CN1164706C - 环氧酯乳液和以该乳液为基料的水性防锈底漆 - Google Patents
环氧酯乳液和以该乳液为基料的水性防锈底漆 Download PDFInfo
- Publication number
- CN1164706C CN1164706C CNB011078731A CN01107873A CN1164706C CN 1164706 C CN1164706 C CN 1164706C CN B011078731 A CNB011078731 A CN B011078731A CN 01107873 A CN01107873 A CN 01107873A CN 1164706 C CN1164706 C CN 1164706C
- Authority
- CN
- China
- Prior art keywords
- epoxy ester
- ester emulsion
- emulsion
- epoxy
- primer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
项目 | 实施例 | 对比例 | ||||||
1 | 2 | 3 | 4 | 5 | I | II | III | |
亚麻油 | 40 | 50 | 60 | 50 | 50 | 50 | 50 | 50 |
甘油 | 9 | 8 | 7 | 8 | 8 | 8 | 8 | 12 |
苯酐 | 20 | 15 | 10 | 15 | 15 | 15 | 15 | 23 |
环氧树脂 | 26 | 23 | 20 | 23 | 23 | 23 | 23 | 10 |
桐油酸 | 5 | 4 | 3 | 4 | 4 | 4 | 4 | 5 |
甲基丙烯酸 | 2 | 2 | 2 | 2 | 2 | 1 | 2 | 2 |
丙烯酸 | 1 | 1 | 1 | 1 | 1 | 1 | 2 | 1 |
甲基丙烯酸甲酯 | 11 | 11 | 11 | 9 | 13 | 11 | 11 | 11 |
丙烯酸丁酯 | 11 | 11 | 11 | 13 | 9 | 11 | 11 | 11 |
工业软水 | 140 | 150 | 130 | 160 | 170 | 180 | 190 | 200 |
2-氨基-1-丙醇 | 5.5 | 5 | 4 | 5 | 4.5 | 3 | 6 | 5 |
自乳化性 | 好 | 好 | 好 | 好 | 好 | 差 | 好 | 好 |
热稳定性 | 好 | 好 | 好 | 好 | 好 | 差 | 好 | 好 |
膜耐水性,h | 48 | 48 | 48 | 48 | 48 | 48 | 36 | 36 |
原料(克) | 实施例 | 对比例 | |||||||||
1# | 2# | 3# | 4# | 5# | 6# | 7# | 8# | 9# | a | b | |
软化水 | 95 | 60 | 50 | 95 | 70 | 50 | 70 | 60 | 55 | 110 | 50 |
SURFYNOL GA | 1.0 | 1.5 | 1.5 | 1.8 | 1.5 | 1.6 | 1.1 | 1.4 | 1.2 | 2.5 | 2.0 |
分散剂5040 | 1.5 | 1.6 | 1.4 | 1.7 | 1.0 | 1.6 | 0 | 0 | 0 | 2.5 | 2.5 |
分散剂5027 | 0 | 0 | 0 | 0 | 0 | 0 | 1.5 | 1.7 | 1.3 | 0 | 0 |
消泡剂NXZ | 0.1 | 0.2 | 0.3 | 0.3 | 0.2 | 0.2 | 0.1 | 0.2 | 0.1 | 0.2 | 0.3 |
KATHON LXE | 2.5 | 1.1 | 1.5 | 2.6 | 2.8 | 1.2 | 2.2 | 1.3 | 2.7 | 2.6 | 2.2 |
SKANE M-8 | 2.6 | 1.2 | 1.0 | 2.3 | 2.2 | 2.0 | 1.8 | 1.3 | 2.4 | 2.3 | 2.5 |
2-氨基-1-丙醇 | 6 | 4 | 3 | 2 | 2.5 | 3 | 4 | 6 | 5 | 3 | 3 |
氧化铁红 | 220 | 190 | 0 | 0 | 0 | 0 | 250 | 190 | 200 | 190 | 190 |
云母氧化铁 | 0 | 0 | 250 | 200 | 190 | 200 | 0 | 0 | 0 | 0 | 0 |
800目滑石粉 | 0 | 105 | 70 | 100 | 80 | 60 | 60 | 50 | 0 | 50 | 50 |
600目云母粉 | 80 | 0 | 0 | 0 | 60 | 65 | 0 | 100 | 80 | 50 | 70 |
沉淀硫酸钡 | 100 | 100 | 0 | 100 | 100 | 50 | 0 | 50 | 100 | 50 | 80 |
煅烧高岭土 | 0 | 0 | 80 | 0 | 0 | 0 | 120 | 50 | 0 | 0 | 0 |
磷酸锌 | 15 | 10 | 10 | 10 | 15 | 35 | 10 | 5 | 20 | 15 | 15 |
钼酸锌 | 5 | 5 | 10 | 10 | 5 | 10 | 5 | 5 | 5 | 10 | 10 |
树脂1 | 450 | 500 | 500 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
树脂2 | 0 | 0 | 0 | 450 | 450 | 500 | 0 | 0 | 0 | 0 | 0 |
树脂3 | 0 | 0 | 0 | 0 | 0 | 0 | 450 | 450 | 500 | 0 | 0 |
B-96乳液 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 500 | 0 |
AZ 476W乳液 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 500 |
VXW催干剂 | 15 | 16 | 17 | 17 | 18 | 19 | 18 | 19 | 20 | 0 | 20 |
TT935增稠剂 | 10 | 9 | 8 | 10 | 9 | 8 | 10 | 9 | 8 | 15 | 10 |
合计 | 1001.7 | 1005.6 | 1005.7 | 1003.7 | 1009.2 | 1008.6 | 1006.2 | 1001.9 | 1002.7 | 1003.1 | 1007.5 |
项目开罐状态 | 实施例 | 对比例 | ||||||||||
1# | 2# | 3# | 4# | 5# | 6# | 7# | 8# | 9# | a | b | ||
