JPS5610121A - Preparation of organic fluorocompound - Google Patents

Preparation of organic fluorocompound

Info

Publication number
JPS5610121A
JPS5610121A JP8438279A JP8438279A JPS5610121A JP S5610121 A JPS5610121 A JP S5610121A JP 8438279 A JP8438279 A JP 8438279A JP 8438279 A JP8438279 A JP 8438279A JP S5610121 A JPS5610121 A JP S5610121A
Authority
JP
Japan
Prior art keywords
halogen
copper
reacted
linked
nucleus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8438279A
Other languages
Japanese (ja)
Other versions
JPS5852966B2 (en
Inventor
Yoshiro Kobayashi
Takamaru Kumazuki
Kenjiro Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP54084382A priority Critical patent/JPS5852966B2/en
Publication of JPS5610121A publication Critical patent/JPS5610121A/en
Publication of JPS5852966B2 publication Critical patent/JPS5852966B2/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain in high yields the title compound having CF3 linked to C not forming an aromatic nucleus, by reacting a halogen-substituted derivative having an activated nucleus-unsubstituted halogen except F with a tetrahalogenomethane and Cu in the presence of a polar solvent.
CONSTITUTION: A halogen-substituted derivative (e.g., alkyl halide, acyl halide, etc. having an activated substituted halogen of Cl, Br, or I linked to C not forming an aromatic nucleus) having an activated nucleus-unsubstituted halogen except F is reacted with a tetrahalogenomethane shown by the formula CF3X(X is Br or I) and metal copper in the presence of a polar solvent (e.g., hexamethyl-phosphoramide, etc.) to give an organic fluorocompound having CF3 linked to C not forming an aromatic nucleus. In the process, preferably CF3 is reacted with copper to prepare a copper complex, unreacted copper is removed, and the complex is reacted with a halogen-substituted derivative at room temperatures to 150°C.
COPYRIGHT: (C)1981,JPO&Japio
JP54084382A 1979-07-05 1979-07-05 Manufacturing method of organic fluorine compounds Expired JPS5852966B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54084382A JPS5852966B2 (en) 1979-07-05 1979-07-05 Manufacturing method of organic fluorine compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54084382A JPS5852966B2 (en) 1979-07-05 1979-07-05 Manufacturing method of organic fluorine compounds

Publications (2)

Publication Number Publication Date
JPS5610121A true JPS5610121A (en) 1981-02-02
JPS5852966B2 JPS5852966B2 (en) 1983-11-26

Family

ID=13828994

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54084382A Expired JPS5852966B2 (en) 1979-07-05 1979-07-05 Manufacturing method of organic fluorine compounds

Country Status (1)

Country Link
JP (1) JPS5852966B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990009972A1 (en) * 1989-02-27 1990-09-07 Nippon Oil And Fats Co., Ltd. Fluoroalkyl derivative and production thereof
WO2022176837A1 (en) * 2021-02-19 2022-08-25 株式会社エーピーアイ コーポレーション Method for producing cyclohexenone compound

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5011891A (en) * 1973-06-07 1975-02-06

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5011891A (en) * 1973-06-07 1975-02-06

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990009972A1 (en) * 1989-02-27 1990-09-07 Nippon Oil And Fats Co., Ltd. Fluoroalkyl derivative and production thereof
WO2022176837A1 (en) * 2021-02-19 2022-08-25 株式会社エーピーアイ コーポレーション Method for producing cyclohexenone compound

Also Published As

Publication number Publication date
JPS5852966B2 (en) 1983-11-26

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