗门尼舍有限公司 环己烯基烷基或烯基酮的异构化方法
US20180044279A1 (en) * 2015-03-09 2018-02-15 Mitsubishi Gas Chemical Company, Inc. Method for isomerizing bis(aminomethyl)cyclohexane
WO2020213731A1 (ja) * 2019-04-19 2020-10-22 株式会社エーピーアイ コーポレーション （１ｒ，３ｒ）－３－（トリフルオロメチル）シクロヘキサン－１－オール及びその中間体の製造法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
G.K. SURYA PRAKASH等: "Preparation of 3-trifluoromethyl-2-cycloalkenones by the oxidative rearrangement of trifluoromethylated tertiary allylic alcohols with pyridinium chlorochromate", JOURNAL OF FLUORINE CHEMISTRY, vol. 101, no. 2, 31 December 2000 (2000-12-31), pages 199 - 202, XP004244518, DOI: 10.1016/S0022-1139(99)00159-1 *
RUICHAO SHEN等: "Studies of the Stereochemistry of [2+2]-Photocycloaddition Reactions of 2-Cyclohexenones with Olefins", ORGANIC LETTERS, vol. 9, no. 6, 10 February 2007 (2007-02-10), pages 1057 - 1059, XP055961024, DOI: 10.1021/ol063092r *

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US20240158328A1 (en) 2024-05-16
EP4296254A4 (en) 2025-03-12
JPWO2022176837A1 (https=) 2022-08-25
WO2022176837A1 (ja) 2022-08-25
EP4296254A1 (en) 2023-12-27

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Application publication date: 20231010