JPS5610121A - Preparation of organic fluorocompound - Google Patents
Preparation of organic fluorocompoundInfo
- Publication number
- JPS5610121A JPS5610121A JP8438279A JP8438279A JPS5610121A JP S5610121 A JPS5610121 A JP S5610121A JP 8438279 A JP8438279 A JP 8438279A JP 8438279 A JP8438279 A JP 8438279A JP S5610121 A JPS5610121 A JP S5610121A
- Authority
- JP
- Japan
- Prior art keywords
- halogen
- copper
- reacted
- linked
- nucleus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain in high yields the title compound having CF3 linked to C not forming an aromatic nucleus, by reacting a halogen-substituted derivative having an activated nucleus-unsubstituted halogen except F with a tetrahalogenomethane and Cu in the presence of a polar solvent.
CONSTITUTION: A halogen-substituted derivative (e.g., alkyl halide, acyl halide, etc. having an activated substituted halogen of Cl, Br, or I linked to C not forming an aromatic nucleus) having an activated nucleus-unsubstituted halogen except F is reacted with a tetrahalogenomethane shown by the formula CF3X(X is Br or I) and metal copper in the presence of a polar solvent (e.g., hexamethyl-phosphoramide, etc.) to give an organic fluorocompound having CF3 linked to C not forming an aromatic nucleus. In the process, preferably CF3 is reacted with copper to prepare a copper complex, unreacted copper is removed, and the complex is reacted with a halogen-substituted derivative at room temperatures to 150°C.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54084382A JPS5852966B2 (en) | 1979-07-05 | 1979-07-05 | Manufacturing method of organic fluorine compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54084382A JPS5852966B2 (en) | 1979-07-05 | 1979-07-05 | Manufacturing method of organic fluorine compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5610121A true JPS5610121A (en) | 1981-02-02 |
JPS5852966B2 JPS5852966B2 (en) | 1983-11-26 |
Family
ID=13828994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54084382A Expired JPS5852966B2 (en) | 1979-07-05 | 1979-07-05 | Manufacturing method of organic fluorine compounds |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5852966B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990009972A1 (en) * | 1989-02-27 | 1990-09-07 | Nippon Oil And Fats Co., Ltd. | Fluoroalkyl derivative and production thereof |
WO2022176837A1 (en) * | 2021-02-19 | 2022-08-25 | 株式会社エーピーアイ コーポレーション | Method for producing cyclohexenone compound |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5011891A (en) * | 1973-06-07 | 1975-02-06 |
-
1979
- 1979-07-05 JP JP54084382A patent/JPS5852966B2/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5011891A (en) * | 1973-06-07 | 1975-02-06 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990009972A1 (en) * | 1989-02-27 | 1990-09-07 | Nippon Oil And Fats Co., Ltd. | Fluoroalkyl derivative and production thereof |
WO2022176837A1 (en) * | 2021-02-19 | 2022-08-25 | 株式会社エーピーアイ コーポレーション | Method for producing cyclohexenone compound |
Also Published As
Publication number | Publication date |
---|---|
JPS5852966B2 (en) | 1983-11-26 |
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