涂层外观 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | |
合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | 合格 | ||
细度,μm | 45 | 45 | 4 5 | 45 | 45 | 45 | 45 | 45 | 45 | 45 | 45 | |
粘度,s,> | 30 | 30 | 3 0 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | |
固体份,%,> | 50 | 50 | 5 0 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | |
干燥时间 | 表干,h | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
实干,h | 24 | 24 | 24 | 24 | 24 | 24 | 24 | 24 | 24 | 24 | 24 | |
附着力,级 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 2 | 1 | |
耐冲击,Kg.cm | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | |
柔韧性,mm | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | |
杯突,mm | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | |
耐盐雾,h | 500 | 500 | 500 | 500 | 500 | 500 | 500 | 500 | 500 | 72 | 168 | |
耐冻融,循环 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 0 | 5 |
Claims (9)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011078731A CN1164706C (zh) | 2001-03-10 | 2001-03-10 | 环氧酯乳液和以该乳液为基料的水性防锈底漆 |
DE10296465T DE10296465T5 (de) | 2001-03-10 | 2002-03-11 | Epoxypolyester, Emulsion, enthaltend einen solchen Polyester, Zubereitungen davon und eine wasserbasierte Farbe, enthaltend die Emulsion |
PCT/CN2002/000144 WO2002072658A1 (fr) | 2001-03-10 | 2002-03-11 | Polyester epoxy, son emulsion, sa preparation, et peintures aqueuses contenant ladite emulsion |
US10/471,312 US7005474B2 (en) | 2001-03-10 | 2002-03-11 | Epoxy polyester, its emulsion and its preparation as well as water-base coatings containing the emusion |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011078731A CN1164706C (zh) | 2001-03-10 | 2001-03-10 | 环氧酯乳液和以该乳液为基料的水性防锈底漆 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1374357A CN1374357A (zh) | 2002-10-16 |
CN1164706C true CN1164706C (zh) | 2004-09-01 |
Family
ID=4656776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011078731A Expired - Lifetime CN1164706C (zh) | 2001-03-10 | 2001-03-10 | 环氧酯乳液和以该乳液为基料的水性防锈底漆 |
Country Status (4)
Country | Link |
---|---|
US (1) | US7005474B2 (zh) |
CN (1) | CN1164706C (zh) |
DE (1) | DE10296465T5 (zh) |
WO (1) | WO2002072658A1 (zh) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20070093067A (ko) * | 2004-12-22 | 2007-09-17 | 임페리알 케미칼 인더스트리즈 피엘씨 | 수성 고분자 분산액 |
CN101177518B (zh) * | 2006-11-09 | 2012-07-11 | 上海涂料有限公司技术中心 | 环氧酯树脂水分散体和以它为基础的防锈底漆的制造方法 |
CN101659740B (zh) * | 2008-08-28 | 2012-05-30 | 上海涂料有限公司技术中心 | 自交联型磺酸盐基环氧酯水分散体及其防锈底漆 |
CN101747500B (zh) * | 2008-12-12 | 2012-02-22 | 上海涂料有限公司技术中心 | 磺酸盐基水可稀释性醇酸树脂及其氨基烘漆 |
CN101942077B (zh) * | 2009-07-07 | 2012-05-30 | 上海涂料有限公司技术中心 | 自干型含磺酸盐基的水可稀释性醇酸树脂 |
CN101787535B (zh) * | 2009-12-30 | 2011-07-20 | 吴昊 | 汽车油箱用水基防锈剂及其制备方法 |
CN101864044B (zh) * | 2010-07-02 | 2012-03-14 | 湖南湘江涂料集团有限公司 | 一种水性丙烯酸改性环氧酯树脂及其合成方法 |
CN101942063B (zh) * | 2010-08-17 | 2012-12-05 | 华南理工大学 | 一种水性环氧酯改性醇酸树脂乳液及其制备方法 |
CN102838914B (zh) * | 2012-09-10 | 2014-07-30 | 中昊北方涂料工业研究设计院有限公司 | 一种可以带锈涂装的水性铁锈转化底漆 |
