JP7757294B2 - 遷移金属ビス（フェノラート）触媒錯体を用いて得られるエチレン－アルファオレフィン－ジエンモノマーのコポリマー及びその生成のための均一プロセス - Google Patents

遷移金属ビス（フェノラート）触媒錯体を用いて得られるエチレン－アルファオレフィン－ジエンモノマーのコポリマー及びその生成のための均一プロセス

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JP7757294B2
JP7757294B2 JP2022548666A JP2022548666A JP7757294B2 JP 7757294 B2 JP7757294 B2 JP 7757294B2 JP 2022548666 A JP2022548666 A JP 2022548666A JP 2022548666 A JP2022548666 A JP 2022548666A JP 7757294 B2 JP7757294 B2 JP 7757294B2
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substituted
hydrocarbyl
borate
ethylene
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JP2023513582A (ja
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ペイジュン ジアン
ジョー アン エム カニッチ
ジョン アール ハガドーン
ル シエ
ジュン シ
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エクソンモービル ケミカル パテンツ インコーポレイテッド
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64158—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/19—Shear ratio or shear ratio index
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27—Amount of comonomer in wt% or mol%
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/39—Tensile storage modulus E'; Shear storage modulus G'; Tensile loss modulus E''; Shear loss modulus G''; Tensile complex modulus E*; Shear complex modulus G*

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2022548666A 2020-02-11 2020-08-11 遷移金属ビス（フェノラート）触媒錯体を用いて得られるエチレン－アルファオレフィン－ジエンモノマーのコポリマー及びその生成のための均一プロセス Active JP7757294B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202062972943P 2020-02-11 2020-02-11
US62/972,943 2020-02-11
PCT/US2020/045822 WO2021162747A1 (en) 2020-02-11 2020-08-11 Ethylene-alpha-olefin-diene monomer copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

Publications (3)

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JP2023513582A JP2023513582A (ja) 2023-03-31
JP2023513582A5 JP2023513582A5 (https=) 2023-08-17
JP7757294B2 true JP7757294B2 (ja) 2025-10-21

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US (1) US20230348642A1 (https=)
EP (1) EP4103631A4 (https=)
JP (1) JP7757294B2 (https=)
KR (1) KR102898201B1 (https=)
CN (1) CN115315455A (https=)
WO (1) WO2021162747A1 (https=)

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KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법
WO2025117379A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Formation of branched polypropylenes using dianionic complexes having eight-membered chelate rings

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003206310A (ja) 2001-02-21 2003-07-22 Mitsui Chemicals Inc オレフィン重合用触媒およびこの触媒を用いるオレフィン重合体の製造方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100844062B1 (ko) * 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US8674040B2 (en) * 2008-07-25 2014-03-18 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
EP2688895A4 (en) * 2011-03-25 2014-10-22 Exxonmobil Chem Patents Inc COMPLEXES OF PYRIDYLDIAMIDO AND TRANSITION METAL, PRODUCTION AND USE THEREOF
JP5793820B2 (ja) * 2011-03-25 2015-10-14 エクソンモービル ケミカル パテンツ インコーポレイテッド 分枝ビニル末端ポリマー及びその製造方法
EP2743000A1 (en) * 2012-12-13 2014-06-18 Basell Poliolefine Italia S.r.l. Catalyst system for the preparation of polyolefins
US9458260B2 (en) * 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9382361B2 (en) * 2014-03-21 2016-07-05 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
WO2016153682A1 (en) * 2015-03-24 2016-09-29 Exxonmobil Chemical Patents Inc. Bisphenolate transition metal complexes, production and use thereof
CN107847920A (zh) * 2015-07-15 2018-03-27 埃克森美孚化学专利公司 包含‑Si‑Si‑桥基的取代的双茚基茂金属催化剂化合物
CN107922527A (zh) * 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
US11352451B2 (en) * 2016-07-13 2022-06-07 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
KR102121437B1 (ko) * 2016-08-23 2020-06-10 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
EP3529287A1 (en) * 2016-10-19 2019-08-28 ExxonMobil Chemical Patents Inc. Mixed catalyst systems and methods of using the same
US11203654B2 (en) * 2019-02-12 2021-12-21 Exxonmobil Chemical Patents Inc. Bis(aryl phenolate) lewis base catalysts and methods thereof
US11214634B2 (en) * 2019-02-12 2022-01-04 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
WO2020167819A1 (en) * 2019-02-12 2020-08-20 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
US11248070B2 (en) * 2019-02-12 2022-02-15 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
WO2020167821A1 (en) * 2019-02-12 2020-08-20 Exxonmobil Chemical Patents Inc. Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
SG11202108010RA (en) * 2019-02-12 2021-08-30 Exxonmobil Chemical Patents Inc Lewis base catalysts and methods thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003206310A (ja) 2001-02-21 2003-07-22 Mitsui Chemicals Inc オレフィン重合用触媒およびこの触媒を用いるオレフィン重合体の製造方法

Also Published As

Publication number Publication date
KR20220152224A (ko) 2022-11-15
CN115315455A (zh) 2022-11-08
JP2023513582A (ja) 2023-03-31
WO2021162747A1 (en) 2021-08-19
EP4103631A1 (en) 2022-12-21
KR102898201B1 (ko) 2025-12-09
EP4103631A4 (en) 2024-06-05
US20230348642A1 (en) 2023-11-02

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