CN115315455A - 使用过渡金属双(酚盐)催化剂络合物获得的乙烯-α-烯烃-二烯单体共聚物及生产该共聚物的均相方法 - Google Patents

使用过渡金属双(酚盐)催化剂络合物获得的乙烯-α-烯烃-二烯单体共聚物及生产该共聚物的均相方法 Download PDF

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CN115315455A
CN115315455A CN202080098845.2A CN202080098845A CN115315455A CN 115315455 A CN115315455 A CN 115315455A CN 202080098845 A CN202080098845 A CN 202080098845A CN 115315455 A CN115315455 A CN 115315455A
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tetrakis
borate
group
substituted
hydrocarbyl
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Chinese (zh)
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江培军
J·A·M·卡尼奇
J·R·哈格多恩
R·谢
石珺
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64158—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/19—Shear ratio or shear ratio index
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27—Amount of comonomer in wt% or mol%
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/39—Tensile storage modulus E'; Shear storage modulus G'; Tensile loss modulus E''; Shear loss modulus G''; Tensile complex modulus E*; Shear complex modulus G*

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202080098845.2A 2020-02-11 2020-08-11 使用过渡金属双(酚盐)催化剂络合物获得的乙烯-α-烯烃-二烯单体共聚物及生产该共聚物的均相方法 Pending CN115315455A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202062972943P 2020-02-11 2020-02-11
US62/972,943 2020-02-11
PCT/US2020/045822 WO2021162747A1 (en) 2020-02-11 2020-08-11 Ethylene-alpha-olefin-diene monomer copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

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Publication Number Publication Date
CN115315455A true CN115315455A (zh) 2022-11-08

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US (1) US20230348642A1 (https=)
EP (1) EP4103631A4 (https=)
JP (1) JP7757294B2 (https=)
KR (1) KR102898201B1 (https=)
CN (1) CN115315455A (https=)
WO (1) WO2021162747A1 (https=)

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법
WO2025117379A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Formation of branched polypropylenes using dianionic complexes having eight-membered chelate rings

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US20150329657A1 (en) * 2012-12-13 2015-11-19 Basell Poliolefine Italia S.R.L. Catalyst system for the preparation of polyolefins
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CN106103507A (zh) * 2014-03-21 2016-11-09 埃克森美孚化学专利公司 乙烯丙烯共聚物的制备方法
CN107428782A (zh) * 2015-03-24 2017-12-01 埃克森美孚化学专利公司 双酚盐过渡金属络合物及其制备和用途
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
CN107847920A (zh) * 2015-07-15 2018-03-27 埃克森美孚化学专利公司 包含‑Si‑Si‑桥基的取代的双茚基茂金属催化剂化合物
CN109641989A (zh) * 2016-07-13 2019-04-16 埃克森美孚化学专利公司 双金属茂催化剂共聚物组合物
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US20040005984A1 (en) * 2002-04-24 2004-01-08 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
CN103443137A (zh) * 2011-03-25 2013-12-11 埃克森美孚化学专利公司 支化的乙烯基封端的聚合物及其制造方法
CN103492397A (zh) * 2011-03-25 2014-01-01 埃克森美孚化学专利公司 吡啶基二氨基过渡金属络合物，其生产方法和用途
US20150329657A1 (en) * 2012-12-13 2015-11-19 Basell Poliolefine Italia S.R.L. Catalyst system for the preparation of polyolefins
CN105358588A (zh) * 2013-07-17 2016-02-24 埃克森美孚化学专利公司 使用取代茂金属催化剂的方法和由其得到的产品
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CN107428782A (zh) * 2015-03-24 2017-12-01 埃克森美孚化学专利公司 双酚盐过渡金属络合物及其制备和用途
CN107847920A (zh) * 2015-07-15 2018-03-27 埃克森美孚化学专利公司 包含‑Si‑Si‑桥基的取代的双茚基茂金属催化剂化合物
CN109641989A (zh) * 2016-07-13 2019-04-16 埃克森美孚化学专利公司 双金属茂催化剂共聚物组合物
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
CN110062777A (zh) * 2016-10-19 2019-07-26 埃克森美孚化学专利公司 混合催化剂体系及其使用方法

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KR20220152224A (ko) 2022-11-15
JP2023513582A (ja) 2023-03-31
WO2021162747A1 (en) 2021-08-19
EP4103631A1 (en) 2022-12-21
KR102898201B1 (ko) 2025-12-09
EP4103631A4 (en) 2024-06-05
JP7757294B2 (ja) 2025-10-21
US20230348642A1 (en) 2023-11-02

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