CN103173096B (zh) * | 2013-03-11 | 2016-01-20 | 邓家润 | 一种盛装白酒用金属容器内壁涂料及其制备方法 |
CN103467748A (zh) * | 2013-08-13 | 2013-12-25 | 嘉兴市清河高力绝缘有限公司 | 水性丙烯酸改性环氧酯乳液及其氨基烤漆的制备方法 |
CN103483986B (zh) * | 2013-09-18 | 2016-01-13 | 中山蓝海洋水性涂料有限公司 | 一种环保型耐冲击水性丙烯酸氨基玻璃酒瓶烤漆及其制备方法和应用 |
CN103554434B (zh) * | 2013-10-21 | 2016-01-20 | 北京金汇利应用化工制品有限公司 | 一种水性环氧酯树脂的制备方法及其应用 |
CN103881574A (zh) * | 2013-11-08 | 2014-06-25 | 东南大学 | 一种防锈清漆 |
CN104371507B (zh) * | 2014-08-13 | 2016-09-07 | 山东奔腾漆业股份有限公司 | 一种高性能水性工业防腐涂料及制备方法 |
CN105001766A (zh) * | 2015-07-15 | 2015-10-28 | 湖州湖杰漆业有限公司 | 一种电梯快干漆 |
CN105017931A (zh) * | 2015-07-29 | 2015-11-04 | 广西梧州龙鱼漆业有限公司 | 水性环氧酯防锈底漆 |
CN105238232B (zh) * | 2015-11-12 | 2017-12-26 | 西北永新涂料有限公司 | 水性防锈漆及其制备方法 |
CN106752665A (zh) * | 2015-11-25 | 2017-05-31 | 湖南开磷雁峰塔涂料有限公司 | 一种环氧脂底漆及其制作方法 |
CN105885012B (zh) * | 2016-06-21 | 2018-07-20 | 山东天茂新材料科技股份有限公司 | 一种用于led封装的改性环氧树脂的制备方法 |
CN108570131B (zh) * | 2017-03-10 | 2021-07-16 | 北京金汇利应用化工制品有限公司 | 环氧酯树脂水分散体与丙烯酸树脂的杂化乳液的制备方法 |
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CN112794999B (zh) * | 2020-12-30 | 2022-08-16 | 长兴化学(天津)有限公司 | 一种环氧改性聚酯乳液及其制备方法和应用 |
CN113637146B (zh) * | 2021-07-30 | 2022-08-26 | 华南农业大学 | 桐油酸马来酸酐改性乙烯基酯树脂及其制备方法和应用 |
CN113637378B (zh) * | 2021-08-01 | 2022-06-28 | 广州励宝新材料科技有限公司 | 一种利用固化后聚脲废料再处理成水性砂纹漆的制备方法 |
CN115491104A (zh) * | 2022-09-30 | 2022-12-20 | 泉州市三星精细化工有限公司 | 一种船舶专用水性漆涂料及其制备方法 |
CN115505320A (zh) * | 2022-10-20 | 2022-12-23 | 吉力水性新材料科技(珠海)有限公司 | 一种水性转绣防锈乳液及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4414357A (en) * | 1979-11-27 | 1983-11-08 | Glasurit America, Inc. | Polyester or alkyd resin composition containing acrylic microgels |
AT377777B (de) | 1983-06-10 | 1985-04-25 | Vianova Kunstharz Ag | Verfahren zur herstellung von waessrigen alkydharzemulsionen fuer lufttrocknende lacke |
JPH07690B2 (ja) | 1989-07-07 | 1995-01-11 | 昭和高分子株式会社 | 不飽和ポリエステル樹脂の改質方法 |
JPH0791432B2 (ja) | 1989-12-22 | 1995-10-04 | 昭和高分子株式会社 | 防錆性水分散性樹脂組成物 |
JPH05271614A (ja) * | 1992-01-29 | 1993-10-19 | Kansai Paint Co Ltd | 水性着色塗料組成物及びそれを用いる塗装方法 |
JPH05306377A (ja) | 1992-04-30 | 1993-11-19 | Dainippon Ink & Chem Inc | 水性被覆用樹脂組成物 |
US6333378B1 (en) * | 1997-08-12 | 2001-12-25 | Eastman Chemical Company | Acrylic modified waterborne alkyd or uralkyd dispersions |
JPH11343456A (ja) | 1998-06-01 | 1999-12-14 | Kansai Paint Co Ltd | 水性塗料組成物 |
-
2001
- 2001-03-10 CN CNB011078731A patent/CN1164706C/zh not_active Expired - Lifetime
-
2002
- 2002-03-11 WO PCT/CN2002/000144 patent/WO2002072658A1/zh not_active Application Discontinuation
- 2002-03-11 DE DE10296465T patent/DE10296465T5/de not_active Withdrawn
- 2002-03-11 US US10/471,312 patent/US7005474B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1374357A (zh) | 2002-10-16 |
WO2002072658A1 (fr) | 2002-09-19 |
US20040116599A1 (en) | 2004-06-17 |
US7005474B2 (en) | 2006-02-28 |
DE10296465T5 (de) | 2004-04-15 |
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